• Title/Summary/Keyword: Model gas

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Pre-service Chemistry Teachers’ Understanding of the Boiling Process of a Liquid Mixture (액체 혼합물의 끓음에 대한 예비 화학교사의 이해)

  • Park, Kira;Yoon, Heesook
    • Journal of the Korean Chemical Society
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    • v.59 no.5
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    • pp.454-465
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    • 2015
  • The goal of this study is to investigate pre-service chemistry teachers’ understanding of the boiling process of a liquid mixture. We surveyed 65 students in the chemistry program of the College of Education about the boiling point of a 50%(by mole) ethanol aqueous solution and the temperature changes during heating. We then interviewed 9 of these students. According to the survey results, the percent of the pre-service teachers who thought that the boiling point of the ethanol solution would be ‘between the boiling points of ethanol and water (78-100 ℃)’ and ‘the same as that of ethanol’ were 52.3% and 35.4%, respectively. The majority of those who stated the former explained that the boiling point of the ethanol solution increased due to the effects of attraction or blocking by water molecules. Most of those who believed the latter explained that physical properties such as the boiling point would not be changed by the addition of water. With regard to the temperature change during heating, 69.2% of the teachers thought that the temperature would increase gradually while boiling, which some thought resulted from the increasing amount of water in the solution as the ethanol boiled off. Others thought that two temperature plateaus would be observed as each component of the liquid mixture underwent phase transition at its specific boiling point. When asked about the particle model of the gas phase during the boiling and evaporation process, some students drew both ethanol and water during evaporation but only ethanol when boiling. We discussed several alternative concepts of pre-service chemistry teachers about the boiling process of liquid mixtures and ways to improve their understanding.

The Analysis and Design of Advanced Neurofuzzy Polynomial Networks (고급 뉴로퍼지 다항식 네트워크의 해석과 설계)

  • Park, Byeong-Jun;O, Seong-Gwon
    • Journal of the Institute of Electronics Engineers of Korea CI
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    • v.39 no.3
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    • pp.18-31
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    • 2002
  • In this study, we introduce a concept of advanced neurofuzzy polynomial networks(ANFPN), a hybrid modeling architecture combining neurofuzzy networks(NFN) and polynomial neural networks(PNN). These networks are highly nonlinear rule-based models. The development of the ANFPN dwells on the technologies of Computational Intelligence(Cl), namely fuzzy sets, neural networks and genetic algorithms. NFN contributes to the formation of the premise part of the rule-based structure of the ANFPN. The consequence part of the ANFPN is designed using PNN. At the premise part of the ANFPN, NFN uses both the simplified fuzzy inference and error back-propagation learning rule. The parameters of the membership functions, learning rates and momentum coefficients are adjusted with the use of genetic optimization. As the consequence structure of ANFPN, PNN is a flexible network architecture whose structure(topology) is developed through learning. In particular, the number of layers and nodes of the PNN are not fixed in advance but is generated in a dynamic way. In this study, we introduce two kinds of ANFPN architectures, namely the basic and the modified one. Here the basic and the modified architecture depend on the number of input variables and the order of polynomial in each layer of PNN structure. Owing to the specific features of two combined architectures, it is possible to consider the nonlinear characteristics of process system and to obtain the better output performance with superb predictive ability. The availability and feasibility of the ANFPN are discussed and illustrated with the aid of two representative numerical examples. The results show that the proposed ANFPN can produce the model with higher accuracy and predictive ability than any other method presented previously.

Optimization Techniques for the Inverse Analysis of Service Boundary Conditions in a Porous Catalyst Substrate with Fluid-Structure Interaction Problems (유체 구조 상호작용 문제를 가진 다공성 촉매 담체에서 실동경계조건의 역문제 해석을 위한 최적화 기법)

  • Baek, Seok-Heum;Cho, Seok-Swoo;Kim, Hyun-Su
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.10
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    • pp.1161-1170
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    • 2011
  • This paper presents a solution to the inverse problem for the service boundary conditions of thermal-flow and structure analysis in a catalyst substrate. The exhaust-gas purification efficiency of a catalyst substrate is influenced by the shape parameter, catalyst ingredients and so on and is estimated by the thermal flow uniformity. The formulations of the inverse problem of obtaining the thermal-flow parameters (inlet temperature, velocity, heat of reaction, convective heat-transfer coefficient) and the direct problem of estimating from a given outlet temperature distribution are described. An experiment was designed and the response-surface optimization technique was used to solve the proposed inverse problem. The temperature distribution of the catalyst substrate was obtained by thermal-flow analysis for the predicted thermal-flow parameters. The thermal stress and durability assessments for the catalyst substrate were performed on the basis of this temperature distribution. The efficiency and accuracy of the inverse approach have been demonstrated through the achievement of good agreement between the thermal-flow response surface model and the results of experimental vehicle tests.

Analysis of the thermal fluid flow between the gas torch and the steel plate for the application of the line heating (선상 가열을 위한 가스 토치와 강판 사이의 열유동 해석)

  • Jong-Hun Woo;Jong-Gye Shin
    • Journal of the Society of Naval Architects of Korea
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    • v.39 no.2
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    • pp.52-60
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    • 2002
  • Line heating is a forming process which makes the curved surface with the residual strain created by applying heat source of high temperature to steel plate. in order to control the residual strain, it is necessary to understand not only conductive heat transfer between heat source and steel plate, but also temperature distribution of steel plate. In this paper we attempted to analyze is temperature distribution of steel plate by simplifying a line heating process to collision-effusive flux of high temperature and high velocity, and conductive heat transfer phenomenon. To analyze this, combustion in the torch is simplified to collision effusive phenomenon before analyzing turbulent heat flux. The distribution of temperature field between the torch and steel plate is computed through turbulent heat flux analysis, and the convective heat transfer coefficient between effusive flux and steel plate is calculated using approximate empirical Nusselt formula. The velocity of heat flux into steel plate is computed using the temperature distribution and convective heat transfer coefficient, and temperature field in the steel plate is obtained through conductive heat transfer analysis in which the traction is induced by velocity of heat flux. In this study, Finite Element Method is used to accomplish turbulent heat flux analysis and conductive heat transfer analysis. FEA results are compared with empirical data to verify results.

Influence and Application of an External Variable Magnetic Field on the Aqueous HCl Solution Behavior: Experimental Study and Modelling Using the Taguchi Method (염산 수용액 거동에 대한 가변 외부 자기장의 적용과 영향: 실험 연구 및 Taguchi 법을 이용한 모델링)

  • Hashemizadeh, Abbas;Ameri, Mohammad Javad;Aminshahidy, Babak;Gholizadeh, Mostafa
    • Applied Chemistry for Engineering
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    • v.29 no.2
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    • pp.215-224
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    • 2018
  • Influences of the magnetic field on 5, 10 and 15 wt% (1.5, 3 and 4.5 M) HCl solution behaviour, which has widespread applications in petroleum well acidizing, were investigated in various conditions. Differences in the pH of magnetized hydrochloric acid compared to that of normal hydrochloric acid were measured. Taguchi design of experimental (DoE) method were used to model effects of the magnetic field intensity, concentration, velocity and temperature of acid in addition to the elapsed time. The experimental results showed that the magnetic field decreases [$H^+$] concentration of hydrochloric acid up to 42% after magnetization. Increasing the magnetic field intensity (with 28% contribution), concentration (with 42% contribution), and velocity of acid increases the effect of magnetic treatment. The results also demonstrated that the acid magnetization was-not influenced by the fluid velocity and heating. It was also displayed that the acid preserves its magnetic memory during time. The optimum combination of factors with respect to the highest change of [$H^+$] concentration was obtained as an acid concentration of 10% and an applied magnetic field of 4,300 Gauss. Due to the reduction of HCl reaction rate under the magnetization process, it can be proposed that the magnetized HCl is a cost effective and reliable alternative retarder in the matrix acidizing of hydrocarbon (crude oil and natural gas) wells.

Analysis of the Effect of Carbon Dioxide Reduction by Changing from Signalized Intersection to Roundabout using Tier 3 Method (Tier 3 방법을 이용한 회전교차로 도입에 따른 $CO_2$ 감축효과)

  • Lee, Jung-Beom;Lee, Seung-Hoon
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.10 no.5
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    • pp.105-112
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    • 2011
  • Delay reduction of vehicles at the intersection is highly dependent on the signal operation method. Improper traffic operation causes the violation of the traffic regulations and increasing traffic congestion. Delay because of congestion has contributed to the increase in carbon dioxide in the atmosphere. The focus of this paper is to measure the amount of carbon dioxide when the intersection is changed to roundabout. Even though, Intergovernmental Panel on Climate Change(IPCC) recommends Tier 1 method to measure the amount of greenhouse gas from vehicles, this paper used Tier 3 method because we could use the data of average running distance per each vehicle model. Two signalized intersections were selected as the study area and the delay reductions of roundabout operation were estimated by VISSIM microscopic simulation tool. The control delay for boksu intersection reduced from 28.6 seconds to 4.4 seconds and the KRIBB intersection sharply reduced from 156.4 seconds to 23.6 seconds. In addition, carbon dioxide for two intersections reduced to 646.5 ton/year if the intersection is changed to roundabout. Future research tasks include testing the experiment for networks, as well as for various intersection types.

Current and Future Changes in the Type of Wintertime Precipitation in South Korea (현재와 미래 우리나라 겨울철 강수형태 변화)

  • Choi, Gwang-Yong;Kwon, Won-Tae
    • Journal of the Korean Geographical Society
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    • v.43 no.1
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    • pp.1-19
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    • 2008
  • This study intends to clarify the characteristics and causes of current changes in wintertime precipitation in Korea and to predict the future directions based on surface observational $(1973/04\sim2006/07)$ and modeled (GFDL 2.1) climate data. Analyses of surface observation data demonstrate that without changes in the total amount of precipitation, snowfall in winter (November-April) has reduced by 4.3cm/decade over the $1973\sim2007$ period. Moreover, the frequency and intensity of snowfall have decreased; the duration of snow season has shortened; and the snow-to-rain day ratio (STDR) has decreased. These patterns indicate that the type of wintertime precipitation has changed from snow to rain in recent decades. The snow-to-rain change in winter is associated with the increases of air temperature (AT) over South Korea. Analyses of synoptic charts reveal that the warming pattern is associated with the formation of a positive pressure anomaly core over northeast Asia by a hemispheric positive winter Arctic Oscillation (AO) mode. Moreover, the differentiated warming of AT versus sea surface temperature (SST) under the high pressure anomaly core reduces the air-sea temperature gradient, and subsequently it increases the atmospheric stability above oceans, which is associated with less formation of snow cloud. Comparisons of modeled data between torrent $(1981\sim2000)$ and future $(2081\sim2100)$ periods suggest that the intensified warming with larger anthropogenic greenhouse gas emission in the $21^{st}$ century will amplify the magnitude of these changes. More reduction of snow impossible days as well as more abbreviation of snow seasons is predicted in the $21^{st}$ century.

Infiltration behavior and face stability of carbonate-added slurry shield tunnel (탄산을 첨가한 슬러리 쉴드 터널에서의 침투 거동 및 굴진면 안정성 평가)

  • Lee, Ik-Bum;Choi, Ki-Hoon;Lee, In-Mo
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.15 no.4
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    • pp.401-413
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    • 2013
  • Slurry shield tunnelling ensures stability by pressurizing the tunnel face with the slurry contained in the chamber. It resists water and earth pressure in order to prevent the failure in the tunnel face during tunnel excavation. If the ground is relatively coarse, slurry can not clog the tunnel face and excessive slurry infiltration will occur. In this case chemical compounds or additives should be added to the slurry in order to improve the clogging phenomena at the tunnel face. In this study, the effect of the carbon dioxide gas as an additive to the slurry instead of chemical compounds on the capability of enhancing the clogging in the tunnel face is investigated. Bubbles arising from the carbonate-added slurry are trapped in the soil voids enhancing the clogging capability. This effect is studied in this paper by performing laboratory model tests simulating in-situ conditions, and by adopting the fine particle clogging theory. Tunnel face stability analysis was also performed and it was found that the effective size ($D_{10}$) of soils which can guarantee tunnel stability utilizing the carbonate-added slurry increased from 1.0 mm up to 2.6 mm. Moreover, Stability analysis showed that the tunnel face is stable if the ${\lambda}$(deposition coefficient) value is greater than $0.007sec^{-1}$.

Extraction of the Tree Regions in Forest Areas Using LIDAR Data and Ortho-image (라이다 자료와 정사영상을 이용한 산림지역의 수목영역추출)

  • Kim, Eui Myoung
    • Journal of Korean Society for Geospatial Information Science
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    • v.21 no.2
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    • pp.27-34
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    • 2013
  • Due to the increased interest in global warming, interest in forest resources aimed towards reducing greenhouse gases have subsequently increased. Thus far, data related to forest resources have been obtained, through the employment of aerial photographs or satellite images, by means of plotting. However, the use of imaging data is disadvantageous; merely, due to the fact that recorded measurements such as the height of trees, in dense forest areas, lack accuracy. Within such context, the authors of this study have presented a method of data processing in which an individual tree is isolated within forested areas through the use of LIDAR data and ortho-images. Such isolation resulted in the provision of more efficient and accurate data in regards to the height of trees. As for the data processing of LIDAR, the authors have generated a normalized digital surface model to extract tree points via local maxima filtering, and have additionally, with motives to extract forest areas, applied object oriented image classifications to the processing of data using ortho-images. The final tree point was then given a figure derived from the combination of LIDAR and ortho-images results. Based from an experiment conducted in the Yongin area, the authors have analyzed the merits and demerits of methods that either employ LIDAR data or ortho-images and have thereby obtained information of individual trees within forested areas by combining the two data; thus verifying the efficiency of the above presented method.

A Review of U.S. Renewable Energy Expansion and Support Policies (미국의 재생 에너지 확대 및 지원정책 연구)

  • Kim, Chu
    • Land and Housing Review
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    • v.9 no.2
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    • pp.41-50
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    • 2018
  • The purpose of this study is to review the U.S. renewable energy policies implemented by the federal government and the state governments to investigate potential barriers of renewable energy expansion and to develop policy implications for the successful renewable energy policy making in Korea. Recently, the restructuring in the energy supply chain has been being a new trend in many countries that shows a transition from traditional fossil fuels to sustainable renewable energy sources. The United States has enforced effective renewable energy policies (i.e., regulatory policies, financial incentives), which have led to the exploding growth of renewable energy facilities and productions over the last ten years. For example, many state governments in the U.S. are implementing Renewable Portfolio Standard (RPS) policies that require increased energy supply from renewable energy sources (i.e., solar, wind and geothermal). These RPS policies are expected to account for at least 10-50 percent of total electricity production in the next fifteen years. As part of results, in the recent three years, renewable energy in the U.S provided over 50 percent of total new power generation constructions. On the other hand, Korea initiated to develop climate change policies in 2008 for the Green Growth Policy that set up a target reduction of national Greenhouse Gas (GHG) emissions up to 37 percent by 2025. However, statistical data for accumulated renewable energy capacity refer that Korea is still in its early stage that contribute to only 7 percent of the total electricity production capacity and of which hydroelectric power occupied most of the production. Thus, new administration in Korea announced a new renewable energy policy (Renewable Energy 3020 Plan) in 2017 that will require over 95 percent of the total new generations as renewable energy facilities to achieve up to 20 percent of the total electricity production from renewable energy sources by 2030. However, to date, there have not been enough studies to figure out the barriers of the current policy environment and to develop implications about renewable energy policies to support the government plan in Korea. Therefore, this study reviewed the U.S. renewable energy policies compared with Korean policies that could show model cases to introduce related policies and to develop improved incentives to rapidly spread out renewable energy facilities in Korea.