• Title/Summary/Keyword: Molecular Separation

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Carbon Molecular Sieve Membranes Derived from Thermally Labile Polymer Containing Polyimide and Their Gas Separation Properties (열분해성 고분자 도입에 따른 탄소분자체막의 기체 투과 특성)

  • Young Moo Lee;Youn Kook Kim;Ji Min Lee;Ho Bum Park
    • Membrane Journal
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    • v.13 no.3
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    • pp.182-190
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    • 2003
  • Carbon molecular sieve (CMS) membranes were prepared by the pyrolysis of polyvinylpyrrolidone containing polyimide precursors. We have prepared the polymer precursors, pyrolyzed polymer and investigated the effect of pyrolyzing polymer on the characteristics of carbon structures and gas separation properties of the CMS membranes. Thermogravimetric analysis (TGA) showed the two-step decomposition of polymer precursor. First decomposition of the pyrolyzing polymer began around $400^{\circ}C$ while carbonizing polymer showed the decomposition around $550^{\circ}C$. The gas permeabilities through the CMS membranes were enhanced by the introduction of the pyrolyzing polymer and decreased with increased final pyrolysis temperature. The CMS membrane pyrolyzed at $550^{\circ}C$. derived from precursor containing 5wt% PVP as a pyrolyzing polymer showed gas permeability for $O_2$ of 808 Barrers [$10^{-10}cm^3 (STP)cm/cm^2scmHg]$ and $O_2/N_2$ selectivity of 7.

Protein Changes in Soymilk and Whole Soymilk due to Enzymatic Hydrolysis (효소적 가수분해에 따른 두유와 전두유의 단백질 변화)

  • Jang, Se-Young;Sin, Kyung-A;Park, Nan-Young;Bang, Kwang-Woong;Jeong, Yong-Jin
    • Food Science and Preservation
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    • v.15 no.6
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    • pp.903-908
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    • 2008
  • This study investigated protein changes in soymilk and whole soymilk due to enzymatic hydrolysis. The total free amino acid contents of low molecular weight soymilk (LSM) and low molecular weight whole soymilk (LWSM) were higher than soymilk (SM) and whole soymilk (WSM). The essential amino acid content was similar in SM and LSM, but was higher in LWSM than WSM. In SDS-PAGE performed to tendency of becoming low molecules, the soy protein molecular weights were 3372 kDa for SM and WSM, but 17 kDa or less for LSM and LWSM. Also, high molecular weight protein spots were evident in 2-D electrophoresis of SM and LSM, but only low molecular weight protein spots of various sizes were evident in WSM and LWSM. This suggests that the high molecular weight protein in SM and WSM is changed to low molecular weight protein by enzymatic hydrolysis. Further investigations of the separation and qualities of these proteins are required.

UPHILL TRANSPORT PHENOMENA THROUGH LIQUID SEPARATION MEMBRANE

  • 양원강
    • Proceedings of the Membrane Society of Korea Conference
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    • 1993.10a
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    • pp.59-60
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    • 1993
  • 막을 도구로 하여 물가등(Ion, Molecular)의 선택 분리 및 정제과정법에 대한 연구는 눈부신 발전을 가져 왔다. 콜로디온 막으로 투석과 한외 여과법이 나온 이래 1950년대 Juda의 연구 이온 교환법의 보고 후 전기투석법에 의한 바닷물의 담수화 농축 방법이 개발되고 Soeb, Sourirajan의 초산 셀루로즈 막의 보고는 Salt의 배제율이 높은 베막 법이 소개 된 후에 다양한 막의 응용법이 전개되었다. 막소제, 제막법, 고 분리기능막, 막형태, 얇은막, 막장치에 이르기 까지 막학 연구의 관심을 모아졌다.

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Recent Developments in Analytical and Preparative Scale Enantioseparations

  • Chankvetadze, Bezhan
    • Proceedings of the PSK Conference
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    • 2002.10a
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    • pp.161-162
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    • 2002
  • Field of enantioseparations represents one of the actual topics of chemistry. Significant, in some cases dramatic differences in a desired activity as well as in toxic properties of enantiomers of chiral drugs, food additives, agrochemicals, cosmetic products, etc. represents a driving force in this field. The enantiomers of all chiral bioactive compounds have to be isolated and to be tested. Besides the ethical or environmental reasons for developing single enantiomers, it may be a real therapeutic benefit and in some cases, it has been used as a strategy for extending patent life. (omitted)

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Supramolecular Assembly toward Organic Nanostructures

  • Lee, Myong-Soo
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.173-173
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    • 2006
  • We have explored a strategy to control the supramolecular nano-structures self-assembled from rigid segments through attachment of flexible chains through microphase separation and anisotropic arrangement. Supramolecular structures formed by self-assembly of rigid building blocks can be precisely controlled from 1-D layered, 3-D bicontinuous cubic to 2-D cylindrical structures by systematic variation of the type and relative length of the respective blocks. Furthermore, depending on the individual molecular architectures, rigid building blocks self-assemble into a wide range of supramolecular structures such as honeycomb, disk, cylinder, helix, tube, barrel stave, and nano-cage.

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Electro-optic Properties of Reflective HPDLC with Fluorinated Polymer Matrices

  • Woo, Ju-Yeon;Kim, Eun-Hee;Kim, Byung-Kyu
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.516-519
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    • 2003
  • We modified the molecular structure of urethane acrylate oligomer by varying raw materials. Also fluorination of the host polymer matrices has been found to influence the morphological and the electrooptical properties of the resulting HPDLC grating. The incorporation of fluorinated monomers in HPDLC formulation enhance the LC phase separation and improved elctro-optical properties.

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Quantitative Analysis of Eleutherosides B and E Using HPLC-ESI/MS (HPLC-ESI/MS를 이용한 Eleutheroside B와 E의 정량)

  • Choi, Young-Hae;Kim, Jin-Woong
    • Korean Journal of Pharmacognosy
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    • v.33 no.2 s.129
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    • pp.88-91
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    • 2002
  • Liquid-chromatography coupled with electrospray-ion trap mass spectrometry was applied to the analysis of the eleutherosides B and E in the Eleutherococcus senticosus cortexes. The optimum ESI/MS results were obtained in the positive ion mode using extracted ion chromatogram targeting Na-adduct molecular ion of each compound. This method allowed rapid and simple gradient separation of underivatized eleutherosides B and E without pre-purification steps at very low concentration.

Molecular Composite of Cellulose Triacetate and Polyester (I) - Solution Property- (셀루로오즈 트리아세테이트와 폴리에스테르의 분자복합체(I) -용액 성질-)

  • Hong, Young-Keun
    • Textile Coloration and Finishing
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    • v.3 no.4
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    • pp.17-21
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    • 1991
  • A rigid polymer, cellulose triacetate (CTA) dissolved in a combination of trifluoroacetic acid (TFA) and methylene chloride (MC) solution are liguid crystalline above a certain concentration. A flexible polymer, polyethylene terephthalate (PET) also dissolves in TFA/MC, but does not form liguid crystal phase. Ternary solutions, CTA/PET/TFA-MC which CTA and PET were mixed in a same solvent TFA/MC (6/4 : v/v) showed phase separation and mesophase formation.

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