• Title/Summary/Keyword: MnO addition

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Dielectric and Piezoelectric Properties of 0.95(K0.5Na0.5)NbO3-0.05Li(Sb0.8Nb0.2)O3 Ceramics according to the Amount of CuO Addition (CuO첨가에 따른 0.95(K0.5Na0.5)NbO3-0.05Li(Sb0.8Nb0.2)O3 세라믹스의 유전 및 압전특성)

  • Lee, Yu-Hyung;Kim, Do-Hyung;Yoo, Ju-Hyun;Kim, In-Sung;Song, Jae-Sung;Hong, Jae-Il
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.6
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    • pp.489-494
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    • 2009
  • In this study, In order to improve dielectric and piezoelectric properties of Lead-free piezoelectric ceramics, $0.95(K_{0.5}Na_{0.5})NbO_3-0.05Li(Sb_{0.8}Nb_{0.2})O_3+0.2\;wt%Ag_2O+0.4\;wt%MnO_2+Xwt%CuO$ were investigated as a function of the amount of CuO addition. With increasing the amount of CuO addition, density was increased up to 0.4 wt.% CuO and then decreased above. And also, electro mechanical coupling factor ($k_p$) was decreased. At the 0.4 wt% CuO added specimen sintered at $1020^{\circ}C$, $k_p$, Qm, density, dielectric constant (${\varepsilon}_r$) and $d_{33}$[pC/N] showed the optimal value of $4.37\;g/cm^3$, 0.354, 305, 645, and 144 pC/N respectively.

Effect of Thermal Aging in PMN-PZT Ceramics (PMN-PZT 세라믹스에 있어서 열에이징 효과)

  • 이개명;박창엽
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.05a
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    • pp.17-21
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    • 1995
  • Tw types of Pb(Mn$\sub$1/3/Nb$\sub$2/3/)O$_3$+PZT Ceramics had been fabricated by hot-pressing method. One had cause grain and the other had fine grain doe to Cr$_2$O$_3$ addition. These specimen were poled by applying the DC electric field in various steps. The effects of thermal aging on their piezoelectric characteristics and temperature stability of the frequency were investigated.

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Study on Dielectric Characteristics of Pb($Zn_{1/3}Nb_{2/3}$)$O_3$-$PbTiO_3$-$PbZrO_3$Ceramics) (Pb($Zn_{1/3}Nb_{2/3}$)$O_3$-$PbTiO_3$-$PbZrO_3$계 세라믹의 유전특성에 관한 연구)

  • 최창문;박정철;소대화
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.11a
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    • pp.13-16
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    • 1994
  • In this paper, xPb(Zn$_{1/3}Nb_{2/3}$)$O_3$-yPbTiO$_3$-zPbZrO$_3$-(0.5wt%)MnO$_2$ ceramics were fabricated by the mixed oxide method sintered at $1250^{\circ}C$ for 2[hr] and then the deielectric, electromechanical coupling factor($K_{p}$ and mechanical coupling factor(Qm) properties were investigated. In 0.1PZN-0.45PT-0.45PZsample, dielectric properties and electromechanical coupling factor were 829 and 29%. In the case of 0.5PZN-0.45PT-0.50PZ sample, that was 101 according to mechanical quality facotr. molphotropic phase boundary(MPB) certained area which $PbTiO_3$addition quatity 40∼50[㏖%].

A Study on the Swine Wastewater Treatment Using UV/TiO2/H2O2 (UV/TiO2/H2O2를 이용한 축산폐수처리에 대한 연구)

  • Kim, Chang-Kyun;Chung, Ho-Jin
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.3B
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    • pp.321-327
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    • 2006
  • This study was performed to provide basic information for evaluating the efficiency and applicable extent of photocatalysis for the treatment of swine wastewater. Acid area was more efficient than neutral and alkalic areas in wastewater treatment, and level of pH3 was the most effective and the treatment efficiency continually increased as the amount of photocatalyst was increased. When the photocatalyst was increased, $TCOD_{Mn}$ was removed faster than chromaticity. Pollutants were more effectively eliminated with both UV light illumination and $TiO_2$ than with either UV or $TiO_2$ alone. The removal efficiency was increased with the addition of $H_2O_2$ as an oxidant, but the removal efficiency was decreased with over an dosage of $H_2O_2$. The optimal dosage of $H_2O_2$ was 200 mg/L. Continuous injection of $H_2O_2$ was required for effective oxidation.

The Non-Linear Characteristics of ZnO Devices. (ZnO 소자의 비직선 특성)

  • Hong, Kyung-Jin;Chon, Kyung-Nam;Cho, Jae-Cheol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05a
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    • pp.43-46
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    • 2001
  • The ZnO devices using semiconductor properties, to include $MnO_2$, $Y_2O_3$ and other material, was fabricated by $Sb_2O_3$ mol ratio from 1 to 4 [mol%]. The non-linearity factor was calculated by setting current to be $1[mA/cm^2]$ and $10[mA/cm^2]$. The spinel structure was fonned by $Sb_2O_3$ addition and it was depressed the ZnO grain formation. The grain growing was controlled by spinel structure that has improved the non-linearity factors. The breakdown voltage characteristics of semiconductor devices to increase with $Sb_2O_3$ was increased in voltage-current. The non-linearity value of ZnO semiconductor devices was 45 over.

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Characteristic Analysis of Chemical Compositions for Ancient Glasses Excavated from the Sarira Hole of Mireuksaji Stone Pagoda, Iksan (익산 미륵사지 석탑 사리공 내 출토 고대 유리 유물의 성분특성 분석)

  • Han, Min Su
    • Journal of Conservation Science
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    • v.33 no.3
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    • pp.215-223
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    • 2017
  • The purpose of this study is to reveal the characteristics, correlations, and colorant materials of those using the chemical compositions of 30 glasses excavated from the Sarari hall of the Mireuksaji stone pagoda, and to determine the correlations between them and other glass excavated from the Wanggungri site. The results of the chemical analysis of the 11 glass beads show that they are a soda glass group with high contents of $SiO_2$ and $Na_2O$; these can be further subdivided into soda-alumina groups ($Na_2O-Al_2O_3-CaO-Si_2O$). The characteristics of the stabilizer are classified as being of the high alumina glass group (LCHA), except for two glasses. It was concluded that colorant materials affected the coloring for glass beads by various components including Ti, Mn, Fe, Cu and Pb. In addition, we examined six lead glasses which are glass plate and unknown fragments that are of a common lead glass system ($PbO-SiO_2$) with respect to the average contents of PbO (70wt.%) and $SiO_2$ (30wt.%). As a result of comparing these relics with those of the glass beads excavated by Wanggungri, there is a similarity in that they belong to the soda glass group. However, the contents of $Na_2O$ are relatively higher than that of the glass beads in the Mireuksaji pagoda, and most of relics include glasses with a low content of $K_2O$ and CaO. In addition, the PbO and $SiO_2$ contents are slightly different in the lead glass. It seems that the glass relics made at two different sites may have used different raw materials or techniques.

Low temperature sintering properties of the $Pb(Mg_{1/2}W_{1/2})O_3-Pb(Mn_{1/3}Nb_{2/3})O_3-Pb(Zi,Ti)O_3$ ceramics with the addition of sintering aids (소결조제 첨가에 따른 PMW-PMN-PZT 세라믹의 저온소결 특성)

  • Lee, Hyun-Seok;Yoo, Ju-Hyun;Lee, Chang-Bae;Jeong, Yeong-Ho;Paik, Dong-Su
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.350-351
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    • 2005
  • In this study, in order to develop the low temperature sintering multilayer piezoelectric transformer, PMW-PMN-PZT system ceramics were manufactured with the addition of sintering aids, and their dielectric and piezoelectric characteristics were investigated. At the composition ceramics sintered at $900^{\circ}C$, dielectric constant(${\varepsilon}r$), electromechanical coupling factor(kp) and mechanical quality factor(Qm) showed the optimal value of 1043, 0.44 and 793, respectively, for multilayer piezoelectric transformer application.

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Activity Comparison According to Prepared Method of Cu-Mn Oxide Catalyst for Toluene Combustion (톨루엔 분해를 위한 구리-망간 산화물 촉매의 제조방법에 따른 활성 비교)

  • Kim, Hye-Jin;Choi, Sung-Woo;Lee, Chang-Seop
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.3
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    • pp.249-256
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    • 2006
  • Catalytic combustion of toluene was investigated on the Cu-Mn oxide catalysts prepared by the impregnation(Imp) and the deposition-precipitation(DP) methods. The mixing of copper and manganese has been found to enhance the activity of catalysts. It is then found that catalytic efficiency of the Cu-Mn oxide catalyst prepared by the DP method on combustion of toluene is much higher than that of the Cu-Mn oxide catalyst prepared by Imp method with the same chemical composition. The catalyst prepared by the deposition-precipitation method observed no change of toluene conversion at time on stream during 10 days and at the addition of water vapor. On the basis of catalyst characterization data, it has been suggested that the catalysts prepared by the DP method showed uniform distribution and smaller particle size on the surface of catalyst and then enhanced reduction capability of catalysts. Therefore, we think that the DP method leads on progressive capacity of catalyst and promotes stability of catalyst. It was also presumed that catalytic conversion of toluene on the Cu-Mn oxide catalyst depends on redox reaction and $Cu_{1.5}Mn_{1.5}O_4$ spinel phase acts as the major active sites of catalyst.

A Study on the Microwave Dielectric Properties of A1$_2$O$_3$ Ceramics Resonator added with Impurities (불순물 첨가에 따른 A1$_2$O$_3$ 세라믹 공진기의 마이크로파 유전특성에 관한 연구)

  • 이문기;박인길;류기윈;이성갑;이영희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.64-67
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    • 1997
  • Microwave dielectric properties of A1$_2$O$_3$ ceramics resonator were investigated with impurity addition. Increasing the contents of Bi$_2$O$_3$Q-value and Q $\times$ f were increased. In the specimen with the content of Bi$_2$O$_3$(0.3wt%), dielectric constant, quality factor and temperature coefficient of resonant frequency(TCRF, $\tau$$_{f}$) had a good values of 10.76,23,253(at 9.68[GHz]) and -39.09(ppm/$^{\circ}C$), respectively. The TCRF value was decreased with MnO$_2$ and increased with Sm$_2$O$_3$. La$_2$O$_3$.>.

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Effect of Fabrication Processes on the Mechanical Properties of 0.14C-6.5Mn TRIP Steels (0.14C-6.5Mn TRIP강의 기계적 성질에 미치는 제조공정의 영향)

  • Lee, O-Yeon;Ryu, Seong-Il
    • Korean Journal of Materials Research
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    • v.11 no.5
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    • pp.431-437
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    • 2001
  • This research was examined the effect of intercritical heat treatment on the mechanical Properties and retained austenite formation in 0.1C-6.5Mn steels for the development of a high strength high ductility steel. using of transformation induced plasticity due to retained austenite. The stability of retained austenite is very important for the good ductility and it depend on diffusion of carbon and manganese during reverse transformation. It is effective to heat treat at$ 645^{\circ}C$ in order to obtain over 30 vol.% of retained austenite. However, it is more desirable to heat treat at $620^{\circ}C$, considering the volume fraction and mechanical stability of retained austenite. The strength-elongation combination in cold rolled steel sheets after reverse transformed at $620^{\circ}C$ for 1hr was about 4000k9/mm7, but it decreased rapidly with increasing holding time at high temperature due to the decrease of ductility. The addition of 1.1%Si in 0.14C-6.5Mn TRIP steel does not improve the mechanical properties and retained austenite formation.

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