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Fabrication of Hierarchical Nanostructures Using Vacuum Cluster System

  • Lee, Jun-Young;Yeo, Jong-Souk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.389-390
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    • 2012
  • In this study, we fabricate a superhydrophobic surface made of hierarchical nanostructures that combine wax crystalline structure with moth-eye structure using vacuum cluster system and measure their hydrophobicity and durability. Since the lotus effect was found, much work has been done on studying self-cleaning surface for decades. The surface of lotus leaf consists of multi-level layers of micro scale papillose epidermal cells and epicuticular wax crystalloids [1]. This hierarchical structure has superhydrophobic property because the sufficiently rough surface allows air pockets to form easily below the liquid, the so-called Cassie state, so that the relatively small area of water/solid interface makes the energetic cost associated with corresponding water/air interfaces smaller than the energy gained [2]. Various nanostructures have been reported for fabricating the self-cleaning surface but in general, they have the problem of low durability. More than two nanostructures on a surface can be integrated together to increase hydrophobicity and durability of the surface as in the lotus leaf [3,5]. As one of the bio-inspired nanostructures, we introduce a hierarchical nanostructure fabricated with a high vacuum cluster system. A hierarchical nanostructure is a combination of moth-eye structure with an average pitch of 300 nm and height of 700 nm, and the wax crystalline structure with an average width and height of 200 nm. The moth-eye structure is fabricated with deep reactive ion etching (DRIE) process. $SiO_2$ layer is initially deposited on a glass substrate using PECVD in the cluster system. Then, Au seed layer is deposited for a few second using DC sputtering process to provide stochastic mask for etching the underlying $SiO_2$ layer with ICP-RIE so that moth-eye structure can be fabricated. Additionally, n-hexatriacontane paraffin wax ($C_{36}H_{74}$) is deposited on the moth-eye structure in a thermal evaporator and self-recrystallized at $40^{\circ}C$ for 4h [4]. All of steps are conducted utilizing vacuum cluster system to minimize the contamination. The water contact angles are measured by tensiometer. The morphology of the surface is characterized using SEM and AFM and the reflectance is measured by spectrophotometer.

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Earthquake events classification using convolutional recurrent neural network (합성곱 순환 신경망 구조를 이용한 지진 이벤트 분류 기법)

  • Ku, Bonhwa;Kim, Gwantae;Jang, Su;Ko, Hanseok
    • The Journal of the Acoustical Society of Korea
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    • v.39 no.6
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    • pp.592-599
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    • 2020
  • This paper proposes a Convolutional Recurrent Neural Net (CRNN) structure that can simultaneously reflect both static and dynamic characteristics of seismic waveforms for various earthquake events classification. Addressing various earthquake events, including not only micro-earthquakes and artificial-earthquakes but also macro-earthquakes, requires both effective feature extraction and a classifier that can discriminate seismic waveform under noisy environment. First, we extract the static characteristics of seismic waveform through an attention-based convolution layer. Then, the extracted feature-map is sequentially injected as input to a multi-input single-output Long Short-Term Memory (LSTM) network structure to extract the dynamic characteristic for various seismic event classifications. Subsequently, we perform earthquake events classification through two fully connected layers and softmax function. Representative experimental results using domestic and foreign earthquake database show that the proposed model provides an effective structure for various earthquake events classification.

Preparation and Properties of Organic Electroluminescent Devices Using Low Molecule Compounds (저분자 화합물을 이용한 유기 전계발광소자의 제작과 특성 연구)

  • 노준서;조중연;유정희;장영철;장호정
    • Journal of the Microelectronics and Packaging Society
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    • v.10 no.1
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    • pp.1-5
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    • 2003
  • The multi-layered OELDs(organic electroluminescent devices) were prepared on the patterened ITO (indium tin oxide)/glass substrates by the vacuum thermal evaporation method. The $Alq_3$ (tris-(8-hydroxyquinoline)aluminum) low molecule compound was used as the light emission layer. TPD(triphenyl-diamine) and $\alpha-NPD$ were used as the hole transport layer. CuPc (Copper phthalocyanine) was also used as the hole injection layers. In addition, QD2 (quinacridone2) organic material with $10\AA$ thickness was deposited in the $Alq_3$ emission layer to improve the luminance efficiency. The threshold voltage was about 7V for all devices. The luminance and efficiency of devices was improved by substitution the $\alpha-NPD$ for TPD as the hole as the hole transport layer. The luminance efficiency of the OELD sample with QD2 thin film in the $Alq_3$ emission layer was found to be 1.55 lm/W, which is about 8 times larger value compared to the sample without QD2 thin layer.

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Interaction analysis of Continuous Slab Track (CST) on long-span continuous high-speed rail bridges

  • Dai, Gonglian;Ge, Hao;Liu, Wenshuo;Chen, Y. Frank
    • Structural Engineering and Mechanics
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    • v.63 no.6
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    • pp.713-723
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    • 2017
  • As a new type of ballastless track, longitudinal continuous slab track (CST) has been widely used in China. It can partly isolate the interaction between the ballastless track and the bridge and thus the rail expansion device would be unnecessary. Compared with the traditional track, CST is composed of multi layers of continuous structures and various connecting components. In order to investigate the performance of CST on a long-span bridge, the spatial finite element model considering each layer of the CST structure, connecting components, bridge, and subgrade is established and verified according to the theory of beam-rail interaction. The nonlinear resistance of materials between multilayer track structures is measured by experiments, while the temperature gradients of the bridge and CST are based on the long-term measured data. This study compares the force distribution rules of ballasted track and CST as respectively applied to a long span bridge. The effects of different damage conditions on CST structures are also discussed. The results show that the additional rail stress is small and the CST structure has a high safety factor under the measured temperature load. The rail expansion device can be cancelled when CST is adopted on the long span bridge. Beam end rotation caused by temperature gradient and vertical load will have a significant effect on the rail stress of CST. The additional flexure stress should be considered with the additional expansion stress simultaneously when the rail stress of CST requires to be checked. Both the maximum sliding friction coefficient of sliding layer and cracking condition of concrete plate should be considered to decide the arrangement of connecting components and the ultimate expansion span of the bridge when adopting CST.

A study of the light trapping mechanism in periodically honeycomb texture-etched substrate for thin film silicon solar cells

  • Kim, Yongjun;Shin, Munghun;Park, Hyeongsik;Yi, Junsin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.147.2-148
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    • 2016
  • Light management technology is very important for thin film solar cells, which can reduce optical reflection from the surface of thin film solar cells or enhance optical path, increasing the absorption of the incident solar light. Using proper light trapping structures in hydrogenated amorphous silicon (a-Si:H) solar cells, the thickness of absorber layers can be reduced. Instead, the internal electric field in the absorber can be strengthened, which helps to collect photon generated carriers very effectively and to reduce light-induced loss under long-term light exposure. In this work, we introduced a chemical etching technology to make honey-comb textures on glass substrates and analyzed the optical properties for the textured surface such as transmission, reflection and scattering effects. Using ray optics and finite difference time domain method (FDTD) we represented the behaviors of light waves near the etched surfaces of the glass substrates and discussed to obtain haze parameters for the different honey-comb structures. The simulation results showed that high haze values were maintained up to the long wavelength range over 700 nm, and with the proper design of the honey-comb structure, reflection or transmission of the glass substrates can be enhanced, which will be very useful for the multi-junction (tandem or triple junction) thin film a-Si:H solar cells.

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Unified solutions for piezoelectric bilayer cantilevers and solution modifications

  • Wang, Xianfeng;Shi, Zhifei
    • Smart Structures and Systems
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    • v.16 no.5
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    • pp.759-780
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    • 2015
  • Based on the theory of piezoelasticity, the static performance of a piezoelectric bilayer cantilever fully covered with electrodes on the upper and lower surfaces is studied. Three models are considered, i.e., the sensor model, the driving displacement model and the blocking force model. By establishing suitable boundary conditions and proposing an appropriate Airy stress function, the exact solutions for piezoelectric bilayer cantilevers are obtained, and the effect of ambient thermal excitation is taken into account. Since the layer thicknesses and material parameters are distinguished in different layers, this paper gives unified solutions for composite piezoelectric bilayer cantilevers including piezoelectric bimorph and piezoelectric heterogeneous bimorph, etc. For some special cases, the simplifications of the present results are compared with other solutions given by other researches based on one-dimensional constitutive equations, and some amendments have been found. The present investigation shows: (1) for a PZT-4 piezoelectric bimorph, the amendments of tip deflections induced by an end shear force, an end moment or an external voltage are about 19.59%, 23.72% and 7.21%, respectively; (2) for a PZT-4-Al piezoelectric heterogeneous bimorph with constant layer thicknesses, the amendments of tip deflections induced by an end shear force, an end moment or an external voltage are 9.85%, 11.78% and 4.07%, respectively, and the amendments of the electrode charges induced by an end shear force or an end moment are both 1.04%; (3) for a PZT-4-Al piezoelectric heterogeneous bimorph with different layer thicknesses, the maximum amendment of tip deflection approaches 23.72%, and the maximum amendment of electrode charge approaches 31.09%. The present solutions can be used to optimize bilayer devices, and the Airy stress function can be used to study other piezoelectric cantilevers including multi-layered piezoelectric cantilevers under corresponding loads.

Application of rhBMP-2 loaded collagen membrane on the buccal plate for ridge preservation: a pilot study in dogs (성견의 발치와 협측골 외측에 적용한 교원질 차단막과 재조합 골형성단백질의 치조제 보존 효과)

  • Lim, Hyun-Chang;Kim, Min-Soo;Yang, Cheryl;Lee, Jung-Seok;Choi, Seong-Ho;Jung, Ui-Won
    • The Journal of the Korean dental association
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    • v.53 no.5
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    • pp.348-359
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    • 2015
  • Objective: The aim of this study was to determine the effect of multi-layer of a collagen membrane alone or loaded rhBMP-2 on the buccal plate for ridge preservation after tooth extraction. Material and methods: Following bilateral extraction of the maxillary 1st and 3rd premolars in five dogs, rhBMP-2 loaded collagen membrane was applied to the buccal plates at the 1st premolar and collagen membrane only was applied to the buccal plates at the 3rd premolar unilaterally. The collagen membranes applied in the experimental groups were piled into four layers. The corresponding sites of the contralateral side healed naturally. After 3months of healing, the animals were sacrificed. Radiographic and histologic analyses were performed. Results: There was no significant difference in the healing of extraction socket at both 1st and 3rd premolars. In microcomputed tomography, the widths of the residual ridge of the experimental groups were similar with the controls. Histologically, the experimental groups did not exhibit different pattern compared to the controls regardless of the addition of rhBMP-2. Conclusion: Layering of the collagen membrane with or without rhBMP-2 on the buccal plate failed to show the effectiveness in dimensional preservation of the extraction socket.

Polybenzimidazole (PBI) Coated CFRP Composite as a Front Bumper Shield for Hypervelocity Impact Resistance in Low Earth Orbit (LEO) Environment

  • Kumar, Sarath Kumar Sathish;Ankem, Venkat Akhil;Kim, YunHo;Choi, Chunghyeon;Kim, Chun-Gon
    • Composites Research
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    • v.31 no.3
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    • pp.83-87
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    • 2018
  • An object in the Low Earth Orbit (LEO) is affected by many environmental conditions unlike earth's surface such as, Atomic oxygen (AO), Ultraviolet Radiation (UV), thermal cycling, High Vacuum and Micrometeoroids and Orbital Debris (MMOD) impacts. The effect of all these parameters have to be carefully considered when designing a space structure, as it could be very critical for a space mission. Polybenzimidazole (PBI) is a high performance thermoplastic polymer that could be a suitable material for space missions because of its excellent resistance to these environmental factors. A thin coating of PBI polymer on the carbon epoxy composite laminate (referred as CFRP) was found to improve the energy absorption capability of the laminate in event of a hypervelocity impact. However, the overall efficiency of the shield also depends on other factors like placement and orientation of the laminates, standoff distances and the number of shielding layers. This paper studies the effectiveness of using a PBI coating on the front bumper in a multi-shock shield design for enhanced hypervelocity impact resistance. A thin PBI coating of 43 micron was observed to improve the shielding efficiency of the CFRP laminate by 22.06% when exposed to LEO environment conditions in a simulation chamber. To study the effectiveness of PBI coating in a hypervelocity impact situation, experiments were conducted on the CFRP and the PBI coated CFRP laminates with projectile velocities between 2.2 to 3.2 km/s. It was observed that the mass loss of the CFRP laminates decreased 7% when coated by a thin layer of PBI. However, the study of mass loss and damage area on a witness plate showed CFRP case to have better shielding efficiency than PBI coated CFRP laminate case. Therefore, it is recommended that PBI coating on the front bumper is not so effective in improving the overall hypervelocity impact resistance of the space structure.

Analysis of the machinability of GFRE composites in drilling processes

  • Khashaba, Usama. A.;Abd-Elwahed, Mohamed S.;Ahmed, Khaled I.;Najjar, Ismail;Melaibari, Ammar;Eltaher, Mohamed A
    • Steel and Composite Structures
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    • v.36 no.4
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    • pp.417-426
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    • 2020
  • Drilling processes in fiber-reinforced polymer composites are essential for the assembly and fabrication of composite structural parts. The economic impact of rejecting the drilled part is significant considering the associated loss when it reaches the assembly stage. Therefore, this article tends to illustrate the effect of cutting conditions (feed and speed), and laminate thickness on thrust force, torque, and delamination in drilling woven E-glass fiber reinforced epoxy (GFRE) composites. Four feeds (0.025, 0.05, 0.1, and 0.2 mm/r) and three speeds (400, 800, and 1600 RPM) are exploited to drill square specimens of 36.6×36.6 mm, by using CNC machine model "Deckel Maho DMG DMC 1035 V, ecoline". The composite laminates with thicknesses of 2.6 mm, 5.3 mm, and 7.7 mm are constructed respectively from 8, 16, and 24 glass fiber layers with a fiber volume fraction of about 40%. The drilled specimen is scanned using a high-resolution flatbed color scanner, then, the image is analyzed using CorelDraw software to evaluate the delamination factor. Multi-variable regression analysis is performed to present the significant coefficients and contribution of each variable on the thrust force and delamination. Results illustrate that the drilling parameters and laminate thickness have significant effects on thrust force, torque, and delamination factor.

Energy separation and carrier-phonon scattering in CdZnTe/ZnTe quantum dots on Si substrate

  • Man, Min-Tan;Lee, Hong-Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.191.2-191.2
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    • 2015
  • Details of carrier dynamics in self-assembled quantum dots (QDs) with a particular attention to nonradiative processes are not only interesting for fundamental physics, but it is also relevant to performance of optoelectronic devices and the exploitation of nanocrystals in practical applications. In general, the possible processes in such systems can be considered as radiative relaxation, carrier transfer between dots of different dimensions, Auger nonradiactive scattering, thermal escape from the dot, and trapping in surface and/or defects states. Authors of recent studies have proposed a mechanism for the carrier dynamics of time-resolved photoluminescence CdTe (a type II-VI QDs) systems. This mechanism involves the activation of phonons mediated by electron-phonon interactions. Confinement of both electrons and holes is strongly dependent on the thermal escape process, which can include multi-longitudinal optical phonon absorption resulting from carriers trapped in QD surface defects. Furthermore, the discrete quantized energies in the QD density of states (1S, 2S, 1P, etc.) arise mainly from ${\delta}$-functions in the QDs, which are related to different orbitals. Multiple discrete transitions between well separated energy states may play a critical role in carrier dynamics at low temperature when the thermal escape processes is not available. The decay time in QD structures slightly increases with temperature due to the redistribution of the QDs into discrete levels. Among II-VI QDs, wide-gap CdZnTe QD structures characterized by large excitonic binding energies are of great interest because of their potential use in optoelectronic devices that operate in the green spectral range. Furthermore, CdZnTe layers have emerged as excellent candidates for possible fabrication of ferroelectric non-volatile flash memory. In this study, we investigated the optical properties of CdZnTe/ZnTe QDs on Si substrate grown using molecular beam epitaxy. Time-resolved and temperature-dependent PL measurements were carried out in order to investigate the temperature-dependent carrier dynamics and the activation energy of CdZnTe/ZnTe QDs on Si substrate.

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