• Title/Summary/Keyword: Molten carbonate

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Development of Power Conditioning System for High Power Fuel Cell System (대용량 연료전지 발전시스템용 전력변환기 개발)

  • Kang, Ho-Hyun;Lee, Jin-Hee;Baek, Seung-Taek;Jung, Hong-Ju;Chung, Joon-Mo;Suh, In-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.153-156
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    • 2007
  • This paper presents the design, development and performance of a power conditioning system (PCS) for application to a 250kW Molten Carbonate Fuel Cell (MCFC) generation system. A DSP controller was used to control the dc-dc and dc-ac converter operation for grid connection and power injection to the grid. The controller must also supervise the total PCS operation while communicating with the fuel cell system controller. A control method for parallel operation of dc-dc converters was proposed and verified. A 250kW prototype was successfully built and tested. Experimental performances are compared to minimum target requirements of the PCS for MCFC.

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Compressive and Bending Behaviors of the Shielded Slot Plate Considering Forming Effect for Fuel Cell Application (성형 이력을 고려한 용융탄산염 연료전지용 쉴디드 슬롯 플레이트의 압축 및 굽힘 거동 분석)

  • Lee, C.W.;Yang, D.Y.;Kang, D.W.;Chang, I.G.;Lee, T.W.
    • Transactions of Materials Processing
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    • v.21 no.6
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    • pp.341-347
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    • 2012
  • The metallic bipolar plates of the molten carbonate fuel cell(MCFC) are composed of shielded slot plates and a center-plate. The shielded slot plates support the center-plate and the membrane electrode assembly. Compressive forces are applied to the shielded slot plate in order to increase the contact area between shielded slot plates and the membrane electrode assembly (MEA). In the design of the shielded slot plate, it is necessary to predict the mechanical behavior of the shielded slot plate. The shielded slot plates are manufactured by a three-stage forming process consisting of slitting, preforming and the final forming process. The mechanical behavior of the shielded slot plate is largely affected by the forming process. In this study, the simulation of the three-stage forming process was used to predict the mechanical behavior of the shielded slot plate. The present simulation approach showed good agreements with the experimental results.

Effect of Titanium Sulfate Addition on Crystal Growth of the Flaky α-Al2O3 (황산티타늄의 첨가가 판상 α-Al2O3의 결정성장에 미치는 영향)

  • Park, Byung-Ki;Cho, Sun-Mi;Lee, Jung-Min
    • Journal of the Korean Ceramic Society
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    • v.42 no.5 s.276
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    • pp.338-345
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    • 2005
  • To prepare the complex gel of flux and pseudo-boehmite used in precursor of the flaky ${\alpha}-A1_2O_3$ crystal, aqueous solution of the mixture of sodium carbonate and sodium phosphate was added with stirring in aqueous solution of the mixture of sodium sulfate, potassium sulfate and titanium sulfate. The complex gel was dried at $110^{\circ}C$ and was crystallized above $1,050^{\circ}C$, and then the effect of the amount of titanium sulfate on size, morphology, thickness and crystal size distribution of the flaky ${\alpha}-A1_2O_3$ crystal was investigated. Addition of titanium sulfate was prevented the aggregation and generation of twin crystal, and had an effect on the crystal size and the thickness during crystal growth. When the amount of titanium sulfate was more than 6 g, particle size was decreased but was free from crystal twining and aggregation. On the other hand, when the amount of titanium sulfate was lower than 6 g, crystal size was increased but crystal twinning and aggregation were noticed.

Integrated Power Generation Systems Based on High Temperature Fuel Cells - A Review of Research and Development Status - (고온형 연료전지 기반 통합형 발전시스템 - 연구개발 동향 고찰 -)

  • Kim, Tong-Seop;Park, Sung-Ku
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.5
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    • pp.299-310
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    • 2009
  • Fuel cells are expected to be promising future power sources in both aspects of thermal efficiency and environmental friendliness. Accordingly, worldwide research and development efforts have been enormously increasing recently in various applications such as power plants, transportation and portable power sources. Among others, high temperature fuel cells, such as solid oxide fuel cells and molten carbonate fuel cells, are suitable for electric power plants. Moreover, their high operating temperature is quite appropriate to construct further advanced integrated systems. This paper reviews recent literatures on research and development of integrated power generation systems based on high temperature fuel cells. Research and development efforts are summarized in the area of fuel cell/ gas turbine hybrid systems, application of carbon capture technology to fuel cell systems, integration of coal gasification with fuel cells, and the use of alternative fuels.

Microstructure and Characteristics of Mechanically Alloyed Ni-W(WC) (기계적 합금화한 Ni-W(WC)의 미세구조 및 특성)

  • Sin, Su-Cheol;Jang, Geon-Ik
    • Korean Journal of Materials Research
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    • v.8 no.12
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    • pp.1133-1137
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    • 1998
  • By the mechanical alloying method Ni-W(WC) composite materials were prepared to improve the resistance for creep and sintering of Ni-anode at the operating temperature of$ 650^{\circ}C$. Amorphization was observed from the XRD analysis of mechanically alloyed powder caused by the destruction of ordered crystals. Sintering was performed at $1280^{\circ}C$ for 10 hours in $H_2$ atmosphere. From the result of dot-mapping and TEM analysis the second phase was not observed at Ni-W interface while W particles of less 0.lam were distributed finely and uniformly in Ni matrix. This finely and uniformly distributed W in Ni matrix is expected to enhance the mechanical properties of Ni-anode through the dispersion and solid solution hardening mechanisms.

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A Study on the Countermeasure Algorithm for Power System Disturbances in Large Scale Fuel Cell Generation System (대용량 연료전지시스템의 계통외란 방지알고리즘에 관한 연구)

  • Choi, Sung-sik;Kim, Byung-ki;Park, Jae-beom;Rho, Dae-seok
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.65 no.5
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    • pp.711-717
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    • 2016
  • Recently, fuel cell generation system with high energy efficiency and low CO2 emission is energetically interconnected with distribution power system. Especially, MCFC(molten carbonate fuel cell) operating at high temperature conditions is commercialized and installed as a form of large scale power generation system. However, it is reported that power system disturbances such as harmonic distortion, surge phenomenon, unbalance current, EMI(Electromagnetic Interference), EMC (Electromagnetic Compatibility) and so on, have caused several problems including malfunction of protection device and damage of control devices in the large scale FCGS(Fuel Cell Generation System). Under these circumstances, this paper proposes countermeasure algorithms to prevent power system disturbances based on the modelling of PSCAD/EMTDC and P-SIM software. From the simulation results, it is confirmed that proposed algorithms are useful method for the stable operation of a large scale FCGS.

Development of Power Conditioning System for High Power Fuel Cell System (대용량 연료전지 발전시스템용 전력변환기 개발)

  • Lee, Jin-Hee;Baek, Seung-Taek;Jung, Hong-Ju;Kang, Ho-Hyun;Chung, Joon-Mo;Suh, In-Young
    • Proceedings of the KIPE Conference
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    • 2007.07a
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    • pp.530-532
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    • 2007
  • This paper presents the design, development and performance of a power conditioning system (PCS) for application to a 250kW Molten Carbonate Fuel Cell (MCFC) generation system. A DSP controller was used to control the dc-dc and dc-ac converter operation for grid connection and power injection to the grid. The controller must also supervise the total PCS operation while communicating with the fuel cell system controller. A control method for parallel operation of dc-dc converters was proposed and verified. A 250kW prototype was successfully built and tested. Experimental performances are compared to minimum target requirements of the PCS for MCFC.

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Numerical Analysis on the Mechanical Press Joining for the Sheet Metal with a Circular Hole (중공 박판의 기계적 프레스 결합에 관한 해석)

  • Lee, Se-Jung;Kim, Min-Woong;Lee, Jae-Won;Lee, Sang-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.7
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    • pp.1453-1458
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    • 2009
  • This study is to apply the mechanical press joining method to join two kinds of sheet metals with circular holes by mechanical pressing instead of laser beam. Usage of the mechanical pressing avoids the thermal deformation of sheet metals which occurs inevitably in laser joining. A die design has been proposed to make the mechanical press joining applicable with finite element analysis. Five design factors related to the joining force have been selected and applied to the Taguchi method for optimization. Among five factors, 'Forming Depth' and 'Punch Corner Radius' have been revealed to be the most influential ones.

Design and Control Method for Critical Load Supply Equipment using MCFC Electricity Generation Systems (대용량 MCFC 발전시스템을 이용한 비상부하 전력 공급 장치 설계 및 제어방법)

  • Kim, Dong-Hee;Kim, Jong-Soo;Choe, Gyu-Yeong;Lee, Byoung-Kuk;Kawk, Cheol-Hoon
    • The Transactions of the Korean Institute of Power Electronics
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    • v.16 no.1
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    • pp.20-29
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    • 2011
  • This paper proposes critical load following back-up system using MCFC stack. This system enables MCFC generation system to supply power to critical load without UPS and to generate rated power under grid fault state. This back-up system includes 'Load Leveler' that is connected with 3-phase inverter and is controlled by additional algorithm that includes critical load following. The proposed system and algorithm are verified by computer simulation based on 5kW system.

Preparation of Fiber-Reinforced $\gamma-LiAlO_2$ Matrixes by the Tape Casting Method (테이프캐스팅법에 의한 화이버 강화 $\gamma-LiAlO_2$ 메트릭스의 제조)

  • 현상훈;백계현;홍성안
    • Journal of the Korean Ceramic Society
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    • v.34 no.3
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    • pp.303-313
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    • 1997
  • To enhance the strength and formability of MCFC matrixes, alumina/${\gamma}$-LiAlO2 fiber-reinforced ${\gamma}$-LiAlO2 ma-trixes have been investigated. The MCFC matrixes with the thickness of 500~600 ${\mu}{\textrm}{m}$ were prepared by tape-casting of the slurry containing 10~30wt% fibers, followed by heat-treating up to $650^{\circ}C$. The porosity of fi-ber-reinforced matrixes decreased with the content of fibers, while the appropriate porosity(50~60%) for MCFC matrixes could be attained by adding larger ${\gamma}$-LiAlO2 particles with the diameter of about 50${\mu}{\textrm}{m}$ up to 50 wt%. The optimum length and content of the alumina fiber, both in the alignment of fibers and the enhancement of the strength, were found to be below 250${\mu}{\textrm}{m}$ and 20 wt%, respectively. On the other hand, the strength(156 gf/$\textrm{mm}^2$) of the ${\gamma}$-LiAlO2 matrix reinforced with ${\gamma}$-LiAlO2 fibers prepared in this study was improved by 20~40% in comparison with the alumina-fiber-reinforced matrix. It was also found that the alu-mina-fiber-reinforced matrix was completely corroded in molten carbonates but the ${\gamma}$-LiAlO2 was not.

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