• 제목/요약/키워드: Monolayer,

검색결과 1,194건 처리시간 0.023초

p-Nitroazobenzene을 함유한 Polyamic Acid 단분자층의 Langmuir-Blodgett 막에 관한 연구 (A Study on the Langmuir-Blodgett Films of Polyamic Acid Monolayer Containing p-Nitroazobenzene)

  • 박근호
    • 한국응용과학기술학회지
    • /
    • 제28권2호
    • /
    • pp.213-218
    • /
    • 2011
  • Displacement current measuring technique has been applied on the study of polyamic acid monolayer containing p-nitroazobenzene. The displacement current was generated from monolayer on the water surface by monolayer compression and expansion. Maxwell displacement current(MDC) was generated when the area per molecule was about $200{\AA}^2$ and $70{\AA}^2$. Maxwell displacement currents were investigated in connection with monolayer compression cycles. It was found that the maximum of MDC appeared at the molecular area just before the initial rise of surface pressure in compression cycles. The monolayer surface morphology of the LB film have been measured by Atomic Force Microscope(AFM). As a result, we confirmed that the microscopic properties of LB film by AFM showed the good orientation of monolayer molecules and the thickness of monolayer was 3.5-4.1nm.

배양 Caco-2 세포 단층막 실험계에서 트란스페린과 옥시다아제효소 포합체의 세포막투과 (Transport of Transferrin-Horseradish Peroxidase Conjugate Through Cultured Caco-2 Cell Monolayer)

  • 김동출;김지혜
    • Journal of Pharmaceutical Investigation
    • /
    • 제29권4호
    • /
    • pp.287-293
    • /
    • 1999
  • Transport study of horseradish peroxidase and transferrin-horseradish peroxidase conjugate was performed using an in vitro Caco-2 cell cultured monolayer grown on a polycarbonate membrane of $Transwell^{\circledR}$, Horseradish peroxidase was not transported across Caco-2 cell monolayer. Transferrin-horseradish peroxidase conjugate was transported through Caco-2 cell monolayer. The apparent membrane permeability coefficient $(P_{app})$ of transferrin horseradish peroxidase conjugate was $6.54{\times}10^{-7}\;cm/sec$. The $P_{app}$ value of transferrin-horseradish peroxidase conjugate across Caco-2 cell monolayer was increased to $11.9{\times}10^{-7}\;cm/sec$ in the presence of $50\;{mu}g/ml$ brefeldin-A. These results suggest the transferrin receptor mediated transcytosis of transferrin-horseradish peroxidase conjugate across Caco-2 cell monolayer.

  • PDF

Monolayer Rotating Ball Electronic Paper Display

  • Cha, Hye-Yeon;Lee, Choong-Hee;Lee, Sang-Moon;Kwak, Jeong-Bok;Chae, Kyoung-Soo;Lee, Hee-Bum;Lee, Young-Woo;Lee, Chong-Seo;Oh, Yong-Soo;Lee, Hwan-Soo
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
    • /
    • pp.367-369
    • /
    • 2009
  • Optically anisotropic rotating balls were disposed in a monolayer, and controllably closely packed with respect to one another in the monolayer. The close packed monolayer configuration provided high brightness and improved contrast. The monolayer rotating ball display (MRB) electrically demonstrated a fast response time of approximately 40 msec at a voltage of 30 V. Measurements of the rotation as a function of voltage led to surface charge density for the balls in the range of 3-4 ${\mu}C/m^2$.

  • PDF

Different Adsorption Behavior of Rare Earth and Metallic Ion Complexes on Langmuir Monolayers Probed by Sum-Frequency Generation Spectroscopy

  • Sung, Woongmo;Vaknin, David;Kim, Doseok
    • Journal of the Optical Society of Korea
    • /
    • 제17권1호
    • /
    • pp.10-15
    • /
    • 2013
  • Adsorption behavior of counterions under a Langmuir monolayer was investigated by sum-frequency generation (SFG) spectroscopy. By comparing SFG spectra of arachidic acid (AA) Langmuir monolayer/water interface with and without added salt, it was found that the simple trivalent cation $La^{3+}$ adsorbed on AA monolayer only when the carboxylic headgroups are charged (deprotonated), implying that counterion adsorption is induced by Coulomb interaction. On the other hand, metal hydroxide complex $Fe(OH)_3$ adsorbed even on a charge-neutral AA monolayer, indicating that the adsorption of iron hydroxide is due to chemical interaction such as covalent or hydrogen bonding to the headgroup of the molecules at the monolayer.

Barbiturates가 소의 대뇌피질 Synaptosomal Plasma Membrane Vesicles로 부터 추출 제제한 총지질 및 총인지질 인공세포막에 형성된 비대칭적 유동성에 미치는 비대칭적 영향 (Effects of Barbiturates on Transbilayer Fluidity Domains of Phospholipid Model Membrane Monolayers)

  • 윤일;강정숙
    • 대한약리학회지
    • /
    • 제28권1호
    • /
    • pp.103-114
    • /
    • 1992
  • 한국산 2년생 소의 신선한 대뇌피질로 부터 synaptosomal plasma membrane vesicles (SPMV)를 분리한 후 이 SPMV로 부터 추출한 총지질 (SPMVTL) 및 총인지질 (SPMVPL)로서 인공세포막을 제제하였다. SPMVTL 및 SPMVPL의 outer monolayer에 trinitrophenyl groups로 공유결합시킴으로써 형광 probe 1,6-diphenyl-1,3,5-hexatriene (DPH)의 outer monolayer 형광을 선택적으로 소광케한 후 SPMVTL 및 SPMVPL의 inner와 outer monolayer 사이의 비대칭적 유동성 존재 유무를 확인하였던 바 inner monolayer에 비하여 outer monolayer가 유동성이 크다는 것을 확인하였으며 SPMVTL에 비하여 SPMVPL의 유동성이 높았다. 뿐만 아니라 barbiturates는 SPMVTL의 유동성에 대하여는 유의성이 있을 만큼의 증감 효과를 나타내지 않았고 SPMVPL의 유동성은 감소시키되 주로 outer monolayer의 유동성을 감소시킨다는 것을 확인하였으며 barbiturates 종류에 따른 SPMVPL의 총유동성 감소의 크기는 pentobarbital > hexobarbital > amobarbital > phenobarbital의 순이었다.

  • PDF

n-Alkanols가 소의 대뇌피질 Synaptosomal Plasma Membrane Vesicles로부터 추출 제제한 총지질 인공세포막 이중층간에 형성된 비대칭적 유동성에 미치는 비대칭적 영향 (Transbilayer Effects of n-Alkanols on the Fluidity of Model Membranes of Total Lipids Extracted from Synaptosomal Plasma Membrane Vesicles)

  • 윤일;강정숙
    • 대한약리학회지
    • /
    • 제28권2호
    • /
    • pp.191-199
    • /
    • 1992
  • 한국산 2년생 소의 대뇌피질로부터 synaptosomal plasma membrane vesicles(SPMV)를 분리한 후 이 SPMV로부터 추출한 총지질로서 인공세포막(SPMVTL)을 제제하였다. SPMVTL의 outer monolayer에 trinitrophenyl group을 공유결합시킴으로써 SPMVTL이중층에 분포된 형광 probe 1,6-diphenyl-1,3,5-hexatriene(DPH)중 outer monolayer에 분포된 DPH형광만을 소광케 하였다. 형광분석기를 통하여 SPMVTL의 inner monolayer에 비하여 outer monolayer의 유동성이 크다는 것을 확인하였다. n-Alkanols는 SPMVTL지질 이중층(inner+outer monolayers)의 회전확산운동을 증가시키되 탄소수 두개가 증가될 때마다 그 효력이 약10배 가량 증가된다는 것을 알았다. 그러나 1-decanol의 경우에는 1-nonanol에 비하여 그 효력이 낮아지는 소위 cut-off현상이 나타났다. 뿐만 아니라 n-alkanols는 SPMVTL의 inner monolayer에 비하여 outer monolayer의 회전확산운동을 주로 증가시켰다. 하지만 n-alkanols의 탄소수가 증가됨에 따라 outer monolayer에 대한 선택적인 작용이 감소된다는 것도 확인되었다.

  • PDF

DMPC 단분자막의 변위전류 특성 연구 (A Study on Displacement Current DMPC Monolayer)

  • 최용성;조장훈;송진원;이경섭
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
    • /
    • pp.168-169
    • /
    • 2006
  • The physical properties of DMPC monolayer were made for dielectric relaxation phenomena by the detection of the surface pressures and displacements current. The phospolipid monolayer of dielectric relaxation takes a little time and depend on the molecular area.

  • PDF

수면상에서 L-α-Dilauryl phosphatidylcholine 단분자층의 맥스웰 변위전류에 관한 연구 (A Study on the Maxwell Displacement Current in Monolayer of L-α-Dilauryl phosphatidylcholine on the Water Surface)

  • 박근호
    • 한국응용과학기술학회지
    • /
    • 제32권3호
    • /
    • pp.522-527
    • /
    • 2015
  • 변위전류 측정법을 L-${\alpha}$-dilauryl phosphatidylcholine(DLPC) 단분자 막의 연구에 적용하였다. 변위전류는 물 표면에서 DLPC 단분자 층에서 압축과 확장에 의해 발생되었다. 맥스웰 변위전류(MDC) 발생은 분자 당 점유면적 $200{\AA}^2$ 에서 $40{\AA}^2$에 대하여 관찰하였다. 맥스웰 변위전류는 단분자 층의 압축 사이클에 대해 조사하였으며, MDC의 최대 값은 압축 사이클의 표면 압력이 처음 상승하기 바로 직전의 분자당 점유면적에서 나타나는 것을 알 수 있었다. LB막의 단분자층 표면 형태는 원자힘 현미경(AFM)으로 측정하였다. 결과적으로, AFM 이미지에 나타난 LB막의 특성은 단분자 층의 배향이 좋았으며 단분자 층의 두께는 약 5~10 nm였다.

메로시아닌 색소 LB 단분자막의 광메모리 특성에 관한 정성적 연구 (A qualitative study of photomemory characteristics of the LB monolayer films of merocyanine dye)

  • 박태곤;권영수;강도열
    • 대한전기학회논문지
    • /
    • 제44권7호
    • /
    • pp.889-894
    • /
    • 1995
  • The structural changes of the merocyanine monolayer LB (Langmuir Blodgett) films were investigated. These changes were compared with the typical changes of the molecular structures of merocyanine solutions. The structural changes of quinoid/benzenoid were attained by exposure to atmosphere gases (HCl gas, N $H_{3}$ gas). The photoisomerization was not observed for the monolayer LB film due to their state of $M_{trans}$. But we could obtain the cis/trans photoisomerization characteristics reversibly, after the films were changed to M $H^{+}$$_{trans}$ structure by exposure to HCl gas. We also found that the cis/trans photoisomerization of the LB monolayer films show the memory characteristics.s.

  • PDF

IMI-O 고분자의 단분자막과 LB막에 대한 표면분석 (Surface Analysis of LB Films and Monolayer for IMI-O Polymer)

  • 정상범;유승엽;박재철;권영수
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2000년도 영호남학술대회 논문집
    • /
    • pp.265-268
    • /
    • 2000
  • We fabricated an IMI-O polymer containing an imidazole group that could form a complex structure between the monolayer and the metal ions at the air-water interface. Also. the monolayer behavior at the air-water interface and the surface morphology of metal-complexed Langmuir-Blodgett(LB) films were investigated by using Brewster angle microscopy(BAM) and Scanning Maxwell-stress Microscopy(SMM). The difference in the BAM and SMM images between the pure water and the aqueous metal ions is attributed to the interactions of the copolymers with the metal ions at the interface and the consequent change of the monolayer organization.

  • PDF