• Title/Summary/Keyword: Mooney

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Studies on the Prevention of Polymer degradation by Ozone (part 1, Effect of Reactive Antioxidant) (오존에 의(依)한 고분자(高分子)의 해중합방지연구(解重合防止硏究), 오존화방지제(化防止劑)의 각탄성체(各彈性體)에 대(對)한 효과(效果) (제1보(第1報)))

  • Choi, Moon-Sul;Paik, Nam-Chul
    • Elastomers and Composites
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    • v.13 no.2
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    • pp.89-98
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    • 1978
  • 1. The effect of reactive type antioxidant, G-1 in comparism to ordinary antioxidant, SP, which are used for NR and SBR has teen studied, and its recipes are equal. The effects against ozone aye been shown that ill ordinary antioxidant, SBR, no an particular effect both for NR and SBR was found, where as in reactive type, considerable influence was recogniged particulary in dynamic ozone test. 2. The influence of reactive antioxidants on velcanization has been studied by means of Mooney viscometer and Rheometer. 3. The ageing properties of vulcanizates containing reactive antioxidant have been studied in terms of tensile strength.

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Cure Characteristics, Mechanical Properties and Abrasion Resistance of Silica Filled Natural Rubber Vulcanizate

  • Lee, Hae Gil;Park, Chan Young
    • Elastomers and Composites
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    • v.50 no.3
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    • pp.159-166
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    • 2015
  • Silica which is used for reinforcing filler in tire industry is widely known as eco-friendly material exerting $CO_2$ reduction effect through decrease of rolling resistance and improvement of wet grip. Generally silica is classified as a highly polar filler because it contains a large number of silanol (Si-OH) group on its surface. And also silica gives a lower reinforcing effect than carbon black due to its poorer rubber-filler interaction. Therefore silica is treated with silane coupling agent or activator, then following the conventional rubber blend method, vulcanized sheets were prepared using a hot press, and cure characteristics, mechanical properties and abrasion resistance of the test specimens were investigated. It was found that with an increase in the silane coupling agent content the tensile strength, 300% modulus and abrasion resistance increased while Mooney viscosity decreased and crosslink density slightly increased with an increase of activator.

Study on Property Modification with Fire Retardant Content in the Manufacture of Compounds for Cable Sheath (전선피복용 컴파운드의 제조에서 난연제의 첨가량에 따른 물성 변화 연구)

  • Li, Xiangxu;Lee, Sang Bong;Cho, Ur Ryong
    • Journal of the Semiconductor & Display Technology
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    • v.18 no.3
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    • pp.47-51
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    • 2019
  • The three different polymer compounds were manufactured with the three different fire retardant (silane coated magnesium dihydroxide) contents, 180, 200, 220 phr, for making cable sheath for ship industry. In the research, ethylene-vinylacetate, polyethylene as matrix polymers and ethylene-vinylacetate grafted maleic anhydride as coupling agent were selected for compounding with fire retardant, closslinking agent, plasticizer, and other additives. In the evaluation. ΔT, Mooney viscosity, and tensile strength increased with the content of fire retardant. But it was found that too much fire retardant damaged aging resistance and cold resistance of the polymer compound.

Influence of Mixing Procedure on Properties of Carbon Black-filled Natural Rubber Compounds

  • Park, Sung-Seen
    • Macromolecular Research
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    • v.8 no.4
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    • pp.192-198
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    • 2000
  • Cure characteristics and physical properties of carbon black-filled natural rubber (NR) compounds depending on the mixing procedure were studied using the compounds with different pre-final mixing (FM-1) stages. Carbon master batch (MB) and first and second remitting (1RM and 2RM) stages were employed as the FM-1 stage. Bound rubber content of the FM compound decreased with increasing the mixing steps. This was due to the decrease of the molecular weight distribution of the polymer by the rubber chain scission during the mixing. The Mooney viscosity decreased with increasing the mixing steps. Cure characteristics of the compounds were found to be different with the mixing procedures. The cure times of the compound became slower by increasing the number of the mixing steps. This was explained by the length of rubber chain, the carbon black network, distribution of the curatives in the compound, and immobilization of the polymeric segments. Modulus and tensile strength of the vulcanizate did not show a specific trend with the mixing procedure. Fatigue life of the vulcanizate increased by increasing the mixing stages.

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Properties of Silica-SBR Compounds Using Cellulose Dispersant Applicable to Tire Tread Rubber

  • Kim, Jung Soo;Kim, Dong Hyun
    • Elastomers and Composites
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    • v.55 no.3
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    • pp.176-183
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    • 2020
  • Silica-styrene butadiene rubber (Silica-SBR) compounds have been used in the preparation of tire treads. The silica dispersibility of silica-SBR compounds is related to the processability, mechanical properties, and wear resistance of tires. Recently, in order to improve the silica dispersibility of the silica-SBR compounds, the wet masterbatch (WMB) process was introduced, which is a method of mixing rubber in the water phase. We aimed to improve the silica dispersibility of the silica-SBR compounds by preparing a silica dispersant applicable to the WMB process. For this purpose, cellulose, 2-hydroxyethyl cellulose, and cellulose acetate were employed as a silica dispersant. The silica dispersibility of the compounds was measured by a moving die rheometer. Improvement in the processability of silica-SBR compounds was evaluated by the Mooney viscometer. The wear resistance of silica-SBR compounds using a cellulose dispersant was improved by up to 29%.

Preparation and Properties of Printing Rubber Roller : (I) Oil Resistance and Mechanical Properties of Butabiene Rubber/Nitrile Rubber Compounds (인쇄용 고무roller의 제조와 물성: (I) 부타디엔고무와 니트릴고무 혼련물의 내유성 및 기계적 성질)

  • 박찬영
    • Journal of the Korean Graphic Arts Communication Society
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    • v.18 no.2
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    • pp.83-101
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    • 2000
  • In this experiment butadiene rubber(BR)/acrylonitrile butadiene rubber(NBR) blends was prepared and then the applicability of BR/NBR blends as printing rubber roller was examined. With the aid of open 2-roll mill, BR, NBR and another chemical additives were compounded. Then rubber vulcanizates were manufactured by hot press and maximum torque, Mooney viscosity, mechanical properties and oil resistance of the test specimens were measured. With prolonged oil aged treating time, BR/NBR blends became soft and so the hardness of blends decreased. It could be explained by the swelling of rubber matrix with oil penetration in to rubber molecules. The undesirable low value of oil resistance of BR was significantly improved by blending BR with NBR.

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Damage Evaluation of CD-RW Drive by Drop Test and Simulation (CD-RW Drive의 낙하충격 손상평가)

  • Woo Jae Chul;Yun Ki Won;Seok Ki Young;Kim Heon Young;Kim Sang Bum
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.29 no.1 s.232
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    • pp.81-87
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    • 2005
  • A fracture of hand held device, such as radio, TV and CD-RW drive, mainly occurs due to drop situation. For CD-RW drive, the need of high reading/writing speed in conjunction with low price accelerates the fracture of the device. Computer simulation can reduce the period of development and enhance impact characteristic of device. In this study, the detailed finite element model of CD-RW drive was developed to predict the damage under drop conditions. Material property for shock absorbing damper was obtained from tensile test of raw material. A MOONEY-RIVLIN type rubber in LS-DYNA was used as the material model of damper. To assess the reliability of the developed model, drop test at 200G-2msec and 150G-10msec condition was conducted and acceleration at pick-up was compared.

Reinforcing Performance of Networked Silicas in Silica-filled Chloroprene Rubber Compounds

  • Ryu, Changseok;Yang, Jae-Kyoung;Park, Wonhyeong;Kim, Sun Jung;Kim, Doil;Seo, Gon;Kim, Wook-Soo;Ahn, Ki Woong;Kim, Beak Hwan
    • Elastomers and Composites
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    • v.54 no.1
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    • pp.40-53
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    • 2019
  • The physical properties of chloroprene rubber (CR) compounds reinforced with networked silicas were investigated by comparing them to those reinforced with conventional silica to observe the effect of the organic connection bonds combining silica particles on their cure, tensile, and aging performance. The introduction of networked silica to CR increase in silica content to 80 phr in rubber, while the content of conventional silica was limited to 60 phr. The CR compounds reinforced with networked silica showed higher resistance to combustion. The gradual increases in delta torque, Mooney viscosity, and modulus of silica-filled CR compounds with silica content were mainly attributed to the specific interaction between the chlorine atoms of CR and the hydroxyl groups of silica. The CR compounds reinforced with networked silica showed low compression set and heat build-up and maintained their high modulus even after thermal, oil, and ozone aging.

Structural Simulation of Wrist Band for Wearable Device According to Design and Material Model

  • Kwon, Soon Yong;Cho, Jung Hwan;Yoo, Jin;Cho, Chul Jin;Cho, Sung Hwan;Woo, In Young;Lyu, Min-Young
    • Elastomers and Composites
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    • v.53 no.4
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    • pp.226-233
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    • 2018
  • Elastomers based on the thermoplastics are widely used in rubber industries. Thermoplastic elastomers have the advantages of an easy shaping process and elimination of recycling problems. Thermoplastic polyester elastomer (TPE) is used for making rubber bands in wearable devices and its applications are increasing. In this study, five wrist bands were designed and their mechanical behaviors were examined by computer simulation, using hyper elastic models, Mooney-Rivlin and Ogden models, and a linear elastic model. Simulation results were compared and discussed in terms of band design and material model.

Study on Manufacture and Properties of Polymer Compounds for Cable Sheath (전선피복용 고분자 컴파운드의 제조 및 물성 연구)

  • Li, Xiangxu;Lee, Sang Bong;Cho, Ur Ryong
    • Journal of the Semiconductor & Display Technology
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    • v.18 no.1
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    • pp.42-47
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    • 2019
  • The four different polymer compounds were manufactured to make cable sheath for ship industry. Two kinds of ethylene-vinyl acetate (EVA) were selected as main matrix polymers for compounding with fire retardant, crosslinking agent, filler, plasticizer, and other additives. The properties of the four compounded materials were investigated with the contents of fire retardant, silane coated aluminum hydroxide (S-ATH). Rheology, Mooney viscosity, and tensile strength increased with S-ATH contents by reinforcing effect. With increasing fire retardant amount, fire resistance increased, but cold resistance didn't show an obvious enhancement due to polar effect of vinyl acetate in EVA.