• 제목/요약/키워드: Molecular properties

검색결과 3,780건 처리시간 0.032초

Molecular gas properties under ICM pressure: A Case study of NGC4402

  • 한유진;정애리
    • 천문학회보
    • /
    • 제37권1호
    • /
    • pp.41.1-41.1
    • /
    • 2012
  • Interactions between the galactic interstellar medium (ISM) and the intra cluster medium (ICM) are believed to be one of the main processes affecting galaxy evolution in cluster environments. The aim of our research is to study the molecular gas properties of a galaxy under the ICM pressure in the cluster environment. It has been well known that cluster galaxies are deficient in atomic hydrogen gas (HI gas) compared to their field counterparts and now there is much evidence that low density ISM is being removed by ram pressure due to ICM wind. Meanwhile, no significant molecular gas deficiency of the cluster galaxy population has been found yet they show overall lower star formation rate than galaxies in the field, and it is still puzzling how the star formation could decrease without stripping of dense molecular gas. To address this issue, we probe the detailed molecular gas properties of NGC 4402, located near the cluster center, as part of a study of four spiral galaxies in the Virgo Cluster. NGC 4402 is well known undergoing ram pressure stripping with a truncated HI disk($D_{HI}/D_{opt}$ - 0.75 and only 36% of HI gas compare to field galaxies of a similar size) and a disturbed gas morphology. Comparing the high resolution 12CO and 13CO data of NGC 4402 from the Sub Millimeter Array (SMA) with existing other wavelength data, we probe the spatial distribution and a physical condition of molecular gas under strong ICM pressure. We discuss the star formation activity might have been altered and hence how the global color of NGC4402 would change in the future.

  • PDF

Syntheses and light-emitting properties of new PPV derivatives containing polyhedral oligomeric silsequioxane

  • Kang, Jong-Min;Lee, Jong-Hee;Jo, Hoon-Hae;Shim, Hong-Ku;Hwang, Do-Hoon
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.II
    • /
    • pp.1421-1423
    • /
    • 2005
  • A new light-emitting poly(p-phenylenevinylene) (PPV) derivative containing a polyhedral oligomeric silsequioxane (POSS-PPV) and its MEH-PPV copolymers, [Poly(POSSPV-co-MEHPV)]s, have been synthesized through the Gilch polymerization, and their light-emitting properties were investigated. The synthesized polymers were characterized by NMR, GPC, thermogravimetric and elemental analysis. The POSS-PPV and copolymers showed almost the same optical properties as the MEH-PPV, regardless of copolymer composition. The POSS-PPV and MEHPPV all showed their peak absorption at 505 and 496nm, and PL emission maxima at 578 and 581nm. POSSPPV showed higher PL quantum efficiency than the MEH-PPV. Synthesis, characterization and electroluminescent properties of the polymers will be presented.

  • PDF

Preparation of Novel Quaternary Plastomers with Extremely Low Glass Transition Temperature

  • Kim, Jin Hoon;Kim, Jung Soo;Kim, Min Seong;Kim, Ki Bum;Yang, Hong Joo;Ha, Sung Chul;Chang, Young-Wook;Kim, Dong Hyun
    • Elastomers and Composites
    • /
    • 제51권3호
    • /
    • pp.188-194
    • /
    • 2016
  • In this study, novel quaternary plastomers consisting of ethylene, 1-hexene, high ${\alpha}$-olefin, and divinylbenzene were prepared using Zr metallocene catalyst, borate type cocatalyst, and tri-isobutylaluminium. The molar ratio changes of 1-hexene and high ${\alpha}$-olefin (1-octene, 1-decene, and 1-dodecene) had an effect on the properties of the quaternary plastomers. The structure of the quaternary plastomers was characterized using $^1H$ NMR. Molecular weight properties, crystallinity, and thermal properties of the plastomers were determined by GPC, WAXS, and DMA, respectively. Compared with the terpolymers prepared in our previous study, molecular weight and molecular weight distribution of the quaternary polymers were very similar, whereas glass transition temperature ($T_g$) was very low. Also, hardness and tensile properties of the quaternary plastomers were measured.

Preparation, Characterization, and Gas Permeation Properties of Carbon Molecular Sieve Membranes Derived from Dense P84-Polyimide Film

  • Park, Ho-Bum;Nam, Sang-Yong;Jang, Jeong-Gyu;Lee, Young-Moo
    • Korean Membrane Journal
    • /
    • 제4권1호
    • /
    • pp.25-35
    • /
    • 2002
  • The gas permeation properties have been studied on carbon molecular sieve (CMS) membranes prepared by pyrolysis of P84 polyimide under various conditions. P84 polyimide shows high permselectivities (O$_2$/N$_2$= 9.17 and CO$_2$/N$_2$= 35) for various gas pairs and has a good processibility because it is easily soluble in high polar solvents such as N-methylpyrrolidinone (NMP), dimethylformamide (DMF), and N,N-dimethylacetamide (DMAc). After pyrolysis under Ar flow, the change in the heating rate was found to affect the gas permeation properties to some extent. The permeabilities of the selected gases were shown to be in the order He > CO$_2$> O$_2$> N$_2$for all the CMS membranes, whose order was in accordance with the order of kinetic gas diameters. It also revealed that the pyrolysis temperature considerably influenced the gas permeation properties of the CMS membranes derived from P84 polyimide. The CMS membranes pyrolized at 700$\^{C}$ temperature exhibited the highest permeability with relatively targe loss in permselectivity. This means that the pyrolysis temperature should be varied in accordance with target gases to be separated.

대두유의 Methyl Ester와 수지 분자량에 따른 평판 잉크의 물성 변화에 관한 연구 (The Variation of Offset Ink Properties According to Methyl Ester of Soy Oil and Resin Molecular Weight)

  • 박정민;김성빈
    • 한국인쇄학회지
    • /
    • 제29권1호
    • /
    • pp.45-59
    • /
    • 2011
  • According as gradually increasing the demand for Eco-friendly products it has been progressed fairly development at a field of printing and printing inks. The Inks are used by soy oil beginning of ink industry for preventing environment. Now it is possible to make Eco-friendly inks with vegetable ester. So it is not necessary to use petroleum-based solvents for preventing environment. But There is some problems if using vegetable ester to inks. Vegetable ester has high solubility, it causes misting and low viscosity of the Inks. So resin is required high performance. Thus, in this paper, I studied about the properties variation of the Varnish and inks According to using the phenolic modified rosin ester and Soy oil Methyl esters. The compared in order of average molecular weight by the GPC method, rheological properties were found by rotational rheometer, and emulsion behavior were compared by high speed emulsification tester.

세미-브로잉 공정에서 석유 아스팔트의 구조, 물성 변화 (Structures and Properties of Semi-blown Petroleum Asphalt)

  • 민경의;정한모
    • 공업화학
    • /
    • 제22권6호
    • /
    • pp.664-671
    • /
    • 2011
  • 무촉매 공기 브로잉 공정에서 석유계 감압 잔사유로부터 세미-부로운 아스팔트를 제조하는 경우, 시간에 따른 아스팔트의 조성, 구조, 물리적 성질의 변화를 조사하였다. 공기 브로잉에 의해 지방족 탄화수소 성분이 방향족 탄화수소 성분으로 전이되고, 고분자화 되어 아스팔텐 성분이 증가함을 박막크로마토그래피를 이용한 조성 분석에서 관찰하였다. 처리시간에 따른 방향족화와 고분자화 정도의 증가는 $^1H-NMR$, 열시차분석, 그리고 열중량분석에서도 확인할 수 있었다. 이러한 아스팔트의 조성과 구조의 변화는 침입도의 감소, 연화점과 인화점의 증가를 초래하였다.

Molecular Weight Distribution of Regenerated Silk Fibroin in Aqueous Solution

  • Jeong, Jae-Ho;Hur, Won
    • 한국생물공학회:학술대회논문집
    • /
    • 한국생물공학회 2003년도 생물공학의 동향(XIII)
    • /
    • pp.621-625
    • /
    • 2003
  • In order to investigate the properties of aqueous fibroin solution, the molecular weight distribution of silk fibroin was determined by gel filtration chromatography. The molecular weights spreaded from 200 kDa to less than 20 kDa. The distribution of molecular weight was significantly affected when the pH of solubilization solution is less than 1. Distributions of fibroin solution stored at various condition were also investigated.

  • PDF

Functional Polymers with Controlled Molecular Architecture: Design, Synthesis and Applications

  • Frechet Jean M.J.
    • 한국고분자학회:학술대회논문집
    • /
    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
    • /
    • pp.1-2
    • /
    • 2006
  • Polymer architecture plays a great role in determining the properties of functional polymers. This lecture will explore the design and the synthesis of polymers with controlled architecture and functionality. Especially featured will be star and dendritic architectures where the functional group placement and the molecular shape can be controlled. This will be followed by examples of applications illustrated with a few model systems of functional polymers designed for use in areas such as organic electronics, catalysis, surface patterning, separation and molecular recognition, and polymer therapeutics.

  • PDF

UV-curable Acrylate/Alkyd Resin 혼합계의 경화특성 II (Curing Properties of UV-ccurable Acrylate/Alkyd Resin Blends II)

  • 남수용;이경옥;대평태문;구철회
    • 한국인쇄학회지
    • /
    • 제18권1호
    • /
    • pp.157-166
    • /
    • 2000
  • UV-curable resins have adventages of quick set, space saving, clean environment, and efficient use of energy. The polymerization induced phase separation has been studied to solve the problem in UV-curing of thick films and develop the new functional materials. On the exposure to UV irradiation, the dynamic elasticity properties were mesured for mixtures of alkyd resin and UV-cruable monomers which have different molecular structures and molecular weights. The curing rate increases with increasing temperature and UV intensity. In addition, The gel point is strongly influenced by temperature and UV intensity

  • PDF

Change of Fine Structure of Aliphatic Polyester fiber by strectching

  • 홍기정;박수민
    • 한국섬유공학회:학술대회논문집
    • /
    • 한국섬유공학회 1997년도 춘계학술발표회 논문집
    • /
    • pp.328-332
    • /
    • 1997
  • Hot stretching focused on the improvement of properties of poly(L-lactic acid) fiber. Some aliphatic polyesters are biodegradable under microbial attack and the new unique applications are expected. Generally, these materials have a somewhat low melting temperature and low mechanical properties compared with the aromatic polyesters. In this study, melt-spinning of poly(L-lactic acid) was conducted. We investigated effects of the stretching and the molecular orientation of aliphatic polyester fibers on the change of fine-structure. Glass transition temperature, molecular orientation and crystallinity increased according to the increase of stretching ratio.

  • PDF