• Title/Summary/Keyword: ND4

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Solvent Extraction of Nd from Chloride Solution with PC88A (염산용액에서 PC88A에 의한 Nd의 용매추출)

  • Lee Gwang-Seop;Lee Jin-Young;Kim Sung-Don;Kim Joon-Soo;Lee Man-Seung
    • Resources Recycling
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    • v.13 no.4
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    • pp.39-45
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    • 2004
  • Solvent extraction experiments of Nd from chloride solution were studied with PC88A. Solvent extraction reaction of Nd with PC88A and the equilibrium constant were evaluated from the extraction experimental data and extraction conditions. Nd$aq^{3+}$ + 1.5 $H_2$$A_2$,org = $NdA_3$,org + 3H/sun $aq^{+}$ , K=0.25 The predicted distribution coefficients of Nd agreed well with the experimental results. The effect of saponification of PC88A on the extraction of Nd and on the change of equilibrium pH was investigated. Saponified PC88A present as a monomer in the organic reaction and enhanced the distribution coefficient of Nd. The initial extraction conditions had a great effect on the equilibrium pH.

Rare Earth Element, Sm-Nd and Rb-Sr Age and its Geochemical Implication of Leucogranite in the Deokgu Hot Spring Area, Yeongnam Massif, Korea (영남육괴 북동부 덕구온천지구 우백질 화강암의 희토류원소 분포도, Sm-Nd, Rb-Sr 연대 및 지구화학적 의의)

  • Lee, Seung-Gu;Kim, Tong-Kwon;Lee, Tae-Jong
    • The Journal of the Petrological Society of Korea
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    • v.20 no.4
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    • pp.207-217
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    • 2011
  • Here we report major element composition, trace and rare earth element abundance, Sm-Nd and Rb-Sr isotopic composition from Deokgu leucogranite. Chondrite-normalized REE pattern and its Eu anomaly are divided into 3 types systematically, and have close relationship with $SiO_2$ contents. Such geochemical characteristic indicates that the leucogranite was derived by feldspar fractionation from a common source magma. Sm-Nd and Rb-Sr whole rock ages are $1,785{\pm}180Ma$ (initial $^{143}Nd/^{144}Nd\;ratio=0.51003{\pm}0.00016,\;2{\sigma}$; ${\varepsilon}_{Nd}(T)=-5.9$) and $1,735{\pm}260Ma$ (initial $^{87}Sr/^{86}Sr\;ratio=0.702{\pm}0.046,\;2{\sigma}$), respectively. Initial ${\varepsilon}_{Nd}$ value indicates that the magma should be derived from the crustal material. This initial ${\varepsilon}_{Nd}$ value also corresponds well with those from the Precambrian granitoids from North-China Craton rather than those of South-China Craton.

100 W class flash lamp pumped single stage Nd:YAG Amplifier (섬광등 펌프형 100 W급 4 중통과 Nd:YAG 증폭기 시스템의 증폭특성)

  • 고광훈;정도영;김재우;박상언;임창환;김철중
    • Korean Journal of Optics and Photonics
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    • v.14 no.5
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    • pp.515-520
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    • 2003
  • Characteristics of an amplifier with repetition rate of a few KHz is investigated. The continuous flash lamp pumped Nd:YAG laser head is used as an amplifier. The thermally induced birefringence of the laser medium is compensated and the depolarization is reduced to 5% in a double-pass amplifier. The amplification factor of a four pass amplifier reaches to about 3.2 at the repetition rate 5-10 KHz and the pulse width is lengthened from 40 ns to 48 ns.

Characteristics of AlNd thin film for TFT-LCD bus line

  • Kim, Dong-Sik;Kwak, Sung-Kwan;Chung, Kwan-Soo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.59-59
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    • 2000
  • Recently low resistance of bus line is required for large screen size TFT-LCD panels. As a result, lower resistance Al-alloy is currently reviewed extensively. The resistivity is required smaller than 10 $\mu$$\Omega$cm. In this paper, Al-Nd thin film were deposited on glass substrates by D.C. magnetron sputtering system under various condition. Its properties were characterized by SEM, AFM, XRD, 4-ping-probe. The optimal condition of Al-Nd was 12$0^{\circ}C$, 125W, 0.4Pa, 30sccm(Ar) and 35$0^{\circ}C$, 20min. annealing. At that condition the resistivity of Al-Nd(2wt.%) was about 4 $\mu$$\Omega$cm. The minimum contact resistance of ITO/Nd was about 110$\mu$$\Omega$cm in the condition of 30$0^{\circ}C$, Ar 30 sccm. O2.

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Electronic and Magnetic Structures of Rare-earth Permanent Magnets (희토류 영구자석의 전자기적 구조)

  • 민병일;장영록
    • Journal of the Korean Magnetics Society
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    • v.1 no.1
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    • pp.6-11
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    • 1991
  • In order to investigate electronic and magnetic properties of permanent magnets, we have performed self-consistent electronic structure calculations on compounds of rare-earth and transition metals, such as $SmCo_{5},\;NdB_{6},\;NdFe_{5},\;NdFe_{4}B$. Employing the local density LMTO(linearized muffin tin orbital) band method, we have obtained the ground state parameters, such as band structures, density of states, Stoner parameters, and magnetic moments. We have also investigated interactions between d,f-electrons of Nd, Sm rare-earths and d-electrons of Fe, Co transition metals, and the s,p electrons of boron and explored effects of such interactions on the bonding mechanism and the electronic and magnetic structures in these rare-earth compounds.

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Investigation on the lasing characteristics of an $Ar^+$ laser-pumped Nd:glass laser ($Ar^+$ 레이저로 펌핑되는 Nd:glass 레이저의 발진특성)

  • 이종무;강응철;남창희
    • Korean Journal of Optics and Photonics
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    • v.3 no.4
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    • pp.222-226
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    • 1992
  • The lasing characteristics of a Nd:phosphate glass laser pumped by 514 nm of an $Ar^{+}$ laser has been investigated. The oscillator consists of a Nd:glass gain medium set at Brewster angle, and two concave mirrors, and a flat mirror with a reflectance of 98%. The $Ar^{+}$ laser pumping beam is focused longitudinally at the beam waist of laser mode for efficient pumping. The pumping beam is chopped at 100 Hz to reduce the heat loading to prevent the thermal damage of the gain medium by the latent heat from the absorbed pumping beam. The maximum laser output power of 70 mW at 1.5 W pumping and the threshold input power of 520 mW have been obtained.

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HDDR Characteristics and Magnetic Properties of Nd15(Fe1-xCox)77B8(x=0-0.6) Alloys

  • Kwon, H.W.
    • Journal of Magnetics
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    • v.7 no.4
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    • pp.127-131
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    • 2002
  • HDDR characteristics and magnetic properties of $Nd_{15}{(Fe_{1-x}Co_{x})}_{77}B_{8}$(x=0-0.6) alloys were investigated. The effect of applying magnetic field during the recombination step on the anisotropic nature of the HDDR-treated material was also examined. The $Nd_{15}{(Fe_{1-x}Co_{x})}_{77}B_{8}$ phase in the Nd-Fe-B alloys with high Co-substitution alloy had remarkably enhanced phase stability. The $Nd_{15}{(Fe_{1-x}Co_{x})}_{77}B_{8}$(x=0-0.6) alloys with high Co-substitution could be HDDR-treated successfully by only using high pressure hydrogen. However, these alloys had no appreciable coercivity. The poor coercivity of the HDDR-treated $Nd_{15}{(Fe_{1-x}Co_{x})}_{77}B_{8}$(x=0-0.6) alloys with high Co-substitution was attributed to the $Nd{(Fe,Co)}_2$ phase in the alloys. The magnetic filed applied during the recombination step had little effect on the anisotropic nature of the HDDR-treated powder.

A Survey on the Immune Status and Productivity of Vaccinated Poultry Flocks against Newcastle Disease in the Epizootic Area (뉴캣슬병백신 접종계군에 있어서 면역상태와 ND 발생시 닭의 생산성에 미치는 영향)

  • 박근식;김선중
    • Korean Journal of Poultry Science
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    • v.11 no.1
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    • pp.49-64
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    • 1984
  • During the 1978-79 Newcastle disease (ND) epizootic period, a detailed survey was conducted on the five representative farms which had been following one of the recommended vaccination programs. When the disease broke out during laying period, clinical symptoms were mild to moderate respiratory distress and greenish diarrhea. Affected flocks experienced weekly mortality from less than 1% to 17%. Egg production returned to normal 18 to 36 days after the initial signs appeared although some flocks never returned to normal. On postmortem examination,, most affected chickens showed severe hemorrhagic lesions in the duodenum, hematoma on ova, and heavy fat accmulation on various visceral organs. Most of the NO affected flocks had geometric mean hemagglutination inhibition antibody(HIA) titers of 7 log$_2$ or higher two to three weeks after the appearance of clinical signs. These HIA titers were at least 16-fold higher than those before infection. Flock mean HIA titers before infection were usually lower than 3 log$_2$. Severity of clinical signs and anamnestic antibody response were maximum in the flocks whose vaccination immunity was insufficient or waned considerably. Observations showed that even young birds, if properly vaccinated, could get effective protection from field ND exposure.

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Residue Levels of Pesticides in Post-Harvest Treated Import Fruits During Storage (수입 과일에 살포된 수확 후 처리농약(Post-harvest pesticide)의 경시적 변화)

  • Hwang, Lae-Hwong;Cho, Tae-Hee;Cho, In-Soon;Eom, Jeung-Hoon;Choe, Bu-Chuhl;Park, Young-Hye;Kim, Hyun-Jeong;Kim, Jung-Hun
    • Journal of Food Hygiene and Safety
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    • v.25 no.3
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    • pp.245-250
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    • 2010
  • The post-harvest concentration change of four kind of pesticides, captan, chlorpyrifos, methidathion and kresoxim-methyl was investigated with the storage period for the import fruit. Then the post-harvest concentration was set to 1000, 250, 400 and 157 $mgkg^{-1}$ for captan, chlorpyrifos, methidathion and kresoxim-methyl respectively. In case of captan, 0.9-12.5 $mgkg^{-1}$ in total fruit base and ND-0.23 $mgkg^{-1}$ in the sarcocarp were measured after atomization and 0.7-3.2 $mgkg^{-1}$ in total fruit base and ND-0.67 $mgkg^{-1}$ in the sarcocarp were measured after four week. For chlopyrifos, menthidathion, and kresoxim-methyl 0.4-2.2, 0.7-3.1 and 1.3-2.1 $mgkg^{-1}$ in total fruit base and ND-0.32, ND-0.05 and ND-0.16 $mgkg^{-1}$ in the sarcocarp were measured after atomization respectively. After four week 0.3-0.9, 0.4-2.0 and 1.3-1.8 $mgkg^{-1}$ in total fruit base and ND-0.02, ND-0.05 and ND-0.15 $mgkg^{-1}$ in the sarcocarp were investigated for other three pesticides. The concentration decreasing ratio of pesticides was largest for captan, 52% and other components were in order of chlopyrifos, menthidathion, and kresoxim-methy, 47, 41, 11% each other.