• Title/Summary/Keyword: Molten state

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Characterization of Glass Melts Containing Simulated Low and Intermediate Level Radioactive Waste

  • Jung, Hyun-Su;Kim, Ki-Dong;Lee, Seung-Heon;Kwon, Sung-Ku;Kim, Cheon-Woo;Park, Jong-Kil;Hwang, Tae-Won;Ahn, Zou-Sam
    • Journal of the Korean Ceramic Society
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    • v.43 no.3 s.286
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    • pp.148-151
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    • 2006
  • In order to examine the process parameters for the vitrification of Low and Intermediate Level radioactive Waste (LILW) generated from nuclear power plants, measurements of several melt properties was performed for four selected glasses containing simulated waste. Electrical conductivity and viscosity were determined at temperatures ranging from 1123 to $1673^{\circ}C$. The temperature dependences of both properties in the molten state showed a similar behavior in which their values decrease as the temperature increases. The values of the electrical conductivity and viscosity at a temperature of 1423K adopted in an induction cold crucible melter process were $0.27{\sim}0.42$ S/cm and $9.8{\sim}42$ dPas, respectively.

A Study on the Utilization of Blast Furnace Slag(I) (Grain-Growth of Slag-Glass) (고노슬라그의 이용에 관한 연구(I) (슬라그유리의 결정성장))

  • Rhee, Jhun;Chi, Ung-Up;Han, Ki-Sung;Choi, Sang-Wook
    • Journal of the Korean Ceramic Society
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    • v.15 no.3
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    • pp.157-167
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    • 1978
  • The batch compositions and physical properties of slag-ceramics were studied with respect to their formability from the molten state and conditions of nucleation and crystal growth treatment. The selected batch compositions for nucleation and growth studies were slag, 56%; silica sand, 28%; $Na_2O+MgO$, 8% and $TiO_2+$chromite, 8%. The optimum nucleation condition was the temperature of 75$0^{\circ}C$ with 6 hrs. holding time and the optimum growth condition was the temperature 975$^{\circ}C$ with zero holding time. The slag-ceramics prepared under the above conditions showed the best developed microtexture. The grown crystals were identified as diopside with the average grain size of 5.7$\mu\textrm{m}$, and the amount of crystal grown were about 53% by weight. The prepared specimens of slag-ceramics showed the microhardness, 793kg/$\textrm{mm}^2$; MOR, 1,050 kg/$\textrm{cm}^2$ and thermal expansion coefficient, $85{\div}10^{-7}$cm/cm/$^{\circ}C$($25^{\circ}C$~$700^{\circ}C$).

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Effects of Process Parameters on Cell Control of Aluminum Foal Material (알루미늄 발포소재의 성형 공정 인자가 기공제어에 미치는 영향)

  • 전용필;강충길
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.10a
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    • pp.163-166
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    • 1997
  • Aluminium foam material is a highly porous material having complicated cellular structure defined by randomly distributed air pores in metallic matrix. this structure gives the aluminium a set of properties which cannot be achieved by any of conventional treatments. The properties of aluminium foam material significantly depend on its porosity, so that a desired profile of properties can be tailored by changing the foam density. Melting method is the one of foaming processes, which the production has long been considered difficult to realize becaues of such problems as the low foamability of molten metal, the varying size of. cellular structures, solidification shrinkage and so on. These problems, however, have gradually been solved by researchers and some manufacturers are now producing foamed aluminum by their own methods. Most of all, the parameters of solving problem in electric furnace were stirring temperature, stirring velocity, foaming temper:iture, and so on. But it has not considered about those in induction heating, foaming velocity and foaming temperature in semi-solid state yet. Therefore, this paper presents the effects on these parameter to control cell size, quantity and distribution.

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Modelling of ZMR process for fabrication of SOI (SOI소자 제죠를 위한 ZMR공정의 모델링)

  • 왕종회;김도현
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.5 no.2
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    • pp.100-108
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    • 1995
  • Heat transfer plays a critical role in determining interface location and shape in ZMR process, which is used for the fabrication of silicon - on - insulator structure. In this work, the two - dimensional pseudo - steady - state ZMR model has been developed that can simulate the heat transfer process during ZMR process. It contains the radiation, convection and conduction heat transfer and determines the interface shapes. Numerical solutions from the model include flow field in the molten zone, temperature field in the full SOl structure and the location of solid/liquid interface in the silicon thin film and silicon substrate. We examined the effects of the various system parameters on the temperature profiles and the interface shape.

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Application of the Polymer Behavior Model to 3D Structure Fabrication (3차원 미세 구조물 제작을 위한 폴리머 유동 모델의 적용)

  • Kim, Jong-Young;Cho, Dong-Woo
    • Journal of the Korean Society for Precision Engineering
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    • v.26 no.12
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    • pp.123-130
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    • 2009
  • This study presents the application of a polymer behavior model that considers fluid mechanics and heat transfer effects in a deposition system. The analysis of the polymer fluid properties is very important in the fabrication of precise microstructures. This fluid behavior model involves the calculation of velocity distribution and mass flow rates that include the effect of heat loss in the needle. The effectiveness of the proposed method was demonstrated by comparing estimated mass fluid rates with experimental values. The mass fluid rates under various process conditions, such as pressure, temperature, and needle size, reflected the actual deposition state relatively well, and the assumption that molten polycaprolactone(PCL) is a non-Newtonian fluid was reasonable. The successful fabrication of three-dimensional microstructures demonstrated that the model is valid for predicting the polymer behavior characteristics in the microstructure fabrication process. The results of this study can be used to investigate the effect of various parameters on fabricated structures before turning to experimental approaches.

Fabrication of $Bi_{2}Sr_{2}CaCu_{2}O_{8}$ Superconducting Films by the LiReac-PreCu Method (급속반응공정에 의한 동 테이프 $Bi_{2}Sr_{2}CaCu_{2}O_{8}$)

  • 성현태;한상철;한영희;이준성;최희락
    • Progress in Superconductivity and Cryogenics
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    • v.1 no.1
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    • pp.7-14
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    • 1999
  • Wekk oriented $Bi_{2} Sr_{2} CaCu_{2} O_{8}$ suppercondcting thick films were fabricared on copper tape by LiReac-PreCu (liquid reaction between a Cu-free precousor and Cu tape) method. Cu-free precursor power which is composed of $Bi_{2}Sr_{2}Ca_{5}$ was printed on a copper tape by screen printing and was heat-treated. The speciment were partially in a molten state at the heat treatment temperature (85$0^{\circ}C$~87$0^{\circ}C$). The heat heat treatments for the reaction were performed in air or low oxygen pressure in several stages. XRD analyses of the resulting Bi2Sr2CaCu2O8 superconducting tapes show that the $Bi_{2} Sr_{2} CaCu_{2} O_{8}$ phase is dominant and a small amount of $Bi_{2} Sr_{2} Cu_{2} O_{6}$ phase is detected. Both phases are aligned in the c-axis direction.

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A Study on the Comparison of Solderability Assessment

  • Salam, B.;Ekere, N.N.;Jung, J.P.
    • Journal of the Korean institute of surface engineering
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    • v.35 no.2
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    • pp.129-137
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    • 2002
  • The purpose of solderability assessment is to predict the effectiveness of soldering process. It is important for companies pursuing zero defects manufacturing because poor solderability is the major cause of two third of soldering failures. The most versatile solderability method is wetting balance method. However, there exist so many indices for wettability in the wetting balance test e.g. time to reach 2/3 values of maximum wetting force, tine to reach zero wetting force, maximum withdrawal force. In this study, three solderability assessment methods, which were the maximum withdrawal force, the wetting balance and the dynamic contact angle (DCA), were evaluated by comparing each other. The wetting balance technique measures the solderability by recording the forces exerted from the specimen after being dipped into the molten solder. Then the force at equilibrium state can be used to calculate a contact angle, which is known as static contact angles. The DCA measures contact angles occurred during advancing and withdrawing of the specimen and the contact angles are known as dynamic contact angles. The maximum withdrawal force uses the maximum force during withdrawal movement and then a contact angle can be calculated. In this study, the maximum withdrawal force method was found to be an objective index for measuring the solderability and the experiment results indicated good agreement between the maximum withdrawal force and the wetting balance method.

Design and Control Method for Critical Load Supply Equipment using MCFC Electricity Generation Systems (대용량 MCFC 발전시스템을 이용한 비상부하 전력 공급 장치 설계 및 제어방법)

  • Kim, Dong-Hee;Kim, Jong-Soo;Choe, Gyu-Yeong;Lee, Byoung-Kuk;Kawk, Cheol-Hoon
    • The Transactions of the Korean Institute of Power Electronics
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    • v.16 no.1
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    • pp.20-29
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    • 2011
  • This paper proposes critical load following back-up system using MCFC stack. This system enables MCFC generation system to supply power to critical load without UPS and to generate rated power under grid fault state. This back-up system includes 'Load Leveler' that is connected with 3-phase inverter and is controlled by additional algorithm that includes critical load following. The proposed system and algorithm are verified by computer simulation based on 5kW system.

Investigation on Dissolution and Removal of Adhered LiCl-KCl-UCl3 Salt From Electrodeposited Uranium Dendrites using Deionized Water, Methanol, and Ethanol

  • Killinger, Dimitris Payton;Phongikaroon, Supathorn
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.4
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    • pp.549-562
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    • 2020
  • Deionized water, methanol, and ethanol were investigated for their effectiveness at dissolving LiCl-KCl-UCl3 at 25, 35, and 50℃ using inductively coupled plasma mass spectrometry (ICP-MS) to study the concentration evolution of uranium and mass ratio evolutions of lithium and potassium in these solvents. A visualization experiment of the dissolution of the ternary salt in solvents was performed at 25℃ for 2 min to gain further understanding of the reactions. Aforementioned solvents were evaluated for their performance on removing the adhered ternary salt from uranium dendrites that were electrochemically separated in a molten LiCl-KCl-UCl3 electrolyte (500℃) using scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS). Findings indicate that deionized water is best suited for dissolving the ternary salt and removing adhered salt from electrodeposits. The maximum uranium concentrations detected in deionized water, methanol, and ethanol for the different temperature conditions were 8.33, 5.67, 2.79 μg·L-1 for 25℃, 10.62, 5.73, 2.50 μg·L-1 for 35℃, and 11.55, 6.75, and 4.73 μg·L-1 for 50℃. ICP-MS analysis indicates that ethanol did not take up any KCl during dissolutions investigated. SEM-EDS analysis of ethanol washed uranium dendrites confirmed that KCl was still adhered to the surface. Saturation criteria is also proposed and utilized to approximate the state of saturation of the solvents used in the dissolution trials.

Impact of molybdenum cross sections on FHR analysis

  • Ramey, Kyle M.;Margulis, Marat;Read, Nathaniel;Shwageraus, Eugene;Petrovic, Bojan
    • Nuclear Engineering and Technology
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    • v.54 no.3
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    • pp.817-825
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    • 2022
  • A recent benchmarking effort, under the auspices of the Organization for Economic Cooperation and Development (OECD) Nuclear Energy Agency (NEA), has been made to evaluate the current state of modeling and simulation tools available to model fluoride salt-cooled high temperature reactors (FHRs). The FHR benchmarking effort considered in this work consists of several cases evaluating the neutronic parameters of a 2D prismatic FHR fuel assembly model using the participants' choice of simulation tools. Benchmark participants blindly submitted results for comparison with overall good agreement, except for some which significantly differed on cases utilizing a molybdenum-bearing control rod. Participants utilizing more recently updated explicit isotopic cross sections had consistent results, whereas those using elemental molybdenum cross sections observed reactivity differences on the order of thousands of pcm relative to their peers. Through a series of supporting tests, the authors attribute the differences as being nuclear data driven from using older legacy elemental molybdenum cross sections. Quantitative analysis is conducted on the control rod to identify spectral, reaction rate, and cross section phenomena responsible for the observed differences. Results confirm the observed differences are attributable to the use of elemental cross sections which overestimate the reaction rates in strong resonance channels.