• 제목/요약/키워드: NIOSH Method #0500

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우리나라에서 사용하는 광물유의 유해특성과 관리대책에 관한 연구 - 공기중 MWF 미스트의 측정방법과 관리대책 - (Control and Investigation for Hazardous Characteristics of Metal Working Fluids Used in Korea - A Study on the Control and Sampling Method for Airborne MWF mist -)

  • 백남원;박동욱;윤충식;조숙자;김신범;임호섭
    • 한국산업보건학회지
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    • 제7권2호
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    • pp.171-180
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    • 1997
  • The objectives of this study were both 10 discuss the sampling method for airborne metalworking fluids(MWF)' mist and 10 suggest measures to minimize worker's exposure to carcinogen contained in metalworking fluids. In order to measure airborne MWF mist, it seems to be appropriate to use NIOSH Method #0500(filler weight) rather than NIOSH Method # 5026(analysis by FTIR). Because MWF mist on PVC filter evaporated and migrated during sampling, worker's exposure to MWF could be underestimated. So, when evaluating worker's exposure to MWF mist, other environmental conditions also must be considered. Enclosure and local exhaust ventilation system seems to he the most effective measure and must be constructed with process facility. In order to control worker exposure to carcinogens contained in MWF, distillation type and condition for crude oil, PAH concentration in MWF, and viscosity index of MWF must legally be described.

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작업환경 중 MWF 미스트와 증기에 대한 측정방법의 개발 - PVC 필터에 채취된 비수용성 MWF손실에 대한 보정 - (The Recommendation of Sampling Method for Airborne MWF in Workplace - Correction for MWF Lost on PVC Filter -)

  • 박동욱;김신범;신철임
    • 한국산업보건학회지
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    • 제8권2호
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    • pp.186-195
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    • 1998
  • The objective of this study was to determine if MWF(metalworking fluids) mass sampled on PVC filter lose during flowing airstream and desiccating and to present direction to correct the underestimated MWF mass. Flowing airstream caused MWF sampled on PVC filter to be breakthrough and lost. Loss of MWF on PVC filter increased in proportion to time of flowing airstream. Meanwhile, loss of MWF was observed during desiccating without flowing airstream. Vapor pressure of MWF is so low that it would not normally be thought to evaporate. However, MWF mist sampled on PVC filter has so great a surface area that loss by flowing airstream and evaporation can be appreciable. Loss between fresh and used MWF was also different. Those study results mean that NIOSH method(#0500 method) to take airborne MWF mist with PVC filter is not valid. Media to sample airborne MWF accurately still have not been introduced. It seems to be needed to estimate how much MWF on PVC filter may be lost during sampling. Regression model between sampling time including 1 day desiccating and total loss of MWF was "Total loss(%)=18.4%+0.06 sampling time(p=0.000, r2=49.6%)". This model help correct MWF lost when one measures airborne MWF using NIOSH # 0500 method.

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대체용매를 이용한 금속가공유 측정방법 타당성 평가 (Validation of an Extraction Method for the Determination of Airborne MWFs using Alternative Solvents)

  • 정지연;백남원
    • 한국산업보건학회지
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    • 제16권2호
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    • pp.91-100
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    • 2006
  • The purpose of this study was to validate alternative method by using non-carcinogenic, and less toxic solvents than NIOSH analytical method 5524 for measuring the airborne MWFs in workplaces. In laboratory tests, the ETM solvents(mixture of same volume for ethyl ether, toluene, and ethanol) were selected. The alternative method of analyzing MWFs, referred to as the ETM solvent extraction method, showed 0.04 mg/sample as LOD, and 0.15 mg/sample as LOQ. The analytical precision (pooled CV, coefficient of variation) of the ETM solvent extraction method for analyzing the straight, soluble, semisynthetic, and synthetic metalworking fluid was 1.5%, 2.0%, 2.6%, 1.6%, respectively, which was similar to the precision (2.6%) of NIOSH analytical method (NIOSH 0500) for total dust. The analytical accuracy by recovery test, spiked mass calculated as extractable mass, was almost 100%. As the result of storage stability test, metalworking fluid samples should be stored in refrigerated condition, and be analyzed in two weeks after sampling. The 95% confidence limit of the estimated total standard error for the ETM solvent extraction method for analyzing the straight, soluble, semisynthetic, and synthetic metalworking fluid was ${\pm}12.6%$, ${\pm}12.5%$, ${\pm}14.0%$, and ${\pm}13.6%$, respectively, which satisfied the OSHA sampling and analytical criteria.

국내 일부 채석장 작업자들의 분진 및 결정형 유리규산 노출평가 사례 (Assessing Dust and Crystalline Silica Exposures among Workers in Some Quarries in Korea)

  • 차원석;김은영;최성원;김미연
    • 한국산업보건학회지
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    • 제33권3호
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    • pp.284-290
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    • 2023
  • Objectives: Work environment assessments were conducted to investigate epidemiologically several cases of lung cancer and COPD (chronic obstructive pulmonary disease) among workers in domestic quarries. Methods: We visited three quarries in South Korea where an epidemiological investigation was requested and measured total dust, respirable dust, and crystalline silica on rock drilling workers (4 people) and rock chipping workers (13 people). Measurement and analysis were conducted according to NIOSH (National Institute for Occupational Safety & Health) method 0500, NIOSH method 0600 for respirable dust, and NIOSH method 7500 for crystalline silica. Results: Among rock drilling workers the AMs (arithmetic mean) of total dust concentrations, respirable dust concentrations, and crystalline silica concentrations were 3.462 mg/m3 (range: 0.764~6.085 mg/m3), 0.613 mg/m3 (range: 0.153~1.251 mg/m3), and 0.105 mg/m3 (range: 0.012~0.228 mg/m3), respectively. Among rock chipping workers, the AMs of total dust concentrations, respirable dust concentrations, and crystalline silica concentrations were 2.446 mg/m3 (range: 0.156~8.494 mg/m3), 0.488 mg/m3 (range: 0.028~1.536 mg/m3), and 0.099 mg/m3 (range: 0.004~0.274 mg/m3), respectively. Conclusions: Although it cannot be said that the dust concentrations were high for both rock drilling workers and rock chipping workers, the concentrations of crystalline silica were found to be high. If such work is performed for a long period of time, diseases such as lung cancer and COPD may occur, so the work environment needs to be improved.

연구실 환경에서의 질량농도 측정을 통한 Aluminium oxide의 거동 평가 (Behavior Evaluation of Aluminium oxide through Measurement of Mass Concentration under Laboratory Environment)

  • 박정화;김동현;김종규;김형식;김정훈
    • 디지털융복합연구
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    • 제14권3호
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    • pp.279-285
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    • 2016
  • 나노기술이 발전함에 따라 나노물질의 사용량이 증가하고, 그에 따른 환경 및 인체 유해성 문제가 사회적 이슈로 대두되고 있으나 나노물질에 대한 규제나 법규는 아직 제정되어 있지 않다. 이에 본 연구에서는 WPMN에서 지정한 제조나노물질 13종 중 국내에서 가장 많이 사용되고 있는 물질인 aluminium oxide의 거동평가를 실시하여 연구활동종사자들을 위한 안전지침의 기초 자료로 활용하고자 하였다. 실험은 실제 연구실을 1/6의 크기로 축소하여 제작한 chamber에서 진행되며, NIOSH method 0500에 준하여 질량농도를 측정하였다. 연구 결과 질량 농도는 물질의 입자 크기에 반비례하는 것으로 나타났으며, 환기 설비의 작동만으로 질량농도가 약 1/8배까지 감소하는 것을 확인 할 수 있었다. 본 연구를 향후 나노물질 관련 연구활동종사자를 위한 안전지침의 기초자료로 활용할 수 있을 것으로 보이나, 연구의 신뢰도를 높이기 위해 입경에 따른 질량농도, 수농도 측정등의 실험이 필요할 것으로 사료된다.

조선소 용접작업자들의 총용접흄과 호흡성분진농도 비교연구 (A Comparison Study on the Concentration of Total Welding Fume and Respirable Particulate Mass for Welding Workers of a Shipbuilding)

  • 강용선;심상효;이송권;빈성오;최은석
    • 한국환경보건학회지
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    • 제33권4호
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    • pp.276-282
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    • 2007
  • The purpose of this study is to assess the accurate state of the following: total welding fumes versus welding fumes in the air, respirable particulate mass, and exposure of dockyard welders to heavy metals. In addition, this study provides basic data for proposing improvements to create efficient and appropriate welding environments and to prevent occupational diseases. The subjects of this study were 94 laborers who worked at the block construction sites of large-scale dockyards located in Gyeongnam Province from March 2005 to June 2005. In order to collect samples on total welding fumes in the air and respirable particulate mass from the welders, Methods 0500 and 0600, established by the National Institute for Occupational Safety and Health (NIOSH), were used. The metals within the welding fumes were also analyzed using Inductively Coupled Plasma (ICP) under Method 7300 from NIOSH. The results of this research are summarized below. The geometric mean concentration of total welding fumes and that of respirable particulate mass were $4.11\;mg/m^3\;and\;3.53\;mg/m^3$, respectively. As a result of comparing the two measurement methods, there were significant differences (p<0.05) between the two groups for Ca, Cu, Cr, and Ni; however, there were no differences in Fe, Mg, Zn, Mg, Pb, and Cd. As a result of the analysis, the correlation between Mn and the concentration of heavy metals in the total welding fumes and respirable particulate mass was found to be -0.29, a significant negative correlation. The correlation between other heavy metals, however, was low. Finally, in the same total welding fumes, the correlation of Fe and Mg was high.

양계장에서 입식 및 출하작업시 분진과 가스상 물질의 노출 측정 조사 (Exposure to Dust and Organic Gas during Chicken Entrance and Shipment Tasks in Poultry Farms)

  • 김경란;김효철;이경숙;채혜선
    • 한국산업보건학회지
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    • 제24권4호
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    • pp.471-477
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    • 2014
  • Objectives: This study was conducted to evaluate area exposure of airborne dust and organic gas during entrance and shipment of chicken in poultry farms Methods: Total dust was measured with NIOSH method 0500. The volume of distributed dust and organic gas(Ammonia, TVOC, Hydrogen Sulfide) were measured using direct reading instrument. Results: The range of concentrations of total dust in area sample was $0.07{\sim}4.91mg/m^3$ during the entrance of chicks and $4.37{\sim}9.4mg/m^3$ during shipment respectively. Concentration of ammonia reached approximately 9 ppm during shipment. There was a difference of concentration of total dust in the area sample between shipment and entrance tasks. Conclusions: It was found that the development of a special intervention program by type of task should be considered for reducing respiratory health effects among poultry farmers.

용접흄 충 금속함량 변화에 관한 연구 (A Study on the Content Variation of Metals in Welding Fumes)

  • 윤충식;박동욱;박두용
    • 한국환경보건학회지
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    • 제28권2호
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    • pp.117-129
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    • 2002
  • Concentration of welding fumes and their components is known to be hazardous to welder and adjacent worker. To determine the generation rates of metals in fumes, $CO_2$ flux cored arc welding on stainless steel was performed in well designed fume collection chamber. Variables were different products of flux cored wire(2 domestic products and 4 foreign products) and input energy(low-, optimal- , high input energy). Mass of welding fumes was determined by gravimetric method(NIOSH 0500 method), and 17 metals were analysed by inductively coupled plasm-atomic emission spectroscopy(NIOSH 7300 method). Flux cored wire tube and flux were analysed by scanning electron microscopy to determine their metal composition. 17 metals were classified by their generation rates. Generation rates of iron, manganese, potassium and sodium were all above 50mg/min at optimal input energy level. Generation rates of chromium and amorphous silica were 25~50mg/min. At 1~25mg/min level, nickel, titanium, molybdenum, and aluminum were included. Copper, zinc, calcium, lead, magnesium, lithium, and cobalt were generated below 1 mg/min. Generation rates of metal components in fumes were influenced by input energy, types of flux cored wire. Flux cored wire was consisted of outer shell tube and inner flux. Iron, chromium, and nickel were the major components of outer tube. Flux contained iron, chromium, nickel, potassium, sodium, silica, and manganese. The use of flux cored wire can increase the hazards by increasing the amounts of fumes formed relative to that of solid wire. The reason might be the direct transfer of elements from the flux, since the flux is fine power. Ratio of metals to the fume of flux cored wire was lower than that of solid wire because non-metal components of flux were transferred. Total metal content of fumes in flux cored arc welding was 47.4(24.3~57.2) percent that is much lower than that of solid wire, 75.9 percent. We found that generation rates of iron, manganese, chromium and nickel, all well known to cause work related disease to welder, increased more rapidly with increasing input energy than those of fumes. To reduce worker exposure to fumes and hazardous component at source, further research is needed to develop new welding filler materials that decrease both the amount of fumes and hazardous components.

오이, 참외, 감자 작목에서의 정식, 수확작업시 총분진과 엔도톡신 노출 특성에 관한 연구 (Research on Exposure to Total Dust and Endotoxin during Planting and Harvest Tasks at Cucumber, Yellow Melon and Potato Farms)

  • 김효철;이경숙;채혜선;민경두;김경란;박윤석
    • 한국산업보건학회지
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    • 제23권4호
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    • pp.412-420
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    • 2013
  • Objectives: This study was conducted in order to evaluate personal and area exposure to airborne total dust and endotoxin during harvest and planting tasks at cucumber, yellow melon and potato farms Materials and Methods: Total dust was measured with NIOSH method 0500. Endotoxin were measured using a 37 mm glass fiber filter which was connected to an air pump calibrated to 2 LPM, and then analyzed with a Turbidmetric kinetic method. Results: The average(arithmetic mean) concentrations of total dust in the personal samples were $0.10-3.81mg/m^3$ for cucumbers, $0.21-1.19mg/m^3$ for yellow melon, and $0.08-2.72mg/m^3$ for potato. There was a significant difference in the harvest task among the three farm types(p=0.019 of personal sample, p=0.048 of area sample), in which the air concentration for potatoes was higher than with cucumbers and yellow melons. Conclusions: It was found that potatoes(planting and harvest) should be considered the first priority for studying and reducing total dust exposure.