• Title/Summary/Keyword: NIR spectroscopy

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Growth and Properties of CrNx/TiNy/Al Based on N2 Gas Flow Rate for Solar Thermal Applications

  • Ju, Sang-Jun;Jang, Gun-Eik;Jang, Yeo-Won;Kim, Hyun-Hoo;Lee, Cheon
    • Transactions on Electrical and Electronic Materials
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    • v.17 no.3
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    • pp.146-149
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    • 2016
  • The CrN/TiN/Al thin films for solar selective absorber were prepared by dc reactive magnetron sputtering with multi targets. The binary nitride CrN layer deposited with change in N2 gas flow rates. The gas mixture of Ar and N2 was an important parameter during sputtering deposition because the metal volume fraction (MVF) was controlled by the N2 gas flow rate. In this study, the crystallinity and surface properties of the CrN/TiN/Al thin films were estimated by X-ray diffraction (XRD), atomic force microscopy (AFM) and field emission scanning electron microscopy (FESEM). The composition and depth profile of thin films were investigated using Auger electron spectroscopy (AES). The absorptance and reflectance with wavelength spectrum were recorded by UV-Vis-NIR spectrophotometry at a range of 300~1,100 nm.

DETECTION OF Hα EMISSION FROM z>3.5 GALAXIES WITH AKARI-FUHYU NIR SPECTROSCOPY

  • Sedgwick, Chris;Serjeant, Stephen;Pearson, Chris;Takagi, Toshinobu;Matsuhara, Hideo;Wada, Takehiko;Lee, Hyung Mok;Im, Myungshin;Jeong, Woong-Seob;Oyabu, Shinki;White, Glenn J.
    • Publications of The Korean Astronomical Society
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    • v.27 no.4
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    • pp.357-360
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    • 2012
  • This paper presents $H{\alpha}$ emission line detections for four galaxies at z > 3.5 made with AKARI as part of the FUHYU mission program. These are the highest-redshift $H{\alpha}$ detections to date in star-forming galaxies. AKARI's unique near-infrared spectroscopic capability has made these detections possible. For two of these galaxies, this represents the first evidence of their redshifts and confirms their physical association with a companion radio galaxy. The star formation rates (SFRs) estimated from the $H{\alpha}$ lines under-predict the SFRs estimated from their far-infrared luminosities by a factor of ~ 2 - 3. We have also detected broad $H{\alpha}$ components in the two radio galaxies which indicate the presence of quasars.

Influence of Carbon diffusion on the characterization of Si nanocrystals in SiC matrix (Carbon diffusion에 의한 SiC matrix 내의 실리콘 양자점 특성 분석)

  • Moon, Jihyun;Kim, Hyunjong;Cho, Jun Sik;Park, Sang Hyun;Yoon, Kyung Hoon;Song, Jinsoo;O, Byungsung;Lee, Jeong Chul
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.100.1-100.1
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    • 2010
  • 고효율 실리콘 양자점 태양전지를 제작하기 위해 Si과 C target을 co-sputtering 방식으로 제조한 SiC matrix를 열처리하여 박막 내에 Si nanocrystal들을 생성하였다. Si nanocrystal의 특성은 다양한 요인에 영향을 받는 데 barrier 물질인 SiC matrix가 가장 큰 영향을 준다. SiC는 900도 이상에서 열처리하는 동안 Si과 C과 SiC으로 재배열 혹은 재결합하는 데 이 때 가장 작은 carbon이 빠르게 diffusion하는 현상에 의해 Si nanocrystal의 성장과 특성에 영향을 주게 된다. 이 현상을 연구하기 위해 stoichiometric SiC/Si-rich SiC/stoichiometric SiC의 3층 구조로 시료를 제작하여 이를 SIMS의 depth profiling을 통하여 열처리 전보다 열처리 후에 Si-rich SiC layer내에 carbon이 약 2~3%정도 증가한 것으로 carbon이 diffusion된 것을 확인하였다. 이 시료를 UV-VIS-NIR spectroscopy, Raman, GIXRD 등의 다양한 측정을 통하여 carbon diffusion에 의한 Si nanocrystal의 특성변화를 연구하였다.

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Properties of the Green Gold Alloys with Indium Content

  • Song, Jeongho;Song, Ohsung
    • Korean Journal of Materials Research
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    • v.28 no.4
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    • pp.221-226
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    • 2018
  • The property changes of 18, 14, and 8K green gold alloys for jewelry are observed by adding 0.0, 3.0, and 5.0 wt% of indium (In), respectively. To check the composition of the alloys, an energy dispersive spectroscopy (EDS) analysis is conducted. Color and microstructure analysis is executed through bare-eye, macro camera, UV-VIS-NIR-colormeter, and optical microscope. The melting point, wetting angle, and hardness are measured using TGA-DTA, a wetting angle tester, and a Vickers hardness tester. The EDS analysis result demonstrates that each of the green gold alloys was manufactured with purposed contents. The color analysis result shows that the color of the alloys is similar to the color of the conventional 4 wt%-Cd 18K green gold, and the green color improves as the In content increases. The micro structure analysis result demonstrates that grain refinement improves as the amount of In increases. Enhancements in the melting point, wettability, and Vickers hardness changes appear as the In content increases and Au content decreases. The hardness is up to 260, which implies good durability. Therefore, the results suggest that the proposed 18, 14, and 8K In-added green gold alloys enhance the properties of jewelry products with regard to the green color, castability, and durability.

Development of Measuring Technique for Somatic Cell Count in Raw Milk by Spectroscopy (분광분석법을 이용한 우유의 체세포수 측정기술 개발)

  • Choi, C.H.;Kim, Y.J.;Kim, K.S.;Choi, T.H.
    • Journal of Biosystems Engineering
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    • v.33 no.3
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    • pp.210-215
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    • 2008
  • The objective of this study was to develop models to predict SCC (somatic cell count) in unhomogenized milk by visible and near-infrared (NIR) spectroscopic technique. Total of 100 milk samples were collected from dairy farms and preserved to minimize propagation of bacteria cells during transportation. Reductive reagents such as methyl red, methylene blue, bromcresol purple, phenol red and resazurin were added to milk samples, and then colors of milk were changed based on SCC of milk. For optimal reductive reagents, reaction time was controlled at 3 level of reaction time. A spectrophotometer was used to measure reflectance spectra from milk samples. The partial least square (PLS) models were developed to predict SCC of unhomogenized milk. The PLS results showed that milk samples with reductive reagents had a good correlation between predicted and measured SCC at 5 minutes of reaction time in the visible range. The PLS models with resazurin reagent had the best performance in $400{\sim}600\;nm$. The prediction results of milk samples with resazurin had 0.86 of correlation coefficient and 14,184 cell/mL of SEP.

Optical Properties of Multi-layer TiNO/AlCrNO/Al Cermet Films Using DC Magnetron Sputtering

  • Han, Sang-Uk;Park, Soo-Young;Kim, Hyun-Hoo;Jang, Gun-Eik;Lee, Yong-Jun
    • Transactions on Electrical and Electronic Materials
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    • v.16 no.5
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    • pp.280-284
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    • 2015
  • Among many the oxynitrides, TiNO and AlCrNO, have diverse applications in different technological fields. We prepared TiNO/AlCrNO/Al thin films on aluminum substrates using the method of dc reactive magnetron sputtering. The reactive gas flow, gas mixture, and target potential were applied as the sputtering conditions during the deposition in order to control the chemical composition. The multi-layer films have been prepared in an Ar and O2+N2 gas mixture rate. The surface properties were estimated by performing scanning electron microscopy (SEM). At a wavelength range of 0.3~2.5 μm, the exact composition and optical properties of thin films were measured by Auger electron spectroscopy (AES) and Ultraviolet-visible-near infrared (UV-Vis-NIR) spectrophotometry. The optimal absorptance of multi-layer films was exhibited above 95.5% in the visible region of the electromagnetic spectrum, and the reflectance was achieved below 1.89%.

Growth and Characteristics of Al2O3/AlCrNO/Al Solar Selective Absorbers with Gas Mixtures

  • Park, Soo-Young;Han, Sang-Uk;Kim, Hyun-Hoo;Jang, Gun-Eik;Lee, Yong-Jun
    • Transactions on Electrical and Electronic Materials
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    • v.16 no.5
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    • pp.264-267
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    • 2015
  • AlCrNO cermet films were prepared on aluminum substrates using a DC-reactive magnetron sputtering method and a water-cooled Al:Cr target. The Al2O3/AlCrNO (LMVF)/AlCrNO (MMVF)/AlCrNO (HMVF)/Al/substrate of the 5 multi-layers was prepared according to the Ar and (N2 + O2) gas-mixture rates. The Al2O3 of the top layer is the anti-reflection layer of triple AlCrNO (LMVF)/AlCrNO (MMVF)/AlCrNO (HMVF) layers, and an Al metal forms the infrared reflection layer. In this study, the crystallinity and surface properties of the AlCrNO thin films were estimated using X-ray diffraction (XRD) and field-emission scanning electron microscopy (FESEM), while the composition of the thin films was systematically investigated using Auger electron spectroscopy (AES). The optical properties of the wavelength spectrum were recorded using UH4150 spectrophotometry (UV-Vis-NIR) at a range of 0.3 μm to 2.5 μm.

Effect of the Calcination Temperature and Li(I) Doping on Ethanol Sensing Properties in p-Type CuO Thin Films

  • Choi, Yun-Hyuk
    • Korean Journal of Materials Research
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    • v.29 no.12
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    • pp.764-773
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    • 2019
  • The gas response characteristic toward C2H5OH has been demonstrated in terms of copper-vacancy concentration, hole density, and microstructural factors for undoped/Li(I)-doped CuO thin films prepared by sol-gel method. For the films, both concentrations of intrinsic copper vacancies and electronic holes decrease with increasing calcination temperature from 400 to 500 to 600 ℃. Li(I) doping into CuO leads to the reduction of copper-vacancy concentration and the enhancement of hole density. The increase of calcination temperature or Li(I) doping concentration in the film increases both optical band gap energy and Cu2p binding energy, which are characterized by UV-vis-NIR and X-ray photoelectron spectroscopy, respectively. The overall hole density of the film is determined by the offset effect of intrinsic and extrinsic hole densities, which depend on the calcination temperature and the Li(I) doping amount, respectively. The apparent resistance of the film is determined by the concentration of the structural defects such as copper vacancies, Li(I) dopants, and grain boundaries, as well as by the hole density. As a result, it is found that the gas response value of the film sensor is directly proportional to the apparent sensor resistance.

Near-infrared Spectroscopy of Iron Knots in Cassiopeia A Supernova Remnant

  • Lee, Yong-Hyun;Koo, Bon-Chul;Moon, Dae-Sik
    • The Bulletin of The Korean Astronomical Society
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    • v.35 no.2
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    • pp.68.1-68.1
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    • 2010
  • Cassiopeia A supernova remnant is a young (~330 yr) remnant of Type IIb SN explosion with a massive progenitor. It shows two distinct optical knots; fast moving ejecta knots (FMKs) and quasi stationary circumstellar knots (QSFs). These knots offer an unique opportunity to explore the details of the explosion and also the end state evolution of the Type IIb SN progenitor. We have obtained NIR long-slit (30") spectra of 7 positions around the bright rim of Cas A in [Fe II] 1.644 micron using Triplespec which is a cross-dispersed near-infrared spectrograph that provides continuous wavelength coverage from 0.95-2.46um at intermediate resolution of 2700. Most of the FMKs show strong sulfur, silicon, and iron forbidden lines but no hydrogen or helium lines. The QSFs, on the other hand, show a much richer spectrum with strong hydrogen, helium, and iron lines, but no sulfur and silicon lines. We measure their fluxes and radial velocities, and derive their physical parameters such as electron density and temperature. We also measure the proper motion of these knots from two [Fe II] 1.644 micron images obtained at 3-year interval. We analyze the physical properties of these knots and discuss the evolution and explosion of the progenitor of Cas A.

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유·무기 하이브리드 태양전지에 적용된 나노와이어 형상 조절 및 특성분석

  • Kim, Min-Su;Kim, Jun-Hui;Lee, Hae-Seok;Kim, Dong-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.487.1-487.1
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    • 2014
  • 현재 전 세계 태양광 시장의 주류를 이루는 단결정 실리콘 태양전지의 효율적 한계를 뛰어넘기 위하여 여러 가지 기술적 구조적 시도들이 이루어지고 있다. 그 중 기존의 피라미드 형태의 텍스쳐링 표면 대신 나노와이어 형상을 가지는 태양전지 개발이 주목을 받고 있다. 실리콘 웨이퍼 표면에 나노와이어가 수직 배열되어 있거나 텍스쳐링 표면에 나노와이어 형상이 있을 경우 SiNx가 증착된 피라미드 텍스쳐링 표면보다 반사도가 월등히 낮아져 light trapping을 기대할 수 있어 태양전지 개발에 응용하기 위한 나노와이어 형상 최적화에 본 연구의 목적이 있다. 실리콘 나노와이어 합성법에는 여러가지 방법들이 있으나 본 연구에서는 비교적 짧은 시간과 상온에서 공정이 이루어지는 무전해 식각법을 이용하여 실리콘 나노와이어를 합성하였다. 무전해 식각법은 은 이온과 실리콘 사이에서 일어나는 산화-환원 반응이 나노와이어 합성의 주요 기전이기 때문에 균일한 나노와이어를 형성하기 위하여 균일한 은 박막 형성과 적절한 반응시간이 요구된다. 본 연구에서는 반응시간을 조절하여 나노와이어의 길이 변화와 반사도의 변화를 FE-SEM과 UV-Vis-NIR spectroscopy를 통하여 관찰하였고 그 결과 나노와이어가 실리콘 웨이퍼 표면에 수직 배열되어 있는 형태와 텍스쳐링 표면에 나노와이어 형상이 있는 경우 SiNx가 증착된 피라미드 텍스쳐링 표면에 비해 월등히 향상된 반사율을 얻을 수 있었다.

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