• Proceedings of the KSME Conference
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• 2003.04a
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• pp.1417-1422
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• 2003

An electrical cascade impactor is a multistage impaction device to separate airborne particles into aerodynamic size classes using electrical method. We designed a real-time three-stage electrical low-pressure impactor, which is proper to nanometer sized environmental aerosols. Performance evaluation was carried out for stage 1 and 2. The monodisperse liquid dioctyl sebacate (DOS) particles were generated using condensation-evaporation followed by electrostatic classification using DMA (differential mobility analizer) for particles with diameters in the range of $0.04{\sim}0.8{\mu}m$. The evaluation of the electrical impactor is based on the use of two electrometers, one connected to the impaction plate of the impactor, and the other to the faraday cage as backup filter. The results showed that the experimental 50% cutoff diameters in the operation pressure were 0.53 and $0.12{\mu}m$ for stage 1 and stage 2. The effect of operation pressure on the cutoff diameter and the steepness of collection effcieicy curves is investigated.

• Applied Chemistry for Engineering
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• v.5 no.6
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• pp.1009-1015
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• 1994

Monodisperse porous poly(styrene-co-divinylbenzene)(St-DVB) gel and poly(acrylonitrile-co-ethylene dimethacrylate)(AN-EDMA) gel have been prepared by seed polymerization using polystyrene seeds, which were prepared by dispersion polymerization. The St-DVB and AN-EDMA gels had a narrow size distribution and pores suitable for packing materials of HPLC. The columns packed with these gels were proved to have high efficiency for GPC or HPLC coluuns. Adsorption properties of $Cu^{2+}$, $Cd^{2+}$ and ${UO_2}^{2+}$ ions on AAN-EDMA gel prepared from amidoximation of AN-EDMA gel were also determined.

• Applied Chemistry for Engineering
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• v.19 no.6
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• pp.609-616
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• 2008

The present study is concerned with a simple numerical method for estimating the hindered settling velocity of noncolloidal suspensions with bidisperse size distribution of particles. The method is based on an effective-medium theory which uses the conditional ensemble averages for describing the velocity fields or other physical quantities of interest in the suspension system with the particles randomly placed. The effective-medium theory originally developed by Acrivos and Chang[1] for monodisperse suspensions is modified for the bidisperse case. Using the radial distribution functions and stream functions the hindered settling velocity of the suspended particles is calculated numerically. The predictions by the present method are compared with the previous experimental results by Davis and Birdsell[2] and Cheung et al.[3]. It is shown that the estimations by the effective-medium model of the present study reasonably agree with the experimental results.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.29 no.6
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• pp.379-382
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• 2019

Synthesis of gold nanoparticles (NPs) made an aqueous environment via the reduction of HAuCl₄ by ascorbic acid (AC) with the surfactant of polyvinylpyrrolidone (PVP). Highly monodisperse gold particles with size ranges from 4 to 20 nm were prepared in high-yield by pH control. The synthesized gold nanoparticles were analyzed for structural and optical properties using transmission electron microscopy (TEM) and UV-vis spectroscopy. In this study, we could reveal that the prepared nanoparticles exhibited efficient surface-enhanced Raman scattering (SERS) properties, and their SERS activities depends on size.

• Particle and aerosol research
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• v.5 no.2
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• pp.83-90
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• 2009

This paper describes a condensation-evaporation method (CEM) to produce size-controlled spherical silver nanoparticles by perturbing coagulation and coalescence processes in the gas phase. Polydisperse silver nanoparticles generated by the CEM were first introduced into a differential mobility analyzer (DMA) to select a group of silver nanoparticles with same electrical mobility, which also enables to make a group of nanoparticles with elongated structures and same projected area. These silver nanoparticles selected by the DMA were then in-situ sintered at ${\sim}600^{\circ}C$, and then they were observed to turn into spherical shaped nanoparticles by the rapid coalescence process. With the assistance of modified converging-typed quartz reactor, we can also produce the 10 times higher number concentration of silver nanoparticles compared with a general quartz reactor with uniform diameter. Finally, the spherical silver nanoparticles with 30 nm were electrostatically deposited on the surface of silicon substrate with the coverage rate of ~4%/hr. This useful preparation method of size-controlled monodisperse silver nanoparticles developed in this work can be applied to the various studies for characterizing the physical, chemical, optical, and biological properties of nanoparticles as a function of their size.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.24 no.6
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• pp.760-768
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• 2000

Filter efficiency of electrically charged particle in uncharged fibrous filter was measured. In previous studies, the effect of charged particle on filter efficiency was investigated but there was difficulty in measuring of image effect that is appeared at the charged small particle. We could easily measure the image effect with charging small particles by photoelectric charging. The spark discharge aerosol generator and a differential mobility analyzer (DMA) were used to generate sub-micron monodisperse particles (${\leq}200$ nm). The generated particles were charged in photoelectric charging process using ultraviolet lamp and electric field. The filter efficiency of the charged particles, classified by another DMA, was measured in filter tester using a condensation nucleus counter (CNC) as function of particle diameter, particle charge and airflow velocity. It is shown that the filter efficiency increases with increasing charge number of the particle and is affected by particle size and flow velocity. Single fiber filter efficiency mainly depends on image force parameter and peclet number. The peclet number was not considered at previous other papers. We propose a modi fied experimental correlation as function of image force parameter and peclet number.

• Journal of Korean Society for Atmospheric Environment
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• v.15 no.6
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• pp.799-804
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• 1999

Particle collection characteristics of the MOUDI cascade impactor has been studied for coarse particles in the range of 2 to 20$mu extrm{m}$ in aerodynamic diameter. A vibrating orifice aerosol generator was empolyed to generate monodisperse test aerosols. The oleic acid and sodium chloride(NaCl) particles were used as test aerosols. Aluminum foil and Teflon filter were selected as impaction media. The sampling flow rate was changed from 25 to 35L/min. Particle collection efficiency for single stage was examined for liquid particles. The stage response was obtained experimentally for the cascade impactor composed of three stages and a backup filter. The results showed that most of particle collection efficiencies measured in this work are similar to the efficiency curves obtained by Marple et al.(1991). For particles less than cut-off size of the stage, the collection efficiencies of solid particles are similar to those of loquid particles. However, the collection efficiency of solid particles decreases with mereasing particle diameter for the particles greater than the actual cut-off size of the impactor. The particle collection efficiency increases with increasing sampling flow rate at the same particel size. However, the collection efficiency curves seem not to be greatly shifted with the flow rate. The stage responses obtained by direct measurements in this work are in good agreement with those derived from the collection efficiency curves for single stage.

• Journal of Korean Society for Atmospheric Environment
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• v.17 no.6
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• pp.441-450
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• 2001

A three stage impactor with the cutoff diameters of 1, 2.5, and 10$\mu\textrm{m}$ in aerodynamic diameter was developed and tested. The gravimetric method and the particle counting method were utilized to evaluate the collection performance of each stage. A vibrating orifice aerosol generator was employed to generate monodisperse test aerosols larger that 2$\mu\textrm{m}$ in diameter. Polystyrene latex (PSL) particles smaller than 2$\mu\textrm{m}$ in diameter were generated by an atomizer and the particle number concentration was measured by an Aerodynamic Particle Sizer Spectrometer. The experimental cutoff diameters obtained from the particle collection efficiency curves are in good agreement with the designed values. The square roots of Stokes number at 50% collection efficiency for stage 1, 2, and 3 are 0.42, 0.48, and 0.45, respectively. Effects of the particle bounce and the impaction plate on the collection efficiency were investigated. The collection efficiency curves including effect of the particle bounce were also compared with those of the MOUDI cascade impactor.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.08a
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• pp.213-213
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• 2011

Gold catalysts supported on TiO2 have shown a unique catalytic behavior on CO oxidation, depending on surface effects. Particle size has an influence on the surface activity. To make monodisperse Au nanoparticles, organic capping ligands, such as alkylthiols, were used by a "greener" synthesis method [1,2] and Au nanoparticles were deposited on TiO2. However, organic capping ligands must be removed for high catalytic activities by the Au nanoparticles without changing the Au size [3]. We used UV ozone treatment to decompose thiol ligands. The samples have been characterized by X-ray photoelectron spectroscopy to examine the surface modification by UV ozone treatment. We show the size distribution of the gold nanoparticles by light scattering analysis and transmission electron microscopy. Au/TiO2 have been prepared using the wetness impregnation method. The catalytic performance of CO oxidation over Au supported on TiO2 under oxidizing reaction conditions (40 Torr CO and 100 Torr O2) were tested. The results show that the catalytic activity depends on particle size and the time of UV ozone exposure, which suggests the role of sulfur bonding in determining the catalytic activity of Au/TiO2 catalysts.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.1-1
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• 2011

We developed a new generalized synthetic procedure, called as "heat-up process," to produce uniform-sized nanocrystals of many transition metals and oxides without a size selection process. We were able to synthesize uniform magnetite nanocrystals as much as 1 kilogram-scale from the thermolysis of Fe-oleate complex. Clever combination of different nanoscale materials will lead to the development of multifunctional nano-biomedical platforms for simultaneous targeted delivery, fast diagnosis, and efficient therapy. In this presentation, I would like to present some of our group's recent results on the designed fabrication of multifunctional nanostructured materials based on uniform-sized magnetite nanoparticles and their medical applications. Uniform ultrasmall iron oxide nanoparticles of <3 nm were synthesized by thermal decomposition of iron-oleate complex in the presence of oleyl alcohol. These ultrasmall iron oxide nanoparticles exhibited good T1 contrast effect. In in vivo T1 weighted blood pool magnetic resonance imaging (MRI), iron oxide nanoparticles showed longer circulation time than commercial gadolinium complex, enabling high resolution imaging. We used 80 nm-sized ferrimagnetic iron oxide nanocrystals for T2 MRI contrast agent for tracking transplanted pancreatic islet cells and single-cell MR imaging. We reported on the fabrication of monodisperse magnetite nanoparticles immobilized with uniform pore-sized mesoporous silica spheres for simultaneous MRI, fluorescence imaging, and drug delivery. We synthesized hollow magnetite nanocapsules and used them for both the MRI contrast agent and magnetic guided drug delivery vehicle.