• Title/Summary/Keyword: MnO 첨가

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An analysis of complex permeability of Mn-Zn ferrite doped with rare earth oxide (희토류가 첨가된 Mn-Zn ferrite의 복소투자율 분석)

  • 김성수;최우성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.93-96
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    • 2000
  • In this study, we investigated the electromagnetic properties of Mn-Zn ferrite doped with rare earth oxide (Dy$_2$O$_3$, Er$_2$O$_3$). The main composition is 52mo1% ${\alpha}$-Fe$_2$O$_3$, 25mol% Mn$_3$O$_4$ 23mo1% ZnO and doped with them(0.05wt% ∼ 0.25wt%, step:0.05wt%). An experimental process has advanced by conventional ferrimagnetism manufacturing that was prepared by standard ceramic techniques. The XRD pattern of all doped sample were observed spinel and secondary phase. The density of sample were measured nearly constant value. As increased the additive, resistivity, initial permeability and real component of the series complex permeability increased with setting limits each other. In case of Mn-Zn ferrite excess doped with them, resistivity, initial permeability and real component of the series complex permeability decreased and magnetic loss increased in proportion to increasing the additive.

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Electrical properties of lead free (Na,K,Li)(Nb,Sb,Ta)$O_3$ ceramics with $MnO_2$ addition ($MnO_2$ 첨가량에 따른 비납계 (Na,K,Li)(Nb,Sb,Ta)$O_3$ 세라믹스의 전기적특성)

  • Lee, Seung-Hwan;Nam, Sung-Pill;Lee, Sung-Gap;Shin, Dong-Jin;Lee, Young-Hie
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1487-1488
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    • 2011
  • Electrical properties and microstructure were investigated on the effects of $MnO_2$ and the lead-free $(Na_{0.44}K_{0.52}Li_{0.04})(Nb_{0.83}Sb_{0.07}Ta_{0.1})O_3$ ceramics with the addition of $MnO_2$ were fabricated by a conventional mixed oxide method. A gradual change in the crystal and microstructure was observed with the increase of $MnO_2$ addition. For the NKN-LST-xmol%$MnO_2$ sintered at $1100^{\circ}C$, bulk density increased with the addition of $MnO_2$ and showed maximum value at addition 1.0mol% of $MnO_2$. Curie temperature of the NKN-LST ceramics slightly decreased with adding $MnO_2$. The dielectric constant, piezoelectric constant ($d_{33}$) and electromechanical coupling factor ($k_p$) increased below 0.25mol% of $MnO_2$ addition, which might be due to the increase in density. The high piezoelectric properties = 145 pC/N, electromechanical coupling factor = 0.421 and dielectric constant = 2883 were obtained for the NKN-LST-0.25mol%$MnO_2$ sintered at $1100^{\circ}C$ for 4h.

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The Effect of $Y_2O_3$ Dispersoids on the High Temperature Oxidation of Ti-34wt%Al-1.5wt%Mn Alloys (Ti-34wt%Al-1.5wt%Mn 합금의 고온산화에 미치는 $Y_2O_3$ 분산입자 첨가효과)

  • Lee, Dong-Bok
    • Journal of Surface Science and Engineering
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    • v.39 no.6
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    • pp.288-294
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    • 2006
  • Alloys of TiAl-Mn-(0, 5, 10)wt.% $Y_2O_3$ were prepared by a powder metallurgical route, and their oxidation behavior was studied at 800, 900 and $1000^{\circ}C$ in 1 atm of air. The scale formed on the alloys consisted of $TiO_2$ and $Al_2O_3$ oxides. During oxidation, Mn tended to diffuse outward, whereas oxygen diffused inward. The dispersoids of $T_2O_3$, which segregated at the matrix grain boundaries, acted as a diffusion channel for cations and oxygen ions, nucleation sites for oxides, and vacancy annihilation sites. $T_2O_3$ increased the scale thickness, but improved the scale adherence.

Effect of Additives and Control of Sintering Atomsphere on Magnetic Properties of Mn-Zn Ferrite (첨가제 및 분위기 제어가 Mn-Zn Ferrite의 자기적 특성에 미치는 영향)

  • 이웅용;이대희;김창현;이병교
    • Journal of the Korean Ceramic Society
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    • v.35 no.8
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    • pp.836-842
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    • 1998
  • In this experiment well-know additives for Mn-Zn ferrites CaO and {{{{ { SiO}_{2 } }} were added at various content and their effects on microstructures and magnetic properties with sintering atmosphere were examined. By adding up to 0.04wt% {{{{ { SiO}_{2 } }} and and 0.06wt% CaO the sintered density was increased and then decreased gra-dually. Higher sintered density and initial permeability were observed by adding both CaO and {{{{ { SiO}_{2 } }} than by adding CaO or {{{{ { SiO}_{2 } }} alone. Without any additives initial permeability and tan$\delta$/${\mu}$ decreased at 1000kHz as oxidation degree(${\gamma}$) increased.

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Photoluminescence Properties of Novel $Mg_{2}SnO_{4}:Mn$ Phosphor (새로운 $Mg_{2}SnO_{4}:Mn$ 형광체의 광 발광 특성)

  • Kim, Kyung-Nam;Jung, Ha-Kyun;Park, Hee-Dong;Kim, Do-Jin
    • Journal of the Korean Ceramic Society
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    • v.38 no.9
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    • pp.817-821
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    • 2001
  • A new $Mg_{2-x}MN_xSnO_4$ phosphor with an inverse spinel structure was synthesized by the solid-state reaction technique. The photoluminescence properties of the $Mg_2SnO_4$:Mn phosphors were investigated under 147nm -vacuum ultraviolet ray excitation. The Mn-doped $Mg_2SnO_4$ phosphor exhibited high emission intensity with the spectrum centered at 500nm wavelength. It was explained that the green emission in $Mg_2SnO_4$:Mn phosphor has originated from energy transfer from $^4T_1$ to $^6A_1$ of $Mn^{2+}$ ion at tetrahedral site of the spinel structure. The $Mn^{2+}$ ion concentration exhibiting the maximum emission intensity under the excitation of 147nm-vacuum ultraviolet ray was 0.25mol%. And the decay time of the phosphor was shorter than 10ms.

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Impedance Properties of LSMC-YSZ Composite Cathode (LSMC-YSZ Composite 양극의 임피던스 특성)

  • 김재동;김구대;문지웅;김창은;이동아
    • Journal of the Korean Ceramic Society
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    • v.35 no.9
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    • pp.917-922
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    • 1998
  • The polarization characteristics of the cathodes were discussed which were composed YSZ and ${(La_{0.75 }Sr_{0.25 })}_{0.95}Mn_{0.8 }Co_{0.2}O_3$ The three-phase-boundary length increased with the addition of YSN resulting in the minimum po-larization resistance at 60(LSMC) : 40(YSZ) wt% When LSMC-YSZ compoiste cathodes was sintered at $1200^{\circ}C$ minimum polarization resistance was observed and the capacitace increased with increasing sintering tem-perature.

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