• Title/Summary/Keyword: Modified materials

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Optimization of L-shaped Corner Dowel Joint in Modified Poplar using Finite Element Analysis with Taguchi Method

  • Ke, Qing;Zhang, Fan;Zhang, Yachi
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.2
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    • pp.204-217
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    • 2016
  • Modified poplar has emerged as a potential raw material for furniture production. Lack of specific modified poplar strength information; however, restricts applications in the furniture industry especially as related to strength in corner-joints. Optimization of strength in L-shaped corner dowel modified poplar joints under compression loads utilizing finite element analysis (FEA) by Taguchi method with the focus of this study. Four experiment factors (i.e., Structure Style, Tenon Length, Tenon Diameter, and Tenon Gap), each at three levels, were conducted by adopting a $L_9-3^4$ Taguchi orthodoxy array (OA) to determine the optimal combination of factors and levels for the von Mises stress utilizing ANSYS software. Results of Signal-to-Noise ratio (S/N) analysis and the analysis of variance (ANOVA) revealed the optimal L-shaped corner dowel joint in modified poplar is $45^{\circ}$ Bevel Butt in structure style, 24 mm in tenon length, 6 mm in tenon diameter, and 20 mm in tenon gap. Tenon length and tenon gap are determined to be significant design factors for affecting von Mises Stress. Confirmation tests with optimal levels and experimental test indicated the predicted optimal condition is comparable to the actual experimental optimal condition.

Effect of Interface on the Properties of Polyamide 6/Carbon Nanotube Nanocomposites Prepared by In-situ Anionic Ring-opening Polymerization

  • Min, Jin Hong;Huh, Mongyoung;Yun, Seok Il
    • Composites Research
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    • v.32 no.6
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    • pp.375-381
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    • 2019
  • Multiwalled carbon nanotubes (MWCNTs) are covalently functionalized with isocyanates by directly reacting commercial hydroxyl functionalized MWCNTs with excess 4,4'-methylenebis (phenyl isocyanate) (MDI) and hexamethylene diiosocyanate (HDI). HDI-modified MWCNTs results in a higher surface isocyanate density than MDI-modified MWCNTs. Anionic ring-opening polymerization of ε-caprolactam is conducted using a sodium caprolactam initiator in combination with a di-functional hexamethylene-1,6-dicarbamoylcaprolactam activator in the presence of isocyanate functionalized MWCNTs. This polymerization proceeds in a highly efficient manner at relatively low reaction temperature (150℃) and short reaction times (10 min). During the polymerization, the isocyanate functionalized MWCNTs act not only as reinforcing fillers but also as second activators. Nanocomposites with HDI modified MWCNTs exhibit higher reinforcement and faster isothermal crystallization than MDI modified MWCNTs. The results show that PA6 chains grow more effectively from HDI modified MWCNT surface than from MDI modified MWCNT surface, resulting in stronger interaction between PA6 and MWCNTs.

A Study in Application and Manufacture Technique of Cold-Mix Cold-Laid Type Asphalt Concrete Using of Polymer Modified Asphal (개질 아스팔트를 이용한 상온아스콘 제조 및 실용화 연구)

  • 김영근;남궁연;박유신
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.04a
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    • pp.627-634
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    • 1997
  • This is the Study on Application and Manufacture Technique of Cold-Mix, Cold-Laid type Asphalt Concrete using of Polymer modified asphalt the could be constructed easily and economically on damaged road repaireless for seasons. The modified materials for this study are SBS(Styrene-Butadiene-Styrene). SBR (Styrene-Butadiene-Rubber) and PUR(Polyurethane). The Marshall stability and the value of flow and resistance in water stability degree according to the alternation types and weight percent of modified materials were compared and evaluated on this study. The results of the study show that PUR modified asphalt have improvement of over 150% Marshall stability in AI MS-14 standard and they are evaluated to have the easiness of storage and better working efficiency compared with other types of modified asphalt compound.

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Enhanced Removal of Phenol from Aquatic Solution in a Schorl-catalyzed Fenton-like System by Acid-modified Schorl

  • Xu, Huan-Yan;Prasad, Murari;Wang, Peng
    • Bulletin of the Korean Chemical Society
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    • v.31 no.4
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    • pp.803-807
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    • 2010
  • Schorl modified by $H_2SO_4$ has been successfully developed to enhance schorl-catalyzed Fenton-like reaction for removal of phenol in an aqueous solution. The phenol removal percentage can be increased from 4% to 100% by the system of modified schorl and $H_2O_2$. Batch experiments indicate that the percent increases in removal of phenol by increasing the dosage of catalyst, temperature and initial concentration of $H_2O_2$. The results of XRD, FT-IR and SEM suggest that no new phases are formed after removal of phenol by modified schorl. ICP-AES results reveal that more dissolution of iron results in higher catalytic oxidant activity in the system of modified schorl and $H_2O_2$. Besides minor adsorption, mineral-catalyzed Fenton-like reaction governs the process.

An Experimental Study on the Micro Friction and Wear Characteristics of Organically Modified Hybrid Ceramic Materials by A Sol-Gel Process (졸-겔 공정에 의한 유기변성 하이브리드 세라믹 물질의 미세 마찰마모 특성)

  • Han, Hung-Gu;Kong, Ho-Sung;Yoon, Eui-Sung;Yang, Seung-Ho
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.05a
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    • pp.215-225
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    • 2002
  • In order to enhance the thermal stability of binder materials of bonded type solid lubricants, several combinations of metal-alkoxide based sol-gel materials such as methyltrimethoxysilane(MTMOS), $titaniumisopropoxide(Ti(Opr^{j})_{4})$, $zirconiumisopropoxide(Zr(Opr^{j})_{4})$ and $aluminumbutoxide(Al(Obu^{t})_{4})$ were chemically modified by epoxy-, acrylic- and fluoro-silane compounds, respectively, in this work. Friction and wear characteristics of these hybrid ceramic materials were tested with a micro tribe-tester where a reciprocating steel ball slid on a test material, and the tribological property was also evaluated with respect to both heat-curing temperature and tile time. Test results generally showed that hybrid ceramic materials modified by epoxy-silane compounds had a low friction compared to others. And the higher heat-curing temperature and the longer heat treatment time resulted in the higher friction and the lower wear. IR spectroscopic analyses revealed that it was caused mainly by the increased metal oxide content in hybrid ceramics when the heat-curing temperature was over $320^{\circ}C$.

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Micro Friction and Wear Characteristics of Organically Modified Hybrid Ceramic Materials Synthesized by A Sol-Gel Process (졸-겔 공정에 의한 유기변성 하이브리드 세라믹 물질의 미세 마찰마모 특성)

  • Han, Hung-Gu;Kong, Ho-Sung;Yoon, Eui-Sung;Yang, Seung-Ho
    • Tribology and Lubricants
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    • v.18 no.5
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    • pp.324-332
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    • 2002
  • In order to enhance the thermal stability of binder materials of bonded type solid lubricants, several metal-alkoxide based sol-gel materials such as methyltrimethoxysilane(MTMOS), titaniumisopropoxide$(Ti(Opr^i)_4),$ zirconiumisopropoxide $(Zr(Opr^i)_4)$ and aluminumbutoxide$(Al(Obu^t)_4)$ were chemically modified by epoxy-, acrylic- and fluoro-silane compounds, respectively. Friction and wear characteristics of these hybrid ceramic materials were tested with a micro tribo-tester, and evaluated with respect to both heat-curing temperature and the time. Test results generally showed that hybrid ceramic materials modified by epoxy-silane compounds had a low friction compared to others. And the higher het-curing temperature and the longer heat treatment time resulted in the higher friction and the lower wear. IR spectroscopic analyses revealed that these results were caused mainly by the increased metal oxide content in hybrid ceramics when the heat-curing temperature was over $320^{\circ}C.$

Long-term Creep Strain-Time Curve Modeling of Alloy 617 for a VHTR Intermediate Heat Exchanger (초고온가스로 중간 열교환기용 Alloy 617의 장시간 크리프 변형률-시간 곡선 모델링)

  • Kim, Woo-Gon;Yin, Song-Nam;Kim, Yong-Wan
    • Korean Journal of Metals and Materials
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    • v.47 no.10
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    • pp.613-620
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    • 2009
  • The Kachanov-Rabotnov (K-R) creep model was proposed to accurately model the long-term creep curves above $10^5$ hours of Alloy 617. To this end, a series of creep data was obtained from creep tests conducted under different stress levels at $950^{\circ}C$. Using these data, the creep constants used in the K-R model and the modified K-R model were determined by a nonlinear least square fitting (NLSF) method, respectively. The K-R model yielded poor correspondence with the experimental curves, but the modified K-R model provided good agreement with the curves. Log-log plots of ${\varepsilon}^{\ast}$-stress and ${\varepsilon}^{\ast}$-time to rupture showed good linear relationships. Constants in the modified K-R model were obtained as ${\lambda}$=2.78, and $k=1.24$, and they showed behavior close to stress independency. Using these constants, long-term creep curves above $10^5$ hours obtained from short-term creep data can be modeled by implementing the modified K-R model.

Statistical Analysis for Creep Crack Growth Behavior of Modified 9Cr-1Mo Steel (Modified 9Cr-1Mo 강의 크리프 균열성장 거동에 관한 통계적 해석)

  • Jung, Ik-Hee;Kim, Woo-Gon;Yin, Song-Nan;Ryu, Woo-Seog;Kim, Seon-Jin
    • Korean Journal of Metals and Materials
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    • v.47 no.5
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    • pp.283-289
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    • 2009
  • This paper dealt with a statistical analysis for evaluating the creep crack growth rate (CCGR) for Modified 9Cr-1Mo (ASTM Grade 91) steel. The CCGR data was obtained by the creep crack growth (CCG) tests conducted under various applied loads at $600^{\circ}C$. To obtain logically the B and q values used in the CCGR equation, three methods such as the least square fitting method (LSFM), the mean value method (MVM) and the probabilistic distribution method (PDM) were adopted and their CCGR lines were compared, respectively. In addition, a number of random variables were generated by using the Monte Carlo simulation (MCS), and the CCGR lines were predicted probabilistically. It was found that both the B and q coefficients followed a 2-parameter Weibull distribution well. In the case of the ranges of 10-90% for the probability variables, P(B, q), the CCGR lines were predicted. Fractographic study was conducted from the specimen after the CCG tests.

Migration of fine granular materials into overlying layers using a modified large-scale triaxial system

  • Tan Manh Do;Jan Laue;Hans Mattsson;Qi Jia
    • Geomechanics and Engineering
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    • v.37 no.4
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    • pp.359-370
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    • 2024
  • The primary goal of this study is to evaluate the migration of fine granular materials into overlying layers under cyclic loading using a modified large-scale triaxial system as a physical model test. Samples prepared for the modified large-scale triaxial system comprised a 60 mm thick gravel layer overlying a 120 mm thick subgrade layer, which could be either tailings or railway sand. A quantitative analysis of the migration of fine granular materials was based on the mass percentage and grain size of migrated materials collected in the gravel. In addition, the cyclic characteristics, i.e., accumulated axial strain and excess pore water pressure, were evaluated. As a result, the total migration rate of the railway sand sample was found to be small. However, the total migration rate of the sample containing tailings in the subgrade layer was much higher than that of the railway sand sample. In addition, the migration analysis revealed that finer tailings particles tended to be migrated into the upper gravel layer easier than coarser tailings particles under cyclic loading. This could be involved in significant increases in excess pore water pressure at the last cycles of the physical model test.

Characterization of SPAES Composite Membrane Containing Variously Funtionallized MMT for Direct Methanol Fuel Cell Application (다양한 관능기를 포함한 MMT/SPAES 복합막의 직접 메탄올 연료전지용 적용을 위한 특성평가)

  • Kim, Deuk-Ju;Hwang, Hae-Young;Kim, Se-Jong;Hong, Young-Taik;Kim, Hyoung-Juhn;Leem, Tae-Hoon;Nam, Sang-Yong
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.1
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    • pp.42-50
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    • 2011
  • The Montmorillonite (MMT) in the polymer matrix is expected to reduce methanol permeability due to the tortous path formed by dispersed silicate layers. However, the polymer composite membranes containing non-proton conducting inorganic particle tend to show low proton conductivity. To solve this problem, we used an ion exchange method to prepare functionalized MMT with various silane coupling agents. The modified MMT was randomly dispersed in sulfonated poly (arylene ether sulfone) (SPAES) matrix to prepare SPAES/modified MMT composite membranes. The performances of hybrid membranes for DMFCs application were investigated. The SPAES/modified composite membrane showed increased proton conductivity compared with the non-modified MMT composite membrane. However, the methanol permeability of the SPAES/modified membrane was higher than that of the non-modified MMT.