• 한국안전학회지
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• 제24권4호
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• pp.40-46
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• 2009

The early identification of thermal hazards associated with a process such as the heats of reaction, exothermic decompositions, and the understanding of thermodynamics before any large scale operations are undertaken. The evaluation of reaction factors and thermal behavior on esterification process in manufacture of concrete mixture agents are described in the present paper. The experiments were performed in the differential scanning calorimetry(DSC), C 80 calorimeter, and thermal screening unit($TS^u$). The aim of the study was to evaluate the thermal stability of single material and mixture in esterification process. We provided the thermal data of chemical materials to present safe operating conditions through this study.

• 공학논문집
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• 제6권2호
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• pp.85-98
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• 2004

The adsorption equilibrium data for the binary gas mixture system from the pure gas adsorption data of carbon dioxide and ethylene on ZSM-5 prepared were predicted. The binary gas mixture adsorption data have been examined against predicted values by two models-the vacancy solution model(VSM) and the statistical thermodynamic model(STM), using parameters obtained from the single component isotherm. The binary gas mixture data for the carbon dioxide-ethylene system were obtained for cation exchanged forms of ZSM-5 for the gas phase carbon dioxide mole fraction of 0.752 at $37^{\circ}C$ and 1 atm. The experimental adsorption phase diagrams were obtained for carbon dioxide-ethylene on sodium form ZSM-5 synthesized. The single component adsorption isotherms for carbon dioxide and ethylene were also obtained for this zeolite. The single component data were used to obtain parameters derived in two models. These parameters were, in turn, used to predict the binary mixture isotherms for this zeolite. Both the vacancy solution and the statistical thermodynamic models give satisfactory predictions of adsorption phase diagrams for the binary gas mixtures of carbon dioxide and ethylene on sodium exchanged ZSM-5. Also the correlation between the experimental data and the predicted values is generally in good agreement. The system appears to show ideal behavior with a relatively constant separation factor. The slight increase in adsorption capacity with an increase in ionic radius is due, in part, to the higher polarizability associated with larger cations.

• Nuclear Engineering and Technology
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• 제55권2호
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• pp.780-791
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• 2023

To study oscillation characteristic of steam and non-condensable gas direct contact condensation through multi-hole sparger at low mass flux, a series of experiments of pure steam and mixture gas condensation have been carried out under the conditions of steam mass flux of 20-120kg/m²s, water temperature of 20-95 ℃ and mass fraction of non-condensable gas of 0-5%. The regime map of pure steam condensation through multi-hole sparger is divided into steam chugging, separated bubble, aggregated bubble and escaping aggregated bubble. The bubbles behavior of synchronization in the same hole columns and desynchronized excitation between different hole columns can be found. The coalescence effect of mixture bubbles increases with water temperature and non-condensable gas content increasing. Pressure oscillation intensity of pure steam condensation first increases and then decreases with water temperature increasing, and increases with steam mass flux increasing. Pressure oscillation intensity of mixture gas condensation decreases with water temperature and non-condensable gas content increasing, which is significantly weaker than that of pure steam condensation. The oscillation dominant frequency decreases with the rise of water temperature and non-condensable gas content. The correlations for oscillation intensity and dominant frequency respectively are developed in pure steam and mixture gas condensation at low mass flux.

• 한국산학기술학회논문지
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• 제17권7호
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• pp.641-647
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• 2016

피에조 DOD(drop-on-demand) 잉크젯 프린팅 방식은 다양한 종류의 잉크를 사용할 수 있기 때문에 최근에 첨단 산업에 적용이 활발히 연구되고 있다. 피에조 잉크젯 헤드에서 토출되는 액적의 형성 과정을 VOF(Volume-of-Fluid) 기법을 이용한 전산해석으로 예측하고 이를 측정결과와 비교하였다. 작동유체는 에틸렌 글리콜 50%와 IPA(Isopropil alchol) 50%의 혼합액을 사용하였다. 노즐 출구에서 메니스커스 변위의 시간에 따른 변화를 직접 측정하여 노즐 입구의 속도분포를 예측하고 이를 해석의 초기조건 입력자료로 사용하였다. 측정치와 해석치를 비교한 결과 전산해석이 측정치의 액적 형성 과정을 잘 예측함을 알 수 있었다. 주액적 형성과정보다 위성액적 형성과정 예측에 오차가 약간 컸는데, 이는 정지중의 공기에 큰 질량의 주액적이 날아가는 것을 예측할 때는 해석오차가 적지만 주액적에 의해서 주변 공기 유동이 활발해진 상태에서 적은 질량의 위성액적이 날아가는 것을 예측할 때는 해석오차가 상대적으로 커지기 때문이다. 또한 에틸렌 글리콜과 IPA의 혼합 비율을 달리하여 물성치를 변화시킨 다른 잉크에 대해서도 잉크 액적 형상을 예측한 결과 실험 결과를 비교적 정확히 예측할 수 있었다.

• 한국화재소방학회논문지
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• 제24권2호
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• pp.172-177
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• 2010

가연성 혼합물의 최소자연발화온도 거동(MAITB, Minimum Autoignition Temperature Behavior)은 어떤 조성에서 두개의 순수물질 가운데 낮은 물질의 AIT보다 낮은 AIT를 갖는 현상을 말하며, 이는 위험물을 취급하는 공정에서 매우 관심있는 분야이다. 본 연구는 ASTM E659-78(Standard Test Method for Autoignition Temperature of Liquid Chemical)을 이용하여 toluene과 iso-propanol(IPA) 및 p-xylene과 n-butanol혼합물의 최소자연발화온도를 측정하였다. Toluene, IPA, p-xylene 그리고 n-butanol의 자연발화 온도는 각각 $547^{\circ}C,\;463^{\circ}C,\;557^{\circ}C,\;340^{\circ}C$였다. Toluene과 iso-propanol(IPA) 계의 경우는 3 : 7(Toluene :IPA) 비율의 혼합물 일 때는 IPA순수물질($464^{\circ}C$)보다 자연발화온도가 약 $3^{\circ}C$ 낮은 혼합물의 최소자연발화온도거동 MAITB(Minimum Autoignition Temperature Behavior)을 보였다.

• 소성∙가공
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• 제23권5호
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• pp.289-296
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• 2014

Uniaxial tensile tests were conducted to accurately evaluate the in-plane mechanical properties of fiber metal laminates (FMLs). The FMLs in the current study are comprised of a layer of self-reinforced polypropylene (SRPP) sandwiched between two layers of aluminum alloy 5052-H34. The nonlinear tensile behavior of the FMLs under in-plane loading conditions was investigated using both numerical simulations and a theoretical analysis. The numerical simulation was based on finite element modeling using the ABAQUS/Explicit code and the theoretical constitutive model was based on the volume fraction approach using the rule of mixture and a modification of the classical lamination theory, which incorporates the elastic-plastic behavior of the aluminum alloy and the SRPP. The simulations and the model are used to predict the inplane mechanical properties such as stress-strain response and deformation behavior of the FMLs. In addition, a post-stretching process is used to reduce the thermal residual stresses before uniaxial tensile testing of the FMLs. Through comparison of both the numerical simulations and the theoretical analysis with the experimental results, it is concluded that the numerical simulation model and the theoretical approach can describe with sufficient accuracy the actual tensile stress-strain behavior of the FMLs.

• Korea-Australia Rheology Journal
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• 제21권3호
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• pp.185-191
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• 2009

Polystyrene/multi-walled carbon nanotube (PS/MWCNT) composites were prepared by the use of latex technology. The monodisperse PS latex was synthesized by an emulsifier-free emulsion polymerization from styrene/potassium persulfate/water system in the presence of ethanol. The MWCNTs were first treated with acid mixture to eliminate impurities, dispersed in deionized water driven by ultrasonicator, and then mixed with the PS latex. From these mixtures, PS/MWCNT composites were prepared by freeze-drying and subsequent compression molding. In the small-amplitude oscillatory shear experiments, both complex viscosity and storage modulus increased with increasing MWCNT content. A pronounced effect of MWCNT content was observed, resulting in larger storage modulus and stronger yield behavior at low frequencies when compared to unmodified PS. It showed a transition from viscous to elastic behavior with increasing MWCNT content. Over the MWCNT content of 3 wt%, the storage modulus was higher than the loss modulus across all frequencies.

• 기술사
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• 제33권5호
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• pp.45-48
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• 2000

DyeMax-L system(a real-time dyeing measuring system) which can do on line monitoring of dyeing process and measurement of the exhaustion of individual dye in mixtured dyes were developed By using the instrument, the compatability of mixture dyes and changes of exhaustion behavior of each dye with the variation of dyeing auxiliaries and dyeing conditions to get factors for control of dyeing

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2004년도 춘계학술강연 및 발표대회 강연 및 발표논문 초록집
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• pp.26-27
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• 2004

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2005년도 추계학술강연 및 발표대회강연 및 발표논문 초록집
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• pp.92-93
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• 2005