• Title/Summary/Keyword: Mole Fraction

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Synthesis and Physical Properties of New Biodegradable Polyester-Polypeptide Copolymer

  • Yong Kiel Sung;Chu
    • Journal of Biomedical Engineering Research
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    • v.13 no.2
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    • pp.147-154
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    • 1992
  • Poly (glycolic aclu-co-glycine-L-lactic aclu) has been prepared by rlng opening polymerlzation. The monomer 6-methyl morpholine-2, 5-dlone was synthe-slzed by bromoproplonylation of 2 bromopropionyl bromide with glycine. Glycolide and 6-methyl morpholine-2, 5-dione have been used as starling materials for polydepsipeptides. The synthesized copolymers have been Identlrled by NMR and FT-lR spectrophotometer. The Tg value of poly(glycollc aclu-co glycine-L-tactic acld ) Is In creased with increasing mole fraction of 6-methylmorpholine-2, 5-dlone(60-$84^{\circ}C$). The glass trasltion temperature of poly(glycolic acid-co-glycine-L-lactic-acid) (62-$86^{\circ}C$) is lower than that of poly (L-lactic acrid-co-glycine-L-lactic acid ). The thermal degradation of poly( L-lactic acid-co- glycine-L-lactic acid ) Is decreased with increasing mole fraction of L-lactide. The thermal degrada pion of poly(glycolic acrid-co-91ycine-L-lactic aclu ) is increased with increasing mole Fraction of glycolide.

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Characteristic absorbance of AlGaN epilayers grown on sapphire substrate (사파이어 기판 위에 성장된 AlGaN 에피층의 광 흡수 특성)

  • 김제원;박영균;김용태;최인훈
    • Journal of the Korean Vacuum Society
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    • v.8 no.2
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    • pp.153-157
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    • 1999
  • The dependence of the absorption edge of wurtzite $Al_xGa_{1-x}N$ on alN mole fraction has been studied. The AlN mole fraction was varied from 0 to 1. The absorption coefficients at room temperature were determined by transmission and photothermal deflection spectroscopy. Photothermal deflection spectroscopy can be applied to determine the low absorbance values. From the results, the effective bandgaps of $Al_xGa_{1-x}N$ alloys were determined by choosing corresponding photon energies of the positions of the absorption coefficient of $6.3\times10^4\textrm{cm}^{-1}$ at the absorption curves of the $Al_xGa_{1-x}N$ alloys. From the energy position of the absorption coefficient versus AlN mole fraction, a bowing parameter of 1.3eV was determined. The bowing parameter agreed quite well with the measured effective bandgaps of AlGaN alloys.

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Simulation on Concentration of CH4 Using Hollow Fiber Membrane Permeator with Countercurrent Flow (향류 흐름 중공사 분리막의 메탄 농축 수치해석)

  • Seo, Yeonhee;Lee, Seungmin;Park, Sungeun;Jung, Woojin;Kim, Jeonghoon;Lee, Yongtaek
    • Membrane Journal
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    • v.24 no.3
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    • pp.223-230
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    • 2014
  • A numerical analysis was performed for concentration of methane from the biogas using a polysulfone hollow fiber membrane permeator. Governing equations were derived for the countercurrent flow and numerically solved by using the Compaq Visual Fortran 6.6 software. When the methane mole fraction of feed was 0.5, the mole fraction of retentate increased from 0.5 to 0.8; the normalized retentate flow rate to the feed flow rate decreased from 1.0 to 0.57 at the given typical operating condition as the feed gas flowed from the inlet to the outlet of the membrane. As the methane mole fraction of feed was changed to 0.9, the methane mole fraction of retentate became 0.93 and the normalized retentate flow rate was changed to 0.91. When the pressure ratio of the permeate to the feed was varied from 0.33 to 0.17, there was a little difference in the methane mole fraction of retentate for the low stage cut of 0.1, whereas there was an significant increment for the high stage cut of 0.3. The retentate methane mole fraction remained relatively high despite the change of a stage cut as the area of the membrane increased from $1.14m^2$ to $2.57m^2$.

Numerical Analysis for Separation of Methane by Hollow Fiber Membrane with Cocurrent Flow (병류흐름 중공사 분리막에 의한 메탄 분리 수치해석)

  • Lee, Seungmin;Seo, Yeonhee;Kang, Hanchang;Kim, Jeonghoon;Lee, Yongtaek
    • Korean Chemical Engineering Research
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    • v.53 no.3
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    • pp.295-301
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    • 2015
  • A theoretical analysis was carried out to examine the concentration behavior of methane from a biogas using a polysulfone membrane. After the governing equations were derived for the cocurrent flow mode in a membrane module, the coupled nonlinear differential equations were numerically solved with the Compaq Visual Fortran 6.6 software. At the typical operating condition of mole fraction of 0.7 in a feed stream, the mole fraction of methane in the retentate increased to 0.76 while the normalized retentate flow rate to the feed flow rate decreased from 1 to 0.79. When either the mole fraction of methane in a feed increased or the pressure of the feed stream increased, the methane mole fraction in the retentate increased. On the other hand, it was found that as either the membrane area decreased or the ratio of the permeate pressure to the feed pressure increased, the methane mole fraction in the retentate decreased. In case that the stage cut increased, the methane mole fraction in the retentate increased while the recovery of methane slightly decreased.

Pervaporation of n-Butanol/water Mixture through Organophilic ZSM-5 Zeolite Membrane (소수성 ZSM-5 제올라이트 분리막을 이용한 n-부탄올/물 혼합물의 투과증발)

  • Cho, Moon-Hee;Kong, Chang-In;Lee, Yong-Taek
    • Membrane Journal
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    • v.21 no.4
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    • pp.336-344
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    • 2011
  • Organophilic ZSM-5 membrane was synthesized on the inside of a porous stainless steel support by a hydrothermal secondary growth with seed crystals. They are used to separate n-butanol from its aqueous solution. Pervaporation characteristics such as a permeation flux and a separation factor are investigated as a function of the feed concentration and the operating temperature. The concentration of n-butanol was changed from 0.001 mole fraction to 0.015 mole fraction with an interval of 0.005 mole fraction; the operating temperature was controlled to be 25C, $35^{\circ}C$ and $45^{\circ}C$. When the operating temperature was $45^{\circ}C$, the flux of n-butanol significantly increased from 2 to $27g/m^2/hr$ as the mole fraction of n-butanol in the feed side increased from 0.001 to 0.015. Consequently, the concentration of n-butanol in the permeate substantially increased from 0.0016 to 0.052 mole fraction. When the feed concentration was 0.015, the flux of n-butanol significantly increased from 13 to $27g/m^2/hr$ as the operating temperature increased from $25^{\circ}C$ to $45^{\circ}C$. As a result, the concentration of n-butanol in the permeate also increased from 0.045 to 0.052 mole fraction.

Scintillation Characteristics of CsI:X(X=Li+,K+,Rb+ Single Crystals (CsI:X(X=Li+,K+,Rb+단결정의 섬광특성)

  • Gang, Gap-Jung;Doh, Sih-Hong;Lee, Woo-Gyo;Oh, Moon-Young
    • Journal of Sensor Science and Technology
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    • v.12 no.1
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    • pp.1-9
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    • 2003
  • CsI single crystals doped with lithium, potassium or rubidium were grown by using Czochralski method at Ar gas atmosphere. The energy resolutions of CsI(Li:0.2 mole%), CsI(K:0.5 mole%) and CsI(Rb:1.5 mole%) scintillators were 14.5%, 15.9% and 17.0% for $^{137}Cs$(0.662 MeV), respectively. The energy calibration curves of CsI(Li), CsI(K) and CsI(Rb) scintillators were linear for $\gamma$-ray energy. The time resolutions of CsI(Li:0.2 mole%), CsI(K:0.5 mole%) and CsI(Rb:1.5 mole%) scintillators measured by CFT(constant-fraction timing method) were 9.0 ns, 14.7 ns and 9.7 ns, respectively. The fluorescence decay times of CsI(Li:0.2 mole%) scintillator had a fast component and slow one of ${\tau}_1=41.2\;ns$ and ${\tau}_2=483\;ns$, respectively. The fluorescence decay times of CsI(K:0.5 mole%) scintillator were ${\tau}_1=47.2\;ns$ and ${\tau}_2=417\;ns$. And the fluorescence decay times of CsI(Rb:1.5 mole%) scintillator were ${\tau}_1=41.3\;ns$ and ${\tau}_2=553\;ns$. The phosphorescence decay times of CsI(Li:0.2 mole%), CsI(K:0.5 mole%) and CsI(Rb:1.5 mole%) scintillators were 0.51 s, 0.57 s and 0.56 s, respectively.

Extended Injectant Mole-Fraction Imaging of Supersonic Mixing using Acetone PLIF

  • Takahashi, Hidemi;Ikegami, Shuzo;Hirota, Mitsutomo;Masuya, Goro
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.03a
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    • pp.781-789
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    • 2008
  • The fluorescence ratio method for processing planar laser induced fluorescence(PLIF) data was generalized for quantitative imaging of the injectant mole-fraction in supersonic mixing flowfields. The original fluorescence ratio approach was introduced by Hartfield et al. for tests in a special closed-loop wind tunnel to eliminate the effects of thermodynamic property variations in compressible flowfields and to provide a quantitative means of mole-fraction measurement. However, they implicitly assumed that the tracer molecules were seeded at the same fraction in both main and secondary flows. In the present study, we proposed generalizing the Hartfield method by considering differences in the tracer seeding rates. We examined the generalized method in a mixing flowfield formed by sonic transverse injection into a Mach 1.8 supersonic air stream. The injectant molefraction distribution obtained from PLIF data processed by our new approach showed better agreement with the gas chromatograph than one based on the Hartfield method.

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Impact Ionization Rates of Electron in GaAs/AlGaAs Qunantum Well Using EMC Simulation (EMC Simulation을 이용한 GaAs/AlGaAs 양자 우물 내 전자의 충돌 이온화율)

  • 윤기정;홍창희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.11a
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    • pp.221-225
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    • 1994
  • We described the impact ionization rates of electron in GaAs/AlGaAs MQH(multi- quantum well) using EMC(ensenble Monte Carlo) simulation. Hot electron energy of injected into quantum well is increasing nearly liearly due to the applied electric field to the barrier of MQM inspite of various Al mole fraction in AlGaAs or barrier width. Impact ionization rates are decreasing exponentially by increasing Al mole fraction, and they have peak vague due to the barrier width.

Optimization of the DC and RF characteristics in AlGaN/GaN HEMT (AlGaN/GaN HEMT 의 DC 및 RF 특성 최적화)

  • Son, Sung-Hun;Kim, Tae-Geun
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.48 no.9
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    • pp.1-5
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    • 2011
  • In this paper, we investigated the characteristics of AlGaN/GaN HEMTs to optimize their DC and RF characteristics by using a two-dimensional device simulator. First, we analyzed the variation of the DC characteristics with respect to the variation of 2DEG concentrations when varying the Al mole fraction and the thickness of the AlGaN layer. Then, we examined the variation of the RF characteristics by varying the size and the location of the gate, source and drain electrodes. When the Al mole fraction increased from 0.2 to 0.45, both the transconductance and I-V characteristics increased. On the other hand, the I-V characteristics were improved but transconductance was decreased as the thickness of the AlGaN layer increased from 10nm to 50nm. In the RF characteristics, the gate length was found to be the most influential parameter, and the RF characteristics were improved when the gate length was shorten.

Computation of Nonpremixed Methane-Air Flames in Microgravity II. Radius and Thickness of Flame (무중력에서의 비예혼합 메탄-공기 화염의 전산 II. 화염의 반경과 두께)

  • Park Woe-Chul
    • Journal of the Korean Society of Safety
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    • v.19 no.3 s.67
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    • pp.124-129
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    • 2004
  • To evaluate the numerical method in simulation of diffusion flames and to see the effects of strain rate and fuel concentration on the flame radius and thickness, the nonpremixed methane-air counterflow flames in microgravity were simulated axisymmetrically by using the MST Fire Dynamics Simulator (FDS). The $1000^{\circ}C$ based flame radius and thickness were investigated for the mole fraction of methane in the fuel stream, $X_m=20,\;50,\;and\;80\%$ and the global strain rates $a_g=20,\;60,\;and\;90s^{-1}$ for each mole fraction. The flame radius increased with the global strain rate while the flame thickness decreased linearly as the global strain rate increased. The flame radius decreased as the mole fraction increased, but it was not so sensitive to the mole fraction compared with the global strain rate. Since there was good agreement in the nondimensional flame thickness obtained with OPPDIF and FDS respectively, it was confirmed that FDS is capable of predicting well the counterflow flames in a wide range of strain rate and fuel concentration.