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Effects of Urease Inhibitor, Nitrification Inhibitor, and Slow-release Fertilizer on Nitrogen Fertilizer Loss in Direct-Seeding Rice

  • Lee, Jae-Hong;Lee, Ho-Jin;Lee, Byun-Woo
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.44 no.3
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    • pp.230-235
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    • 1999
  • To study the effects of an urease inhibitor, N-(n-butyl)-thiophosphoric triamide (NBPT), and a nitrification inhibitor, dicyandiamide (DCD), on nitrogen losses and nitrogen use efficiency, urea fertilizer with or without inhibitors and slowrelease fertilizer (synthetic thermoplastic resins coated urea) were applied to direct-seeded flooded rice fields in 1998. In the urea and the urea+DCD treatments, NH$_4$$^{+}$ -N concentrations reached 50 mg N L$^{-1}$ after application. Urea+NBPT and urea+ NBPT+DCD treatments maintained NH$_4$$^{+}$ -N concentrations below 10 mg N L$^{-1}$ in the floodwater, while the slow-release fertilizer application maintained the lowest concentration of NH$_4$$^{+}$ -N in floodwater. The ammonia losses of urea+NBPT and urea+NBPT+DCD treatments were lower than those of urea and urea+DCD treatments during the 30 days after fertilizer application. It was found that N loss due to ammonia volatilization was minimized in the treatments of NBPT with urea and the slow-release fertilizer. The volatile loss of urea+DCD treatment was not significantly different from that of urea surface application. It was found that NBPT delayed urea hydrolysis and then decreased losses due to ammonia volatilization. DCD, a nitrification inhibitor, had no significant effect on ammonia loss under flooded conditions. The slow-release fertilizer application reduced ammonia volatilization loss most effectively. As N0$_3$$^{[-10]}$ -N concentrations in the soil water indicated that leaching losses of N were negligible, DCD was not effective in inhibiting nitrification in the flooded soil. The amount of N in plants was especially low in the slow-release fertilizer treatment during the early growth stage for 15 days after fertilization. The amount of N in the rice plants, however, was higher in the slow-release fertilizer treatment than in other treatments at harvest. Grain yields in the treatments of slow-release fertilizer, urea+NBPT+ DCD and urea+NBPT were significantly higher than those in the treatments of urea and urea+DCD. NBPT treatment with urea and the slow-release fertilizer application were effective in both reducing nitrogen losses and increasing grain yield by improving N use efficiency in direct-seeded flooded rice field.field.

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A Study on the Mitigation of Nitrous Oxide emission with the Horticultural Fertilizer of Containing Urease Inhibitor in Hot Pepper and Chinese Cabbage Field (고추와 배추 재배지에서 요소분해효소 억제제 함유 원예용 비료 시용에 따른 아산화질소 배출 저감 효과)

  • Ju, Ok Jung;Lim, Gap June;Lee, Sang Duk;Won, Tae Jin;Park, Jung Soo;Kang, Chang Sung;Hong, Soon Sung;Kang, Nam Goo
    • Korean Journal of Environmental Agriculture
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    • v.37 no.4
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    • pp.235-242
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    • 2018
  • BACKGROUND: About 81% of nitrous oxide ($N_2O$) emissions from agricultural land to the atmosphere is due to nitrogen (N) fertilizer application. Mitigation of $N_2O$ emissions can be more effective in controlling biochemical processes such as nitrification and denitrification in the soil rather than decreasing fertilizer application. The use of urease inhibitors is an effective way to improve N fertilizer efficiency and reduce $N_2O$ emissions. Several compounds act as urease inhibitors, but N-(n-butyl) thiophosphoric triamide (NBPT) has been used worldwide. METHODS AND RESULTS: Hot pepper and chinese cabbage were cultivated in five treatments: standard fertilizer of nitrogen-phosphorus-potassium(N-P-K, $N-P_2O_5-K_2O$: 22.5-11.2-14.9 kg/ha for hot pepper and $N-P_2O_5-K_2O$: 32.0-7.8-19.8 kg/ha for chinese cabbage), no fertilizer, and NBPT-treated fertilizer of 0.5, 1.0, and 2.0 times of nitrogen basal application rate of the standard fertilizer, respectively in Gyeonggi-do Hwaseong-si for 2 years(2015-2016). According to application of NBPT-treated fertilizer in hot pepper and chinese cabbage, $N_2O$ emission decreased by 19-20% compared to that of the standard fertilizer plot. CONCLUSION: NBPT-treated fertilizer proved that $N_2O$ emissions decreased statistically significant in the same growth conditions as the standard fertilization in the hot pepper and chinese cabbage cultivated fields. It means that NBPT-treated fertilizer can be applied for N fertilizer efficiency and $N_2O$ emissions reduction.

The Activity and Utilization of Urease Inhibitors (요소분해효소 억제물질의 작용과 응용에 관한 연구)

  • 주영규
    • Asian Journal of Turfgrass Science
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    • v.6 no.1
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    • pp.23-28
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    • 1992
  • Urea, the major N source of world agriculture involves a serious urea-N loss through NH$_3$volatilization. Approaches to decrease N loss include using urease inhibitors in view of the environmental protection and the increase of urea-N efficiency. The purpose of laboratory researches was toassess the potential value of urease inhibitors to increase urea-N efficiency in soil and Kentucky blue-grass(Poa Pratensis L.) turf. The activity of urease inhibitors Phenyiphosphorodiamjdate(ppD) and N-(n-butyl) thiophosphoric triamjde(NBPT) measured to break-down ammonia volatilization. The soil and turf used in this project were from the fairway in one of the Korean gof course. The researches were carried out for two weeks to measure the urease activities on urea hydrolysis under four temperatures (10~ 40$^{\circ}C$) and for one week on turfgrass using forced-draft system. Results indicated that Urea-N involves considerable loss through gaseous NH$_3$ by urease activities in plant-soil systems. Urease inhibitors PPD and NBPT have potential value for increasing N use efficiency by reduing NH$_3$ volatilization. NBPT deserves futher evaluation as fertilizer amendment than PPD use of urea in turf industries.

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A Comparative Analysis of Pseudophase Ion-Exchange (PIE) Model and Berezin Pseudophase (BPP) Model: Analysis of Kinetic Data for Ionic Micellar-mediated Semi-ionic Bimolecular Reaction

  • Cheong, May-Ye;Ariffin, Azhar;Khan, M.Niyaz
    • Bulletin of the Korean Chemical Society
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    • v.28 no.7
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    • pp.1135-1140
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    • 2007
  • Pseudo-first-order rate constants (kobs) for the reaction of N-benzylphthalimide (NBPT) with HO- have been determined at 2.0 × 10?4 M NBPT, 1.0 × 10?3 and 2.0 × 10?3 M NaOH as well as varying concentrations of cetyltrimethylammonium bromide ([CTABr]T = 0.0-1.7 × 10?1 M). The effects of [CTABr]T ? CMC (with CMC representing the critical micelle concentration of CTABr) on kobs have been analyzed in terms of Berezin's pseudophase (BPP) model and pseudophase ion-exchange (PIE) model. Although both models give the best observed data fit with least-squares values not significantly different from each other, the calculated values of KS from BPP model appear to be more reliable compared to those from PIE model because the values of KS from BPP model are similar to the corresponding KS values determined spectrophotometrically.

Uncertainty-based Decision on Mitigation of Nitrous Oxide Emissions in Upland Soil (불확도 기반 밭토양 아산화질소 배출 저감 여부 판정)

  • Ju, Okjung;Kang, Namgoo;Lim, Gapjune
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.21 no.4
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    • pp.307-316
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    • 2019
  • In the agricultural sector, greenhouse gas emissions vary depending on the interaction of all ecosystem changes such as soil environment, weather environment, crop growth, and anthropogenic farming activities. Agricultural sector greenhouse gas emissions resulting from many of these interactions are highly variable. Uncertainty-based evaluation that defines the interval with confidence level of greenhouse gas emission and absorption is necessary to take account of the variance characteristics of individual emissions, but research on uncertainty evaluation method is insufficient. This study aims to decide on the effect of reducing N2O emissions from upland soils using an uncertainty-based approach. An uncertainty-based approach confirmed whether there was a difference between confidence intervals in the 5 different fertilizer treatment groups to reduce greenhouse gas emissions. Unlike the statistically significant test with three repetition averages, the uncertainty-based approach method estimated in this study is able to estimate the confidence interval considering the distribution characteristics of the emissions, such as the dispersion characteristics of individual emissions. Therefore, it is considered that the reliability of emissions can be improved by statistically testing the variance characteristics of emissions such as the uncertainty-based approach. It is hoped that the direction of the uncertainty-based approach for the effect of reducing greenhouse gas emissions in agriculture will be helpful in the future development of agricultural greenhouse gas emission reduction technology, adaptation to climate change, and further development of sustainable eco-social system.

An Improved Synchronization Control Scheme of a Low Cost 400Hz Power Supply for No-Break Power Transfer (저가격 고 신뢰성의 400Hz 전원의 무순단 전력절환용 개선된 동기화 기법)

  • Joung, Seok-Eon;Hyun, Dong-Seok
    • The Transactions of the Korean Institute of Power Electronics
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    • v.19 no.5
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    • pp.470-474
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    • 2014
  • This study proposes an improved synchronization control scheme for a low-cost 400Hz power supply for a no-break power transfer system. In the case of aircraft applications, the 400Hz power supply called ground power units is accepted and used as the external electrical power system during stopovers on ground. A momentary break in the supply occurs when shifting from one power source to another. To allow shifting without a break in the supply, the two power sources are momentarily connected in parallel. The proposed synchronization control is achieved by connecting an existing synchronization bus to the voltage zero-crossing signal of a generator power with discrete logic ICs and analog circuits. Therefore, unlike expensive controllers, such as DSP and CAN, the proposed control scheme is rather simple and may decrease operational cost. The practical feasibility of the proposed control scheme is proven by experimental results.

A Study on Certification Requirements and Personnel Standards for the School Library Media Specialist in the United States (미국 학교도서관 전문직 자격제도와 배치기준)

  • Kwon, Eun-Kyung
    • Journal of Korean Library and Information Science Society
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    • v.37 no.4
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    • pp.67-90
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    • 2006
  • This paper investigats the state of the art of the school library media specialist(SLMS)'s certification in the United States. The content includes development of the SLMS certification, certification requirements, titles, preparatory education programs especially accredited by ALA and NCATE, personnel standards and regulations of states. The basic certification requirements are teacher certification and/or MLIS(MLS), but varying from state to state. Personnel standards are regulated by the Education Department of states, otherwise regional associations of colleges and schools. Nineteen states have the standards and three regional associations among six have very specified ones. The paper also analyzes NBPTS for Library Media and discussions on '65% Solution' which is an education reform movement affecting school library seriously.

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