• International Journal of Precision Engineering and Manufacturing
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• v.6 no.2
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• pp.50-54
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• 2005

We report a simple, low cost, and reliable method for assembling a multi-walled nanotube (MWNT) to the end of a metal coated scanning probe microscopy (SPM) tip. By dropping the MWNT solution and applying an electric field between an SPM tip and an electrode, MWNTs which were dispersed into a dielectric solution were directly assembled onto the apex of the SPM tip due to the attraction by the dielectrophoretic force. The effective measurement of a MWNT -attached SPM tip was demonstrated by direct comparison with AFM images of a standard sample with a bare AFM tip.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.32 no.5
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• pp.432-436
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• 2019

In this study, we produced a light, flexible, wearable gas sensor by depositing MWCNTs (Multi-walled Carbon Nanotubes) into nylon. MWCNTs are widely used as a gas sensor material due to their excellent mechanical, electrical and physical characteristics. We produced a gas sensor to detect NOx gases by depositing nylon yarn in a MWCNT solution. The MWCNT solution was made by mixing 3 mg MWCNT in 5 ml of ethanol. Nylon yarn was placed in the manufactured solution and ultrasonic waves were applied using an ultrasonicator for 3 h, resulting in MCWNT deposition. The MWCNT-deposited nylon yarn was dried at room temperature for 24 h. The MWCNT-thin-film-coated nylon yarn was masked 1 mm apart, and gold was then deposited on the masked nylon yarn to create the gas sensor. The sensor then was installed in a chamber with a controlled atmospheric environment and exposed to NOx gas. The changing signal from the sensor was amplified to analyze its gas detection characteristics.

• Journal of the Korean institute of surface engineering
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• v.54 no.4
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• pp.194-199
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• 2021

In this study, rebar corrosion detection sensor was fabricated using multi-walled carbon nanotubes (MWCNTs). MWCNTs were pre-treated in the acid electrolytes to attach the carboxylic acid to the surface of MWCNTs. The fabricated sensor was attached on the surface of rebar and it detected the corrosion of steel using LCR meter with variation of capacitance. The surface morphology and electrical properties were characterized using scanning electron microscope (SEM) and electrical test equipment, respectively. To verify the corrosion detection characteristics, comparison experiment using plastic bar was performed. Moreover, mechanism of corrosion detection sensor was discussed.

• Steel and Composite Structures
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• v.29 no.5
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• pp.569-578
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• 2018

This paper aims to investigate the transient vibration behavior of functionally graded carbon nanotube (FG-CNT) reinforced nanocomposite plate resting on Pasternak foundation under pulse excitation. The plate is considered to be composed of matrix material and multi-walled carbon nanotubes (MWCNTs) with distribution as per the functional grading concept. The functionally graded distribution patterns in nanocomposite plate are explained more appropriately with the layer-wise variation of carbon nanotubes weight fraction in the thickness coordinate. The layers are stacked up in such a way that it yields uniform and three other types of distribution patterns. The effective material properties of each layer in nanocomposite plate are obtained by modified Halpin-Tsai model and rule of mixtures. The governing equations of an illustrative case of simply-supported nanocomposite plate resting on the Pasternak foundation are derived from third order shear deformation theory and Navier's solution technique. A converge transient response of nanocompiste plate under uniformly distributed load with triangular pulse is obtained by varying number of layer in thickness direction. The validity and accuracy of the present model is also checked by comparing the results with those available in literature for isotropic case. Then, numerical examples are presented to highlight the effects of distribution patterns, foundation stiffness, carbon nanotube parameters and plate aspect ratio on the central deflection response. The results are extended with the consideration of proportional damping in the system and found that nanocomposite plate with distribution III have minimum settling time as compared to the other distributions.

• Carbon letters
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• v.22
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• pp.14-24
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• 2017

Carboxylated multi-wall carbon nanotubes (MWCNTs-COOH) have been used as efficient adsorbents for the removal of picric acid from aqueous solutions under stirring and ultrasound conditions. Batch experiments were conducted to study the influence of the different parameters such as pH, amount of adsorbents, contact time and concentration of picric acid on the adsorption process. The kinetic data were fitted with pseudo-first order, pseudo-second-order, Elovich and intra-particle diffusion models. The kinetic studies were well described by the pseudo-second-order kinetic model for both methods. In addition, the adsorption isotherms of picric acid from aqueous solutions on the MWCNTs were investigated using six two-parameter models (Langmuir, Freundlich, Tempkin, Halsey, Harkins-Jura, Fowler-Guggenheim), four three-parameter models (Redlich-Peterson, Khan, Radke-Prausnitz, and Toth), two four-parameter equations (Fritz-Schlunder and Baudu) and one five-parameter equation (Fritz-Schlunder). Three error analysis methods, correlation coefficient, chi-square test and average relative errors, were applied to determine the best fit isotherm. The error analysis showed that the models with more than two parameters better described the picric acid sorption data compared to the two-parameter models. In particular, the Baudu equation provided the best model for the picric acid sorption data for both methods.

• Korean Journal of Materials Research
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• v.18 no.9
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• pp.457-462
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• 2008

Through the electrostatic interaction between the poly-diallydimethylammonium chloride (PDDA) modified Multi-walled carbon nanotube (MWNT) and $SnO_2$ suspension in 1mM $NaNo_3$ solution, MWNT-$SnO_2$ nanocomposites (MSC) for anode electrodes of a Li-ion battery were successfully fabricated by colloidal heterocoagulation method. TEM observation showed that most of the $SnO_2$ nanoparticles were uniformly deposited on the outside surface of the MWNT. Galvanostatic charge/discharge cycling tests showed that MSC anodes exhibited higher specific capacities than bare MWNT and better cyclability than unsupported nano-$SnO_2$ anodes. Also, after 20 cycles, the MSC anode fabricated by heterocoagulation method showed more stable cycle properties than the simply mixed MSC anode. These improved electrochemical properties are attributed to the MWNT, which adsorbs the mechanical stress induced from volume change and increasing electrical conductivity of the MSC anode, and suppresses the aggregation between the $SnO_2$ nanoparticles.

• Polymer(Korea)
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• v.34 no.2
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• pp.108-115
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• 2010

The effects of acid-treated MWCNT and coupling agent on properties of MWCNT/SBR are investigated in this work. The MWCNTs oxidized using sulfuric and nitric acids were analyzed by the Raman scattering and Fourier transformed infrared spectroscopy(FT-IR). The FT-IR results indicate the presence of -COOH groups in the treated samples, and Raman spectroscopy of the acidtreated MWCNTs further corroborates the formation of surface defect due to the introduction of carboxyl groups. And the nanocomposites reinforced with MWCNTs were characterized extensively using the scanning electron microscopy(SEM), electrical conductivity, thermal conductivity, and tensile properties measurements. The results showed that nanocomposites onto acid-treated MWCNTs enhanced mechanical properties compared to those containing MWCNTs without acid treatment. These findings confirmed the improved interfacial interactions between MWCNTs and SBR arising from the coupling agents. But the electrical and thermal conductivity of nanocomposites decreased due to the chopping and formation of surface defects of MWCNTs.

• Korean Chemical Engineering Research
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• v.53 no.1
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• pp.83-90
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• 2015

In this study, we investigated optimum conditions for the introduction of a lot of free radical polymerizable methacrylate groups on the multi-walled carbon nanotube (MWCNT) surface. Carboxyl groups were introduced first on MWCNT surfaces by treating with a mixture of sulfuric acid and nitric acid with ultrasonic bath for 2 hours, and oxidized MWCNTs were reacted further with thionyl chloride followed by triethylenetetramine (TETA) to introduce amino groups on the oxidized MWCNT surface, to make MWCNT-$NH_2$. To introduce free radical polymerizable methacrylate groups on the MWCNT-$NH_2$, MWCNT-$NH_2$ was reacted with 3-(acryloyloxy)-2-hydroxypropyl methacrylate (AHM) by Michael addition reaction. We investigated progress of modification reactions for MWCNT by fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA) and elemental analysis (EA). We found maximum degree of Michael addition reactions between AHM and TETA grafted on MWCNT-$NH_2$ for 10:1 mol ratio and 8 hour reaction time in our reaction conditions.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.34 no.2
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• pp.211-217
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• 2010

It is important to measure the mechanical properties of nanostructures because they are required to determine the lifetime and reliability of nanodevices developed for various fields. In this study, tensile tests for a multi-walled carbon nanotube (MWCNT) and a ZnO nanorod were performed in a scanning electron microscope (SEM). The force sensor was a cantilever type and was mounted in front of a nanomanipulator placed in the chamber. The nanomanipulator was controlled using a joystick and personal computer. The nanostructures dispersed on the cut area of a transmission electron microscope (TEM) grid were gripped with the force sensor by exposing an electron beam in the SEM; the tensile tests were the performed. The in situ tensile loads of the nanostructure were obtained. After the tensile test, the cross-sectional areas of the nanostructures were observed by TEM and SEM. Based on the TEM and SEM results, the elastic modulus of the MWCNT and ZnO nanorod were calculated to be 0.98 TPa and 55.85 GPa, respectively.

• Steel and Composite Structures
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• v.35 no.4
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• pp.463-474
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• 2020

In this paper, the influence of adding multi-walled carbon nanotube (MWCNT) on the pull behavior of steel and GFRP bars in ultra-high-performance concrete (UHPC) was examined experimentally and numerically. For numerical analysis, 3D nonlinear finite element modeling (FEM) with the help of ABAQUS software was used. Mechanical properties of the specimens, including Young's modulus, tensile strength and compressive strength, were extracted from the experimental results of the tests performed on standard cube specimens and for different values of weight percent of MWCNTs. In order to consider more realistic assumptions, the bond between concrete and bar was simulated using adhesive surfaces and Cohesive Zone Model (CZM), whose parameters were obtained by calibrating the results of the finite element model with the experimental results of pullout tests. The accuracy of the results of the finite element model was proved with conducting the pullout experimental test which showed high accuracy of the proposed model. Then, the effect of different parameters such as the material of bar, the diameter of the bar, as well as the weight percent of MWCNT on the bond behavior of bar and UHPC were studied. The results suggest that modifying UHPC with MWCNT improves bond strength between concrete and bar. In MWCNT per 0.01 and 0.3 wt% of MWCNT, the maximum pullout strength of steel bar with a diameter of 16 mm increased by 52.5% and 58.7% compared to the control specimen (UHPC without nanoparticle). Also, this increase in GFRP bars with a diameter of 16 mm was 34.3% and 45%.