• Title/Summary/Keyword: Mixture formation

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A Study on the Spray Characteristics of Flash Boiling Using Two Component Mixing Fuel (2성분 혼합연료를 이용한 감압비등 분무특성에 관한 연구)

  • Myong, Kwang-Jae;Yoon, Jun-Kyu
    • Journal of Advanced Marine Engineering and Technology
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    • v.33 no.4
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    • pp.451-458
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    • 2009
  • This experimental study was conducted to investigate macroscopic characteristics of the flash boiling spray with tow component mixing fuel. Homogeneous Charge Compression Ignition (HCCI) is a newer combustion method for internal combustion engines to reduce nitrogen oxide and particulate matter simultaneously. But it is difficult to put this combustion method to practical use in an engine because of such problems as instability of combustion in low load operating conditions and knocking in high load operating conditions. In HCCI, combustion characteristics and exhaust emissions depend on conditions of air/fuel mixture and chemical reactions of fuel molecules. The fuel design approach is achieved by mixing two components which differ in properties such as density, viscosity, volatility, ignitability and so on. We plan to apply the fuel design approach to HCCI combustion generated in a real engine, and examine the possibility of mixture formation control using the flash boiling spray. Spray characteristics of two component fuel with a flash boiling phenomenon was investigated using Shlieren and Mie scattering photography. Test fuel was injected into a constant volume vessel at ambient conditions imitated injection timing BTDC of a real engine. As a result, it was found that a flash boiling phenomenon greatly changed spray structure, especially in the conditions of lower temperature and density. Therefore, availability of mixture formation control using flash boiling spray was suggested.

A Study of Hydroxyapatite Production from Waste Oyster Used Mechanochemical Treatment

  • Kim, Sun-Tae;Oh, Chi-Jung;Kim, Wan-Tae;Kim, Young-Sig;Kim, Myong-Jun
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.469-471
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    • 2001
  • Dry grinding of a mixture of CaCO$_3$ and Ca(H$_2$PO$_4$)$_2$.$H_2O$ was conducted using a planetary ball mill in order to investigate solid state reaction for a synthesis of hydroxyapatite(Ca$_{10}$(PO$_4$)$_{6}$(OH)$_2$, HAp) through mechanochemical treatment method. The raw materials, which are composed of waste oyster and calcium biphosphate Ca(H$_2$PO$_4$)$_2$.$H_2O$, were mixed and then treated mechanochemically. The synthesis of hydroxyapatite(Ca$_{10}$(PO$_4$)$_{6}$(OH)$_2$, HAp) from the mixture was almost completed by about 60 minute grinding. The formation of HAp monophase in the ground mixture was characterized through X-ray diffraction (XRD) analysis. Moreover, the formation of HAp monophase depending on the grinding time was improved by increasing the grinding time.ime.ime.

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Studies on the Detergency of Oily Soils (Part III) -Detergency of Liquid Oily Soils by the Formation of Liquid Crystal- (유성오염의 세척성에 관한 연구(제3보) -액수형성에 의한 액체유성오염의 세척성-)

  • 김영희;정두진
    • Journal of the Korean Society of Clothing and Textiles
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    • v.19 no.3
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    • pp.425-425
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    • 1995
  • The interaction and detergency between liquid oily soil and surfactant solution were studied by the mechanism of formation of liquid crestal(LC). Samples used were triolein as a triglyceride, oleic acid as a free fatty acid and sodium dodgily sulfate (SDS) as a surfactant. The results were as follows: In the phase diagram of SDS/oil/Water system, the area of liquid crystalline phase region were in the order of SDS/trillion/water< SDS/oleic acid/water< SDS/mixture of trillion and oleic acid/water. In the system of oleic acid alone or mixture of trillion and oleic acid contacted with SDS solution, the LC phase was formed right after or after some time with SDS concentration. But in a case of trillion alone, the LC phase was not formed although the concentration of the SDS solution was relatively high. The detergency of model oily soils were seldom changed with temperature, and the detergency of oleic acid was very high compared to that of the trillion. The detergency of mixed soil was improved with the increase of the ratio of oleic acid in the mixture.

Studies on the Detergency of Oily Soils (Part III) -Detergency of Liquid Oily Soils by the Formation of Liquid Crystal- (유성오염의 세척성에 관한 연구(제3보) -액수형성에 의한 액체유성오염의 세척성-)

  • 김영희;정두진
    • Journal of the Korean Society of Clothing and Textiles
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    • v.19 no.3
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    • pp.426-433
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    • 1995
  • The interaction and detergency between liquid oily soil and surfactant solution were studied by the mechanism of formation of liquid crestal(LC). Samples used were triolein as a triglyceride, oleic acid as a free fatty acid and sodium dodgily sulfate (SDS) as a surfactant. The results were as follows: In the phase diagram of SDS/oil/Water system, the area of liquid crystalline phase region were in the order of SDS/trillion/water< SDS/oleic acid/water< SDS/mixture of trillion and oleic acid/water. In the system of oleic acid alone or mixture of trillion and oleic acid contacted with SDS solution, the LC phase was formed right after or after some time with SDS concentration. But in a case of trillion alone, the LC phase was not formed although the concentration of the SDS solution was relatively high. The detergency of model oily soils were seldom changed with temperature, and the detergency of oleic acid was very high compared to that of the trillion. The detergency of mixed soil was improved with the increase of the ratio of oleic acid in the mixture.

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Oxidative Stress in C100 Cells Induced by Combined Treatmentof Benzo(a)pyrene and/or 2,3,7,8-Tetrachlorodibenzo-p-dioxin(TCDD)

  • Bae, Mi-Ok;Choi, Kyung-Ho;Lee, Hu-Jang;Kim, Hyun-Woo;Kim, Jun-Sung;Hwang, Soon-Kyung;Park, Jin-Hong;Cho, Hyun-Sun;Cho, Myung-Haing
    • Korean Journal of Veterinary Research
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    • v.44 no.3
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    • pp.379-387
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    • 2004
  • When an organism is exposed to various toxicants chronically, reactive oxygen species(ROS) are accumulated and eventually result in several biological effects from gene expression to cell death. In the present study we investigated the oxidative damage of 2, 3, 7, 8-tetrachlorodibenzo-p-dioxin(TCDD) and/or benzo(a)pyrene (B(a)P) in C100 cells. C100 cells treated with TCDD(30 nM) and B(a)P($3{\mu}M$) underwent diverse oxidative stress as determined through thiobarbituric acid-reactive substances(TBARS) formation, DNA fragmentation, DNA single strand break(SSB) assay, immunohistochemical staining of 8-hydroxy-2'-deoxyguanosine(8-OHdG), and mRNA expressions of antioxidant enzymatic genes such as Cu/Zn-SOD gene, GPx(glutathione peroxidase 5) gene, and catalase gene. Lipid peroxidation in C100 cells was determined through measuing the formation of TBARS. For theat, the cells were pretreated with TCDD(30 nM) and/or B(a)P($3{\mu}M$) for 0.5, 1, 2 and 4 days. TBARS formation was increased in TCDD(30 nM) and B(a)P($3{\mu}M$) and mixture($30nM\;TCDD+3{\mu}M\;B(a)P$) and positive control treatment groups comparing to the controls. Mixture treatment induced more DNA fragmentation than the single treatment group at day 6. Also, SSB in all treatment groups was clearly observed when compared with the negative control group. As with the expression of antioxidant enzyme, GPx 5mRNA, B(a)P alone and mixture($30nM\;TCDD+3{\mu}M\;B(a)P$) treatment were higher comparing to those of the negative control and TCDD treatment groups. Our results suggest that exposure of C100 cells to mixture of TCDD and B(a)P leads to significant oxidative damage comparing to the exposures to the individual chemicals. Mechanisms of action are discussed. Additional studies are needed to elucidate the detailed mechanism of mixture-induced toxicity.

The Study on Two-color PIV Algorithm for a Measurement of Droplet Velocity (액적의 속도 측정을 위한 이색 PIV 알고리즘 연구)

  • Lee, K.H.;Lee, C.S.;Oh, S.I.
    • Journal of ILASS-Korea
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    • v.4 no.1
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    • pp.13-18
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    • 1999
  • It has been known that spray characteristics have an important effect on the mixture formation and directly influence the engine performances and the emissions. Up to now, the measurement of droplet size is well developed such as PDPA and PMAS though the behavior of small droplets during secondary atomization is not clear. Particle image velocimetry(PIV), a planar measuring technique, is a very efficient tool for studying complicated behavior and a fast and reliable method to track numerous droplets during injection. In this study, two-color scanning PIV is designed to obtain quasi-instantaneous two dimensional velocity data by using he-ion laser, rotating mirror and beam splitter. This PIV method which has high temporal and spatial resolution provides the information about the small complex droplet behavior.

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A Study of Abnormal Expansion to be Synthesized Barium Titanate in Solid-solid Reaction (Barium Titanate를 고상반응으로 합성할때 일어나는 이상팽창에 관한 연구)

  • 이은상;임대영
    • Journal of the Korean Ceramic Society
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    • v.22 no.6
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    • pp.9-14
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    • 1985
  • When the barium titanate is Synthesized in Solid-solid reaction the abnormal expansion occurs at about 110$0^{\circ}C$. The mixture was made of corresponding to the theoretical composition of barium titanate. The mixture was fired at various temperature from 90$0^{\circ}C$ to 130$0^{\circ}C$, After that the specimen was tested closely with XDR dilatometer and SEM. The results indicate that 1, The activation energy of barium titanate formation was 42 Kcal/mole. 2, Thermal expansion up to to 90$0^{\circ}C$ was mainly caused by $CO_2$ whereas it was mainly caused by the formation of the secondary phase above 100$0^{\circ}C$. 3. Thermal expansion was not influenced by the forming pressure up to 1000kg/$cm^2$ but it was largely influenced bythe forming pressure above 200kg/$cm^2$.

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Synthesis and Characteristics of W-l5wt%Cu Nanocomposite Powder by Oxide Reduction (산화물환원에 의한 W-15wt%Cu 나노복합분말의 합성과 특성)

  • 윤의식
    • Journal of Powder Materials
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    • v.4 no.4
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    • pp.304-309
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    • 1997
  • The synthesis of W-l5wt%Cu nanocomposite powder by hydrogen reduction of ball milled W-Cu oxide mixture was investigated in terms of powder characteristics such as particle size, mixing homogeneity and micropore structure. It is found that the micropores in the ball milled oxide (2-50 nm in size) act as an effective removal path of water vapor, followed by the formation of dry atmosphere at reaction zone. Such thermodynamic condition enhances the nucleation of W phase but suppresses the growth process, being in favor of the formation of W nanoparticles (about 21 nm in size). In addition, the superior mixing homogeneity of starting oxide mixture turned out to Play a significant role for forming extraordinary chemical homogeneity of W-l5wt%Cu nanocomposite powder.

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The Flame Characteristics by Combustion Chamber Shape in 2 Stroke D.I. Diesel Engine -The Influence of Scavenging Pressure and Scavenging Temperature- (직접분사식 2행정 디젤기관의 연소실 형상에 따른 화염 특성 -소기압력 및 소기온도의 영향을 중심으로-)

  • 최익수;방중철
    • Transactions of the Korean Society of Automotive Engineers
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    • v.11 no.1
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    • pp.55-63
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    • 2003
  • In a diesel engine, air-fuel mixture formation and ignition delay period have great influence on the performance of engine. Their main factors are combustion chamber shape, fuel injection system. air volume, air flow and so on. So, the combustion process in the cylinder is complex because of many factors which have direct and indirect effects on it. In this study, we take into consideration of scavenging pressure and scavenging temperature that are hewn as the main factor to the combustion process of two-stroke D.1. diesel engine. It is taken a picture of the combustion flame process for combustion chamber of re-entrant type and cylindrical type. So, it is applied to the basis data of combustion chamber design from an image analysis.

Th-determination in Rare Earth(1) studies on the Hydrogen Peroxide Method of Th-determination (稀土類中 토리움의 分離定量 에 관하여 (第一報) 過酸化水素法에 對한 檢討)

  • Choi, Han-Suk;Park Soon Za
    • Journal of the Korean Chemical Society
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    • v.4 no.1
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    • pp.10-12
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    • 1957
  • On the performance of the hydrogen peroxide method for Th-determination we encountered some difficulties, namely the formation of the insoluble matter occured in the nearly neutral solution after evaporation. We carried out the Th-determination in the mixture of the Th and some kind of the rare earth, and found that the insoluble matter was not formed in case of the mixture of Th and some kind of rare earth, but formed in case of Monazite. The formation of the insoluble matter in the case of Monazite sand, however, could be avoid by using the beaker instead of the evaporating dish and by adding the water repeatedly before it was completely evaporated to dryness.

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