• Title/Summary/Keyword: N-complex

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A Study on Antimicrobial Activity of N-(fluorodichlomethylthio) Phthalimide-Ag Complex of Reclaimed Rubber Mat (리사이클 고무 매트의 N-(fluorodichlomethylthio) Phthalimide-Ag Complex에 관한 항미생물 활성 연구)

  • Kim, Ki-Jun;Lee, Joo-Youb;Park, Tae-Sul
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.4
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    • pp.491-496
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    • 2011
  • N-(fluorodichlomethylthio) phthalimide-silver complexes were prepared and investigated the antimicrobial activity on rubber mat manufactured with waste rubber. We are exposed to harmful bacteria and fungi all the time. We manufactured antimicrobial mat to be imposed to mats that it can prevent generation of bacteria and microorganisms, and restrict their reproduction. Infection of medical devices causes significant morbidity and mortality. For aim of this study, we measured the antimicrobial mat manufactured with N-(fluorodichlomethylthio) phthalimide-Ag complex by CCD, FT-IR and NMR. The effect of mole ratio of N-(fluorodichlomethylthio) phthalimide-Ag complex on antibacterial activity to bacteria and fungi is investigated. Reduction rate is evaluated using the Quinn method. Escherichia Coli is effectively inhibited than Staphylococcus aureus by antimicrobial mat.

Acquisition of English Complex Predicates in SLA

  • Park, Hye-Son
    • English Language & Literature Teaching
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    • v.12 no.2
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    • pp.177-194
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    • 2006
  • Snyder (2001) proposes that complex predicate constructions are interrelated by shared dependence on a single parameter, the Compounding Parameter, and that the global application of the parameter explains the simultaneous acquisition of the complex predicate constructions and N-N compounds in L1 acquisition of English. Slabakova (2002) examined the status of the Compounding Parameter in the acquisition of L2 Spanish by instructed learners. The result of the study, however, was not compatible with the prediction of the Compounding Parameter, possibly due to the availability of negative evidence in the input. Building upon Slabakova's study, this paper examines the status of the Compounding Parameter in naturalistic L2 learning. It is shown that the naturalistic L2 learners do not acquire the complex predicate constructions and N-N compounds concurrently contra to the prediction of the Compounding Parameter. It is suggested that the validity of the Compounding Parameter as a theoretical construct be reconsidered.

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Coordination Modes and Properties of Ag(I) Complex with N,N,N',N',N''-Pentamethyldiethylenetriamine

  • Chun, In-Sung;Kwon, Jung-Ah;Bae, Myung-Nam;Lee, Sim-Seong;Jung, Ok-Sang
    • Bulletin of the Korean Chemical Society
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    • v.27 no.7
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    • pp.1005-1008
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    • 2006
  • The reaction of $AgClO_{4}$ with acyclic potential tridentate N,N,N',N',N''-pentamethyldiethylenetriamine (pmdeta) has given colorless crystals suitable for X-ray crystallography. The crystal structure ($P2_{1}$/n, a = 14.413(1) $\AA$, b = 25.270(2) $\AA$, c = 16.130(1) $\AA$, b = $103.012(1){^{\circ}}$, V = 5723.7(8) A$\AA^{3}$, Z = 4, R = 0.0349) has been solved and refined. Three silver(I) ions connect four pmdeta ligands to produce discrete complex of $[Ag_3(pmdeta)_4](ClO_4)_3$. A pmdeta ligand is bridged to three silver(I) ions, and three other pmdeta ligands are chelated to each silver(I) center in a tridentate mode. Thus, the product is a rare tri-nuclear silver(I) complex with two different chemical environments. $^{13}C$ NMR and $MAS\;^{13}$C NMR indicate that the tri-nuclear silver(I) complex is not rigid in solution. The contact angles and thermal analyses of the complex are measured and discussed.

Magnetic Field Structure and Formation Scenario of the N159/N160 Star-Forming Complex in the Large Magellanic Cloud

  • Kim, Jaeyeong;Jeong, Woong-Seob;Pyo, Jeonghyun;Pak, Soojong;Park, Won-Kee;Kwon, Jungmi;Tamura, Motohide
    • The Bulletin of The Korean Astronomical Society
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    • v.42 no.1
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    • pp.38.3-39
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    • 2017
  • The N159 and N160 ionized regions in the Large Magellanic Cloud are an important extragalactic star-forming complex. The physical environments and the star formation stages are different in N159 and N160. We performed near-infrared polarimetry to those star forming regions with IRSF/SIRPOL 1.4-m telescope. Near-infrared polarization enabled us to trace the detailed structure of magnetic fields in star-forming regions. Through the polarimetric data of J, H, and Ks bands, we examined the magnetic field structures in the N159/N160 complex. In this presentation, we show complex distribution of the magnetic fields associated with dust and gas structures. We verify the local magnetic fields in each star-forming region, which appear to be related with local environments, such as interior and boundary of shell structure, star-forming HII regions, and boundaries between HII regions and dense dark clouds. We discuss the formation scenario of the N159/N160 complex suggested from the magnetic field structure.

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COMPLEX FACTORIZATIONS OF THE GENERALIZED FIBONACCI SEQUENCES {qn}

  • JUN, SANG PYO
    • Korean Journal of Mathematics
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    • v.23 no.3
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    • pp.371-377
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    • 2015
  • In this note, we consider a generalized Fibonacci sequence {$q_n$}. Then give a connection between the sequence {$q_n$} and the Chebyshev polynomials of the second kind $U_n(x)$. With the aid of factorization of Chebyshev polynomials of the second kind $U_n(x)$, we derive the complex factorizations of the sequence {$q_n$}.

Kinetics for the Transformation of Outer Charge Transfer Complex to Inner Complex (Outer Charge Transfer Complex가 Inner Complex로의 변환에 따른 속도론적 연구)

  • Kwon Oh-Yun;Paek U-Hyon;Kim Eung-Ryul
    • Journal of the Korean Chemical Society
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    • v.35 no.4
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    • pp.343-349
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    • 1991
  • Formation of charge transfer complex between iodine and substituted aniline [aniline, N,N-dimethylaniline(N,N-DMA), 2,6-dimethylaniline(2,6-DMA), 2,4,6-trimethylaniline(2,4,6-TMA)] in CHCl$_3$, CH$_2$Cl$_2$ : CHCl$_3$ (1 : 1), and CH$_2$Cl$_2$ have been studied kinetically by using conductivity method. In the transformation of initially formed outer charge transfer complex to inner complex, the effects of substituted aniline as electron donor and polar medium on the reaction were investigated. The rate of transformation depend on the dielectric contribution of medium and pK$_a$ value of substituted aniline. The order of rate increasing is 2,4,6-TMA, 2,6-DMA, aniline, and N,N-DMA. The activation enthalpy ${\Delta}H^{\neq}$ for 2.5 M-substituted aniline in CHCl$_3$ at 25$^{\circ}C$ is respectively N,N-DMA, 3.47 kcal/mol; aniline, 4.25 kcal/mol; 2,6-DMA, 7.79 kcal/mol and 2,4,6-TMA, 7.96 kcal/mol; and activation entropy ${\Delta}S^{\neq}$ is large and negative value of -41 ~ -55 cal/mol${\cdot}$K.

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Cobalt(III) Complex of Ethylenediamine-N,N'-di-S-${\alpha}$-Propionic Acid (Ethylenediamine-N,N'-di-S-${\alpha}$-Propionic Acid의 코발트(III) 착물)

  • Moo Jin Jun;Yoon Bong Park;Chang Yun Han;Sung Rack Choi
    • Journal of the Korean Chemical Society
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    • v.29 no.3
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    • pp.247-251
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    • 1985
  • Dichloro cobalt(III) complex of a flexible tetradentate ligand of ethylenediamine-N,N'-di-S-${\alpha}$-propionic acid (eddp) has been prepared via the air-oxidation technique. Only ${\Delta}$-cis isomer has been yielded showing high stereoselectivity of the eddp ligand. Elemental analysis, ir, nmr and electronic absorption spectra have been used to characterize the complex and the absolute configuration of the complex is assigned by means of the nmr spectroscopy.

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A Fast IFFT Algorithm for IMDCT of AAC Decoder (AAC 디코더의 IMDCT를 위한 고속 IFFT 알고리즘)

  • Chi, Hua-Jun;Kim, Tae-Hoon;Park, Ju-Sung
    • The Journal of the Acoustical Society of Korea
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    • v.26 no.5
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    • pp.214-219
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    • 2007
  • This paper proposes a new IFFT(Inverse Fast Fourier Transform) algorithm, which is proper for IMDCT(Inverse Modified Discrete Cosine Transform) of MPEG-2 AAC(Advanced Audio Coding) decoder. The $2^n$(N-point) type IMDCT is the most powerful among many IMDCT algorithms, however it includes IFFT that requires many calculation cycles. The IFFT used in $2^n$(N-point) type IMDCT employ the bit-reverse data arrangement of inputs and N/4-point complex IFFT to reduce the calculation cycles. We devised a new data arrangement method of IFFT input and $N/4^{n+1}$-type IFFT and thus we can reduce multiplication cycles, addition cycles, and ROM size.

Study on the Cu/polyimide interface using XPS: Initial growth of Cu sputter-deposited on the polyimide at room temperature (I) (XPS를 이용한 Cu/Polyimide 계면에 관한 연구 : 상온에서 증착한 Cu의 초기성장과정(I))

  • 이연승;황정남
    • Journal of the Korean Vacuum Society
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    • v.6 no.3
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    • pp.187-193
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    • 1997
  • We investigated the initial growth mode of Cu deposited on polyimide at room temperature using x-ray photoelectron spectroscopy. We could find that when Cu is sputter-deposited on the polymide, Cu-N-O complex of strong interaction is mainly formed first, Cu-oxide of weak interaction is formed successively, and then finally metallic Cu grow. From these results, we could conclude that Cu/polyimide interface consists of Cu-N-O complex and Cu-oxide.

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