• Journal of the Korean GEO-environmental Society
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• v.7 no.6
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• pp.5-12
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• 2006

This study was conducted to investigate the effect of operational parameters such as dosage of magnesium and phosphate, pH, reaction time and existence crystal core for the removal of nitrogen and phosphorus in anaerobic fermentation supernatant by struvite crystallization. Optimal mole ratio of $Mg^{2+}:NH_4{^+}:PO_4{^{3-}}$ was 1.2:1.0:1.2. Under the optimal molar ratio, removal ratio and reaction rate constant of $NH_4{^+}-N$ and $PO_4{^{3-}}-P$ were 79.2, 96.8%, 0.157 and $0.344min^{-1}$, respectively. Optimal pH and reaction time were 11 and 10 minutes, respectively, in the optimal molar ratio. Residual concentration of $NH_4{^+}-N$ and $PO_4{^{3-}}-P$ showed lowest value with 1 g/L of crystal core addition. SEM analysis of struvite crystallization with crystal core showed higher crystal core growth than that of without crystal core. Struvite precipitate proved to be orthorhomic crystal structure by XRD analysis.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2006.04a
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• pp.402-406
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• 2006

The physical and chemical characteristics of ALC were analyzed and showed 2.2 of specific gravity and 9.05 of pH. The results of leaching tests with standard method for soil and waste indicated heavy metals(Cu, Cd, Pb, $Cr^{6+}$) were under maximum concentration level. The anaerobic digestion sludge was attached in the surface of ALC within 90 hours. As the results of batch test, pH of the ALC and Bio-ALC were decreased from initial pH of ALC to 8.7 and 7.8 respectively Also, the concentration of heavy metals was rapidly eliminated in the solution with the batch test. The result of column experiment indicates that the removal efficiency of ALC was showed 66% of T-P, 60% of T-N, and 67% of CODcr. Also, removal efficiency of Bio-ALC was slightly higher than that of ALC in T-N (64%) and CODcr (74%).

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.5
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• pp.929-936
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• 2011

To treat non-point source pollution in Dongbok lake, removal efficiencies of pollutants were investigated in Dongbokcheon constructed wetlands (CWs) at different treatment time and wastewater loading. The wetlands consisted of forebay, wetlands ($1^{st}$, $2^{nd}$, $3^{rd}$, $4^{th}$, $5^{th}$, $6^{th}$, $7^{th}$, and $8^{th}$ wetlands) and sedimentation pond. The concentrations of BOD, SS, T-N, and T-P in inflow ranged $0.85{\sim}3.14mg\;L^{-1}$, $3.33{\sim}9.70mg\;L^{-1}$, $0.64{\sim}5.33mg\;L^{-1}$, and $0.03{\sim}0.10mg\;L^{-1}$ from April to October in 2008, respectively. The removal rates of BOD, SS, T-N, and T-P in Dongbokcheon CWs were 34%, 5%, 31%, and 13%, respectively. The removal rates of BOD and T-N were higher than those for SS and T-P. The amounts of pollutant removal in Dongbokcheon CWs were higher in the order of forebay > wetlands > sedimentation pond for BOD, sedimentation pond > wetlands > forebay for SS, sedimentation pond > forebay > wetlands for T-N. The amount of T-P removal in wetlands was higher than forebay and sedimentation pond.

• Journal of Korean Society of Water and Wastewater
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• v.22 no.2
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• pp.179-182
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• 2008

The KIDEA process, occurred in single reactor, is operated by three consequential steps, i.e., aerobic, settling, and discharge while introducing wastewater into the bottom of reactor continuously. It could accomplish biological oxidation (BOD), nitrification, denitrification (T-N), phosphate removal (T-P), and solid separation (SS) through the operational mode mentioned. Especially, this system has removed the T-P by wasting certain amount of sludge at the end of aeration phase during 5~10 minutes and not returned the activated sludge into the reactor, that is, no RAS (Return Activated Sludge). All running mode and instrumentation were controlled by the PLC equipment automatically. In this study, therefore, we have evaluated T-P removal efficiency and moisture content (MC) performance under the different excess sludge wasting mode. T-P track study and MC with TS concentration were analyzed during aerobic and settling phase. It has revealed that there was no significant difference of released T-P concentration between the first case which waste the sludge at the end of aerobic phase (0.2mg/L) and the second case which waste the sludge at 40 min of settling phase (0.25mg/L). Also, dewatering duration and MC have decreased 1.7% when TS concentration was increased from 0.31% to 0.5% during aerobic condition. Hence, it has concluded the system performance was less influenced by the operation time change of PLC program.

• Journal of Environmental Health Sciences
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• v.27 no.1
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• pp.63-68
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• 2001

A laboratory experiment was performed to invstigate the nitrate removal using FeCl$_3$ -treated activated carbon. Iron chloride(III) was coated onto the surface of activated carbon. The removal efficiency of nitrate was increased with increasing of FeCl$_3$ was used for coating material. About 22~26mg of Fe per unit g of activated carbon was adsorbed. The nitrate removal was not affected by the pH under the experiment range of pH, but the pH value in solution decrease to 3.5~4.0 after reaction. The removal efficiency of nitrate was increased with increasing of dosage of adsorbents. Ammonia was not detected and the Fe concentration as low as 0.22mg/$\ell$ was desorbed from the adsorbents. The adsorbents was regenerated using KCl solution, and recovery was 76.6% at 1 M of KCl. The adsorption of nitrate by FeCl$_3$-treated activated carbon followed the Freundlich isotherm equation and the Freundlich constant, 1/n, was 0.346. These results showed that the FeCl$_3$-treated activated carbon could serve as the basis of a useful nitrate removal.

• Korean Journal of Environmental Agriculture
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• v.19 no.5
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• pp.426-432
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• 2000

Field experiment was performed from August 1996 to December 1999 to examine the feasibility of constructed wetland system for sewage treatment in rural areas. A pilot system was installed in Konkuk University and the effluent of septic tank for school building was used as an influent to the wetland treatment basin. The system was composed of sand and reed, and operated continuously including winter time. Average removal rate of about 70% was observed for BOD, COD, and SS, about 50% for T-P, and about 25% for T-N. The reason for poor T-N removal might be due to high loading rate and short retention time. The system demonstrated satisfactory effluent concentration and stable performance in growing season. And it also worked adequately in wintertime even below $10^{\circ}C$ without freezing, and removal was still significant. The amount removed in BOD, COD, and SS was almost the same as in the growing season, and the amount removed in nutrients was about half of the one in growing season. Overall performance of the experimental system was compared with existing data base (NADB, 1994), and it was within the range of general system performance. As study period increased, removal rates for BOD, COD, SS, and T-P were consistently maintained and even enhanced, but removal rate for T-N decreased slightly. Wetland system was thought to be a feasible alternative for sewage treatment in rural area considering its low cost and low maintenance requirement. However, the effluent of the experimental wetland system often exceeded current effluent water quality standards, therefore, further treatment could be required if the effluent should be discharged to public waters. Wetland system of interest locates in rural area and is a part of rural ecosystem, therefore, ultimate disposal of reclaimed sewage for agricultural purpose or subsequent land treatment might be available and further research in this matter is recommended.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.2
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• pp.141-148
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• 2010

Feasibility of floating aquatic plants (Eichhornia crassipes and Water dropwort) was investigated in order to control of sewage depending on various initial loading in a lab scale test. In addition, field test was conducted to assess the uptake rate of nutrient by E. crassipes. Lab-scale test applying primary domestic effluent operated at 4 day HRT shows that the highest uptake rates were 1.06 g N/$m^2{\cdot}day$ and 0.39 g P/$m^2{\cdot}day$ in the E. crassipes reactor. BOD removal efficiency in E. crassipes reactor was as high as 80% when the loading value was lower than 185 kg BOD/$ha{\cdot}day$. While 70 ~ 80% removal efficiency of BOD was achieved when the loading value was lower 80 kg BOD/$ha{\cdot}day$ at the W. Dropwort reactor. Experiment results show that E.crassipes has a higher nutrients removal efficiency than W. dropwort under high pollutant loading. Input loadings of TN and TP should not exceed to 10 kg TN/$ha{\cdot}day$ and 2.0 kg TP/$ha{\cdot}day$ respectively to provide a 50% TN and 80% TP removal efficiencies using E. crassipes. The field test demonstrated that an annual yield of E. crassipes mass was estimated as a fresh weight of 30.9 $m^3/ha{\cdot}yr$. E. crassipes grown in field pads absorbed 76.7 kg N/$ha{\cdot}yr$ and 13.4 kg P/$ha{\cdot}yr$ as a dry weight.

• Membrane and Water Treatment
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• v.15 no.1
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• pp.1-9
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• 2024

Biological nutrient removal is gaining increasing attention in wastewater treatment plants; however, it is adversely affected by low temperatures. This study examined temperature effects on nutrient removal and morphological stability of the granular and denitrifying phosphorus accumulating organisms (PAO and DPAO, respectively) using sequencing batch reactors (SBRs) at 5, 10, and 20 ℃. Lab-scale SBRs were continuously operated using anaerobic-anoxic and anaerobic-oxic cycles to develop the PAO and DPAO granules for 230 d. Sludge granulation in the two SBRs was observed after approximately 200 d. The average removal efficiency of soluble chemical oxygen demand (SCOD) and PO₄^3--P remained >90% throughout, even when the temperature dropped to 5 ℃. The average removal efficiency of NO₃^--N remained >80% consistently in DPAO SBR. However, nitrification drastically decreased at 10 ℃. Hence, the removal efficiency of NH₄⁺-N was decreased from 99.1% to 54.5% in PAO SBR. Owing to the increased oxygen penetration depth at low temperatures, the influence on nitrification rates was limited. The granule in DPAO and PAO SBR was observed to be unstable and disintegrated at 10 ℃. In conclusion, morphological characteristics showed that changed conversion rates at low temperatures in aerobic granular sludge altered both nutrient removal efficiencies and granule formation.

• Korean Journal of Environmental Agriculture
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• v.27 no.1
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• pp.27-34
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• 2008

To effectively treat the domestic sewage that was produced on a small-scale in farming and fishing village in order to encourage an ecologically friendly environment, a small-scale sewage treatment apparatus using natural purification methods that consisted of an aerobic and an anaerobic plots were constructed. The efficiency of sewage treatment according to the sewage loading was investigated to obtain the optimum sewage loading in small-scale sewage treatment apparatus. Removal rate of pollutants according to the sewage loading were in the order of $150\;Lm^{-2}day^{-1}{\fallingdotseq}300\;Lm^{-2}day^{-1}>600\;Lm^{-2}day^{-1}$. Therefore, the optimum sewage loading was 300 L m-2 day-1. Under the optimum sewage loading, removal rate of BOD, $COD_{Mn}$, turbidity, T-N and T-P were 99, 94, 99, 49 and 89%, respectively. However, to satisfy the water quality standard in effluent in small-sclae sewage treatment apparatus for domestic sewage treatment, the low removal efficiency of T-N and T-P must be improved. So to improve the removal rate of T-N and T-P, the efficiency of sewage treatment according to the improved sewage treatment process such as, re-treatment at aerobic plot, anaerobic condition of aerobic plot, changing the filter media sizes and the depths in anaerobic plot, and also addition of oyster shells to filter media at anaerobic plot were investigated. In case of 150 cm depth in anaerobic plot with filter medium A (effectivity particle size 1.50 mm) and addition of oyster shells to filter media at anaerobic plot, removal rate of T-N and T-P in both plots were increased by 10 and 3%, and 14 and 7% in comparison with 100 cm depth in anaerobic plot with filter medium B(effectivity particle size 0.95 mm), respectively. The optimum improved sewage treatment process in small-scale sewage treatment apparatus were 150 cm depth in anaerobic plot with filter medium A and addition of oyster shells to filter media at anaerobic plot.

• Journal of Animal Science and Technology
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• v.45 no.5
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• pp.875-884
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• 2003

Operational parameters for struvite crystallization, as a process to recover nitrogen and phosphorus resources from animal wastewater, were studied in this research. Crystallization distinctive of NH$_4$-N and PO$_4$$^{3-}$ in accordance to chemical sources, influent pH, aeration and stirring was examined using 2L of working volume of struvite reactor. Also, to find an effective treatment process combining with electrolysis method, removal characteristics of NH$_4$-N and PO$_4$$^{3-}$ in 6 different processes was tested. As chemical sources for the derivation of struvite formation, MgSO$_4$ and MgCl$_2$ were superior to CaCO$_3$ and CaCl$_2$. From experiment which was conducted to know the effects of aeration and stirring on struvite formation, it was revealed that aeration stimulated the crystallization reaction by inducing faster pH increase. While 90% of P removal was achieved within 1 hour under aeration, 14 hours was consumed under stirring condition. Struvite formation under aeration was affected by influent pH. No crystallization was observed at pH 5 level, but active crystallization reaction was induced over pH 6.0. 95% of P removal by struvite formation at pH 6, 7 and 9 was achieved within 3h, 2h and 10 min., respectively. However, over pH 10, operational problem due to excessive foam formation occurred, and blunting of crystallization reaction was observed at pH 11. When consider the pH range of animal wastewater, pH 7 to 9, efficient struvite formation could be achieved by simple aeration, without any chemical usage for pH adjustment. Among tested processes, the treatment process which electrolyzing the supernatant from struvite reactor, providing air to both reactors, showed best pollutant removal efficiencies. In this combined process, the removal efficiencies of NH$_4$-N and PO$_4$$^{3-}$ was 86% and 98%, respectively, and 92.4% of color removal was obtained.