• Title/Summary/Keyword: Mixture Gases

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Evaluation of ammonia emission reducing effect by adding waste cooking oil in pilot-scale composting of dairy cattle manure

  • Kazutaka Kuroda;Akihiro Tanaka;Kenichi Furuhashi;Naoki Fukuju
    • Animal Bioscience
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    • v.36 no.10
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    • pp.1612-1618
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    • 2023
  • Objective: In our previous study, we observed that the addition of waste cooking oil (WCO) reduced ammonia (NH3) emissions during laboratory-scale composting of dairy cattle manure under low-aeration condition. Therefore, this study aimed to evaluate the effect of addition of WCO on NH3 emissions reduction during pilot-scale composting of dairy cattle manure, which is close to the conditions of practical composting treatment. Methods: Composting tests were conducted using pilot-scale composting facilities (1.8 m3 of capacity). The composting mixtures were prepared from manure, sawdust, and WCO. Two treatments were set: without WCO (Control) and with WCO added to 3 wt% of manure (WCO3). Composting was conducted under continuous aeration at 40 L/min, corresponding to 22.2 L/(min·m3) of the mixture at the start of composting. The changes in temperatures, NH3 concentrations in the exhaust gases, and contents of the composted mixtures were analyzed. Based on these analysis results, the effect of WCO addition on NH3 emissions and nitrogen loss during composting was evaluated. Results: During composting, the temperature increase of the composting mixture became higher, and the decreases of weight and water content of the mixture became larger in WCO3 than in Control. In the decrease of weight, and the residual weight and water content of the mixture, significant differences (p<0.05) were detected between the two treatments at the end of composting. The NH3 concentrations in the exhaust gases tended to be lower in WCO3 than in Control. Nitrogen loss was 21.5% lower in WCO3 than in Control. Conclusion: Reduction of NH3 emissions by the addition of WCO under low aeration condition was observed in pilot-scale composting, as well as in laboratory-scale composting. This result suggests that this method is effective in reducing NH3 emissions in practical-scale composting.

Influence of SF6/N2 Gas Mixture Ratios on the Lightning Streamer Propagation Characteristics of 22 kV MV Circuit Breaker

  • Gandhi, R.;Chandrasekar, S.;Nagarajan, C.
    • Journal of Electrical Engineering and Technology
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    • v.13 no.4
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    • pp.1663-1672
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    • 2018
  • In recent times, gas insulated medium voltage (MV) circuit breakers (CB) form a vital component in power system network, considering its advantages such as reduced size and safety margins. Gas insulation characteristics of circuit breakers are generally measured by lightning impulse (LI) test according to IEC standard 60060-1 as a factory routine test. Considering the environmental issues of $SF_6$ gas, many research works are being carried out towards the mixture of $SF_6$ gases for high voltage insulation applications. However, few reports are only available regarding the LI withstand and streamer propagation characteristics (at both positive and negative polarity of waveform) of $SF_6/N_2$ gas mixture insulated medium voltage circuit breakers. In this paper, positive and negative polarity LI tests are carried out on 22 kV medium voltage circuit breaker filled with $SF_6/N_2$ gas mixture at different gas pressures (1-5 bar) and at different gas mixture ratios. Important LI parameters such as breakdown voltage, streamer velocity, time to breakdown and acceleration voltage are evaluated with IEC standard LI ($1.2/50{\mu}s$) waveform. Weibull distribution analysis of LI breakdown voltage data is carried out and 50% probability breakdown voltage, scale parameter and shape parameter are evaluated. Results illustrate that the $25%SF_6+75%N_2$ gas filled insulation considerably enhances the LI withstand and breakdown strength of MV circuit breakers. LI breakdown voltage of circuit breaker under negative polarity shows higher value when compared with positive polarity. Results show that maintaining the gas pressure at 0.3 MPa (3 bar) with 10% $SF_6$ gas mixed with 90% $N_2$ will give optimum lighting impulse withstand performance of 22 kV MV circuit breaker.

Fabrication of Fluorinated Polymeric Membranes and Their Noble Gas Separation Properties (불소 표면 개질 고분자 분리막의 제조와 노블가스 분리특성)

  • Kim, Gi-Bum;Yoon, Kuk-Ro
    • Applied Chemistry for Engineering
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    • v.21 no.4
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    • pp.475-478
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    • 2010
  • Fluorinated polymeric membranes were prepared by direct surface modification of PDMS with fluorine gas ($50{\sim}2000\;{\mu}mol/mol$ in nitrogen). The formed fluorinated polymeric membranes were characterized by FT-IR spectroscopy, GC (Gas chromatography), atomic force microscopy, and scanning electron microscopy. Direct fluorination resulted in the change of permeability and selectivity of various gases (pure gases such as $CO_2$, $O_2$, $N_2$, $C_2H_4$, mixture of He, Ne, Kr, Xe) through PDMS membranes. Fluorination resulted in the maximum 50% increase of selectivity through PDMS membrane.

A Study of the Transient Characteristics of LRE Startup Using Several Starting Gases (다양한 구동가스를 사용한 액체로켓엔진의 시동특성 연구)

  • Moon, Yoon-Wan;Cho, Won-Kook;Seol, Woo-Seok
    • Aerospace Engineering and Technology
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    • v.7 no.2
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    • pp.170-175
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    • 2008
  • In this study, it was investigated that the characteristics of startup and compatibility using several type hot and cold gases. The characteristics of starting LRE by pyro starter was compared with that by a Helium spinner. The compatibility of pyro gas, a gaseous Helium, Hydrogen+Nitrogen mixture gas, and air was investigated by a simple 1D turbine analysis considered the properties of each gas and turbine efficiency. Most of them were compatible to start up the LRE however air was properly used only for low power mode of turbine.

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Analysis of Gases in Nuclear Fuel Rod by Quadrupole Mass Spectrometry (Quadrupole Mass Spectrometry를 이용한 핵연료봉내 기체분석)

  • Kim, Seung-Soo;Kang, Moon-Ja;Park, Soon-Dal;Park, Yong-Joon;Joe, Kih-Soo
    • Analytical Science and Technology
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    • v.12 no.2
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    • pp.94-98
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    • 1999
  • An analysis method of components and isotopic compositions of low pressure gases from nuclear fuel rod using quadrupole mass spectrometer was studied. The calibration curves of each gas in pure and mixtures of He, $N_2$, $O_2$, Ar, Kr and Xe were obtained as a function of pressure and concentration, respectively. Effect of molecular leak, located between sample chamber and analyser chamber, on the sensitivites was also studied. The results suggested that samples could be analysed accurately at the same analytical condition as that of synthetic gas mixture. The difference of sensitivities among isotopes of Kr and Xe was not observed in the range of measured pressure.

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Numerical Study for the Design of Biogas-fired Low Emission Cyclone Incinerator (바이오 가스 소각용 저공해 사이클론 소각기 개발을 위한 수치 해석적 연구)

  • 전영남;김시욱;백원석
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.5
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    • pp.401-410
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    • 2002
  • Concerns for energy conservation, environmental pollution, and the fact that organic wastes account for a major portion of our waste materials, have created the interest of biogas, which usually contains about 60 to 70 percent methane, 30 to 40 percent carbon dioxide, and other gases, including ammonia, hydrogen sulfide, mercaptans and other noxious gases. Cyclone combustors are used for homing a wide range of fuels such as low calorific value gas, waste water, sludge. coal, etc. The 3-dimensional swirling flow, combustion and emission in a tangential inlet cyclone incinerator under different inlet conditions are simulated using a standard k-s turbulence model and ESCRS (Extended Simple Chemically-Reacting System) model. The commercial code Phoenics Ver.3.4 was used for the present work. The main parameters considered in this work are inlet velocity and air to fuel ratio. The results showed that the change of operating conditions had an influence on the shape and size of recirculation zones, mixture fraction and axial velocity which are important factors for combustion efficiency and emission behavior. The application of this kind of computer program seams to be promising as a potential tool for the optimum design of a cyclone combustor with low emission.

Experiment on the Polish Condition of Needle Electrode on the Insulation Properties of Gas Mixtures (침전극 가공상태에 따른 혼합가스의 절연특성에 관한 실험)

  • Go, Yeon-Seong;Yeo, Dong-Goo;Seo, Ho-Joon;Lee, Dong-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.339-340
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    • 2006
  • AC spark discharge voltage of SF6/CO2and SF6/N2 containing various mixed rate in volume percent (1, 5 and 10%) of SF6 in non-uniform fields are investigated. The needle to plane electrode gap spacing was 5 and 10 mm, and the gas pressure was varied within the range of 0.1~0.7 MPa. We have observed a N-characteristic typical for the electronegative gases even in gas mixtures of 1% SF6 with CO2 and N2 as buffer gases. Especially, the materials of the needle electrode affect the insulation properties of the gas mixtures drastically. On the contrary to the case of needle electrodes made by mild steel or high carbon steel, the N-characteristics are hardly perceived in the case of stainless steel needle in this experiment.

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Study on the Characterization of the Methane Stream Reforming in the High Pressure Using Reforming Catalyst (개질촉매를 이용한 고압에서 메탄 수증기 개질 특성연구)

  • 조종훈;백일현
    • Journal of Energy Engineering
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    • v.12 no.2
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    • pp.145-153
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    • 2003
  • In order to develop the carbonation process as a core technology of zero emission coal power plant, study on characterization of methane steam reforming (MSR) which is main reaction of this process was carried out. The effects of gas hourly space velocity (GHSV), steam/carbon (S/C) ratio and pressure in the MSR using reforming catalyst were investigated. The equilibrium composition of the gases produced in the MSR were obtained below GHSV 7,000 hr$\^$-1/. The operating conditions of carbonation process using hybrid reaction (MSR+CO$_2$ adsorption using CaO) were 700∼800$^{\circ}C$ and S/C ratio of 2.5∼3. The equilibrium mixture of gases composed of 75∼78% H$_2$ and 8∼9% CO$_2$ at atmospheric pressure and 60∼78% H$_2$ and 9∼l1% CO$_2$ at 1∼30 atm respectively under above operating conditions.

Effect of plasma polymerized film on fouling of heat exchangers

  • Kim, Ki-Hwan;Park, Sung-Chang;doo-Jin choi;Jung, Hyung-Jin;Ha, Sam-Chul;Kim, Chul-Hwan;Koh, Seok-Keun
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.160-160
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    • 1999
  • To reduce the fouling of heat exchangers, the plasma polymerized films was coated on the heat exchangers, and an effect of plasma polymerized film on fouling of heat exchangers was investigated. Monomer and reactive gases were used as the precursors of plasma polymerization. Plasma polymerized films were deposited with process parameters of pressure, power, and ratio of gases. Plasma polymerized films could be served as functional layers of good wettability and high resistance to corrosion. Wettability of plasma polymerized film could be controlled by the ratio change gas mixture. Hydrophilicity of plasma polymerized films on heat exchanger in air conditioner can provide improvement in performance of heat exchanger which results from good water drainage, decrease of pressure drop. DC-plasma polymerized films improve resistance to corrosion whcih is related to deposit formation in heat exchangers. The difference in the build up of fouling deposits between bare substrate and plasma polymerized substrate was investigated by scanning electron microscopy (SEM). An effect of plasma polymerized film on fouling of heat exchangers was discussed in terms of surface properties such as wettability, surface chemical state.

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Friction and Wear of Nitrogen Incorporated Diamond-like Carbon Films Under a Vacuum

  • Yoon, Eui-Sung;Kong, Hosung;Lee, Kwang-Ryeol;Oh, Jae-Eung
    • Tribology and Lubricants
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    • v.11 no.5
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    • pp.59-65
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    • 1995
  • Tribological behaviors of nitrogen incorporated amorphous diamond-like carbon films were experimentally measured under a vacuum ($3 \times 10^{-5}$ Torr) using a ball (AISI 52100 steel)-on-disk wear-rig. Nitrogen incorporated DLC films were deposited by r.f. plasma assisted chemical vapor deposition method. Mixtures of benzene and ammonia or nitrogen gases were used as the reaction gases for the r.f. PACVD, and Si (100) wafer was used as the substrate. In the tribo-test, effects of DLC film thickness and normal load in friction were measured and discussed. Results showed that friction of nitrogen incorporated DLC films from a mixture gas of benzene and ammonia was lower than that of 100% benzene, specially in the measurement of minimum coefficient of friction. Differences in frictional characteristics of nitrogen incorporated DLC films were explained with the changes in chemical structures of the films. Result also showed that friction of DLC films increased with the sliding contact cycle, which remarkably accompanied with roll-shaped wear debris. Mechanisms and roles of the polymer-like wear debris were presented and discussed.