• Title/Summary/Keyword: Molten state

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Investigation of Characteristics of Passive Heat Removal System Based on the Assembled Heat Transfer Tube

  • Wu, Xiangcheng;Yan, Changqi;Meng, Zhaoming;Chen, Kailun;Song, Shaochuang;Yang, Zonghao;Yu, Jie
    • Nuclear Engineering and Technology
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    • v.48 no.6
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    • pp.1321-1329
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    • 2016
  • To get an insight into the operating characteristics of the passive residual heat removal system of molten salt reactors, a two-phase natural circulation test facility was constructed. The system consists of a boiling loop absorbing the heat from the drain tank, a condensing loop consuming the heat, and a steam drum. A steady-state experiment was carried out, in which the thimble temperature ranged from $450^{\circ}C$ to $700^{\circ}C$ and the system pressure was controlled at levels below 150 kPa. When reaching a steady state, the system was operated under saturated conditions. Some important parameters, including heat power, system resistance, and water level in the steam drum and water tank were investigated. The experimental results showed that the natural circulation system is feasible in removing the decay heat, even though some fluctuations may occur in the operation. The uneven temperature distribution in the water tank may be inevitable because convection occurs on the outside of the condensing tube besides boiling with decreasing the decay power. The instabilities in the natural circulation loop are sensitive to heat flux and system resistance rather than the water level in the steam drum and water tank. RELAP5 code shows reasonable results compared with experimental data.

A Review of Kinetic Model for Production of Highgrade Steel : Part. 2. Complex Reaction Model and Single Reaction Model (고급강 제조 반응 모델의 검토 : Part. 2. 종합 모델 및 단일 반응 모델)

  • Kim, Jeong-In;Kim, Sun-Joong
    • Resources Recycling
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    • v.30 no.1
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    • pp.14-25
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    • 2021
  • As a demand of high-end steel raises, the importance of secondary refinement process also increases. However, the content of each component in molten steel, slag and inclusions change with the time, meaning the secondary refinement process is not an equilibrium state. Furthermore, many reactions occur between molten steel, slag, inclusion, refractory and alloying element during secondary refinement process. In order to consider the above complex reactions with non-equilibrium state, a few researchers developed kinetic models in secondary refinement process based on the experimental numerical equations. It is important to analyze and review to the previously reported models to develop a precise model. Therefore, in present study, the complex reaction models based on kinetic in secondary refinement process were analyzed, reviewed, and introduced. Moreover, the single reaction models also introduced which would be applied to the complex reaction models.

Condition Monitoring of Internal State of Oxygen Converter Chamber Using Lance Behavior Analysis (랜스 거동 분석을 이용한 전로 내부 상태 감시)

  • Lim, Eun-Seop;Kim, Heung-Mook;Kim, Seong-Gon
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2000.06a
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    • pp.658-663
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    • 2000
  • Slopping phenomena deteriorate the productivity and the stability of operation in oxygen converter process. To predict and prevent that, it needs reliable perception of the internal state of the oxygen converter chamber. Equipment was developed to measure the dynamic and static behavior of the oxygen-blowing lance 3-dimensionally and the measured signal is analyzed in relation to slopping phenomena. It was found that the behavior of the lance is strongly correlated to the change of slag foam height and the instability of molten steel behavior. So slopping phenomena can be predicted by simultaneously analyzing the measured behavior of the lance and the control factors such as the flow rate of oxygen and the height of lance.

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Wet chemical etching of molten KOH/NaOH eutectic alloy to evaluate AlN single crystal (AlN 단결정의 품질평가를 위한 molten KOH/NaOH eutectic alloy의 화학적 습식에칭)

  • Park, Cheol Woo;Park, Jae Hwa;Hong, Yoon Pyo;Oh, Dong Keun;Choi, Bong Geun;Lee, Seong Kuk;Shim, Kwang Bo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.6
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    • pp.237-241
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    • 2014
  • We investigated the optimal etching conditions and properties of the surface change due to molten KOH/NaOH chemical wet etching using an AlN wafer which has been put to practical use in the present study. Results were observed using a scanning electron microscope after 5 minutes etching at $350^{\circ}C$, was found to have a surface form of the respective other Al-face, the N-face. In particular, etch-pit in the form of a hexagon, which is observed in the Al-face appeared, It was calculated at $2{\times}10^6/cm^2{\sim}10^{10}/cm^2$ dislocation density. In the case of N-face, lattice defects in the form of the hexagonal pyramids is formed. It was discovered that in order to observe the orientation of the wafer, which corresponds to the C-axis direction of the resulting hexagonal AlN which was analyzed using XRD (0002) and is a state of being oriented in the (0004) plane. The Radius of curvature of AlN wafer was 1.6~17 m measured by DC-XRD rocking curve position.

Thermodynamic Analysis of the Low- to Physiological-Temperature Nondenaturational Conformational Change of Bovine Carbonic Anhydrase

  • Hollowell, Heather N.;Younvanich, Saronya S.;McNevin, Stacey L.;Britt, B. Mark
    • BMB Reports
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    • v.40 no.2
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    • pp.205-211
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    • 2007
  • The stability curve - a plot of the Gibbs free energy of unfolding versus temperature - is calculated for bovine erythrocyte carbonic anhydrase in 150 mM sodium phosphate (pH = 7.0) from a combination of reversible differential scanning calorimetry measurements and isothermal guanidine hydrochloride titrations. The enzyme possesses two stable folded conformers with the conformational transition occurring at ~30$^{\circ}C$. The methodology yields a stability curve for the complete unfolding of the enzyme below this temperature but only the partial unfolding, to the molten globule state, above it. The transition state thermodynamics for the low- to physiological-temperature conformational change are calculated from slow-scan-rate differential scanning calorimetry measurements where it is found that the free energy barrier for the conversion is 90 kJ/mole and the transition state possesses a substantial unfolding quality. The data therefore suggest that the x-ray structure may differ considerably from the physiological structure and that the two conformers are not readily interconverted.

The effects of aluminium contents on the mechanical properties of magnesium-aluminium alloy (Mg-Al계 합금의 기계적 성질에 미치는 Al의 영향)

  • Maeng, W.Y.;Bac, J.H.;Oh, I.S.;Nam, T.W.
    • Journal of the Korean Society for Heat Treatment
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    • v.7 no.2
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    • pp.139-146
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    • 1994
  • In the molten state, magnesium alloys vigousey react with oxygen in the air, is protected from oxidation and burning by the addition of $SF_6$ to $CO_2$ atmosphere over the melt. The mechanical properties and metallographic examinatin have made of Mg-Al alloys containing 3, 6, 9% in the solution treated state and precipitated state, comparing mechanical properties obtained during unidirectional solidification with me chanical properties obtained during conventional casting. For a given solution treatment, a higher aluminum contents produce more or less fine grains in conventional casting. For a given artifical aging treatment, a higher aluminum contents produces much precitates at the grain boundary as well as within the grain in unidirectional solidification. As a result of this experiment, for a given heat treatment, the higher is aluminum contents the higher is the ultimate tensile strength, yield strength, hardness while the lower the elongation. Also the mechanical properties of unidirectional solidification is larger than that of conventional casting.

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Enzymatic Hydrolysis of Beef Tallow (효소에 의한 우지의 가수분해 반응)

  • 김인호;박태현
    • Microbiology and Biotechnology Letters
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    • v.19 no.4
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    • pp.377-382
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    • 1991
  • Reef tallow was hydrolyzed with lipase under the conditions of liquid state and solid state. Lipase OF 360 was used for that purpose, and the lipase had the maximum activity when the olive oil was used as a substrate at pH 6 and $37^{\circ}C$. Beef tallow was dispersed by an agitator to perform a liquid enzymatic reaction. Water content, reaction temperature, and enzyme amount were varied as parameters affecting hydrolysis percentage. Ninety three percents of tallow were hydrolyzed at the following conditions: water content 80% w/w, temperature $37^{\circ}C$, and enzyme amount 200 unitlg tallow. In order to conduct a solid phase enzymatic reaction, sonication was employed for pretreating tallow with the enzyme solution. Molten tallow was sonified with the enzyme solution, and solidified by lowering temperature. And then hydrolysis reaction proceeded at $30^{\circ}C$. Sonication intensity and time were varied to control hydrolysis percentage. Optimum values of the intensity and the time were found to exist since the hydrolysis percentage did not increase further according to the increases of the intensity and the time.

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CONTROL OF LASER WELD KEYHOLE DYNAMICS BY POWER MODULATION

  • Cho, Min-Hyun;Dave Farson
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.600-605
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    • 2002
  • The keyhole formed by high energy density laser-material interaction periodically collapses due to surface tension of the molten metal in partial penetration welds. The collapse sometimes traps a void at the bottom of the keyhole, and it remains as welding defects. This phenomenon is seen as one cause of the instability of the keyhole during laser beam welding. Thus, it seems likely that improving the stability of the keyhole can reduce voids and uniform the penetration depth. The goal of this work is to develop techniques for controlling laser weld keyhole dynamics to reduce weld defects such as voids and inconsistent penetration. Statistical analysis of the penetration depth signals in glycerin determined that keyhole dynamics are chaotic. The chaotic nature of keyhole fluctuations and the ability of laser power modulation to control them have been demonstrated by high-speed video images of laser welds in glycerin. Additionally, an incident leading beam angle is applied to enhance the stability of the keyhole. The quasi-sinusoidal laser beam power of 400Hz frequency and 15$^{\circ}$ incident leading beam angle were determined to be the optimum parameters for the reduction of voids. Finally, chaos analyses of uncontrolled signals and controlled signals were done to show the effectiveness of modulation on the keyhole dynamics. Three-dimensional phase plots for uncontrolled system and controlled system are produced to demonstrate that the chaotic keyhole dynamics is converted to regular periodic behavior by control methods: power modulation and incident leading beam angle.

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Fabrication of $Al_2O_3/Al$ Composite Materials by Mashy State Forming and its Hot Extrusion Process (반용융가공에 의한 $Al_2O_3/Al$ 복합재료의 제조 및 열간압출공정)

  • Kang, Chung-Gil;Kang, Sung-Soo
    • Journal of Korea Foundry Society
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    • v.13 no.3
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    • pp.248-258
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    • 1993
  • A semi-solid alloy in which solid and liquid phase are co-existing is obtained by stirring of A17075 molten metal. A semi-solid alloy is dependent on the corresponding temperature within the solid-liquid range, and the process parameters should be controlled accurately to obtain the homogeneous semisolid alloy. The fabrication possibility of fiber-reinforced aluminum alloy containing $Al_2O_3$ short fibers with vigorous agitation of short fibers were obtained by control of stirring time, solid fraction and impeller speed in extrusion billet fabrication processes. The microstructure to extrusion billet fabricated by low pressure casting was investigated for fiber dispersion state. The relationship between the extrustion force and velocity at hot extrustion, the flow strain and extrusion ratio were theoretically described. The surface defects with lubricants and without lubricant after hot extrusion were investigated. The composites materials after hot extrusion were measured by vickers hardness with extrusion ratio. It has become clear that the secondary working such as hot extrusion was very useful to obtained improved the mechanical properties of metal matrix composites.

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Studies on the Detergency Characteristics of Triglyceride -Correlating the substrates- (Triglyceride의 세척성에 관한 연구 -기질의 영향-)

  • Chung Hae Won
    • Journal of the Korean Society of Clothing and Textiles
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    • v.8 no.1
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    • pp.39-45
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    • 1984
  • The effects of Temperature on the removal of triglyceride were studied with soaps having various chain lengths of alkyl group. Cellophane, polyester film and alkali-treated polyester film were soiled with tripalmitin, tagged with 0" and detergency was evaluated by analysing the tripalmitine on the fabric before and after washing by means of liquid scintillation counting. The results were as following: 1) Triglyceride was completely removed from cellophane in distilled water without surfactant at any temperature, because of the hydrophillic nature of cellulose. The detergency of triglyceride from polyester film fully depended on the state of tripalmitin. The detergency of alkali treated polyester film was better than that of untreated polyester film at lower temperature due to increased hydrophillcity, but worse at higher temperature due to the diffusion of molten tripalmitin into the grooves, formed by alkali treatment. 2) The detergency from polyester film was increased with elevating temperature and after reaching some optimum detergencies, the detergencies were rather decreased with increasing temperature. The temperatures of optimum detergency were shifted to higher with increasing chain length of alkyl group. 3) When the soiled film was baked at $60^{\circ}C$ and $70^{\circ}C$ for 20 min, the detergency vs. temperature was much the same as the case of without-baking. These results indicate that the detergency of triglyceride was largely correlated with the suspending power of surfactants at low temperature and with state of soil and hydrophilicity of substrates with elevating temperature.

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