• Title/Summary/Keyword: Modified materials

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Study of the Enhancement of Magnetic Properties of NdFeB Materials Fabricated by Modified HDDR Process

  • Fu, Meng;Lian, Fa-zeng;Wang, jie-Ji;Pei, Wen-Ii;Chen, Yu-lan;Yang, Hong-cai
    • Journal of Magnetics
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    • v.9 no.4
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    • pp.109-112
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    • 2004
  • The HDDR (Hydrogenation-Disproportionation-Desorption-Recombination) process is a special method to produce anisotropic NdFeB powders for bonded magnet. The effect of the modified HDDR process on magnetic properties of $Nd_2Fe_{14}B$-based magnet with several composition $Nd_{11.2}Fe_{66.5-x}Co_{15.4}B_{6,8}Zr{0.1}Ga_x(x=0{\sim}1.0)$ and that of microelement Ga, disproportional temperature and annealing temperature on $_jH_c$, grain size were investigated in order to produce anisotropic powder with high magnetic properties. It was found that modified HDDR process is very effective to enhance magnetic properties and to fine grain size. The addition of Ga could change disproportionation character remarkably of the alloy and could improve magnetic properties of magnet powder. Increasing annealing temperature induces significant grain growth. And grain size produced by modified HDDR process is significantly smaller than those produced by conventional HDDR process.

Gd effect on microstructure and properties of the Modified-690 alloy for function structure integrated thermal neutron shielding

  • Cheng Zhang;Jie Pan;Zixie Wang;Zhaoyu Wu;Qiliang Mei;Qianxue Ding;Jing Gao;Xueshan Xiao
    • Nuclear Engineering and Technology
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    • v.55 no.5
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    • pp.1541-1558
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    • 2023
  • The new Modified-690Gd alloy, namely as Ni-30Cr-(10-x) Fe-xGd (x = 0.5, 1.0, 1.5,2.0, 3.0 wt%) for function structure integrated thermal neutron shielding has been prepared and characterized. The Modified-690Gd alloy was mainly composed of γ austenite matrix and (Ni, Cr, Fe)5Gd precipitated along grain boundaries. The new Modified-690Gd alloy had great mechanical properties, which had the tensile strength exceeding 620 MPa and the elongation being above 50%. Meanwhile, this alloy had excellent weldability and good corrosion resistance in boric acid. The new Modified-690Gd alloy is expected to be a kind of high efficiency thermal neutron shielding materials.

Development of Low Fat Mayonnaise Made with Modified Starch (변성전분을 이용한 저지방 마요네즈의 개발)

  • Song, Eun-Seung;Kim, Eun-Kyung;Woo, Na-Ri-Yah
    • Journal of the Korean Society of Food Culture
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    • v.22 no.2
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    • pp.254-260
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    • 2007
  • This study was examined closely physiological activation and intended to present the possibility of developing food low-fat food. Developing carbohydrate fat replacer as materials for low-fat food made of Korean potato starch, it is expected that the new demand of fat replacer will be created. Potato starch was modified by chemical modification. The calorie of starch of GPS was measured to be 3.0 kcal/g, those of chemically modified starch, HPR showed 2.5 kcal/g respectively, suggesting that calorie is decreased by modified treatment. The appropriateness of processing food was experimented by substituting the existing oil and fat containing food with gel of starch and modified starch in constant rate through utilization of modified starch. When producing mayonnaise by substituting edible oil with gel of modified starch in 10-50%, calorie was reduced by 44${\sim}$45% when substituted by 50%, suggesting the potential of low-fat food. Measuring viscosity of mayonnaise by Brookfield viscometer, the mayonnaise with HPR showed high viscosity and the chemical modified starch group of EZ also showed high viscosity. Generally, the material property of mayonnaise tended to reduce in all measured items when oil and fat are substituted by starch substituting materials and the substituting materials increase. When it comes to the emulsification stability of mayonnaise with starch substituting materials, emulsification stability of all mayonnaise with starch substituting materials is lower than that of compared group. While the group with NL as commercial fat replacer showed emulsification stability which was slightly higher than group with modified starch and the substitution group of HPR showed higher emulsification stability. Sensory evaluation for low-fat mayonnaise by substituting oil the products substituted by modified starch was more preferred than general starch substituting products such as GPS. While NL as commercially fat replacer showed the hight preference, products with H40, EZ were also highly preferred.

Influence of Hydrogen and Oxygen on the Thermotransport of Hydrogen in Modified Zircaloy-4 (Modified Zircaloy-4에서 수소의 Thermotransport에 있어서 수소와 산소의 보고)

  • Kim, Hyun-Sook;Kim, Seon-Jin
    • Korean Journal of Materials Research
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    • v.13 no.7
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    • pp.473-477
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    • 2003
  • The hydrogen redistribution induced by thermotransport at temperatures likely to be encountered in nuclear power reactors (300-$340^{\circ}C$) was investigated in modified Zircaloy-4 alloys. Modified Zircaloy-4 alloys were prepared by altering the chemical composition of Zircaloy-4; the oxygen content of Zircaloy-4 (0.1 wt%) was increased to 0.2, 0.5 and 1.0 wt%. The heat of transport ($Q^{*}$ ) for hydrogen was measured by changing the initial hydrogen and oxygen concentrations. It was found that the heat of transport was not affected by increases in the initial hydrogen concentration from 63.3 to 91.7 ppm. However, the value of $Q^{Q}$ decreased from 6.8 to 4.5 ㎉/mol as the initial oxygen concentration was increased from 0.2 to 1.0 wt%.

Effects of Palladium Buffer Layer on the Oxidation Resistance of Inconel 738LC Oxidation Resistant Coating Layer by Pt Modified-pack Aluminizing (Inconel 738LC의 Pt Modified-pack Aluminizing 내산화 코팅의 산화저항성에 미치는 Palladium 완충층의 영향)

  • Han W. K.;Choi J. W.;Hong S. J.;Hwang G. H.;Kang S. G.
    • Korean Journal of Materials Research
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    • v.15 no.4
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    • pp.233-239
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    • 2005
  • In this study, the effects of Pd buffer layer on the oxidation resistance of Pt modified-pack aluminized Inconel 738LC, used for gas turbine, were investigated. Pd was electroplated on Inconel 738LC, and Pt was electroplated on the electroplated Pd surface. Thus, the thickness of electroplated Pt/Pd was $10\;{\mu}m$ and the atomic ratio of Pt : Pd was about 6 : 4. After Pt/Pd electroplating, Inconel 738LC was pack aluminized to form the oxidation resistant layer. To investigate the oxidation resistance of Pt/Pd modified-pack aluminized Inconel 738LC, iso-thermal oxidation and cyclic oxidation were performed. The iso-thermal oxdation and the cyclic oxidation data indicated that the Pt/Pd modified-pack aluminized Inconel 738LC was more oxidation resistant than the Pt modified-pack aluminized Inconel 738LC. It was thought that the difference of thermal expansion coefficient between Inconel 738LC and Pt was lowered by the Pd buffer layer.

Application of Modified Vacuum Assisted Closure with Silver Materials in Chronic Infected Wound (만성 감염성 창상에 대한 변형 음압요법과 은이온 제재의 이용)

  • Park, Gun Wook;Jeong, Jae Ho
    • Archives of Plastic Surgery
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    • v.35 no.4
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    • pp.393-399
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    • 2008
  • Purpose: Chronic infected wounds sustained over 4 weeks with exposed tendon or bone are difficult challenges to plastic surgeons. Vacuum assisted closure (VAC) device has been well used for the management of chronic wounds diminishing wound edema, reducing bacterial colonization, promoting formation of granulation tissue and local blood flow by negative pressure to wounds. But Commercial ready-made VAC device might have some difficulties to use because of its high expenses and heavy weight. So we modified traditional VAC device with silver dressing materials as topical therapeutic agents for control of superimposed bacterial wound infection such as MRSA, MRSE and peudomonas. Methods: We designed the modified VAC device using wall suction, 400 cc Hemovac and combined slow release silver dressing materials. We compared 5 consecutive patients' data treated by commercial ready-made VAC device(Group A) with 11 consecutive patients' data treated by modified VAC device combined with silver dressing materials(group B) from September 2004 to June 2007. Granulation tissue growth, wound discharge, wound culture and wound dressing expenses were compared between the two groups. Results: In comparison of results, no statistical differences were identified in reducing rate of wound size between group A and B. Wound discharge was significantly decreased in both groups. Modified VAC device with silver dressing materials showed advantages of convenience, cost effectiveness and bacterial reversion. Conclusion: In combination of modified VAC device and silver dressing materials, our results demonstrated the usefulness of managing chronic open wounds superimposed bacterial infection, cost effectiveness compared with traditional VAC device and improvement of patient mobility.

Fabrication and characterization of photocurable inorganic-organic hybrid materials using organically modified colloidal-silica nanoparticles and acryl resin

  • Kang, Dong-Jun;Han, Dong-Hee;Kang, Young-Taec;Kang, Dong-Pil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.422-422
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    • 2009
  • Photocurable inorganic-organic hybrid materials were prepared from colloidal-silica nanoparticles synthesized through the solgel process and using acryl resin. The synthesized colloidal-silica nanoparticles had uniform diameters of around 20 nm, and they were organically modified, using methyl and methacryl functional silanes, for efficient hybridization with acryl resin. The organically modified and stabilized colloidal-silica nanoparticles could be homogeneously hybridized with aeryl resin without phase separation. The successfully fabricated hybrid materials exhibit efficient photocurability and simple film formation due to the photopolymerization of the organically modified colloidal-silica nanoparticles and acryl resin upon UV exposure. The fabricated hybrid films exhibit an excellent optical transmission of above 90% in the visible region as well as an enhanced surface smoothness of around 1 nm RMS roughness. In addition, the hybrid films exhibit improved thermal and mechanical characteristics, much better than those of acryl resin. More importantly, these photocurable hybrid materials fabricated through the synergistic combination of colloidal-silica nanoparticles with acryl resin are candidates for optical and electrical applications.

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The effect of acidic drinks on the surface of tooth-colored restorative materials (산성음료가 치아색 수복재의 표면에 미치는 영향)

  • Bang, Seok-Yun;Kim, Eun-Jung;Kim, Hyun-Jung;Nam, Soon-Hyeun;Kim, Young-Jin
    • Journal of the korean academy of Pediatric Dentistry
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    • v.33 no.3
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    • pp.469-481
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    • 2006
  • Among the etiologic factors of enamel corrosion, daily intake has been considered with a profound interest, especially the intake of acidic drinks. It is thought that the rapid consumption of acidic drinks will not only results in the affection to the teeth but also to the surface of the tooth-colored restorative materials. Therefore, the puopose of this study is to examine the alterations occurred in the surface of the tooth-colored materials according to the exposed time, with 3 most common acidic drinks in contact with daily life. Resin-modified glass-ionomer, polyacid-modified composite resin, composite resin were immersed on 0.9% NaCl, Coke, orange juice, sports beverages as 4 groups in each. The surface hardness and the surface roughness of specimens were measured with following methods: before immersion, 1 day after immersion, 1-,2-,3-,4- weeks after immersion. Results were as follows. 1. Tooth-colored restorative materials, with the exception of composite resin, showed statistically significant changes in surface hardness and roughness when immersed on acidic drinks(p<0.05). 2. The degree of change in surface hardness and roughness occurred as follows, in order of severity from greatest to least resin-modified glass-ionomer, polyacid-modified composite resin, composite resin 3. Sports beverages resulted in greater alterations to surfaces than Coke and orange juice. 4. In the SEM image of the groups immersed in acidic drinks, resin-modified glass-ionomer and polyacid-modified composite resin showed loss of filer. Severe cracks were observed, especially on the resin-modified glass-ionomer.

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Mobility-Spectrum Analysis of an Anisotropic Material System with a Single-Valley Indirect-Band-Gap Semiconductor Quantum-Well

  • Joung, Hodoug;Ahn, Il-Ho;Yang, Woochul;Kim, Deuk Young
    • Electronic Materials Letters
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    • v.14 no.6
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    • pp.774-783
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    • 2018
  • Full maximum-entropy mobility-spectrum analysis (FMEMSA) is the best algorithm among mobility spectrum analyses by which we can obtain a set of partial-conductivities associated with mobility values (mobility spectrum) by analyzing magnetic-field-dependent conductivity-tensors. However, it is restricted to a direct band-gap semiconductor and should be modified for materials with other band structures. We developed the modified version of FMEMSA which is appropriate for a material with a single anisotropic valley, or an indirect-band-gap semiconductor quantum-well with a single non-degenerate conduction-band valley e.g., (110)-oriented AlAs quantum wells with a single anisotropic valley. To demonstrate the reliability of the modified version, we applied it to several sets of synthetic measurement datasets. The results demonstrated that, unlike existing FMEMSA, the modified version could produce accurate mobility spectra of materials with a single anisotropic valley.