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Influence on Dielectric Properties and Evaporation of PbO According to Substituting $Nd^{3+}$ for $Pb^{2+}$ in $Pb(Mg_{1/3}Nb_{2/3})O_3$ System ($Pb(Mg_{1/3}Nb_{2/3})O_3$계 세라믹스의 $Pb^{2+}$$Nd^{3+}$로 치환함에 따른 유전특성 및 PbO 휘발에 관한 연구)

  • 김성열;이응상
    • Journal of the Korean Ceramic Society
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    • v.30 no.3
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    • pp.175-180
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    • 1993
  • Influence of Nd3+ substitution for Pb2+ on the dielectric properties and the PbO evaporation according to substituting Nd3+ for Pb2+ in Pb(Mg1/3Nb2/3)O3 system ceramics have been investigated. The dielectric constant at the curie temperature and evaporation of PbO were decreased with increase of Nd3+ amounts. The percentage of PbO evaporation was 2.5wt% in the PMN system substituted Nd3+ for Pb2+, while it was 3.7wt% in the PMN system.

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Effect of Ga, Nb Addition on Disproportionation Kinetics of Nd-Fe-B Alloy

  • Kwon, H.W.;Yu, J.H.
    • Journal of Magnetics
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    • v.14 no.4
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    • pp.150-154
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    • 2009
  • The effect of Ga and, Nb addition on the kinetics and mechanism of the disproportionation of a Nd-Fe-B alloy were investigated by isothermal thermopiezic analysis (TPA) using $Nd_{12.5}Fe_{(81.1-(x+y))}B_{6.4}Ga_xNb_y$ (x=0 and 0.3, y= 0 and 0.2) alloys. The addition of Ga and Nb retarded the disproportionation kinetics of the Nd-Fe-B alloy significantly, and increased the activation energy of the disproportionation reaction. The disproportionation kinetics of the $Nd_{12.5}Fe_{(81.1-(x+y))}B_{6.4}Ga_xNb_y$ alloys measured under an initial hydrogen pressure of 0.02 MPa were fitted to a parabolic rate law. This suggested that during the disproportionation of $Nd_{12.5}Fe_{(81.1-(x+y))}B_{6.4}Ga_xNb_y$ alloys with an initial hydrogen pressure of 0.02 MPa, a continuous disproportionation product is formed and the overall reaction rate is limited by the diffusion of hydrogen atoms (or ions).

$M\"{o}ssbauer$ studies of $NdFe_{10.7}TiM{0.3}(M\;=\;B,\;Ti)$ ($NdFe_{10.7}TiM{0.3}(M\;=\;B,\;Ti)$$M\"{o}ssbauer$ 연구)

  • 김철성;이용종;김윤배;김창석
    • Journal of the Korean Magnetics Society
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    • v.5 no.1
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    • pp.64-70
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    • 1995
  • The authors have studied crystallographic and magrletic properties of $NdFe_{10.7}TiM_{0.3}(M=B,\;Ti)$ by X-ray diffraction, VSM magnetometer, and Mossbauer spectrometer. The Alloys were prepared by arc-melting under argon atmosphere. The $NdFe_{10.7}TiM_{0.3}$ has pure single phase, whereas the $NdFe_{10.7}Ti_{1.3}$ contains some $\alpha-Fe$, from powder X-ray diffractometry. The $NdFe_{10.7}TiM_{0.3}$ has the $ThMn_{12}$-type tetragonal structure with $a_{0}=8.587\;{\AA}\;and\;c_{0}=4.788\;{\AA}$. The Curie temperature ($T_c$) is $570{\pm}3\;K$ from $M\"{o}ssbauer$ spectroscopy performed at various temperatures ranging from 13 to 770 K. Each spectrum of below $T_c$ was fitted with five subspectra of Fe sites in the structure ($8i_{1},\;8i_{2},\;8j_{1},\;8j_{2}\;and\;8f$). The area fraction of the subspectra at room temperature are 16.4, 8.2, 14.8, 21.3 and 39.3 %, respectively. Magenetic hyperfine fields for the Fe sites decrease in the order, $H_{hf}(8i)>H_{hf}(8j)>H_{hf}(8f)$.

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A Study on Heat Transfer Characteristics of Laser Cutting for the CSP 1N Sheet Using High-power CW Nd:YAG Laser (고출력 CW Nd:YAG 레이저를 이용한 CSP 1N 박판 절단공정의 열전달 특성 분석)

  • Ahn, Dong-Gyu;Kim, Min-Su
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.5 no.1
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    • pp.51-58
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    • 2006
  • The objective of this research work is to investigate into heat transfer characteristics of the laser cutting of CSP 1N sheet using high power CW Nd:YAG laser. In order to investigate the heat transfer characteristics, three dimensional quasi stationary and steady-state heat transfer analysis has been carried out. The laser heat source is assumed as a volumetric heat source with a gaussian heat distribution in a plane. Through the comparison of the results of analyses with those of experiments, the proper finite element model has been obtained. In addition, characteristics of the three-dimensional heat transfer and temperature distribution have been estimated by the finite element model. Finally, the minimum temperature at the center for cutting of the material has been estimated.

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Effect of Nd Doping on the Electrical Conductivity and Lattice Parameters of barium-Lead Titanate (Nd첨가가 Barium-Lead Titanate의 전기전도도와 격자상수에 미치는 영향)

  • Tadashi NAKANO;;Hiroaki YANAGIDA
    • Journal of the Korean Ceramic Society
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    • v.22 no.4
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    • pp.15-20
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    • 1985
  • $(Ba_{0.5} Pb_{0.5})_{1-x} Nd_x TiO_3$ 중의 $_x(Nd$의 양)를 변화시키면서 격자상수와 전기전도도를 측정하였다 c축과 a축의 비(c/a) 의 극대값은 실온에 있어서 전기전도도의 극대값과 일치하였다. 이것은 Nd원자의 치환위치와 강유 전성의 변화에 의한 것으로 고찰되었다 Curie 온도이하에서는 Nd 첨가량의 증가에 따라 전기전도도의 활성화에너지가 증가하는 경향을 나타내었다 이것은 입경의 감소에 따른 Spontaneous polarization의 저하가 원인으로 고찰되었다 첨가량의 역학을 입계의 potential barrier의 높이와 관련지어 논하였다.

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Effect of Strip-cast Conditions on the Formation of Microstructures in Nd-Fe-B alloys (Strip-cast 조건이 Nd-Fe-B 합금의 미세조직 형성에 미치는 영향)

  • Lee, D.H.;Jang, T.S.;Kim, D.H.;Kim, Andrew S.
    • Journal of the Korean Magnetics Society
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    • v.12 no.1
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    • pp.34-40
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    • 2002
  • In order to improve the microstructure of the strip cast Nd-Fe-B alloys that are frequently used for production of high energy sintered magnets, influence of various strip casting conditions on the microstructure and phase formation and distribution were investigated. Nd-Fe-B strips consisting of microstructures suitable for preparation of high energy sintered magnets could be obtained when the wheel speed was below 5 m/s. The compositional limit that can avoid the crystallization of free iron in the as-cast state was estimated to be Nd$\_$14/Fe$\_$79/B$\_$7/. Regardless of the compositional variation, <001> preferred orientation of Nd$_2$Fe$\_$14/B normal to the strip surface was always occurred below 5 m/s, which would eventually enhance the grain alignment during pressing the powder under a magnetic field. While the coercivity of the strip cast alloys increased with the increase of the wheel speed, mainly due to the refinement of Nd$_2$Fe$\_$14/B grains, it decreased with the reduction of Nd content in the alloy composition as the formation of free iron increased.

The Characteristics of Electric Resistivity on the Ceramic Oxide, $Nd_{2-x}Ce_xCuO_4$ (세라믹 초전도체, $Nd_{2-x}Ce_xCuO_4$의 전기적 저항 특성)

  • Kim, Jeong-Sik
    • Korean Journal of Materials Research
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    • v.6 no.2
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    • pp.133-137
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    • 1996
  • 본연구에서는 n-type 세라믹 초전도체인 Nd2-xCexCuO4상의 산소함량에 따른 \ulcorner기적저항의 변화를 고찰하고자 하였다. 일반적인 소결과 어닐링과정을 결쳐 제조된 Nd1.85Ce0.15CuO4-x 시편을 여러 온도와 산소분압의 분위기하에서 어닐링시킴으로써 산소의 함유량이 다른 시편들을 준비하였고 각각의 시편의 산소함량은 TGA(Thermogravimetric Analysis0에 의해 측정하였다. Nd1.85Ce0.15CuO4-x시편의 전기적 저항 측정은 표준 4-탐침방법을 이용하여 액체헬륨을 주입시켜 상온으로부터 4K까지 측정하였다. Nd1.85Ce0.15CuO4-x시편의 산소함량, 3.96$\leq$4-x$\leq$4.0의 범위에서 전기적저항을 측정한 결과 초전도특성이 나타나기 시작한 임계산소함량은 4-x=3.990이었고 이때의 임계온도 Tc=12K이었다. 또한 임계온도, Tc는 산소함량 4-x=3.96에서 24K로 측정되었다. 특이할 만한 현상은 CuO/Cu2O 열역학적 상전이가 일어나는 조건이 Nd1.85Ce0.15CuO4-x 시편의 초전도가 일어나는 임계와 일치하였다. 즉, Cu2O가 안정한 영역에서는 초전도특성이 나타났고 CuO가 안정한 영역에서는 초전도특성이 나타나지 않았다.

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Optimization of Q-switched Operation at a Laser-Diode Pumped Nd:YAG Ceramic Laser (반도체레이저 여기 세라믹 Nd:YAG 레이저에서 Q-스위칭 동작 최적화)

  • Shin, Dong-Joon;Kim, Byung-Tai;Kim, Duck-Lae
    • Korean Journal of Optics and Photonics
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    • v.19 no.4
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    • pp.320-326
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    • 2008
  • The output characteristics of a laser-diode pumped electrooptic Q-switched Nd:YAG ceramic laser were investigated. The output energy of a Q-switched Nd:YAG ceramic laser was optimized under an output coupler reflectivity of 77%, a laser-diode pulse width of $1,000\;{\mu}s$, and a delay time of $985\;{\mu}s$. The output energy of the Q-switched pulse was measured to be 0.35 mJ with a pulse width of 4 ns under a pump energy of 17.9 mJ. The output efficiency and the peak power were 1.9% and 87.5 kW, respectively.

Effect of oxygen pressure on properties of $NdBa_2Cu_3O_{7-{\delta}}$ films on $SrTiO_3$ (100) substrates grown by pulsed laser deposition

  • Wee, Sung-Hun;Moon, Seung-Hyun;Park, Chan;Yoo, Sang-Im
    • Progress in Superconductivity and Cryogenics
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    • v.6 no.4
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    • pp.9-12
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    • 2004
  • We report a successful fabrication of high-$J_C$ $NdBa_2Cu_3O_{7-{\delta}}$ (NdBCO) films on (100) $SrTiO_3$ substrates by pulsed laser deposition (PLD) in high oxygen pressures ranging from 400 to 800 mTorr. Fabricated NdBCO films exhibited only c-axis orientation, good out-of-plane and in-plane textures, and also excellent superconducting properties, including critical temperature ($T_C$) and critical current density ($J_C$) of above 90 K and the highest of $3.1MA/cm^2$ at 77 K in self-field, implying that NdBCO is a perspective alternative to YBCO for coated conductor. In low oxygen pressures ranging from 100 to 200 mTorr, however, the films showed a-, c-mixed orientation and degraded $T_{C,zero}$ values due to the formation of $Nd_{1+x}Ba_{2-x}Cu_3O_{7-{\delta}}$-type solid solutions with an excessive substitution of $Nd^{3+}$ ions for the $Ba^{2+}$ sites.

Thermal Stability of Superconductor NdBCO Sintered at Various Oxygen Partial Pressures (다양한 산소분압에서 소결한 NdBCO 초전도체의 열적 안정성)

  • Chung, J.K.;Kim, W.J.;Park, S.C.;Kang, S.G.;Lim, Y.J.;Kim, C.J.
    • Progress in Superconductivity
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    • v.10 no.2
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    • pp.133-138
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    • 2009
  • The $Nd_{1+x}Ba_{2-x}Cu_3O_{7-{\delta}}$(Nd123) superconductor exhibits high performance in high magnetic field and high temperature. We have studied phase stability for Nd123 under reduced oxygen partial pressure and various heat-treatment conditions. The main phase is Nd123 and some samples contain small amounts of Nd422 depending on the temperature and oxygen partial pressure. The decomposition temperature decreases with decreasing oxygen partial pressure from $1052^{\circ}C(P(O_2)$=150 Torr) to about $845^{\circ}C(P(O_2)$=0.1 Torr). The liquidus line was steeper temperature with decreasing oxygen partial pressure. In same condition of oxygen partial pressure, the region of stable Nd123 phase was formed at slightly higher temperature than the region of stable YBCO phase.

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