• 제목/요약/키워드: Multicomponent analysis

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산화물과 질산염으로 제조한 투명전극 타깃용 다성분계 IGZO 세라믹스 (Multicomponent IGZO Ceramics for Transparent Electrode Target Fabricated from Oxides and Nitrates)

  • 이현권;윤지혜;조경식
    • 한국분말재료학회지
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    • 제26권5호
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    • pp.375-382
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    • 2019
  • Homogeneous multicomponent indium gallium zinc oxide (IGZO) ceramics for transparent electrode targets are prepared from the oxides and nitrates as the source materials, and their properties are characterized. The selected compositions were $In_2O_3:Ga_2O_3:ZnO$ = 1:1:2, 1:1:6, and 1:1:12 in mole ratio based on oxide. As revealed by X-ray diffraction analysis, calcination of the selected oxide or nitrides at $1200^{\circ}C$ results in the formation of $InGaZnO_4$, $InGaZn_3O_6$, and $InGaZn_5O_8$ phases. The 1:1:2, 1:1:6, and 1:1:12 oxide samples pressed in the form of discs exhibit relative densities of 96.9, 93.2, and 84.1%, respectively, after sintering at $1450^{\circ}C$ for 12 h. The $InGaZn_3O_6$ ceramics prepared from the oxide or nitrate batches comprise large grains and exhibit homogeneous elemental distribution. Under optimized conditions, IGZO multicomponent ceramics with controlled phases, high densities, and homogeneous microstructures (grain and elemental distribution) are obtained.

NEWTONIAN COSMOLOGICAL PERTURBATIONS

  • Hwang, Jai-Chan
    • 천문학논총
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    • 제7권1호
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    • pp.107-148
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    • 1992
  • This paper presents a cosmological perturbation analysis in a Newtonian framework, using the Newtonian multi component version of the relativistic covariant equations. This work considers the fully nonlinear evolution of the perturbations, and is generalized to multicomponent systems and imperfect fluids. Known nonlinear solutions are presented in a general framework. Quasi-nonlinear analysis, considering both the compressible and rotational modes, is presented, including cases already known in the literature. The Fourier space representation of the conservation equations is also derived in a general context, with various decompositions of the velocity field. Commonly accepted cosmogonical frameworks are critically examined in the context of nonlinear evolution. This work may be regarded as the Newtonian counterpart of a recently presented general relativistic covariant formulation.

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다성분계 산화물의 요업재료 제조를 위한 석유 증발 건조 방법 (Hot Petroleum Drying Method to the Preparation of Multicomponent Oxide Ceramic Material)

  • 변수일
    • 한국세라믹학회지
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    • 제14권3호
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    • pp.163-168
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    • 1977
  • As a wet chemical drying process "hot petroleum drying method" was applied and developed for preparing uniformly fine oxide powder with high purity and sinterreactivity. Using this method solution of sulfates was dried in hot petroleum bath (~17$0^{\circ}C$) to sulfate powder from which corresponding mullite doped by Fe3+ ion was formed. Particle size, shape, decomposition by heat, and phase identification of sulfate andoxide powders determined by DTA, TGA, X-ray diffraction, analysis and electron microscopy: sulfate powder prepared by this drying method is an intimate mixture of the amorphous form of uniformly and finely distributed spherical particles (0.05-0.1$\mu$). Mullitization with the sulfate powder occurs at 110$0^{\circ}C$ in air. The morphology of mullite particle made by firing the sulfate powder at 135$0^{\circ}C$ in oxygen atmosphere is granular of 0.1-0.3$\mu$ in size. This drying process proved to be a very effective method for preparing fine, homogeneous, and highly sinterreactive multicomponent oxide powder without conventional ceramic process of mixing, milling, and granulating. This process can be also applied for preparing electronic ceramic materials which are requisite for high purity and homogeneity.mogeneity.

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다성분계 Glass Fiber의 La$_2$O$_3$첨가에 따른 광학적 특성에 관한 연구 (The Study on Optical Properties by Adding La$_2$O$_3$ in Multicomponent Glass Fiber)

  • 김용호;강원호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1985년도 추계학술대회 논문집
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    • pp.21-23
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    • 1985
  • By adding La$_2$O$_3$ to optical multicomponent glass composition, after making mother glass and core fiber that enable to enlarge the infrared transmittance region, then surveyed the optical properties. Through thermal analysis of the glass abstained by melt-quenching after selecting stable basic composition on devitrification and replace SiO$_2$ by 4-12wt% La$_2$O$_3$. As La$_2$O$_3$ increases up to l2wt% transition temperature, refractive index, density, deformation temperature increased, whereas thermal expansion coefficient decreased. As a result of inspectig transmittance in UV/VIS/IR region, visable region indicated the decrease of transmittance by increasing the La$_2$O$_3$ and transmittance region was enlarged by increasing the La$_2$O$_3$ in IR region. Also, fabricate core fiber at 820$^{\circ}C$ and severy the optical loss we could fact that La$_2$O$_3$ composition added 12wt% showed the minimum optical loss.

Correlation between rare earth elements in the chemical interactions of HT9 cladding

  • Lee, Eun Byul;Lee, Byoung Oon;Shim, Woo-Yong;Kim, Jun Hwan
    • Nuclear Engineering and Technology
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    • 제50권6호
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    • pp.915-922
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    • 2018
  • Metallic fuel has been considered for sodium-cooled fast reactors because it can maximize the uranium resources. It generates rare earth elements as fission products, where it is reported by aggravating the fuel-cladding chemical interaction at the operating temperature. Rare earth elements form a multicomponent alloy (Ce-Nd-Pr-La-Sm-etc.) during reactor operation, where it shows a higher reaction thickness than a single element. Experiments have been carried out by simplifying multicomponent alloys for mono or binary systems because complex alloys have difficulty in the analysis. In previous experiments, xCe-yNd was fabricated with two elements, Ce and Nd, which have a major effect on the fuel-cladding chemical interaction, and the thickness of the reaction layer reached maximum when the rare earth elements ratio was 1:1. The objective of this study is to evaluate the effect and relationship of rare earth elements on such synergistic behavior. Single and binary rare earth model alloys were prepared by selecting five rare earth elements (Ce, Nd, Pr, La, and Sm). In the single system, Nd and Pr behaviors were close to diffusion, and Ce showed a eutectic reaction. In the binary system, Ce and Sm further increased the reaction layer, and La showed a non-synergy effect.

다성분 복소 트레이스 분석법을 이용한 지진파 입자운동 연구 (Seismic Studies on Ground Motion using the Multicomponent Complex Trace Analysis Method)

  • 이소영;김기영;김한준
    • 지구물리
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    • 제3권1호
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    • pp.37-48
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    • 2000
  • 다성분 복소 트레이스 분석법을 이용하여 지진에 의한 지면운동을 밝히고자 컴퓨터 합성 탄성파 자료와 자연 지진 자료를 대상으로 파선방향의 입자운동을 분석하였다. 합성 탄성파 자료에 적용시킨 결과, 실체파 합성 부분에서는 도달시각, 지속시간, 접근각 등을 정확히 찾을 수 있으며, 레일리파도 쉽게 인지된다. 규모 7.3의 심발 지진 자료로부터 입자운동의 분극특성을 계산한 결과, 종파의 수직성분과 수평성분의 순간위상차, 순간역타원율, 접근각은 각각 약 ${\pm}180^{\circ},\;0{\sim}0.25,\;-30^{\circ}{\sim}-45^{\circ}$의 값을 가지며, 이러한 분극특성으로부터 진원시간함수는 $6{\sim}7\;s$ 정도 지속되는 것으로 분석된다. 횡파의 경우는 순간위상차가 일정하지 않으며, $0{\sim}0.3$의 순간역타원율과 거의 수직의 접근각을 나타낸다. 횡파 도달 직전에 기록된 비교적 저주파의 신호는 분극특성으로부터 횡파와는 구별되는 종파의 일종으로 해석된다. 종파와 횡파의 도달시각을 이용하여 구한 속도와 파선변수는 각각 8.633 km/s, 4.762 km/s와 0.074 s/km, 0.197 s/km이며 동포와송비는 0.281로 계산된다.

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다성분 에어로졸계의 동특성 묘사를 위한 전산 코드의 개발 -불확실성 및 민감도 해석- (Development of Computer Code for Simulation of Multicomponent Aerosol Dynamics -Uncertainty and Sensitivity Analysis-)

  • Na, Jang-Hwan;Lee, Byong-Whi
    • Nuclear Engineering and Technology
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    • 제19권2호
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    • pp.85-98
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    • 1987
  • 중대사고시 LMFBR의 에어로졸(aerosol) 동특성을 살피기 위해 전산코드인 MCAD (Multicomponent Aerosol Dynamics)가 개발되었다. 사고경과에 따른 두 방사능원의 상대적인 충돌확률을 적용하여 에어로졸계를 모사할 수 있다. Brownian 확산과 중력작용에 의한 결합 및 제거과정을 고려했으며, 입자형태를 묘사하기 위해 밀도보정과 형태요소(shape factor)를 동시에 고려하였다. ORNL의 NSPP-300 계열 실험자료와 기존의 코드를MCAD의 입증에 이용하였다. 그 결과 MCAD의 계산치와 실험치 및 기존의 코드 계산값이 일치함을 보여준다. 여러 입력자료의 불화실한 값들을 정의하고, 그들값의 한계로 설정하기 위하여 불확실성 및 민감도해석을 수행하였다. 14개의 입력자료를 선택하여 실험계획법과 Latin hypercube sampling에 의한 입력자료를 조합하여 그 회귀 (regression) 정도를 반응표면 계획법(Response surface method)에 의해 구하였다. 각 변수들의 중요성 및 시간경과에 따른 그들의 상대적인 등위를 결정하기 위하여 단계식 회귀방법 (Stepwise regression method)을 고려했다. LHS에 의한 회귀모형에 Monte Carlo Method를 적용하여 계산값 및 변수들에의 신뢰도를 향상시켰다.

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Manifestation of metabolic Aberration in Rat urine Following Hypothalamic Lesions

  • Anbar, Michel;Kim, Kyoung-Rae
    • Archives of Pharmacal Research
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    • 제7권2호
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    • pp.101-107
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    • 1984
  • The concentrations of metabolites of low molecular weights (90 to 310 amu) present in rat urine were determined by field ionization mass spectrometry. Three groups of rats were examined; intact controls, sham-operated rats and rats with selective lesions in their hypothalamus. The latter lesions are shown to induce characteristic aberrations in the metabolic profile, demonstrable five weeks after treatment, which are distinct from those induced by a sham operation.

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가스 연료의 연소 방식에 따른 NOx 생성 특성 (NOx Formation Characteristics in Diffusion, Partial Premixed and Premixed Jet flame)

  • 최영호;이창언
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 1998년도 제17회 KOSCI SYMPOSIUM 논문집
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    • pp.155-164
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    • 1998
  • Numerical analysis was performed with multicomponent transport properties and detailed reaction mechanisms for axisymetric 2-D CH4 jet diffusion, partial premixed, premixed flame. Calculations were carried out twice with C2-Full Mechanism including prompt NO reaction in addition to the above C2-Thermal NO Mechanism. The role of thermal NO mechanism and prompt NO mechanism on each flame's NO production is investigated by using the numerical result. The NOx production of each flame were evaluated Quantitatively in terms of the NOx emission index

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다성분 산화물 요업체의 고온 물라이트화 반응 정량분석 (Quantitative Analysis of High-Temperature Mullitization from a Multicomponent Oxide System)

  • 신현호;김철수;김창욱;장순남;성완;장동환;강석원;최석홍
    • 한국세라믹학회지
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    • 제35권1호
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    • pp.5-10
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    • 1998
  • Mullitization in a multicomponent oxide system(alumina-kaolin-quartz-feldspar-talc) was studied as a function of sintering temperature from 1200 to 1500$^{\circ}C$ based upon a quantitative X-ray diffraction analysis. In the present study mullite grew as wiskers and its formation reaction showed characteristic there stages as follows In the first stage(1255-1295$^{\circ}C$) an appreciable mullitization(nucleation) occurred while corun-dum dissolution into glass (increasing glass content ) limited the rate of the reaction. At 1295-1335$^{\circ}C$ (second state) the reaction was significantly enhanced with a considerable glass consumption and with no appreciable change in corundum content. Finally (above 1335$^{\circ}C$) the reaction rate was attenuated re-markably with an apparent decrease in glass consumption rate. The impingement of mullite whiskers by oth-er whiskers and crystals was speculated to cause mullite growth in thickness direction with a slow growth rate resulting in the diminished reaction rate in the final stage.

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