• 제목/요약/키워드: Moisture cure

검색결과 27건 처리시간 0.018초

할로겐화고무의 수가교에 관한 연구(Polychloroprene Rubber의 수가교) (A Study on the Moisture Cure of Halogenated Rubber(I) (Moisture Cure of Polychloroprene Rubber))

  • 윤정식;유종선;백남철;민병권
    • Elastomers and Composites
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    • 제26권2호
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    • pp.115-122
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    • 1991
  • Polychloroprene rubber was moisture-cured after treating them with silane coupling agents such as 3-mercaptopropyltrimethoxysilane(MPS), 3-methacryloxypropyltrimethoxysilane(MAS) and vinyltriethoxysilane(VES), especially MPS. The cure reaction is composed of two steps. The first is the reaction between chlorine atoms of CR and silane coupling agents. The second is the formation of cross-links which are siloxane linkage. The linkage is formed by the condensation of silanol groups which are produced by the hydrolysis of alkoxysilyl groups. The first reaction was kinetically studied and the reactivity of CR to silane coupling agents was determined in previous literature. Crosslinking density and mechanical properties of the moisture-cured elastomer filled with silica or non-filled were studied and the feasibility of this cure system was discussed.

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할로겐화 고무의 수가교에 관한 연구(II) (할로겐화 부틸고무의 수가교) (A Study on the Moisture-Cure of Halogenated Rubber(II) (Moisture-Cure of CIIR and BIIR))

  • 윤정식;유종선;백남철;민병권
    • Elastomers and Composites
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    • 제27권1호
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    • pp.20-26
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    • 1992
  • Reactions between chlorinated or brominated poly(isobutylene-isoprene) (CIIR and BIIR, respectively) and 3-mercaptopropyltrimethoxysilane(MPS) were kinetically studied by gas chromatography in solution state. CIIR and BIIR were mixed with MPS and dibutyltin dilaurate as catalyst on roll mill and then the compounds were cured in hot water or atmosphere. From the gas chromatography, reaction order, activation energy, and frequency factor were determined. Crosslinking density and physical properties of moisture-cured CIIR and BIIR were measured. CIIR and BIIR were effectively moisture-cured and physical properties of these rubbers were comparatively good.

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Time Dependent Extension and Failure Analysis of Structural Adhesive Assemblies Under Static Load Conditions

  • Young, Patrick H.;Miller, Zachary K.;Gwasdacus, Jeffrey M.
    • 접착 및 계면
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    • 제21권1호
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    • pp.6-13
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    • 2020
  • The objective of the current study is to characterize the long-term stability and efficacy of a structural adhesive assembly under static load. An apparatus was designed to be used in the Instron tensile test machine that would allow for real time modeling of the failure characteristics of an assembly utilizing a moisture- cure adhesive which was bonded to concrete. A regression model was developed that followed a linear - natural log function which was used to predict the expected life of the assembly. Evaluations at different curing times confirmed the structure was more robust with longer cure durations prior to loading. Finally, the results show that under the conditions the assembly was tested, there was only a small amount of inelastic creep and the regression models demonstrated the potential for a stable structure lasting several decades.

경화공정 및 수분흡수에 따른 복합재료 하니콤 샌드위치 판넬의 접합강도특성 연구 (Bondline Strength Evaluation of Honeycomb Sandwich Panel For Cure Process and Moisture Absorption)

  • 최흥섭;전흥재;남재도
    • 대한기계학회논문집A
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    • 제25권1호
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    • pp.115-126
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    • 2001
  • In this paper, through a series of comparative experiments, effects of two different cure processing methods, cocure and precure, on the mechanical properties of honeycomb core materials for aircraft applications are considered. Mass of moisture accumulated into the closed cells of the sandwich panel specimen from the measured mass of moisture diffused to the full saturation state into the elements(skin, adhesive layer, Nomex honeycomb), consisting the honeycomb sandwich specimen has been calculated. Water reservoir of 70$\^{C}$ was used to have specimens absorb moisture to see the influence of moisture absorbed into sandwich panel on its mechanical properties. For the repair condition holding for 2 hours at 177$\^{C}$(350℉) temperature, a pressure due to the vapor expansion in each cell of the sandwich panel, which may result in the local separation of the interface between laminated skin and the surface of the honeycomb, has been estimated by vapor pressure-temperature relation from the thermodynamic steam table and compared to the pressure from the ideal gas state equation. The bonding strengths of the laminated skins on the flat surface of the Nomex honeycomb have been compared by the flatwise tension test and climbing drum peel test performed at room temperature for dry, wet and wet-repair specimens, respectively.

Chlorosulfonated Polyethylene의 저온가황반응(低溫加黃反應) (Low Temperature Vulcanization of Chlorosulfonated Polyethylene)

  • 박근식;박성하;최세영
    • Elastomers and Composites
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    • 제27권4호
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    • pp.255-261
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    • 1992
  • Chlorosulfonated polyethylene(CSM) was moisture-cure after treating them with silane coupling agents such as ${\gamma}-mercapto$ propyl trimethoxy silane, ${\gamma}-glycidoxy$ propyl triethoxy silane and methyl triethoxy silane, 3-(trimethoxy silyl) propyl methacrylate and 3-thiocyanopropyl triethoxy silane. The cure reaction is composed two steps. The first is the reaction between chlorosulfonyl groups of CSM and silane coupling agents. The second is the formation of cross-links which are siloxane linkage. The linkage is formed by the condensation of silanol groups which are produced by the hydrolysis of alkoxysilyl groups. CSM was mixed with MPS etc., and dilaurate dilaurate as catalyst on two open mill and the compounds were lured in hot water at $70^{\circ}C$ Physical properties of moisture-cured CSM was measured. CSM was effectively moisture-cured and r-mercapto propyl trimethoxy silane and r-glycidoxy propyl trimethoxy silane were capable of the vulcanizing agents.

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환경친화적 Spray UV-Cure 가공 기술을 이용한 물세탁 모직물(washable wool)의 개발 -광가교 고분자인 dextran-methacrylate를 이용하여- (Development of Washable Wool Using Environmental-friendly Spray UV-cure Finishing Technique - Using Photocrosslinkable Polymerr Dextran-methacrylate-)

  • 김신희
    • 한국의류학회지
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    • 제28권11호
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    • pp.1507-1515
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    • 2004
  • Washable wool was developed using environmental-friendly spray UV-cure technique. Photocrosslinkable polymer, dextran-methacrylate, was synthesized starting from natural biopolymer, dextran. The aqueous solution of dextran-methacrylate was applied to wool fabric with various concentrations to find out the optimum condition in minimizing felting shrinkage. The wool fabric subsequently cured by 365 nm UV, The effects of UV-cure time and photoinitiator concentration on felting behavior of wool were examined. As the concentration of dextran-methacrylate increased, the felting shrinkage decreased gradually. At concentration 0.5g/ml, the felting shrinkage of wool was negligible. Other properties such as air permeability, moisture content, wrinkle recovery, thickness and wettability were also evaluated. The surface coating of dextran polymer onto wool fiber was identified by SEM.

환경친화적 ATH - FILLED XLPE COMPOUND 특성 연구 (ECO Characteristic of ATH - Filled XLPE Compound Composites)

  • 정영섭;김경룡;한신호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 춘계학술대회 논문집 유기절연재료 방전 플라즈마연구회
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    • pp.44-48
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    • 2003
  • 할로겐 난연재료 및 고분자의 연소시 Dioxine의 문제점이 대두되고 있어 유럽국가를 중심으로 할로겐 난연제 사용을 규제하고 있다. 환경과 인체에 대한 안정성을 고려해서 저 유해 가스화, 저 발연화, 저 부식성, 리사이클링 등을 겸비한 제품의 개발로 관심이 모아지고 있는 실정이다. 본 연구에서는 환경친화적인 금속화합(수산화 알루미늄)을 사용하여 연소시 발생할 수 있는 난연성, 무독성, 소연성 등을 함량별로 확인하고 난연재가 증가할수록 취약한 기계적 물성 보완을 위해 moisture cure crosslikable 기술로 케이블절연 및 자켓 피복층 특성을 증가 시켰다. 그러나 수산화알루미늄 함량이 증가할수록 기계적 물성과 기타 특성도 감소하는 경향을 보이고 있어 최적의 난연제 조성함량이 약 130~150 phr정도에서 우수한 결과를 확인하였다. 또한 moisture cure agent는 전선압출 시 표면에 scorch 및 장기 압출에 영향을 주므로 약 1.5~2phr 범위에서 처방하는 것이 우수하다. 원료투입 후 mixing 공정 중에서는 온도관리가 매우 중요하므로 되도록 믹싱 온도를 $130^{\circ}C$ 이하를 유지해야한다. 온도는 수산화알루미늄의 분산성과 케이블 피복압출 시 표면에도 영향을 주기 때문이다 본 연구는 이런 작업방법을 통해 친환경 가교 난연콤파운드가 비(比) 가교된 제품에 비해 특성이 증가되는 것을 입증할 수 있었다.

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비만의 원인과 치료에 대한 동서의학적 고찰 (Oriental and Western Medical Study on the cause and treatment of Obesity)

  • 이상봉;금동호;이명종
    • 동국한의학연구소논문집
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    • 제5권
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    • pp.33-52
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    • 1996
  • The purpose of this study was to investigate efficient treatment in obesity. In order to help clinical application in obesity treatment, this study was performed to investigate the cause and treatment in obesity. The main finding of this study were as follows. 1. In the cause of oriental medicine in obesity, that were moisture(濕), phlegm(痰), gore(瘀), the productive heat(積熱), overeating, supemutrition, underaction, heredity and habitude, psychologic factor(stress) etc. 2. In the western medicine, the cause of obesity were genetic cause, endocrine disorder, hypothalamic extraodinary and secondary effect of drug. But simple obesity is the greater part. Also there were psychologicai and environmental causes. 3. Ear acupuncture of wide application were Naebunbi, Sinmun, Taejang, $ij{\check{o}}m$, $Pyej{\check{o}}m$, $Bij{\check{o}}m$ etc. 4. Body acupuncture of application were $Naej{\check{o}}ng$, $Sangg{\check{o}}h{\check{o}}$, Pungnyung, Kokchi, $Sam{\check{o}}mgyo$, $Umn{\check{o}}ngch{\check{o}}n$ etc. 5. In oriental medical treatment of obesity, Bangpungtongs ngsan(防風通聖散), Daesihotang(大柴胡湯), Seungkitang(承氣湯), Bangkihwangkitang(防己黃?湯), Richulsaryeungtang(二朮四笭湯), Taeksatang(澤瀉湯), Opieum(五皮飮), Gongyundan(控涎丹) etc were wide applicated. 6. The western medical treatment in obesity encourage the dietary cure, exercise cure and behavior adjustment than medical therapy or operation. In treatment of obesity, the dietary cure and herb-drug therapy, ear acupuncture and body acupuncture are effective. But weight maintenance after treating is more important. After all the continuous dietary cure, behavior adjusting cure and exercise cure are necessary.

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BS 치환 모르타르의 ERCO 도포시 수분증발 및 수축변화에 미치는 영향 (Impact of BS replacement mortar's application to ERCO on moisture evaporation and contraction changes)

  • 백철;이제현;황찬우;장덕배;한민철;한천구
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2016년도 추계 학술논문 발표대회
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    • pp.115-116
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    • 2016
  • This study applied BS replacement mortar's ERCO to see what impact it has on moisture evaporation and contraction changes, and resulted in the following. Depending on the rate of change in length according to the cure method of BS replacement mortar, high-strength areas were shown to have a bigger increase in the rate of change in length than regular or low-strength areas, and differences in rate of change in length due to ERCO cure methods were shown to be slight. For rate of changes in mass, on the whole there was an increase in the order of dry curing, cover curing, 7-day water curing, and28-day water curing. A comprehensive view says that after removal of test piece specimens, ERCO application did not expect a sufficient curing effect in the BS area.

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Some Characteristics of Anisotropic Conductive and Non-conductive Adhesive Flip Chip on Flex Interconnections

  • Caers, J.F.J.M.;De Vries, J.W.C.;Zhao, X.J.;Wong, E.H.
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제3권3호
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    • pp.122-131
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    • 2003
  • In this study, some characteristics of conductive and non-conductive adhesive inter-connections are derived, based on data from literature and own projects. Assembly of flip chip on flex is taken as a carrier. Potential failure mechanisms of adhesive interconnections reported in literature are reviewed. Some methods that can be used to evaluate the quality of adhesive interconnections and to evaluate their aging behavior are given. Possible finite element simulation approaches are introduced and the required critical materials properties are summarized. Response to temperature and moisture, resistance to reflow soldering and resistance to rapid change in temperature and humidity are elaborated. The effect of post cure during accelerated testing is discussed. This study shows that only a combined approach using finite element simulations, and use of appropriate experimental evaluation methods can result in revealing, understanding and quantifying the complex degradation mechanisms of adhesive interconnections during aging.