• 제목/요약/키워드: Multi-layered materials

검색결과 232건 처리시간 0.023초

Tm2O3가 첨가된 MLCC용 BaTiO3 유전체의 전기적 특성 및 열화거동 (Electrical properties and degradation behavior of Tm2O3 doped barium titanate ceramics for MLCCs)

  • 김도완;김진성;후이;이희수
    • 한국결정성장학회지
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    • 제20권6호
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    • pp.278-282
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    • 2010
  • Tm 도핑에 따른 $BaTiO_3$ ceramics의 전기적 특성과 열화 거동에 미치는 영향에 대하여 core-shell 형성과 가속열화시험에 의한 미세화학변화의 관점에서 연구하였다. $Tm_2O_3$를 첨가하지 않은 $BaTiO_3$와 1 mol%를 첨가한 $BaTiO_3$를 펠렛과 적층 형태의 시편으로 각각 제조하였다. 1 mol% $Tm_2O_3$가 첨가된 유전체 시편의 유전상수는 $Tm_2O_3$를 첨가하지 않은 시편에 비해 약 40% 높게 나타났고 X7R 조건을 만족하였다. 절연저항 또한 1 mol% $Tm_2O_3$가 첨가된 시편은 $5.43{\times}10^{10}{\Omega}$으로 $Tm_2O_3$를 첨가하지 않은 시편의 $1.11{\times}10^{10}{\Omega}$보다 높게 나타났다. 이는 $Tm^{3+}$ 이온이 Ba site와 Ti site에 선택적으로 치환되고 유전체 미세조직 내에 core-shell 구조를 형성하여 전기적 특성을 향상시킨 것으로 설명된다. 각각의 조성에 따라 제조된 적층 시편의 $150^{\circ}C$, 70 V, 24시간 가속열화시험결과에 따르면, 1 mol% $Tm_2O_3$가 첨가된 $BaTiO_3$는 첨가되지 않은 시편에 비해 전극 층으로의 산소확산이 감소됨을 확인하였고, 이는 $Tm^{3+}$ 이온의 Ti site 치환에 의해 발생한 산소공공이 Ni 전극과 반응할 수 있는 과잉 산소를 줄여주기 때문으로 판단된다.

Statistical Qualitative Analysis on Chemical Mechanical Polishing Process and Equipment Characterization

  • Hong, Sang-Jeen;Hwang, Jong-Ha;Seo, Dong-Sun
    • Transactions on Electrical and Electronic Materials
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    • 제12권2호
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    • pp.56-59
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    • 2011
  • The characterization of the chemical mechanical polishing (CMP) process for undensified phophosilicate glass (PSG) film is reported using design of experiments (DOE). DOE has been used by experimenters to understand the relationship between the input variables and responses of interest in a simple and efficient way, and it typically is beneficial for determining the appropriatesize of experiments with multiple process variables and making statistical inferences for the responses of interest. The equipment controllable parameters used to operate the machine consist of the down force of the wafer carrier, pressure on the back side wafer, table and spindle speeds (SS), slurry flow (SF) rate, pad condition, etc. None of these are independent ofeach other and, thus, the interaction between the parameters also needs to be understoodfor improved process characterization in CMP. In this study, we selected the five controllable equipment parameters the most recommendedby process engineers, viz. the down force (DF), back pressure (BP), table speed (TS), SS, and SF, for the characterization of the CMP process with respect to the material removal rate and film uniformity in percentage terms. The polished material is undensified PSG which is widely used for the plananization of multi-layered metal interconnects. By statistical modeling and the analysis of the metrology data acquired from a series of $2^{5-1}$ fractional factorial designs with two center points, we showed that the DF, BP and TS have the greatest effect on both the removal rate and film uniformity, as expected. It is revealed that the film uniformity of the polished PSG film contains two and three-way interactions. Therefore, one can easily infer that process control based on a better understanding of the process is the key to success in current semiconductor manufacturing, in which the size of the wafer is approaching 300 mm and is scheduled to continuously increase up to 450 mm in or slightly after 2012.

Early Detection of Lung Cancer Risk Using Data Mining

  • Ahmed, Kawsar;Abdullah-Al-Emran, Abdullah-Al-Emran;Jesmin, Tasnuba;Mukti, Roushney Fatima;Rahman, Md. Zamilur;Ahmed, Farzana
    • Asian Pacific Journal of Cancer Prevention
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    • 제14권1호
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    • pp.595-598
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    • 2013
  • Background: Lung cancer is the leading cause of cancer death worldwide Therefore, identification of genetic as well as environmental factors is very important in developing novel methods of lung cancer prevention. However, this is a multi-layered problem. Therefore a lung cancer risk prediction system is here proposed which is easy, cost effective and time saving. Materials and Methods: Initially 400 cancer and non-cancer patients' data were collected from different diagnostic centres, pre-processed and clustered using a K-means clustering algorithm for identifying relevant and non-relevant data. Next significant frequent patterns are discovered using AprioriTid and a decision tree algorithm. Results: Finally using the significant pattern prediction tools for a lung cancer prediction system were developed. This lung cancer risk prediction system should prove helpful in detection of a person's predisposition for lung cancer. Conclusions: Most of people of Bangladesh do not even know they have lung cancer and the majority of cases are diagnosed at late stages when cure is impossible. Therefore early prediction of lung cancer should play a pivotal role in the diagnosis process and for an effective preventive strategy.

Delamination behaviors of GdBCO CC tapes under different transverse loading conditions

  • Gorospe, Alking B.;Bautista, Zhierwinjay M.;Shin, Hyung-Seop
    • 한국초전도ㆍ저온공학회논문지
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    • 제17권3호
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    • pp.13-17
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    • 2015
  • In superconducting coil applications particularly in wet wound coils, coated conductor (CC) tapes are subjected to different type of stresses. These include hoop stress acting along the length of the CC tape and the Lorentz force acting perpendicular to the CC tape's surface. Since the latter is commonly associated with delamination problem of multi-layered CC tapes, more understanding and attention on the delamination phenomena induced in the case of coil applications are needed. Difference on the coefficient of thermal expansion (CTE) of each constituent layer of the CC tape, the bobbin, and the impregnating materials is the main causes of delamination in CC tapes when subjected to thermal cycling. The CC tape might also experience cyclic loading due to the energizing scheme (on - off) during operation. In the design of degradation-free superconducting coils, therefore, characterization of the delamination behaviors including mechanism and strength in REBCO CC tapes becomes critical. In this study, transverse tensile tests were conducted under different loading conditions using different size of upper anvils on the GdBCO CC tapes. The mechanical and electromechanical delamination strength behaviors of the CC tapes under transverse tensile loading were examined and a two-parameter Weibull distribution analysis was conducted in statistical aspects. As a result, the CC tape showed similar range of mechanical delamination strength regardless of cross-head speed adopted. On the other hand, cyclic loading might have affected the CC tape in both upper anvil sizes adopted.

Statistical Qualitative Analysis on Chemical Mechanical Polishing Process and Equipment Characterization

  • Hong, Sang-Jeen;Hwang, Jong-Ha;Seo, Dong-Sun
    • Transactions on Electrical and Electronic Materials
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    • 제12권3호
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    • pp.115-118
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    • 2011
  • Process characterization of the chemical mechanical polishing (CMP) process for undensified phosphosilicate glass (PSG) film is reported using design of experiments (DOE). DOE has been addressed to experimenters to understand the relationship between input variables and responses of interest in a simple and efficient way. It is typically beneficial for determining the adequate size of experiments with multiple process variables and making statistical inferences for the responses of interests. Equipment controllable parameters to operate the machine include the down force (DF) of the wafer carrier, pressure on the backside of the wafer, table and spindle speed (SS), slurry flow rate, and pad condition. None of them is independent; thus, the interaction between parameters also needs to be indicated to improve process characterization in CMP. In this paper, we have selected the five controllable equipment parameters, such as DF, back pressure (BP), table speed (TS), SS, and slurry flow (SF), most process engineers recommend to characterize the CMP process with respect to material removal rate (RR) and film uniformity as a percentage. The polished material is undensified PSG. PSG is widely used for the plananization in multi-layered metal interconnects. We identify the main effect of DF, BP, and TS on both RR and film uniformity, as expected, by the statistical modeling and analysis on the metrology data acquired from a series of $2^{5-1}$ fractional factorial design with two center points. This revealed the film uniformity of the polished PSG film contains two and three-way interactions. Therefore, one can easily infer that the process control based on better understanding of the process is the key to success in semiconductor manufacturing, typically when the wafer size reaches 300 mm and is continuously scheduled to expand up to 450 mm in or little after 2012.

태양전지모듈용 고내구성 저가형 백시트 (Low-costBacksheet Materials with Excellent Resistance to Chemical Degradation for Photovoltaic Modules)

  • 표세연;이창현
    • 멤브레인
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    • 제25권3호
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    • pp.287-294
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    • 2015
  • 태양전지는 태양복사에너지를 반도체의 광전효과를 통해 전기에너지로 변환시키는 친환경 에너지변환장치를 의미한다. 수분을 포함하는 다양한 화학물질들에 대한 높은 차단성을 갖는 다층형 필름인 백시트는 태양전지의 중요한 요소이다. 대표적인 백시트는 polyvinyl fluoride (PVF)와 poly(ethylene terephthalate) (PET)의 다층필름으로 구성된다. PVF는 높은 내후성을 가지는 반면, 가격이 상대적으로 비싼 단점을 보인다. 따라서, 백시트의 제조가격을 낮출 수 있으면서, 동시에 실제 태양전지모듈에 적용할만한 수명특성을 만족시킬 수 있는 대체소재의 개발이 필수적이다. 본 연구에서는 일정수준의 결정성을 갖는 PET 필름을 PVF 필름 대신 사용하였다. 그러나, PET 소재는 다양한 pH 조건에서 trans-esterification 및 가수분해에 의해 분해될 수 있기 때문에, 태양전지의 구동조건에서 PET의 분해거동을 이해할 필요가 있다. 단시간 내 화학적 분해거동을 평가하기 위해서, 가속화된 PET 분해실험 프로토콜이 개발되었다. 마지막으로, 제안 개념의 효용성은 태양전지모듈의 장기운전성능 평가를 통해 확인하였다.

그래핀이 코팅된 스테인리스강의 고분자전해질 연료전지 분리판 적용을 위한 표면 특성 (Surface Characteristic of Graphene Coated Stainless Steel for PEMFC Bipolar Plate)

  • 이수형;김정수;강남현;조형호;남대근
    • 한국표면공학회지
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    • 제44권5호
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    • pp.226-231
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    • 2011
  • Graphene was coated on STS 316L by electro spray coating method to improve its properties of corrosion resistance and contact resistance. Exfoliated graphite (graphene) was made of the graphite by chemical treatment. Graphene is distributed using dispersing agent, and STS 316L was coated with diffuse graphene solution by electro spray coating method. The structure of the exfoliated graphite was analyzed using XRD and the coating layer of surface was analyzed by using SEM. Analysis showed that multi-layered graphite structure was destroyed and it was transformed into fine layers graphene structure. And the result of SEM analysis on the surface and the cross section, graphene layer was uniformly formed with 3~5 ${\mu}m$ thickness on the surface of substrate. Corrosion resistance test was applied in the corrosive solution which is similar to the PEM fuel cell stack inside. And interfacial contact resistance test was measured to simulate the internal operating conditions of PEM fuel cell stack. The results of measurements show that stainless steel coated with graphene was improved in corrosion resistance and surface contact resistance than stainless steel without graphene coating layer.

하수슬러지-(SO2-O2-H2O-bal. CO2) 혼합 가스 분위기에서 Fe-Cr 강의 고온부식거동 연구 (Study of High Temperature Corrosion Behavior of Fe-Cr Steel in Sewage Sludge-(SO2-O2-H2O-bal. CO2) mixed Gas Environment)

  • 김민정;박주창;유인선
    • 한국표면공학회지
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    • 제53권2호
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    • pp.72-79
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    • 2020
  • Two Fe-Cr steels of T22 steel and STS430 steel were corroded at 650 and 750℃ for 100hr in sewage sludge-(0.3% SO2-6% O2-10% H2O-balance CO2) mixed gas environment. T22 steel corroded faster than STS430, indicating that the Cr content significantly influence the corrosion rates. T22 formed thick and non-protective Fe2O3 as the major oxide and Fe3O4 as the minor one. With an increase in corrosion temperature, their corrosion rates increased, being accompanied with formation of pores and cracks in the thickened oxide scales that were non-adherent. STS430 steel formed Fe2O3, Fe3O4 as the outer scale and (Fe, Cr)-O as the inner layer by which its corrosion rate is greatly reduced. Both the T22 and STS430 steel samples formed multi-layered scales by outward diffusion of Fe ions and inward diffusion of oxygen and sulfur ions at high-temperature more than 650℃.

Step-Up 공법에 의한 단층래티스돔의 시공시 안정성 연구 (A Study on the Stability of the Single-Layer Latticed Dome during Erection Using the Step-Up Method)

  • 구충모;정환목;김철환
    • 한국공간구조학회논문집
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    • 제12권4호
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    • pp.109-118
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    • 2012
  • The large-space single-layer lattice dome is relatively simpler in terms of the arrangement of the various framework members and of the design of the junction than the multi-layered lattice dome, can reduce the numbers and quantity of the framework members, and has the merit of exposing the beauty of the framework as it stands. The single-layer lattice dome, however, requires a stability investigation of the whole structure itself, along with an analysis of the stress of the framework members, because an unstable phenomenon called "buckling" occurs when its weight reaches critical levels. Many researchers have systematically conducted researches on the stability evaluation of the single-layer lattice dome. No construction case of a single-layer lattice dome with a 300-m-long span, however, has yet been reported anywhere in the world. The large-space dome structure is difficult to erect due to the gigantic span and higher ceiling compared with other common buildings, and its construction cost is generally huge. The method of erecting a structure causes major differences in the construction cost and period. Therefore, many researchers have been conducting various researches on the method of erecting such structure. The step-up method developed by these authors can reduce the construction cost and period to a great extent compared with the other general methods, but the application of this method inevitably requires the development of system supports in the center section as well as pre-existing supports in the boundary sections. In this research, the safety during the construction of a single-layer lattice dome with 300-m-long span using pre-existing materials was examined in the aspect of structural strength, and the basic data required for manufacturing the supports in the application of the step-up method developed by these authors during the erection of the roof structure were obtained.

협업설계를 위한 엔지니어링 프레임워크 개발에 관한 연구 -자동차 서스펜션 모듈에의 적용- (e-Engineering Framework to Support Collaborative Design of Automotive Suspension Systems)

  • 박성환;이재경;이한민
    • 한국전산구조공학회논문집
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    • 제21권6호
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    • pp.555-561
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    • 2008
  • 본 논문에서는 한국기계연구원에서 개발된 자동차 서스펜션을 대상으로 한 협업설계 지원 엔지니어링 프레임워크 개발에 관하여 기술한다. 개발된 엔지니어링 프레임워크는 각 분야별 전문가 지식에 기초한 엔지니어링 task agent를 포함한 다양한 복수 계층의 소프트웨어 에이전트로 구성된다. 본 프레임워크는 폭 넓은 국내 중소제조기업 적용 확산을 목적으로 JADE(Java Agent Development Framework)와 같은 공개 소스 프로그램 기반으로 개발하였으며, 프레임워크의 확장성을 유지하기 위하여 관련 H/W 및 응용 S/W의 독립성을 가능한 한 유지하도록 노력하였다. 개발된 프레임워크는 제품개발과 정에 있어 지역적으로 분산된 사용자 및 엔지니어링 자원 등을 효과적으로 활용할 수 있는 통합된 협업 설계환경을 제공한다. RR/FR lower arm 및 RR cross member와 같은 몇 개의 실제 자동차 서스펜션 모듈의 설계엔지니어링 문제에의 적용을 통하여 본 시스템의 적용성과 효율성을 확인하였다.