• Resources Recycling
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• v.19 no.5
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• pp.68-74
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• 2010

The aim of this study is to investigate the behaviors of synthesis of Calcium Chloroaluminte($11CaO{\cdot}7Al_2O_3{\cdot}CaCl_2$) under the melting temperature of municipal solid waste incineration fly ash(MSWI fly ash); $900^{\circ}C-1300^{\circ}C$ of sintering temperature. A sludge generated from a water purification plant (SW) was also used to fill up $Al_2O_3$ source, which might be deficient in MSWI fly ash. MF and SW were mixed at mixing ratio of 10 to 7, which is the mole ratio of CaO to $Al_2O_3$ of calcium Chloroaluminte. Mixed samples were sintered in the opened sintering reactor and the closed sintering reactor, respectively. The results showed that calcium chloroaluminte was formed at $1,000^{\circ}C$ in both reactors, but the temperature of decomposition of calcium chloroaluminte depended upon sintering reactor type; an opened sintering reactor and a closed sintering reactor, owing to the vaporization velocity of Cl.

• Journal of the Korea Organic Resources Recycling Association
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• v.14 no.1
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• pp.139-150
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• 2006

Landfilling is one of the most widely used methods for the final disposal of solid wastes. Landfilled wastes are degraded by residing microorganisms and the microbial degradation is affected by many factors such as moisture, oxygen, pH, alkalinity, sulphate, nutrient, temperature, and so on. Especially among these factor, oxygen and moisture within aerobic landfill play a major role in microbial degradation. In this study, 1) the effects of oxygen on the velocity of waste degradation and 2) the effect of moisture on the degradation of municipal solids waste (MSW) in aerobic condition were investigated. It was found that the BOD and CODcr concentration from the leachate of aerobic lysimeters dropped faster by 80 days after the start of the test compared to those from the anaerobic lysimeters. To see the effect of moisture, four aerobic lysimeters filled with MSW and four different levels of moisture (20, 30, 40, and 50%) were installed. From this test, higher moisture in MSW produced higher $CO_2$ concentration, meaning moisture was effective for the microbial degradation. thus, we concluded that higher moisture level in the aerobic landfill might help early-stabilization microbial degradation.

• Analytical Science and Technology
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• v.14 no.3
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• pp.274-285
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• 2001

In this study, the thermal desorption-cryofocusing-gas chromatographic(TD-C-GC) method was developed for determination of volatile organic compounds(VOCs) in ambient air and was applied at the municipal solid waste landfill sites. On-column cryofocusing was possible only with a 100 ml dewars bottle in TD-C-GC method with a stainless steel column. However, high operating pressure was needed for purging VOCs from the absorbent trap, which was able to solve by pressure programming with a electric pressure controller. By using both pressure and temperature programming brought increasing of resolution power in on-column cryofocusing method, but the high pressure caused a leakage of sample tube with repeated use. A loop cryofocusing devise was also developed and compared with the direct on-column method. In loop cryofocusing method, VOCs were concentrated on a 0.8mm i.d. loop which is located between the injector and separation column by using liquid nitrogen. In order to purge VOCs from the absorbent trap, only 0.4 psi of pressure was need in the loop cryofocusing method. Dual detection system was applied for the analysis of VOCs; a FID was used for hydrocarbons and a FPD was used for sulfur-containing compounds. Qualitative analysis was done by on-column cryofocusing GC-MS system. Among the large number of VOCs, toluene was the most abundant. Hydrogen sulfide, dimethyl sulfide, carbon disulfide, dimethyl disulfide and methyl propyl disulfide were detected at landfill site by FPD.

• Journal of Environmental Impact Assessment
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• v.6 no.1
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• pp.105-110
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• 1997

Sanitary landfill is a general method as a final disposal of municipal solid waste(MSW), therefore leachate characteristics are very various as lime goes by because of highly concentrated organic acids are contained non biodegradable COD. So it is hard to abide by the mandatory standards of discharge eventhough applying the physicochemical and biological processes to treat the leachate. The process of treating leachate are determined by the degree of removal and components, but they are highly contained organic materials. It is a removal method to use jointly with the physicochemical process if the hard and fast rule is needed. The critical components of material are COD, ammonia, salts and heavy metals in the case of treating biologically. Biological process is to use metabolism of microorganism, therefore it is a desirable condition which heavy metals are not contained, because they acting as an inhibitor of enzyme. Of these are contained, organic decomposition and synthetic function of microorganisms decrease significantly. Consequently, this research paper lays emphasis on the concentration of heavy metals in leachate and for the purpose of forecasting the factors which are affecting the leaching of metalic waste in some degree, experimented the various reacting conditions. 1. When the concentration of heavy metals in leachate is in comparison with the level eluted after reaction, at pH 7.9 the result of reaction for PCB to CCL scrap showed that Zn, Mn, Cu was more eluted 11.6 times, 340.3 times, and 2,705.5 times respectively than the leachate undiluted solution. 2. At the condition of strong acid pH 4.7, the concentration of heavy metals in EM undiluted solution showed that Zn, Mn, Cu was more eluted 26.5 times, 147.3 times, and 3,656.3 times respectively than leachate undiluted solution. 3. When the ratio leachate to EM was 50 vs 50(V/V%), Mn was more eluted 198.7 times than leachate undiluted solution, but Zn and Cu do not show the meaningful results. 4. The color of landfill leachate was black-brown. And fulvic acid that is main ingredient of NBD COD contained, oxygen of 44~50%. For that reason, I estimated that the level of Zn, Mn, Cu was higher than the case of leachate. 5. COD of leachate from general landfill is difficult to remove. Because the solution of heavy metals is improved by the character of leachate(pH & ingredient of oxygen etc.) hence the Mn, Cu, Zn act as disturbing factor, the biochemical treatment is hard. Therefore the type of PCB & CCL scrap, iron, aluminum contained metals need to previously separate from general wastes as much as possible.

• Resources Recycling
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• v.19 no.1
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• pp.40-48
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• 2010

It was investigated that effects of NaOH concentration on synthesis of mesoporous materials using municipal solid waste incinerator ash slag (MSWI-ash slag). In order to increase the purity and maximize the amount of extracted Si content the raw MSWI-ash slag was mechanically activated. Extraction of Si from the MSWI-ash slag was carried out by alkali treatment using concentrated NaOH solution, which varied from 1M to 4M. Physical properties (i.e., pore size, specific surface area and total pore volume) of the synthesized mesoporous silica were also evaluated as a function of NaOH concentration via BET, SEM, TEM and small-angle X-ray scattering analyses. Over the entire range of NaOH concentration investigated (i.e., 1-4M), the synthesized mesoporous materials were determined to be SBA-15, which exhibited a hexagonal structure with the pore size of approximately 7 nm. On the other hand, specific surface area and total pore volume increased with NaOH concentration up to 3M while the values decreased at 4M, indicating that the optimal NaOH concentration for the synthesized mesoporous silica was approximately 3M. Further comparison analysis between two conditions (3M versus 4M) showed that the decrease in two physical properties at 4M NaOH concentration was likely due to the potential inhibition by excess Na ions on the formation of mesophase and the consequent increase of pore wall thickness by remaining Si ions.

• Analytical Science and Technology
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• v.19 no.1
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• pp.86-95
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• 2006

This study was carried out to estimate leaching characteristics of incineration residues from municipal solid waste incinerators, and determine organic compounds in raw ash, leaching water and leaching residue. A total of 44 organic compounds, which were analyzed by GC/MSD and identified by wiley library search, were contained in bottom ashes. A total of 17 organic compounds were contained in fly ashes. Bottom ash and fly ash were found to contain a wide range of organic compounds such as aliphatic compounds and aromatic compounds. Organic compounds such as Ethenylbenzene, Benzaldehyde, 1-Phenyl-Ethanone and 1,4-Benzenedicarboxylic acid dimethyl ester were detected in raw ash, leaching water and residues (from bottom ash). Organic compounds such as Naphthalene, Dodecane, 1,2,3,5-Tetrachlorobenzene, Tetradecane, Hexadecane and Pentachlorobenzene were detected in raw ash, leaching water and residues (from fly ash). Through the leaching characteristics of incineration residue, it was represented that the open dumping of incineration residue can contaminate the soil and undergroundwater. In order to prevent environmental contamination that derived from extremely toxic substances in the incineration residues, it is particularly important that the incineration residues should be treated before disposal the incineration residues. Further study and proper management about leaching characteristics of organic compounds might be required.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.1
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• pp.93-100
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• 2005

Comparative thickening and dewatering characteristics of municipal wastewater sludge were investigated in terms of separated and combined treatment of primary and secondary BNR sludge. Also, various conditioning methods such as cation polymer addition, steam and ultrasonication treatment were examined to improve dewaterability of sludge. The dewaterability was measured by using specific resistant test, wedge zone simulator and centrifuge. The result of the sludge thickening test revealed that separated thickening was better in terms of solids recovery and supernatant quality. Particularly, the thickening of primary sludge with high solids (about 3.5% TS) showed very poor solid separation. The addition of cation polymer showed better conditioning characteristic for dewatering and the optimal polymer dosage was 0.26% for primary sludge, 0.43% for secondary sludge and 0.38% for combined sludge. Contrary to the result of the thickening, the dewatering test revealed that dewatering of the combined sludge is better than that of separated sludge, representing better solids separation and filtrate quality. The polymer addition was essential to improve dewaterability in filter (belt) press type dewatering but it was inefficient for the dewatering of secondary sludge only. The centrifuge type dewatering showed better performance and the dewaterability was slightly improved when the polymer was added. Based on the results of this research a sustainable sludge treatment process, particularly in terms of the recycle water quality and solids recovery, was proposed.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.6
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• pp.2833-2845
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• 2012

In this study, the amount of waste resource that could be recovered was analyzed. The installation and operation costs of waste resource recovery for both single- and multi-regional facility were calculated, and compared with the costs of landfill to investigate the feasibility of them. RDF(Refuse Derived Fuel) process and resource recovery by incineration process were considered as waste resource recovery facility. And, the multi-regions for cost analysis were established on the basis of the proper generation rate of municipal waste with the consideration of combustible ratio. The study results showed that single region facility for both RDF and incineration process has no economic benefit, compared with the landfill method. For the multi-regional facility, RDF process could save a large cost than the landfill method, but the incineration facility couldn't. Separate from the economic benefits, the waste resource recovery should be importantly considered when considering the depletion of fossil fuel, global warming, environmental toxicity, and the enormous expenses due to social conflict and confuse. When the CDM(Clean Development Mechanism) is vitalized in the near future, the additional economic benefits by CERs(Certified Emission Reductions) could be expected. CERs for RDF facility is corresponding to about 256.5 billion won, and CERs for incineration facility is corresponding to about 54 and 77.4 billion won for single- and multi-regional facility, respectively.

• Journal of Korean Society of Environmental Engineers
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• v.36 no.3
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• pp.172-177
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• 2014

Low pressure air flotation (LAF) pilot plant for sludge thickening was installed in Chung Nam N.S. municipal waste water treatment plant to verify its application possibility. Effects of operating conditions such as coagulant dosages and microbubble water ratio on thickening of the mixed sludge were examined. Microbubbles which were generated in the chamber of $1.5kgf/cm^2$ by high speed collision method with foaming agent were used to float sludge. Solid loading of $30kg/m^2/hr$, solid contents in thickened sludge of 60,300 mg/L and SS removal efficiency of 99% were obtained through long period operating LAF in conditions of mixed sludge concentration of 14,400 mg/L, coagulant dosage of 27.6 mg/L, foaming agent addition of 4.0 mg/L and microbubble water injection ratio of 9.7%.

• Journal of the Korean Geotechnical Society
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• v.18 no.4
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• pp.137-146
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• 2002

Geomembrane, compacted clay liner, and geosynthetic clay liner (GCL) are widely used to prevent leachate from leaking to adjacent geo-environment at a municipal solid waste (MSW) landfill. Interface shear strength between GCL and geomembrane installed at a landfill side slope is important properties for the safe design of side liner or final cover systems. The interface shear strength between two geosynthetics was estimated by a large direct shear test in this study. The shear strength was evaluated by the Mohr-Coulomb failure criterion. The effects of normal stress, hydration or dry condition, and a hydration method were investigated. The test results show that the interface shear strength and shear behavior varied depending up on the level of normal stress, the type of geosynthetic combinations, and a hydration method. When GCLs were sheared after being hydrated under 6kPa loading, the results were consistent with those published by other researchers. Summaries of friction angles, normal stress and hydration condition is presented. These friction angles could be used as a reference value at a site where similar geosynthetics are installed.