• Journal of the Korean Society of Food Science and Nutrition
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• v.3 no.1
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• pp.69-76
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• 1974

The method of amino acid sequence determination from the C-terminal amino acid is proposed and mass spectrometric identification of thiohydantoins described previously. In this paper was discussed the fragmentation of thiohydantoin-ring by deutero substitution and model tripeptide have been degraded through three stages each, with interpretable results. The conditions employed in this method are mild enough for biological materials. The main features of the method are the following. 1. Thiohydantoins were formed in a non-aqueous medium a mixture of acetic anhydride, acetic acid and ammonium thiocyanate. 2. Mass sepectra of thiohydantoins derived from 20 amino acids were obtained with a mass spectrometer, JEOL model JMS-06H. 3. Cleavage of peptidyl thiohydantoin was made with an acidic from of a cation-exchange resin. (Amberlite IR-120) 4. Separation of the cleaved thiohydantoin and the parent peptide less one amino acid moiety was made by chromatography on a Sephadex G-10 column. 5. The peptide fraction was concentrated by freezedrying. 6. Thiohydantoin derivative of carboxyl terminal amino acid residue was introduced with a direct inlet probe in methanol solution.

• Journal of Power System Engineering
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• v.13 no.5
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• pp.25-33
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• 2009

In the present study, the numerical investigation has been carried out to see the effects of water mist sprays on the fire suppression mechanism. The special-purposed program named as FDS was used to simulate the interaction of fire plume and water mists. This program solves the fire-driven flows using LES turbulence model, the mixture fraction combustion model, the finite volume method of radiation transport for a non-scattering gray gas, and conjugate heat transfer between wall and gas flow. The computational domain was composed of a rectangular space dimensioned as $L{\times}W{\times}H=4.0{\times}4.0{\times}2.5\;m^3$ with a mist-injecting nozzle installed 1.0 m high from the fire pool. In this paper, two types of nozzles were chosen to compare the performance of the fire suppression. Numerical results showed that the nozzle, type A, with more orifices having smaller diameters had poorer performance than the other one, type B because the flow injected through side holes deteriorated the primary flow. The fire-extinguishing time of type A was 2.6 times bigger than that of type B.

• Transactions of the Korean Society of Automotive Engineers
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• v.13 no.1
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• pp.68-75
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• 2005

By utilizing a semi-empirical soot model, the applicability of the laminar flamelet concept fur simulating the formation and oxidation of soot in the laminar diffusion flame has been studied. The source terms for two transport equations of the soot formation and oxidation are calculated in the mixture fraction/scalar dissipation rate space for laminar flamelets and stored in a library. In this study, emphasis is given to the interaction associated with radiation and soot formation. The radiative heat loss is obtained by solving the radiative transfer equation using the unstructured grid finite volume method with the WSGGM. The calculated temperatures and soot volume fractions agree relatively well with the experimental data and the previous numerical results of Kaplan et al. using the detailed chemistry.

• Geomechanics and Engineering
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• v.24 no.3
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• pp.267-280
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• 2021

The research presented in this paper deals with dynamic stability analysis of the graphene nanoplatelets (GPLs) reinforced composite spinning disk. The presented small-scaled structure is simulated as a disk covered by viscoelastic substrate which is two-parametric. The centrifugal and Coriolis impacts due to the spinning are taken into account. The stresses and strains would be obtained using the first-order-shear-deformable-theory (FSDT). For Poisson ratio, as well as various amounts of mass densities, the mixture rule is employed, while a modified Halpin-Tsai model is inserted for achieving the elasticity module. The structure's boundary conditions (BCs) are obtained employing GPLs reinforced composite (GPLRC) spinning disk's governing equations applying principle of Hamilton which is based on minimum energy and ultimately have been solved employing numerical approach called generalized-differential quadrature-method (GDQM). Spinning disk's dynamic properties with different boundary conditions (BCs) are explained due to the curves drawn by Matlab software. Also, the simply-supported boundary conditions is applied to edges 𝜃=𝜋/2, and 𝜃=3𝜋/2, while, cantilever, respectively, is analyzed in R=R_i, and R₀. The final results reveal that the GPLs' weight fraction, viscoelastic substrate, various GPLs' pattern, and rotational velocity have a dramatic influence on the amplitude, and vibration behavior of a GPLRC rotating cantilevered disk. As an applicable result in related industries, the spinning velocity impact on the frequency is more effective in the higher radius ratio's amounts.

• Geomechanics and Engineering
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• v.33 no.4
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• pp.381-391
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• 2023

The aim of this work is to analyze and predict the wave propagation behavior of the carbon nanotube reinforced composites (CNTRC) beams within the framework of various higher order shear deformation beam theory. Using the Euler-Lagrange principle, the wave equations for CNTRC beams are derived, where the determining factor is to make the determinant equal to zero. Based on the eigenvalue method, the relationship between wave number and circular frequency is obtained. Furthermore, the phase and group velocities during wave propagation are obtained as a function of wave number, and the material properties of CNTRC beams are estimated by the mixture rule. In this paper, various higher order shear beam theory including Euler beam theory, Timoshenko beam theory and other beam theories are mainly adopted to analyze the wave propagation problem of the CNTRC beams, and by this way, we conduct a comparative analysis to verify the correctness of this paper. The mathematical model provided in this paper is verified numerically by comparing it with some existing results. We further investigate the effects of different enhancement modes of CNTs, volume fraction of CNTs, spring factor and other aspects on the wave propagation behaviors of the CNTRC beams.

• Steel and Composite Structures
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• v.50 no.1
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• pp.63-75
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• 2024

In this paper, the modified couple stress theory (MCST) and first order shear deformation theory (FSDT) are employed to investigate the free vibration and bending analyses of a three-layered micro-shell sandwiched by piezoelectric layers subjected to an applied voltage and reinforced graphene nanoplatelets (GPLs) under external and internal pressure. The micro-shell is resting on an elastic foundation modeled as Pasternak model. The mixture's rule and Halpin-Tsai model are utilized to compute the effective mechanical properties. By applying Hamilton's principle, the motion equations and associated boundary conditions are derived. Static/ dynamic results are obtained using Navier's method. The results are validated with the previously published works. The numerical results are presented to study and discuss the influences of various parameters on the natural frequencies and deflection of the micro-shell, such as applied voltage, thickness of the piezoelectric layer to radius, length to radius ratio, volume fraction and various distribution pattern of the GPLs, thickness-to-length scale parameter, and foundation coefficients for the both external and internal pressure. The main novelty of this work is simultaneous effect of graphene nanoplatelets as reinforcement and piezoelectric layers on the bending and vibration characteristics of the sandwich micro shell.

• Journal of the Korea institute for structural maintenance and inspection
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• v.25 no.3
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• pp.40-47
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• 2021

This study investigates the influence of hooked-end steel fiber volume fraction and aspect ratio on the mechanical properties, such as compressive and flexural performance, of concrete with specified compressive strength of 30MPa. Three types of hooked-end steel fibers with aspect ratios of 64, 67 and 80 were selected. The flexural tests of steel fiber reinforced concrete (SFRC) prismatic specimens were conducted according to EN 14651. The compressive performance of SFRC with different volume fractions (0.25, 0.50 and 0.75%) were evaluated through standard compressive strength test method (KS F 2405). Experimental results indicated that the flexural strength, flexural toughness, fracture energy of concrete were improved as steel fiber volume fraction increases but there is no unique relationship between steel fiber volume fraction and compressive performance. The flexural and compressive properties of concrete incorporating hooked-end steel fiber with aspect ratio of 64 and 80 are a little better than those of SFRC with aspect ratio of 67. For each SFRC mixture used in the study, the residual flexural tensile strength ratio defined in Model Code 2010 was more than the limit value to be able to substitute rebar or welded mesh in structural members with the fiber reinforcement.

• Korean Chemical Engineering Research
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• v.46 no.4
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• pp.824-832
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• 2008

micellar solution which is comprised of surfactant monomers, monodisperse micelles, and solvent(water) is studied from a statistical-mechanical point of view. The model examined in this article is for the ideal mixture of monomers, micelles, and solvent with the dielectric constant identical to that of solvent, which is an assumption common to continuum models. The model also reflects interactions between monomer and solvent molecule, and also between micelle and solvent molecule. The statistical-mechanical model under consideration yields ln $X_{CMC}=A+BT+C/T+D{\ln}T$ with $X_{CMC}$ being critical mcielle concentration (in mole fraction), being temperature, and A, B, C, D being constants which depend on the properties of the surfactant molecules. The statistical-mechanical model discussed in this article provides a theoretical basis on the thermal dependence of critical micelle concentration

• The Journal of the Petrological Society of Korea
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• v.23 no.3
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• pp.187-195
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• 2014

In this paper, we report new OSL ages of the marine terrace sediments at Suryum fault site, using single grains of quartz, and briefly discuss their chronological implications on the timing of terrace formation along the southeastern coast of Korea. Of 1200 grains measured, 93 quartz grains were found to have OSL properties suitable for dating, the equivalent dose ($D_e$) values of which varied significantly, ranging from 50 Gy to 610 Gy with the overdispersion of $30{\pm}4%$. Applied to the Central Age Model (CAM) and Minimum Age Model (MAM), these quartz grains showed the OSL ages of $83{\pm}4ka$ and $60^{+3}{_{-7}}ka$, respectively, both of which are stratigraphically inconsistent with the previously reported OSL ages of lower $2^{nd}$ terrace (MIS 5a; ~80 ka). However, Finite Mixture Model (FMM) revealed that a small fraction of the measured quartz grains ($6{\pm}4%$) were of the ages ($194{\pm}24ka$) corresponding to MIS 7. Conclusively, based on single grain OSL ages, it would be prudent not to exclude the possibility that the marine terrace sediments at Suryum fault site have formed during MIS 7. Further, our single grain OSL ages imply that multiple grain(single aliquot) OSL dating methods are not applicable to the marine sediments at Suryum fault site.

• Advances in nano research
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• v.12 no.1
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• pp.73-79
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• 2022

Due to the extensive use of concrete structures in various applications, the improvement of their strength and quality has become of great importance. A new way of achieving this purpose is to add different types of nanoparticles to concrete admixtures. In this work, a mathematical model has been employed to analyze the vibration of concrete beams reinforced by graphene oxide (GO) nanoparticles. To verify the accuracy of the presented model, an experimental study has been conducted to compare the compressive strengths of these beams. Since GO nanoparticles are not readily dissolved in water, before producing the concrete samples, the GO nanoparticles are dispersed in the mixture by using a shaker, magnetic striker, ultrasonic devices, and finally, by means of a mechanical mixer. The sinusoidal shear deformation beam theory (SSDBT) is employed to model the concrete beams. The Mori-Tanaka model is used to determine the effective properties of the structure, including the agglomeration influences. The motion equations are calculated by applying the energy method and Hamilton's principle. The vibration frequencies of the concrete beam samples are obtained by an analytical method. Three samples containing 0.02% GO nanoparticles are made and their compressive strengths are measured and compared. There is a good agreement between our results and those of the mathematical model and other papers, with a maximum difference of 1.29% between them. The aim of this work is to investigate the effects of nanoparticle volume fraction and agglomeration and the influences of beam length and thickness on the vibration frequency of concrete structures. The results show that by adding the GO nanoparticles, the vibration frequency of the beams is increased.