• Title/Summary/Keyword: Multiwall carbon nanotube

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Antibacterial and Mechanical Properties of Glass Ionomer Cements Containing Functionalized Multi-wall Carbon Nanotube(MWCNT) (기능화 다중벽 탄소나노튜브를 첨가한 글라스아이오노머 시멘트의 항균효과 및 기계적 성질)

  • Jeong, Mi-Ae;Kim, Dong-Ae
    • The Journal of the Korea Contents Association
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    • v.17 no.10
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    • pp.300-306
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    • 2017
  • The purpose of this study was to investigate the antibacterial effect of functional multiwall carbon nanotube (MWCNT) on the conventional glass ionomer cement(GIC). The MWCNT was incorporated into a commercial powder at 0.125, 0.25, 0.5 and 1.0 wt%. Specimens for vickers hardness(VHN) disks(Ø$10mm{\times}2mm$) each were prepared. Indention were made using a load of 200 N and 20 s dwell on four specimens for each distilled water storage time 1d, 7d, and 14days. The antibacterial effects using agar diffusion test with S. mutans and S. aureus. The diameters of the inhibition zones produced around the materials were measured. The results revealed that all the vickers hardness values were increase significantly with incubation time(p<0.05). Regarding the antibacterial effect for S. mutans, all the tested groups showed a slightly higher value not significantly with the control group(p<0.05). However S. aureus statistical analysis indicated a significant difference for antibacterial agents between control and MWCNT containing 0.25 wt%(p<0.05). These results of this study provide that the conventional GIC with containing MWCNT show good antibacterial effect against and favorable mechanical properties. Further this study on the efficient functionalization of multiwall carbon nanotube will be needed.

Investigation of the antibacterial and mechanical properties of glassionomer cement containing multiwall carbon nanotube(MWCNT) (다중벽 탄소나노튜브를 첨가한 글라스아이오노머시멘트의 항균효과 및 기계적 특성)

  • Jeong, mi-ae;Kim, dong-ae
    • Proceedings of the Korea Contents Association Conference
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    • 2017.05a
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    • pp.485-486
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    • 2017
  • 치과용 글라스아이오노머(GIC)는 치과에서 폭넓게 응용되고 있는 재료 중 하나이다. 그러나 GIC의 낮은 기계적 특성으로 인해 구강내 사용범위가 제한적이다. 이에 본 연구는 기능성 다중벽 탄소나노튜브(multi wall carbon nanotube; MWCNT-COOH)를 각 농도별(0.25-1.0 wt%)로 기존의 분말에 첨가하여 복합체를 제조한 후 제조사의 지시에 따란 분말(2):액(1)의 비율로 시편을 제작하여 다중벽탄소나노튜브가 GIC의 기계적 특성과 항균효과에 미치는 영향을 조사하였다.

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Silicon Nitride Composites with Different Nanocarbon Additives

  • Balazsi, Csaba
    • Journal of the Korean Ceramic Society
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    • v.49 no.4
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    • pp.352-362
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    • 2012
  • This paper explores the use of a variety of carbon nanoparticles to impart electrical, thermal conductivity, good frictional properties to silicon nitride matrices. We used the highly promising types of carbon as carbon nanotubes, exfoliated graphene and carbon black nanograins. A high-efficiency attritor mill has also been used for proper dispersion of second phases in the matrix. The sintered silicon nitride composites retained the mechanical robustness of the original systems. Bending strength as high as 700 MPa was maintained and an electrical conductivity of 10 S/m was achieved in the case of 3 wt% multiwall carbon nanotube addition. Electrically conductive silicon nitride ceramics were realized by using carbon nanophases. Examples of these systems, methods of fabrication, electrical percolation, mechanical, thermal and tribological properties are discussed.

C60@MWCNT: Room Temperature Encapsulation of C60 into Multiwall Carbon Nanotubes

  • Gupta, Vinay;Bahl, Om P.;Mathur, Rakesh B.
    • Carbon letters
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    • v.11 no.1
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    • pp.9-12
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    • 2010
  • The synthesis of $C_{60}$@MWCNT was carried out at room temperature (${\sim}25^{\circ}C$) from arc-discharge prepared Multi-wall carbon nanotubes (MWCNTs). They were oxidized and acid treated for tube opening. Then $C_{60}$ molecules were encapsulated into MWCNTs by wetting them with $C_{60}$-toluene solution for several minutes followed by ultrasonification. $C_{60}$@MWCNT was cleaned by pure toluene to remove any excess $C_{60}$. $C_{60}$@MWCNT was characterized by electron microscopy, which showed large scale filling of $C_{60}$ into MWCNTs. It was observed that the mechanism of insertion of $C_{60}$ into MWCNTs may be due to the capillary suction at the opening ends of MWCNTs.

Dopamine determination using a biosensor based on multiwall carbon nanotubes paste and burley tobacco-peroxidase (담배 잎-peroxidase와 다중벽 탄소 나노튜브를 이용한 dopamine의 정량)

  • Kwon, Hyoshik;Jeon, Byong-Suk;Pak, Yongnam
    • Analytical Science and Technology
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    • v.28 no.2
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    • pp.98-105
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    • 2015
  • The development of an enzymatic biosensor for dopamine determination based on multiwall carbon nanotubes (MWCNTs) and peroxidase obtained from the crude extract of burley tobacco (Nicotiana tabacum L.) was proposed. Peroxidase catalyzes the oxidation of dopamine to dopamine quinone. The influence on the response of analytical parameters of biosensors such as enzyme concentration, dopamine concentration, pH, and phosphate buffer solution concentration were investigated. The analytical parameters obtained, including sensitivity, linearity, and stability, were investigated. The proposed method for dopamine determination presented good selectivity even in the presence of uric acid and ascorbic acid. The sensor presented a higher response for dopamine in 0.010 M phosphate buffer at pH 6.50, with an applied potential of -0.15 V. The detection limit of the electrode was 2.7×10−6 M (S/N = 3) and the relative standard deviation of the measurements, which were repeated 10 times using 5.0×10−2 M dopamine, was 1.3%.

Switch-on Phenomena and Field Emission from Multi-Walled Carbon Nanotubes Embedded in Glass

  • Bani Ali, Emad S;Mousa, Marwan S
    • Applied Microscopy
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    • v.46 no.4
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    • pp.244-252
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    • 2016
  • This paper describes a new design of carbon nanotube tip. $Nanocly^{TM}$ NC 7000 Thin Multiwall Carbon Nanotubes of carbon purity (90%) and average diameter tube 9.5 nm with a high aspect-ratio (>150) were used. These tips were manufactured by employing a drawing technique using a glass puller. The glass microemitters with internal carbon nanotubes show a switch-on effect to a high current level (1 to $20{\mu}A$). A field electron microscope with a tip (cathode)-screen (anode) separation at ~10 mm was used to characterize the electron emitters. The system was evacuated down to a base pressure of ${\sim}10^{-9}$ mbar when baked at up to ${\sim}200^{\circ}C$ overnight. This allowed measurements of typical Field Electron Emission characteristics; namely the current-voltage (I-V) characteristics and the emission images on a conductive phosphorus screen (the anode). Fowler-Nordheim plots of the current-voltage characteristics show current switch-on for each of these emitters.

The Effects of Substrate Temperature on Properties of Carbon Nanotube Films Deposited by RF Plasma CVD (RF Plasma CVD법에 의해 증착된 카본나노튜브(CNT)의 특성에 대한 기판 온도의 영향)

  • Kim, Dong-Sun
    • Korean Chemical Engineering Research
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    • v.46 no.1
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    • pp.50-55
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    • 2008
  • Carbon Nanotube (CNT) films were deposited with varying deposition temperature by RF plasma CVD on Fe catalysts deposited onto $SiO_2$ films grown thermally on the silicon wafer using $C_2H_2$ and $H_2$ gases. The Fe catalysts on silicon oxide film were made by RF magnetron sputtering. The grounded grid mesh cover on the substrate holder was used for depositing CNT thin films with high purity. The surface morphologies and chemical structure of deposited CNT films were characterized using SEM, Raman, XPS and TEM. It was observed that deposited CNTs films were carbon fiber type having Bamboo-like multiwall structure and CNT film grown at $600^{\circ}C$ was more dense than that at $550^{\circ}C$, but become less dense at $650^{\circ}C$.

Vertically aligned carbon nanotubes grown on various substrates by plasma enhanced chemical vapor deposition

  • Han, Jae-hee;Moon, Byung-Sik;Yang, Won-Suk;Yoo, Ji-Beom;Park, Chong-Yun;Han, In-Taek;Lee, Nae-Sung;Kim, Chong-Min;Kim, Tae-Il
    • Journal of Korean Vacuum Science & Technology
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    • v.3 no.2
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    • pp.121-125
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    • 1999
  • Vertically well aligned multiwall carbon nanotubes were grown on nickel coated different substrates by plasma enhanced hot filament chemical vapor deposition at low temperatures below 650$^{\circ}C$. Acetylene and ammonia gas were used as the carbon source and a catalyst. The surface roughness of nickel layer increased as NH3 etching time increased. The diameters of the nanotubes decreased and the density of nanotubes increased as NH3 etching time increased. diameter of nanotube was 30 to 70 nm. Nickel cap was observed on the top of the grown nanotube and very thin carbon amorphous layer was fonde on the nickel cap.

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Electrode Fabrication of MWCNT-PDMS Strain Sensors by Wet-etching (습식 식각을 이용한 MWCNT-PMDS 변형율 센서 전극 생성에 관한 연구)

  • Jung, La-Hee;Hwang, Hui-Yun
    • Composites Research
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    • v.34 no.6
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    • pp.387-393
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    • 2021
  • This paper investigated the electrical properties of multiwall carbon nanotube reinforced polydimethylsiloxane (CNT-PDMS) strain sensors with copper electrodes on the wet-etched surface. MWCNT-PDMS strain sensors were fabricated according to the wt% of MWCNT. Surfaces on the electrode area were wet-etched with various etching duration and silver epoxy adhesives were spread on the wet-etched surface. Finally, we attached the copper electrodes to the MWCNT-PMDS strain sensors. We checked the electric conductivities by the two-probe method and sensing characteristics under the cyclic loading. We observed the electric conductivity of MWCNT-PDMS strain sensors increased sharply and the scattering of the measured data decreased when the surface of the electrode area was wet-etched. Initial resistances of MWCNT-PDMS strain sensors were inversely proportion to wt% of MWCNT and the etching duration. However, the resistance changing rates under 30% strain increased as wt% of MWCNT and the etching duration increased. Decreasing rate of the electric resistance change after 100 repetitions was smaller when wt% of MWCNT was larger and the etching duration was short. This was due to the low initial resistance of the MWCNT-PMDS strain sensors by the wet-etching.