• Journal of Animal Environmental Science
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• v.4 no.2
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• pp.149-160
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• 1998

Hog manure slurry amended with sawdust was composted in pilot-scale reactor vessels using continuous aeration nuder different C/N ratios and pH conditions during composting high rate (decomposition) process. For each material two replicated piles were built and monitored over a period of three weeks. The compost piles had an initial volume of 0.18 ㎥. In this study we evaluated the temperature in compost O2 and CO2 evolution, aeration rate, NH3 concentration etc. and investigated the stability of compost during composting high rate process. According to measured results, while the maximum NH3 concentration during composting high rate process. According to measured results, while the maximum NH3 concentration during composting high rate was in the range of 213 to 412 ppm on 5th day which was near the optimum C/N(22∼24) and pH(7.5∼7.9). And then, the NH3 concentration reduced to between 22∼26 ppm by 13th day. The maximum NH3 concentration for the lower C/N(18∼19) and pH value of 6 reached 574∼1,063 ppm by the 16th through 11th days and the NH3 concentration during continuous aerated composting high rate process, it was more important to manage NH3 gas so that compost odor is reduced.

• Proceedings of the Korea Society of Poultry Science Conference
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• 2001.11a
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• pp.86-88
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• 2001

An experiment was conducted to determine how broiler performance, feces and litter concentration of N can be maintained and whether NH3 gas concentration can be reduced with reducing dietary CP, adding ALUM(AL2(SO4)3.14H20) in litter and supplementing with amino acid and vitamin D in feed. The experiment was divided into a starter period(1 to 21d) and grower period(22 to 42d), each having three different CP with 90 birds per treatment of 3 replications. The CP treatments consisted of a mean CP of 23.0(control 71), 20.4 (72) and 18.0 (73) % for starter and 21.0(control 71),19.3 (72) and 17.0 (73) % for grower, respectively, but with similar amino acid levels as the control. Alum was mixed in each treatment except control treatment with 200g in kilogram litter(rice bran) weight. Results suggested that reducing CP below control in the diets fed during 3wks and 6wks slightly increased feed gain and slightly decreased feed intake and weight gain. However, there were no significant difference among treatments. Reducing CP caused NH3 gas concentration to decline by 74.8 - 80.9% when Alum was mixed in litter(P < 0.05). Litter N concentration did not show any difference(P > 0.05) among treatments. These results suggest that dietary manipulation with adding Alum in litter show for significant reducing NH3 gas concentration while maintaining acceptable Production performance from broiler.

• Clean Technology
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• v.13 no.2
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• pp.122-126
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• 2007

When ammonia ($NH_3$) gas was supplied to a biofilter packed with bio-carrier made of waste polyurthane and worm cast. No odor gases were detected at the outlet of the biofilter when $NH_3$ gas was supplied to the biofilter at the space velocity(SV) of $50\;h^{-1}$ until the inlet $NH_3$ concentration increased to $4\;{\sim}\;454\;ppmv$. The gradual inlet $NH_3$ concentration was set and the removal efficiency of $NH_3$ gas was measured at each condition, while the SV of $NH_3$ increased step by step from 100 to $400\;h^{-1}$. The maximum possible inlet $NH_3$ loading was $11.38\;g-NH_3{\cdot}m^{-3}{\cdot}h^{-1}$ and $34.42\;g-NH_3{\cdot}m^{-3}{\cdot}h^{-1}$ while maintaining the removal efficiency of 100% when the SV was $50\;h^{-1}$ and $100 \;h^{-1}$, respectively. The maximum $NH_3$ loading was $71.28 \;g-NH_3{\cdot}m^{-3}{\cdot}h^{-1}$ with the $NH_3$ removal efficiency of 99.85% at SV $300\;h^{-1}$.

• Journal of Korean Society for Atmospheric Environment
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• v.18 no.E1
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• pp.29-36
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• 2002

The selective catalytic reduction (SCR) reaction of promoter catalysts was investigated in this study. A pure anatase type of TiO$_2$ was used as support. Activation measurement of prepared catalysts was practiced on a fixed reactor packing by the glass bead after filling up catalysts in 1/4 inch stainless tube. The reaction temperature was measured by K-type thermocouple and catalyst was heated by electric furnace. The standard compositions of the simulated flue gas mixture in this study were as follows: NO 1,780ppm, NH$_3$1,780ppm, $O_2$1% and $N_2$ as balance gas. In this study, gas analyzer was used to measure the outgassing gas. Catalyst bed was handled for 1hr at 45$0^{\circ}C$, and the reactivity of the various catalyst was determined in a wide temperature range. Conversion of NH$_3$/NO ratio and of $O_2$ concentration was practiced at 1,1.5 and 2, respectively. The respective space velocity were as follows . 10,000, 15,000 and 17,000 hr-1. It was found that the maximum conversion temperature range was in a 5$0^{\circ}C$. It was also found toi be very sensitive at space velocity, $O_2$ concentration, and NH$_3$/NO ratio. We also noticed that the maximum conversion temperature of (W, Mo, Sn) -V$_2$O$_{5}$/TiO$_2$ catalysts was broad. Specially WO$_3$-V$_2$O$_{5}$TiO$_2$2 catalyst appeared nearly 100% conversion at not only above 30$0^{\circ}C$ ut also below 25$0^{\circ}C$. At over 30$0^{\circ}C$, NH$_3$ oxidation decreased with decrease of surface excess oxygen. In addition, WO$_3$-V$_2$O$_{5}$TiO$_2$ catalyst did not appear to affect space velocity, $O_2$ concentration, and NH$_3$/NO ratio.ratio.

• Journal of the Korean Institute of Gas
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• v.26 no.5
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• pp.35-40
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• 2022

PCVD (Plasma Chemical Vapor Deposition), a solar cell manufacturing facility, is a facility that deposits plasma generated in a chamber (NH₃, SIH₄, O₂ on a wafer. In the PCVD facility, gas movement and injection is performed in the gas cabinet, and there are many leak points inside because MFC, regulator, valve, pipe, etc. are intricately connected. In order to prevent explosion in case of leakage of NH₃ with an upper explosive limit (UEL) of 33.6% and a lower explosive limit (LEL) of 15%, the dilution capacity must be capable of allowing the concentration of NH₃ to be out of the explosive range. This study was analyzed using the CFD analysis technique, which can confirm the dilution ability in 3D and numerical values when NH₃ gas leaks from the existing PCVD gas cabinet. As a result, it was concluded that it corresponds to medium dilution and that testicular ventilation is possible through facility improvement.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.5
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• pp.368-377
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• 2011

A package type of SCR (selective catalytic reduction) system that was proposed for removing the $NO_x$ found in flue gas from the small scale of air pollution sources was evaluated. The efficiency of the SCR system is determined by the proper utilization of catalytic media installed inside of the system, and the proper distribution of flow velocity and $NH_3$ concentration in the flue gas is a crucial factor for using the catalytic media. In this study, the distributions of $NH_3$ concentration were estimated under the various arrays and shapes of AIG at the given gas flow condition. The value of RMS (%) in $NH_3$ concentration is 95.3% at co-current flow (at $0^{\circ}$) injection but it is 90.1% at the condition of counter-current flow (at $120^{\circ}$) condition, which implies the counter-current injection is more favorable. By rearranging the $NH_3$ injection flow rates based on the distribution of velocity and $NH_3$ distribution in basic calculation, the value of RMS (%) in $NH_3$ concentration was reduced to 62.8%. The enhanced effect of $NH_3$ mixing by the combined effect of arrays and shapes are complied in the study.

• Journal of Advanced Marine Engineering and Technology
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• v.23 no.4
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• pp.462-472
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• 1999

De-NOx facility using Selective Catalytic Reduction method is the most widely applied one that removes NOx from flue gas emitted from combustion facility such as boiler for power generation engine incinerator etc. Reductant $NH_3\;or\;NH_4OH$ is sprayed into flue gas to convert NOx into $H_2O$ and $N_2.$ Good mixing between flue gas and $NH_3$ is the most important factor to increase reduction in catalytic layer and to reduce unreacted NH3 slip. Therefore the development of mixer device for mixing effect is one of the important part for SCR facility. Objectives of this study are to investigate the relation between flow and concentration field by observation at the wake of delta-wing type mixer. At the first stage qualitative measurement of flow field is conducted by flow visualization using laser light sheet in lab. scale wind tunnel. Also we have conducted the quantitative analysis by comparing flow field measurement using LDV with numerical simulation. On the basis of qualitative and quantitative analysis we investigate the dis-tribution of flow and concentration in flow model facility. The results of an experimental and compu-tational examination of the vortex structures shed from delta wing type vortex generator having $40^{\circ}$ angle of attack are presented, The effects of vortex structure on the gas mixing is discussed, too.

• Journal of Sensor Science and Technology
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• v.19 no.3
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• pp.176-183
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• 2010

It is considered that the urea injection DeNOx SCR(selective catalytic reduction) system is the only promising method to satisfy the worldwide NOx emission standards. As for the theoretical aspect, reactants of NO and $NO_2$ with $NH_3$ produce $H_2O$, $N_2$ and $O_2$ which do not harm human beings and environmental as well. The realization of maximum NOx conversion (without using a post oxidation catalyst) is only possible with closed loop controlled urea dosing. It means built-in $NH_3$ gas sensor have to be developed for detecting accurate $NH_3$ concentration for the feedback system. Using YSZ(yttria-stabilized zirconia) as a solid state electrolyte and $In_2O_3$ as a sensing material, this paper aims to study dependable $NH_3$ gas sensor for the promising solution of DeNOx technology, which have a reproducible electric output signal, a high sensitivity and fast response.

• Applied Chemistry for Engineering
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• v.25 no.2
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• pp.193-197
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• 2014

The electrode for gas sensor was prepared by using pitch-based activated carbon fibers and polyvinyl alcohol (PVA) to investigate the toxic gas sensing characteristics. The physicochemical properties of activated carbon fibers electrode for gas sensor were analyzed with SEM and BET. Toxic gases sensing property of the electrode was also identified by different toxic gases such as $NH_3$, NO and $CO_2$. The specific surface area of activated carbon fibers electrode for gas sensor was decreased by 33% owing to PVA used as a binder compared with the activated carbon fibers. However, its pore size distribution of the ACF electrode was not greatly influenced by PVA. The activated carbon fibers electrode for gas sensor responded to toxic gases by electron hopping unlike semiconductor based gas sensors. In this study, activated carbon fibers electrode was decreased to 7.5% in resistance for the NH3 gas of the 100 ppm concentration and its $NH_3$ gas sensing property was confirmed the most excellent compared with other toxic gases.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.12
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• pp.1329-1336
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• 2007

This study was carried out to develop an efficient process abating high NO concentration. A hybrid process of selective catalytic reduction(SCR) and activated carbon fiber(ACF) adsorption was newly designed and tested. Used ACF in NO adsorption was regenerated by simultaneously applying heat and vacuum. The result of ACF regeneration was for superior in the desorption condition at $140^{\circ}C$ and vacuum 600 mmHg. A commercial catalyst was used at the conditions of reaction temperature at $300^{\circ}C$, $NH_3/NO$ mole ratio = 1.0 for SCR process. NO evolved from ACF regeneration reactor could be removed by SCR reactor up to 98%. But high concentration of NO was exhausted from SCR reactor for one minute when the flue gas of NO 300 ppm and deserted NO from ACF regeneration were simultaneously treated by the same SCR reactor. Therefore, it is necessary to use additional small sized SCR reactor or to increase $NH_3$ concentration for a short time along with NO concentration rather than to mix flue gas with the gas evolving from ACF regeneration at fixed $NH_3$ inlet concentration. The hybrid process of SCR and ACF showed high NO removal efficiency over 80% at any time courses. Through the repeated cycles, stable DeNOx efficiency was maintained, indicating that the hybrid process would be a good countermeasure to the spotaneously high NO concentration instead of increasing the SCR capacity.