• Title/Summary/Keyword: N-complex

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Synchronization in Complex Systems

  • Bae, Young-Chul;Kim, Chun-Suk;Koo, Young-Duk
    • Journal of information and communication convergence engineering
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    • v.2 no.4
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    • pp.237-242
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    • 2004
  • In this paper, we introduce a complex systems synchronization method using hyper-chaos circuit consist of State-Controlled Cellular Neural Network (SC-CNN). We make a complex systems using SC-CNN with the n-double scroll. A complex system is created by applying identical n-double scroll or non-identical n-double scroll and Chua's oscillator with weak coupled method to each cell. Complex systems synchronization were achieved using GS(Generalized Synchronization) method between the transmitter and receiver about each state variable in the SC-CNN.

Near-IR Spectroscopic Studies of the Hydrogen Bonding between Thioacetamide and N,N-Dimethylacetamide in $CCl_4$ ($CCl_4$중에서 Thioacetamide와 N,N-Dimethylacetamide사이의 수소 결합에 관한 분광학적인 연구)

  • Kang Bong Lee;Byung-Chul Kim;Chang-ju Yun;O. D. Bonner;Young-Sang Choi
    • Journal of the Korean Chemical Society
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    • v.30 no.6
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    • pp.510-515
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    • 1986
  • Spectra for the $v_3$+ Amide II combination band of thioacetamide(TA) were obtained in carbon tetrachloride solutions and in very dilute solutions of TA-N,N-dimethlylacetamide (DMA) in carbon tetrachloride in the range of 5~55$^{\circ}$C. The combination band in the three component system can be resolved into components due to monomeric TA, 1 : 1 TA-DMA complex and 1 : 2 TA-DMA complex. In the dilute solutions the experimental spectrum was resolved by using the computer into its two Lorentzian-Gaussian product components which have been identified with the monomeric TA and the 1 : 1 complex. The equilibrium constants and thermodynamic parameters of 1 : 1 complex were determined by analysis of concentration and temperature dependent spectra. The ${\Delta}H^{\circ}$ and ${\Delta}S^{\circ}$ for the 1 : 1 complex were -14.4 KJ mol$^{-1}$ and -15.6 J mol$^{-1}deg^{-1}$, respectively.

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Spectrophotometric Study of Copper Complex of N-Benzylisonitrosoacetylacetone Imine (N-Benzylisonitrosoacetylacetone Imine의 구리착물에 대한 분광광도법적 연구)

  • Byung Kyo Lee;Dae Sub O;Heung Rak Lee
    • Journal of the Korean Chemical Society
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    • v.30 no.2
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    • pp.201-206
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    • 1986
  • A new analytical reagent N-benzylisonitrosoacetylacetone imine (H-IAA-N-Bz) has been synthesized and identified its structure by IR, NMR and mass spectra. H-IAA-N-Bz forms a copper chloroform-soluble complex in a basic aqueous solution (pH = 7.0∼10.0). The other optimum conditions for the spectrophotometric study of the copper complex have been determined at 420nm. Beer's law is obeyed below the concentration of 64$\mu$g of copper per 10ml of chloroform. The composition of the copper complex has been found to be $Cu(IAA-N-Bz)_2$ and the over-all stability constant is calculated to be $8.55 {\times} 10^6$. The molar absorption coefficient, $\varepsilon$ of the $Cu-(IAA-N-Bz)_2 $complex is 3500l/$cm{\cdot}mol$.

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Cobalt(III) Complex of Ethylenediamine-N,N'-di-${\alpha}$-Isobutyric Acid (Ethylenediamine-N,N'-di-${\alpha}$-Isobutyric Acid의 코발트(III) 착물)

  • Moo-Jin Jun;Chang-Yoon Han;Chang-Woo Park;Sung Rack Choi;Kwang-Ha Park
    • Journal of the Korean Chemical Society
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    • v.30 no.1
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    • pp.84-89
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    • 1986
  • A newflexible $N_2O_2$-type tetradentate ligand. Ethylenediamine-N,N'-di-${\alpha}$-isobutyric acid(eddib), has been synthesized, and dichloro cobalt(III) complex of eddib has been prepared via the air-oxidation technique. Only S-cis isomer has been yielded during the preparation of complex. Ring strain and steric hinderance are cited as the cause for the preference for the S-cis geometric configuration. On series of cobalt(III) complexes of eddib, $[Co(eddib)L]^{n+}$ $(L = Cl{\cdot}(H_2O),\;CO_3^{2-},\;(H_2O)_2)$have been prepared in situ. In their electronic absorption spectra, the absorption maxima and their intensities of the above series of complexes are on the ordinary line of the spectrochemical and hyperchromic series. Elemental analysis, IR, NMR and electronic absorption spectra have been used to characterize the complex and geometries of the complex.

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AN ESCAPE CRITERION FOR THE COMPLEX POLYNOMIAL, WITH APPLICATIONS TO THE DEGREE-n BIFURCATION SET

  • Kim, Young Ik
    • Journal of the Chungcheong Mathematical Society
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    • v.16 no.1
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    • pp.7-14
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    • 2003
  • Let $P_c(z)=z^n+c$ be a complex polynomial with an integer $n{\geq}2$. We derive a criterion that the critical orbit of $P_c$ escapes to infinity and investigate its applications to the degree-n bifurcation set. The intersection of the degree-n bifurcation set with the real line as well as with a typical symmetric axis is explicitly written as a function of n. A well-defined escape-time algorithm is also included for the improved construction of the degree-n bifurcation set.

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ON SOME CR-SUBMANIFOLDS OF (n-1) CR-DIMENSION IN A COMPLEX PROJECTIVE SAPCE

  • Kwon, Jung-Hwan
    • Communications of the Korean Mathematical Society
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    • v.13 no.1
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    • pp.85-94
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    • 1998
  • The purpose of this paper is to give sample characterizations of n-dimensional CR-submanifolds of (n-1) CR-semifolds of (n-1) CR-dimension immersed in a complex projective space $CP^{(n+p)/2}$ with Fubini-Study metric and we study an n-dimensional compact, orientable, minimal CR-submanifold of (n-1) CR-dimension in $CP^{(n+p)/2}$.

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A Study on Complex Formation of Heavy Metal Ions with N,N'-Oxalybis(salicylaldehyde hydrazone) (N,N'-Oxalylbis(salicylaldehyde hydrazone)과 중금속이온과의 착물 형성에 관한 연구)

  • Kyu-Seong Choi;Ick-Hee Lee;Yong-Nam Kim
    • Journal of the Korean Chemical Society
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    • v.35 no.2
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    • pp.135-141
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    • 1991
  • The complexation of N,N'-oxalylbis(salicylaldehyde hydrazone) (OBSH) with Zn (II), Cd (II), and Pb(II) ions was studied by polarographic method in DMSO solution. The order of stability constants was Cd(II) < Zn(II) < pb(II), and all heavy metal ions formed stable complex with OBSH ligand. The stability constants of complexation were measured at various temperatures. As the results, enthalpy and entropy changes of the complexation were distributed on the complex stabilities.

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ON THE SIMPLICIAL COMPLEX STEMMED FROM A DIGITAL GRAPH

  • HAN, SANG-EON
    • Honam Mathematical Journal
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    • v.27 no.1
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    • pp.115-129
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    • 2005
  • In this paper, we give a digital graph-theoretical approach of the study of digital images with relation to a simplicial complex. Thus, a digital graph $G_k$ with some k-adjacency in ${\mathbb{Z}}^n$ can be recognized by the simplicial complex spanned by $G_k$. Moreover, we demonstrate that a graphically $(k_0,\;k_1)$-continuous map $f:G_{k_0}{\subset}{\mathbb{Z}}^{n_0}{\rightarrow}G_{k_1}{\subset}{\mathbb{Z}}^{n_1}$ can be converted into the simplicial map $S(f):S(G_{k_0}){\rightarrow}S(G_{k_1})$ with relation to combinatorial topology. Finally, if $G_{k_0}$ is not $(k_0,\;3^{n_0}-1)$-homotopy equivalent to $SC^{n_0,4}_{3^{n_0}-1}$, a graphically $(k_0,\;k_1)$-continuous map (respectively a graphically $(k_0,\;k_1)$-isomorphisim) $f:G_{k_0}{\subset}{\mathbb{Z}}^{n_0}{\rightarrow}G_{k_1}{\subset}{\mathbb{Z}^{n_1}$ induces the group homomorphism (respectively the group isomorphisim) $S(f)_*:{\pi}_1(S(G_{k_0}),\;v_0){\rightarrow}{\pi}_1(S(G_{k_1}),\;f(v_0))$ in algebraic topology.

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Charge Transfer Complex Formation of Amines with Organic Halides (I) (아민과 有機할로겐 化合物間의 Charge Transfer Complex 形成에 關한 硏究 (I))

  • Kim, Yoo-Sun;Oh, Jung-Hee
    • Journal of the Korean Chemical Society
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    • v.11 no.4
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    • pp.121-125
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    • 1967
  • The formation of a charge transfer complex between various amines and organic halogen compounds was closely investigated. A mixture of amine (piperidine, pyridine, diethylamine, ethylamine, triethylamine and triethanolamine) and organic halides(carbon tetrachloride and chloroform) was checked for its UV absorption spectrum in presence of n-hexane solvent. A red shift was observed. The formation of charge transfer complex was observed in the case of triethylamine and diethylamine, whereas the formation of contact complex was distinct in case of piperidine. The relation between the nucleophilicity of amines and their tendency of forming charge transfer complex was discussed.

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