• 제목/요약/키워드: N $O_{}$ x/

검색결과 2,142건 처리시간 0.029초

Characterization and Potent Application of Pleurotus floridanus Trypsin Inhibitor (PfTI)

  • Pannippara, Manzur Ali;Kesav, Sapna;Raghavan, Rekha Mol Kollakal Naduvil;Mathew, Abraham;Bhat, Sarita Ganapathy;Kozhiyil, Elyas Kothanan
    • Natural Product Sciences
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    • 제26권3호
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    • pp.207-213
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    • 2020
  • Characterization and in vitro inhibition studies of protease inhibitor from the mushroom Pleurotus floridanus (PfTI) towards the pest Papilio demoleus is studied. The addition of 1 mM Mn2+, Na2+, Ba2+ and Ni 2+ enhanced the PfTI activity. The ICP-atomic emission spectrum showed the presence of Ca2+, Mg2+ and Zn2+ in the PfTI. Surfactants SDS and CTAB at a concentration of 1% reduced the PfTI activity whereas, the nonionic detergents Triton X and Tween 80 increased the activity. The inhibitory activity gradually decreased with increase in concentration of DMSO and H2O2. The activity was increased by dithiothreitol up to a concentration of 80 μM and inactivated at 140 μM. The activity of PMSF modified PfTI was drastically reduced to 0.234 U/mL at 4 mM concentration and similar results were obtained for modification of cysteine by N-Ethylmaleimide at slightly higher concentrations. The complex of trypsin and PfTI showed complete loss in fluorescence intensity at 343 nm compared with control. In vitro inhibition studies of PfTI with midgut proteases isolated from citrus pest P. demoleus with protease activity of 1.236 U was decreased to 0.613 U by 50 μL (0.1 mg/mL) of the inhibitor. Inhibitor was stable up to 0.04 M concentration of HCl.

APPLICATION OF MERGED MICROWAVE GEOPHYSICAL OCEAN PRODUCTS TO CLIMATE RESEARCH AND NEAR-REAL-TIME ANALYSIS

  • Wentz, Frank J.;Kim, Seung-Bum;Smith, Deborah K.;Gentemann, Chelle
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 2006년도 Proceedings of ISRS 2006 PORSEC Volume I
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    • pp.150-152
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    • 2006
  • The DISCOVER Project (${\underline{D}}istributed$ ${\underline{I}}nformation$ ${\underline{S}}ervices$ for ${\underline{C}}limate$ and ${\underline{O}}cean$ products and ${\underline{V}}isualizations$ for ${\underline{E}}arth$ ${\underline{R}}esearch$) is a NASA funded Earth Science REASoN project that strives to provide highly accurate, carefully calibrated, long-term climate data records and near-real-time ocean products suitable for the most demanding Earth research applications via easy-to-use display and data access tools. A key element of DISCOVER is the merging of data from the multiple sensors on multiple platforms into geophysical data sets consistent in both time and space. The project is a follow-on to the SSM/I Pathfinder and Passive Microwave ESIP projects which pioneered the simultaneous retrieval of sea surface temperature, surface wind speed, columnar water vapor, cloud liquid water content, and rain rate from SSM/I and TMI observations. The ocean products available through DISCOVER are derived from multi-sensor observations combined into daily products and a consistent multi-decadal climate time series. The DISCOVER team has a strong track record in identifying and removing unexpected sources of systematic error in radiometric measurements, including misspecification of SSM/I pointing geometry, the slightly emissive TMI antenna, and problems with the hot calibration source on AMSR-E. This in-depth experience with inter-calibration is absolutely essential for achieving our objective of merging multi-sensor observations into consistent data sets. Extreme care in satellite inter-calibration and commonality of geophysical algorithms is applied to all sensors. This presentation will introduce the DISCOVER products currently available from the web site, http://www.discover-earth.org and provide examples of the scientific application of both the diurnally corrected optimally interpolated global sea surface temperature product and the 4x-daily global microwave water vapor product.

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A Method for Absolute Determination of the Surface Areal Density of Functional Groups in Organic Thin Films

  • Min, Hyegeun;Son, Jin Gyeong;Kim, Jeong Won;Yu, Hyunung;Lee, Tae Geol;Moon, Dae Won
    • Bulletin of the Korean Chemical Society
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    • 제35권3호
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    • pp.793-797
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    • 2014
  • To develop a methodology for absolute determination of the surface areal density of functional groups on organic and bio thin films, medium energy ion scattering (MEIS) spectroscopy was utilized to provide references for calibration of X-ray photoelectron spectroscopy (XPS) or Fourier transformation-infrared (FT-IR) intensities. By using the MEIS, XPS, and FT-IR techniques, we were able to analyze the organic thin film of a Ru dye compound ($C_{58}H_{86}O_8N_8S_2Ru$), which consists of one Ru atom and various stoichiometric functional groups. From the MEIS analysis, the absolute surface areal density of Ru atoms (or Ru dye molecules) was determined. The surface areal densities of stoichiometric functional groups in the Ru dye compound were used as references for the calibration of XPS and FT-IR intensities for each functional group. The complementary use of MEIS, XPS, and FT-IR to determine the absolute surface areal density of functional groups on organic and bio thin films will be useful for more reliable development of applications based on organic thin films in areas such as flexible displays, solar cells, organic sensors, biomaterials, and biochips.

중.고등학교 여학생의 의생활태도에 관한 연구 (A Study on Clothing Attitudes of Middle and High School Girls)

  • 최은영;전경란
    • 한국가정과교육학회지
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    • 제12권1호
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    • pp.75-87
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    • 2000
  • The purpose of this study is to find out how middle and high school girls show their clothing attitudes and their life-style. clothing behavior. use their ornaments according to demographic variables. The subject of this study consists o 345 middle and high school girls living in Chung-Nam Province and Taejon Metropolitan City. SPSS/PC+ program was utilized to calculate frequency(N) mean value(M) and standard deviation (SD) for statistical analysis. Differences among the populations are examined through t-test. F-test and X2-test. The results of this study are as follow : 1. Correlation between the life style and demographic variables. Especially. life-style has significant difference(p<. 05) according to type of school. middle school girls have high tendency in the type of modern and fashion. Life-style has significant difference(p< .01) according to level of achievement studying, high level girls has high tendency in the type of practical and secure. 2. Correlation between the clothing behavior and demographic variables. According to type of school. middle school girls showed higher than high school girls in clothing conformity and clothing aesthetics. According to level of achievement studying, high level girls have high tendency in clothing conformity and clothing modesty. 3. Correlation between the use their ornaments and demographic variables. Buying the ornaments, higher-level achievement studying girl’s get information in show window. but lower-level achievement studying girl’s get information in TV or radio. The use of ornaments according to the site of school, most of school girls who live in small city or town use the ornaments as usual school life but school girls who live in big city use the ornaments to look good on their clothes. Following suggestions can be made based on the discussions above: It is necessary for us to have correct understanding about the correlation between the ornaments and clothing of school girls in order to lead them to have appropriate clothing behavior. Furthermore. it is required to construct a bridge linking a course of study to rational habits guidance which will provide us more appropriate tools for clothing behavior guidance.

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SULEV LPG 자동차의 배출가스 저감효과 평가 (Estimation on the Emission Reduction of SULEV LPG Vehicles)

  • 박준홍;이종태;김선문;김정수;강대일;임윤성;한보영
    • 한국대기환경학회지
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    • 제28권1호
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    • pp.68-76
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    • 2012
  • SULEV (Super Ultra Low Emission Vehicle) which is one of the emission standards in Fleet Average System introduced to Korea from 2009 is known as the most severe standard to achieve with internal combustion engine. Considering low sales volume of hybrid vehicles in Korea, vehicle manufacturers are required to develop SULEV technologies for conventional gasoline and LPG vehicles to meet the future Fleet Average standard. In this study, the comparison of emissions has been made between SULEV developed and ULEV LPG vehicles mainly produced in this time. To estimate the emission reduction of SULEV vehicles, CVS-75 and NIER test modes have been used. CVS-75 has been used for emission certification of gasoline and LPG vehicles. NIER modes cover various average vehicle speed and reflect Korean real driving patterns better than CVS-75. The test results show that SULEV LPG vehicles have very high potential to reduce $NO_x$ in regulated emissions, $N_2O$ in green house gases and toluene in VOCs. However, SULEV LPG vehicles don't affect much on the reduction of CO and total green house gases.

Origin of High Critical Current density in $MgB_2$ thin films

  • Kang, W.N.;Kim, Hyeong-Jin;Park, Eun-Mi;Kim, Mun-Seong;Kim, Kijoon H. P.
    • Progress in Superconductivity
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    • 제3권2호
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    • pp.135-139
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    • 2002
  • We have fabricated high-quality c-axis-oriented $MgB_2$ thin films by using a pulsed laser deposition technique. The thin films grown on (1 1 0 2) $Al_2$$O_3$ substrates show an onset transition temperature of 39.2 K with a sharp transition width of ~0.15 K. X-ray diffraction patterns indicate a c-axis-oriented crystal structure perpendicular to the substrate surface. We observed high critical current densities ($J_{c}$) of ~ 16 $MA/\textrm{cm}^2$ at 15 K and under self-field, which is comparable to or exceeds those of cuprate high-temperature superconductors. The extrapolation $J_{c}$ at 5 K was estimated to be ~ 40 MA/$\textrm{cm}^2$, which is the highest record for $MgB_2$ compounds. At a magnetic field of 5 T, the $J_{c}$ of~ 0.1 $MA/\textrm{cm}^2$ was detected at 15 K, suggesting that this compound is very promising candidate for the practical applications at high temperature with lower power consumption. As a possible explanation for the high current-carving capability, the vortex-glass phase will be discussed.d.d.d.

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The electronic structure of the ion-beam-mixed Pt-Cu alloys by XPS and XANES

  • Lim, K.Y.;Lee, Y.S.;Chung, Y.D.;Lee, K.M.;Jeon, Y.;Whang, C.N.
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 1998년도 제14회 학술발표회 논문개요집
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    • pp.133-133
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    • 1998
  • In the thin film alloy formation of the transition metals ion-beam-mixing technique forms a metastable structure which cannot be found in the arc-melted metal alloys. Sppecifically it is well known that the studies about the electronic structure of ion-beam-mixed alloys pprovide the useful information in understanding the metastable structures in the metal alloy. We studied the electronic change in the ion-beam-mixed ppt-Ct alloys by XppS and XANES. These analysis tools pprovide us information about the charge transfer in the valence band of intermetallic bonding. The multi-layered films were depposited on the SiO2 substrate by the sequential electron beam evapporation at a ppressure of less than 5$\times$10-7 Torr. These compprise of 4 ppairs of ppt and Cu layers where thicknesses of each layer were varied in order to change the alloy compposition. Ion-beam-mixing pprocess was carried out with 80 keV Ae+ ions with a dose of $1.5\times$ 1016 Ar+/cm2 at room tempperature. The core and valence level energy shift in these system were investigated by x-ray pphotoelectron sppectroscoppy(XppS) pphotoelectrons were excited by monochromatized Al K a(1486.6 eV) The ppass energy of the hemisppherical analyzer was 23.5 eV. Core-level binding energies were calibrated with the Fermi level edge. ppt L3-edge and Cu K-edge XANES sppectra were measured with the flourescence mode detector at the 3C1 beam line of the ppLS (ppohang light source). By using the change of White line(WL) area of the each metal sites and the core level shift we can obtain the information about the electrons pparticippating in the intermetallic bonding of the ion-beam-mixed alloys.

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플라즈마 처리에 의한 원뿔형 다중벽 탄소나노튜브 다발의 형성기전

  • 임선택;김곤호
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2010년도 제39회 하계학술대회 초록집
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    • pp.129-129
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    • 2010
  • 플라즈마 처리를 통하여 수직 합성된 다중벽 탄소나노튜브가 원뿔형 다발이 될 수 있으며 원뿔형 탄소나노튜브 다발은 기존의 구조적, 기계적 성질의 향상과 더불어 향상된 전계방출 능력을 가질 것으로 기대되어 이를 X-선원, 전계방출디스플레이(FED), 유기발광다이오드(OLED) 백라이트 등의 전자빔 원으로 적용하기 위한 연구가 진행되고 있다. 원뿔형 탄소나노튜브 다발의 형상 제어를 통하여 전계방출특성을 향상시킬 수 있으며 이를 위해 원뿔형 탄소나노튜브 다발이 생성되는 메커니즘과 조사되는 플라즈마의 역할에 대해서 이해하는 것이 중요하다. 본 연구에서는 플라즈마 생성부와 조사부를 분리한 유도결합형 플라즈마 원을 사용하여 입사되는 이온의 에너지, 조사량, 입자 종을 독립적으로 제어하였고 이를 통하여 원뿔형 탄소나노튜브 다발이 형성되는 메커니즘과 플라즈마의 역할을 밝혀내었다. 알곤 및 수소 플라즈마 처리에서는 원뿔형 탄소나노튜브 다발이 형성되지 않았으나 질소 및 산소 플라즈마 처리에서는 원뿔형 탄소나노튜브 다발이 형성되었다. 특히 산소 플라즈마 처리가 원뿔형 탄소나노튜브 다발 형성에 효과적이었다. 원뿔형 탄소나노튜브 다발의 형성 메커니즘은 탄소나노튜브의 분극과 쉬스 전기장의 상호작용을 이용한 모델을 사용하여 설명하였다. 질소 및 산소 플라즈마 처리에서는 탄소나노튜브 끝단에 생성되는 C-N, C-O 결합에 의해 향상된 유도 쌍극자와 쉬스 전기장에 의해 탄소나노튜브 끝단이 모여 원뿔형 탄소나노튜브 다발이 생성됨을 밝혀내었다. 산소 플라즈마 처리에서 입사되는 이온의 에너지 조절에 의한 쉬스 전기장 조절과 조사량 조절을 독립적으로 수행하여 원뿔형 탄소나노튜브 다발의 직경 및 높이가 쉬스 전기장 및 조사량에 따라 조절 가능함을 보였다. 이로부터 입사되는 이온의 입자 종, 쉬스 전기장 및 조사량 조절 등의 플라즈마 인자 조절을 통하여 원뿔형 탄소나노튜브 다발의 형상 제어가 가능함을 보였다. 탄소나노튜브의 형상 제어와 더불어 세슘 입자 삽입을 통한 탄소나노튜브의 일함수 감소를 통하여 향상된 전계 방출 특성을 갖는 탄소나노튜브 팁의 제조 가능성을 확인하였다.

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헬륨냉동계통의 헬륨가스 순도 제어 운전

  • 최호영;손우정;이문;안국훈
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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    • pp.171-171
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    • 2011
  • 헬륨냉동계통은 연구용 원자로인 하나로에서 냉중성자를 생산할 수 있도록 설치된 수조내기기 내의 감속재인 수소가 정상적으로 열 사이펀을 유지하기 위한 주요 계통이다. 헬륨냉동계통은 헬륨가스를 압축하는 헬륨 압축부분과 헬륨가스를 팽창시켜 저온을 생성시키는 헬륨 팽창부분으로 나누어진다. 헬륨 압축부분은 두 개의 스크류가 맞물려 회전하면서 약 1.05 bar(a)의 헬륨가스를 최대 13 bar(a)까지 압축시키는 압축기가 있으며, 헬륨 팽창부분인 냉동박스의 팽창 터빈은 self-acting gas bearing에 의해 구동되며, 저온모드 운전 시작시 헬륨 압축부분에서 일부의 가스는 팽창 터빈 축(shaft)으로 유입되어 회전속도가 서서히 증가하면서 고속으로 회전하여 극저온의 헬륨가스(14~18 K)를 생성하는 주요 기기이다. 헬륨을 팽창하는 부분인 냉동박스 내로 헬륨 압축가스를 유입하기 전에 압축된 헬륨가스 내 불순물의 순도를 분석하여 냉동박스의 주요 부품인 팽창터빈의 운전에 영향을 미치지 않는 것이 가장 중요하다. 따라서 헬륨 저압측에 헬륨가스 내 불순물 즉, 수소($H_2$), 수분($H_2O$), 질소($N_2$), 탄화수소류(CxHy) 및 오일(Oilaerosol) 등의 함량을 분석하기위해 가스 분석기가 설치되어 있으며, 냉동박스 내로 유입되기 전에 헬륨압축에서 순환되는 가스 내 불순물인 수분, 질소, 탄화수소류 및 오일은 10 vpm 이하이어야 하며, 수소 함량은 0.1 % 이내이어야 한다. 헬륨 압축부분에서 순환되는 가스의 불순물이 요구 조건에 만족하도록 헬륨 고압측과 헬륨 저압측에 cryogenic adsorber를 설치하여 가스 내 불순물을 제거하는 가스순도제어 작업을 수행해야 한다. cryogenic adsorber를 사용하기 위해서는 장치 내의 불순 가스를 공정진공도(1.33 X $10^{-3}$ mbar) 이하로 진공배기하는 작업이 매우 중요하다. 이는 계통의 헬륨가스가 오염되지 않도록 하는 것으로 cryogenic adsorber 내에는 액체질소를 충전하여 액체질소 온도에 노출된 활성탄층을 헬륨가스가 흐르면서 수분, 질소, 탄화수소류 및 오일 등이 제거된다. 이 논문에서는 헬륨냉동계통의 가스 순도 제어 작업을 통해 헬륨가스의 순도가 요구조건 이하로 만족하며, 팽창 터빈의 운전에 영향을 미치지 않음을 기술하고자 한다.

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CO2를 포함한 Simulated-EGR 압축착화엔진에서 당량비 변화에 따른 성능 예측 (Performance Prediction according to Equivalence Ratio Change in Simulated-EGR Compression Ignition Engine Containing CO2)

  • 서현규
    • 한국분무공학회지
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    • 제25권1호
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    • pp.21-26
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    • 2020
  • The objective of this work is to numerically reveal the effect of equivalence ratio change on the simultaneous reduction of NOX and soot emissions from the simulated-EGR compression ignition engine containing CO2. An experiment was conducted by using a single-cylinder common-rail injection system engine, an intake control system, and exhaust emissions analyzers. The numerical analysis results were validated under the same experimental conditions. To investigate the effect of equivalence ratio by simulated-EGR containing CO2, the O2, N2, and CO2 mole fraction were changed in the initial air conditions to the cylinder. The results were analyzed in terms of peak cylinder pressure, indicated mean effective pressure, indicated specific nitrogen oxide, and indicated specific soot. It was revealed that ignition delay characteristics and heat release rate (ROHR) characteristics were not significantly different according to the equivalence ratio. However, as the equivalence ratio increased from 0.68 to 0.83, the maximum combustion pressure and IMEP decreased by about 6.5% and 9.4%, respectively. In the case of ISFC, as is well known, the trend is opposite of IMEP. In the case of ISNO, as the equivalence ratio increased, less NO was generated, and as the equivalence ratio increased by 0.05, the ISSoot value of about 10% increased.