• 공업화학
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• 제10권6호
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• pp.949-953
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• 1999

반도체 봉지재에 쓰이는 EMC(Epoxy Molding Compound)는 고농도의 충전제를 함유하고 있는데, 이 충전제의 양과 성질에 따라 유동 특성이 크게 달라진다. 본 연구에서는 충전제의 농도, 입자모양, 크기에 따른 EMC(에폭시/실리카)의 점도변화 특성을 조사하였고, 이를 Mooney 식을 사용하여 예측하여 보았다. Mooney 식에 포함되어 있는 최대 충전율과 형상인자 중 최대 충전율은 Ouchiyama의 충전 모델과 Taguchi의 방법을 이용하여 구하였고, 형상인자는 실험자료를 이용하여 구하였다. 구해진 Mooney 식은 EMC의 점도 거동을 잘 예측하였다.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2010년도 추계학술대회 논문집
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• pp.895-896
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• 2010

• 한국자동차공학회논문집
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• 제11권4호
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• pp.125-134
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• 2003

In this study, Mooney-Rivlin 1st model and Mooney-Rivlin 3rd model are adopted as strain energy density functions of the rubber compounds of a radial tire. It is shown that the FE analysis using Mooney-Rivlin models for rubber compounds may provide good approximations by employing the appropriate strain range of experimental stress-strain data in a way to describe the stress-strain relationship accurately. Especially, Mooney-Rivlin 3rd model gives an accurate stress-strain relationship regardless of the fitting strain range used within the strain of 100%. The static nonlinear FE analysis of a tire inflation is performed by employing an axisymmetric model, which shows that the outside shapes of the tire before and after inflating the tire agree well with those of the real tire. Additionally, the deformations at crown center and turning point on sidewall, distribution of belt cord force, interlaminar shear strain are predicted in terms of variation of belt cord angle which is known as the most influential factor in inflation behavior of a tire.

• 대한기계학회논문집A
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• 제30권10호
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• pp.1227-1234
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• 2006

Up to now, several mathematical theories based on strain energy functions have been developed for rubber materials. These theories, coupled with the finite element method, can be used very effectively by engineers to analyze and design rubber components. However, due to the complexities of the mathematical formulations and the lack of general guidelines available fur the analysis of rubber components, it is a formidable task for an engineer to analyze rubber components. In this paper a method for predicting strain energy functions - Neo-Hookean model and Mooney-Rivlin model - from the hardness using the empirical equation without any experiment is discussed. First based on the elasticity theories of rubber, the relation between stress and strain is defined. Then for the butyl rubbers, the model constants of Neo-Hookean model and Mooney-Rivlin model are calculated from uniaxial tension tests. From the results, the usefulness of the empirical equation to estimate elastic modulus from hardness is confirmed and, fur Mooney-Rivlin model, the predicted and the experimental model constants are compared and discussed.

• Elastomers and Composites
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• 제17권1호
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• pp.13-21
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• 1982

The purpose of this dissertation is to compare bound andtioxidant, MHPPD with the ordinary one, IPPD, when high polymers are used like NR and SBR. The effect of rubber bound antioxidant and ordinary antioxidant on the Mooney scorch time has been studied by means of the Mooney viscometer. The ageing properties of vulcanizates containing rubber-bound antioxidant and ordinary antioxidant have been studied in terms of hardness, tensile strength and elongation. The results of the Mooney scorch time and ageing properties are as follows: When MHPPD was mixed with NR or SBR compounds, the Mooney scorch time was faster than the IPPD compounds. Also the ageing properties of the vulcanizates containing MHPPD were much superior to the IPPD compounds. Furthermore, the vulcanizates comporised of MHPPD have taken andvantage of and resistance in the ozone test.

• 한국정밀공학회지
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• 제20권11호
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• pp.150-157
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• 2003

In this paper, the large deformation of hollow silicon rubber gasket is treated. The frictional contact occurs between groove and the outer part of hollow gasket, and the frictional self-contact exists in the inner parts of hollow gasket. The silicon rubber has the nonlinear elastic behavior and its material property is approximately incompressible. Hence, the stress analysis requires an existence of a strain energy function, which is usually defined in terms of invariants or stretch ratio such as generalized Mooney-Rivlin and Ogden model. Considering large compressive deformation and friction, Mooney-Rivlin 3rd model and Coulomb's friction model are assumed. The numerical analysis is obtained by the commercial finite element program MARC. But, due to large deformation, the elements degenerate in the inner parts of hollow gasket. This means that the analysis of subsequent increments is carried out with a very poor mesh. In order to continue the analysis with a sufficient accuracy, it is necessary to use new finite element modeling by remesh. Experiments are also performed to show the validity of present method. As a conclusion, numerical results by this research have good agreements with experiments.

• Elastomers and Composites
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• 제7권1호
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• pp.21-37
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• 1972

We have studied the blending effects of Diene NF 35R and Turfdene 1000R at various blending ratios 100/0, 70/30, 50/50, 30/70, 0/100, and of carbon black NAF and ISAF at various compounding ratios of 55 PHR, 65PHR, 75PHR for tyre tread rubber. As the results, it was found that; 1. For tyre tread rubber, as the blending ratio, Diene NF 35R/Turfdene 1000R, indicated 30/70, the physical properties we examined were most excellent. 2. Excellent result was obtained in case of carbon black compounding ratio of 63PHR. The compounding of ISAF made better result than that of HAF for tensile strength, tearing strength, and abrasion quantity. 3. Heat buildup obtained from compounding carbon black HAF indicated low temperature than that from compounding carbon black ISAF. As the compounding amount of carbon black increased, the heat buildup improved, and as the blending amount of Diene NF 35R decreased, the heat buildup dropped. 4. Carbon black was more efficient to Turfdene 1000R than to Diene NF 35R. 5. In this pysical properties, mooney viscosity, and mooney scorch time, as the compounding amount of carbon black increased, the values of mooney viscosity increased, but that of mooney scorch time dropped.

• Elastomers and Composites
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• 제48권2호
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• pp.148-155
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• 2013

폴리머의 가교밀도는 팽윤 실험 데이터를 이용한 Flory-Rehner 식에 의하여 정량적으로 계산할 수 있는데, Flory-Rehner 식에서 상호계수 (${\chi}$) 항에 있는 lattice constant ${\beta}_1$ 값은 주의해서 선정되어야 한다. 이 ${\beta}_1$ 값은 경험에 의한 실험값으로 연구자에 따라 조금씩 다른 값이 선택되어 사용되고 있다. 일반적으로 Mooney-Rivlin 식에서 가교점 사이의 평균 분자량 $M_c$ 값은 Flory-Rehner 식에서의 $M_c$ 값과 동일한 의미를 가지며 Mooney-Rivlin 식으로부터 $M_c$ 값을 구하면 Flory-Rehner 식에서 ${\beta}_1$ 값을 구할 수 있다. 따라서 본 연구에서는 먼저 Flory-Rehner 식의 상호계수 (${\chi}$) 항의 ${\beta}_1$ (=0.34) 과 1,2,3-트리아졸 폴리머의 팽윤 실험 데이터를 적용하여 $M_c$ 값을 계산하고, 두 번째로 인장 실험 데이터를 이용한 Mooney-Rivlin 식을 이용하여 $M_c$ 값을 계산 후 비교하였다. 결과적으로 두 개의 $M_c$ 값이 거의 유사하여 Flory-Rehner 식의 상호계수 (${\chi}$) 를 위해 선정한 ${\beta}_1$ (=0.34) 값이 적절함을 증명하였다.

• Elastomers and Composites
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• 제17권3호
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• pp.151-158
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• 1982

The purpose of this study is to get comparitive results on the combined accelerator systems comprised of MBT, MBTS, DPG and CBS with TMTD, TMTM, Zn-MDC and DPG to SBR compound. Vulcanization characterstics and physical properties of the combined accelerators have been studied by mean of the Mooney viscometer, tensile testing machine, aging chamber and so on. According to the test results, TMTD with DPG system has shown faster Mooney scorch time than other system. The vulcanizate comprise of Zn-MDC with DPG and TMTD with DPG accelerator system has taken advantage of heat resistance.

• 한국산업융합학회 논문집
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• 제2권1호
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• pp.97-103
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• 1999

The power curve during rubber mixing presents useful information for the understanding of rubber mixing process, because the power curve is determined the mixing state of rubber at the point. The time to the second peak on the power curve is known as carbon black incorporation time, BIT. This study gets the quantity relationship of BIT and viscosity of natural rubber, so by determining the mixing time of the compound on the ground of viscosity of the raw rubber. The mixing with natural rubber and carbon black is examined for various grade natural rubbers, encompassing a wide range of Mooney viscosity. Alter smoothing the mixing power curve using a polynomial, the carbon black incorporation time, BIT, was determined time to second power peak on the curve, The BIT's versus specific values on Mooney viscometer test curve show a linear relation, Especially, the peak of initial maximum torque on Mooney viscometer curve, PMT, is most relevant property relating to the BIT. PMT is useful index for determined optimum mixing time, To apply this results at the mixing, we effectively control the natural rubber mixing but can also know the grading of natural rubber upon processability.