한국정보디스플레이학회:학술대회논문집

The Korean Infomation Display Society (한국정보디스플레이학회)
권호 표지

Syntheses and light-emitting properties of new PPV derivatives containing polyhedral oligomeric silsequioxane

  • Kang, Jong-Min (Department of Applied Chemistry, Kumoh National Institute of Technology) ;
  • Lee, Jong-Hee (Center for Advanced Functional Polymers, Department of Chemistry and School of Molecular Science (BK21), Korea Advanced Institute of Science and Technology) ;
  • Jo, Hoon-Hae (Center for Advanced Functional Polymers, Department of Chemistry and School of Molecular Science (BK21), Korea Advanced Institute of Science and Technology) ;
  • Shim, Hong-Ku (Center for Advanced Functional Polymers, Department of Chemistry and School of Molecular Science (BK21), Korea Advanced Institute of Science and Technology) ;
  • Hwang, Do-Hoon (Department of Applied Chemistry, Kumoh National Institute of Technology)
  • Published : 2005.07.19
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Abstract

A new light-emitting poly(p-phenylenevinylene) (PPV) derivative containing a polyhedral oligomeric silsequioxane (POSS-PPV) and its MEH-PPV copolymers, [Poly(POSSPV-co-MEHPV)]s, have been synthesized through the Gilch polymerization, and their light-emitting properties were investigated. The synthesized polymers were characterized by NMR, GPC, thermogravimetric and elemental analysis. The POSS-PPV and copolymers showed almost the same optical properties as the MEH-PPV, regardless of copolymer composition. The POSS-PPV and MEHPPV all showed their peak absorption at 505 and 496nm, and PL emission maxima at 578 and 581nm. POSSPPV showed higher PL quantum efficiency than the MEH-PPV. Synthesis, characterization and electroluminescent properties of the polymers will be presented.

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