• Title/Summary/Keyword: Mixture Behavior

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The Minimum Autoignition Temperature Behavior(MAITB) of n-Decane and Acetic acid Mixture (n-Decane과 Acetic acid 혼합물의 최소자연발화온도 거동)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.28 no.2
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    • pp.49-54
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    • 2013
  • The autoignition temperature(AIT) is important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AITs and ignition delay time for n-Decane and Acetic acid system by using ASTM E659 apparatus. The AITs of n-Decane and Acetic acid which constituted binary system were $212^{\circ}C$ and $512^{\circ}C$, respectively. The experimental AITs of n-Decane and Acetic acid system were a good agreement with the calculated AITs by the proposed equations with a few A.A.D.(average absolute deviation). And n-Decane and Acetic acid system was shown the minimum autoignition temperature behavior(MAITB).

A Study on the Dynamic Characteristics of Center Pivot Rocker Arm Type OHC Valve Trains with Hydraulic Lash Adjuster (유압식 밸브 간극 조정장치를 가진 중심지지 로커암형 OHC 밸브기구의 동특성에 관한 연구)

  • 김도중;신병현
    • Transactions of the Korean Society of Automotive Engineers
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    • v.4 no.6
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    • pp.97-108
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    • 1996
  • A modeling technique is proposed for dynamic simulations of OHC valve trains with HLA(hydraulic lash adiuster). HLA is expressed by an air-oil mixture model considering HLA leak-down and aeraton effects. A compact nonlinear equation is derived which describe the short term dynamic behavior of the HLA. Valve spring is analyzed by a distributed parameter model including nonlinear characteristics in the spring surge phenomena. Global behavior of the remaining valve train is expressed by a lumped mass model. The experiental results prove that the simulation model developed here is accurate and useful for the dynamic simulations of OHC valve trains with HLA.

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Formation of $FeAl_2O_4$ in $H_2-CO_2$ and its behavior in $CO_2$(I) ($H_2-CO_2$에서 $FeAl_2O_4$의 생성기구와 $CO_2$ 중에서의 거동(I))

  • 이홍림;강명구
    • Journal of the Korean Ceramic Society
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    • v.19 no.4
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    • pp.309-315
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    • 1982
  • $FeAl_2O_4$ was formed from the starting material of $Fe_2O_3$ and $Al_2O_3$ by controlling the oxygen partial pressure using $H_2-CO_2$ gas mixture, over the temperature range of 800~120$0^{\circ}C$. The formation mechanism of $FeAl_2O_4$ was found to be a second order chemical reaction, and the activation energy of formation was observed as 39.97 kcal/mole. Vaporization behavior of $FeAl_2O_4$ under $CO_2$ atmosphere was observed over the temperature range of 800~120$0^{\circ}C$. $FeAl_2O_4$ was vaporized by a second order chemical reaction and the activation energy was found to be 21.8kcal/mole. Electrical conductivity of $FeAl_2O_4$ was also measured.

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A Study on Corrosion Behavior of the Clay-Bonded Kaolin Chamotte by Molten Aluminum (용융 알루미늄에 의한 점토결합 카올린 샤모트의 침식에 관한 연구)

  • 박정현;이승주
    • Journal of the Korean Ceramic Society
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    • v.17 no.4
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    • pp.188-196
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    • 1980
  • To investigate the corrosion behavior of the clay-bonded kaolin chamotte by molten aluminum, the mixture of 20 wt% fire clay and 80 wt% kaolin chamotte was prepared and fired in the temperature range 900~120$0^{\circ}C$. The specimens fired at each temperature were reacted with molten aluminum at 90$0^{\circ}C$. The results obtained in this experiment are as followed. 1) It was confirmed through X-ray diffraction analysis that the clay-bonded kaolin chamotte exposed to molten aluminum suffered penetration by the reaction of aluminum with silica forming alumina and metallic silicon. 2) Penetration was independent whether the silica existed as free or one component of mullite. 3) Penetration of the specimen fired at 90$0^{\circ}C$ was negligible while the others fired above 100$0^{\circ}C$ showed remarkable penetration. 4) Penetration rate at 90$0^{\circ}C$ was parabolically increased with the holding time as in the case of metal oxidation.

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A Lattice Model for Intramolecular and Intermolecular Association in Alkane + Nonionic Surfactant Systems (알칸과 비이온계면활성 계를 위한 분자 내외부 회합을 위한 격자모델)

  • Shin, Moon-Sam
    • Proceedings of the KAIS Fall Conference
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    • 2009.12a
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    • pp.103-107
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    • 2009
  • Intramolecular association is an important contribution to the overall hydrogen bonding in supercritical fluid systems, especially in systems of colloidal and biological interest. Amphiphile systems, especially micelle and microemulsion systems, showed highly non-ideal behavior due to the intermolecular association and intramolecular association. The objective of this research is to present a lattice fluid equation of state that combines the quasi-chemical nonrandom lattice fluid model with modified Veytsman statistics for intra + inter molecular association to calculate phase behavior for mixture containing surfactant systems. The present EOS could correlate the literature data well for mixtures containing nonionic surfactant systems.

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In-Cylinder Fuel Behavior According to Fuel Injection Timing and Port Characteristics in an Sl Engine : Part II-With Low/Medium Swirl (가솔린 엔진에서 연료분사시기와 포트특성에 따른 실린더 내 연료거동 : Part II - 저/중 와류의 경우)

  • 엄인용;조용석
    • Transactions of the Korean Society of Automotive Engineers
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    • v.9 no.3
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    • pp.9-17
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    • 2001
  • This paper is the second of 3 companion papers which investigate axial stratification process. In-cylinder fuel behavior has been investigated in the port injected Sl engine by visualizing for the purpose of understanding stratification. Planar laser light sheet from an Nd:YAG laser has been illuminated through the transparent quartz cylinder of the single cylinder optical engine and the Mie scattered light has been captured through the quartz window in the piston head with an ICCD camera. Fuel has been replaced with an air-ethanol mixture to utilize atomized fuel spray fur the visualization purposes. This results have been compared with steady flow concentration measurement. For low/medium swirl port, the early injection makes such a fuel distribution state that is upper-rich, middle-lean and lower-rich along the combustion chamber and cylinder by tumbling motion. On the other hand, the late injection induces upper-rich, middle-lean and lower-rich state due to the short fuel penetration.

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In-Cylinder Fuel Behavior According to Fuel Injection Timing and Port Characteristics in an SI Engine : Part III-With High Swirl (가솔린 엔진에서 연료분사시기와 포트특성에 따른 실린더 내 연료거동 : Part III - 고와류의 경우)

  • 엄인용;조용석
    • Transactions of the Korean Society of Automotive Engineers
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    • v.9 no.3
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    • pp.18-26
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    • 2001
  • This paper is the third of 3 companion papers which investigate axial stratification process. In-cylinder fuel behavior has been investigated in the port injected SI engine by visualizing for the purpose of understanding stratification. Planar laser light sheet from an Nd:YAG laser has been illuminated through the transparent quartz cylinder of the single cylinder optical engine and the Mie scattered light has been captured through the quartz window in the piston head with an ICCD camera. Fuel has been replaced with an air-ethanol mixture to utilize atomized fuel spray for the visualization purposes. This results have been compared with steady flow concentration measurement. In high swirl port, the most fuel remains at combustion chamber and upper cylinder region without being affected by injection timing. The macro-distributed state is not changed but the difference of the amount of fuel around the spark plug varies according to injection timing, which determines LML.

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A Molecular Associating Lattice Model for Mixtures Containing Amphiphiles (양친매성 물질을 함유한 혼합물을 위한 회합성 격자모델)

  • Shin, Moon-Sam
    • Proceedings of the KAIS Fall Conference
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    • 2012.05a
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    • pp.177-181
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    • 2012
  • Association is an important contribution to the overall hydrogen bonding in surfactant systems, especially in systems of colloidal and biological interest. Amphiphile systems, especially micelle and microemulsion systems, showed highly non-ideal behavior due to the intermolecular association and intramolecular association. The objective of this research is to present a lattice fluid equation of state that combines the quasi-chemical nonrandom lattice fluid model with modified Veytsman statistics for intra + inter molecular association to calculate phase behavior for mixture containing surfactant systems. The present EOS could correlate the literature data well for mixtures containing nonionic surfactant systems.

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Oxidation Behavior of $SiC/MoSi_2$ Composites Prepared by Reaction Sintering Method (반응소결에 의하여 제조된 $SiC/MoSi_2$ 복합체의 산화 거동)

  • 양준환;한인섭;우상국;서동수
    • Journal of the Korean Ceramic Society
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    • v.31 no.12
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    • pp.1588-1598
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    • 1994
  • The SiC/MoSi2 composite materials were fabricated by infiltrating the mixture of molybdenum disilicide and metal silicon(MoSi2+Si=100) to a porous compact of silicon carbide and graphite under the vacuum atmosphere of 10-1 torr. The specimen were oxidized in dry air under 1 atm at 130$0^{\circ}C$~150$0^{\circ}C$ for 240 hours. The oxidation behavior was evaluated by the weight gain and loss per unit area of the oxidized samples. Also, SEM and XRD analysis of the oxidized surface of the samples were carried out. With increasing the MoSi2 content and oxidation temperature, the passive oxidation was found. The trend of weight gain of all samples was followed the parabolic rate law with the formation of a protective layer of cristobalite on the surface.

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High Temperature Deformation Behavior of Fe-base High Strength Alloys (고강도 Fe계 합금의 고온 변형 특성)

  • Kwon, Woon-Hyun;Choi, Il-Dong
    • Journal of Advanced Marine Engineering and Technology
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    • v.32 no.6
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    • pp.938-946
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    • 2008
  • Fe-base amorphous alloy and two crystalline phases composite were fabricated. The effect of temperature and strain rate on mechanical properties was evaluated utilizing compression test. Mixture of non-crystalline and crystalline phases were found using X-ray diffraction (XRD) and differential thermal analysis (DTA) tests. Based on glass transition temperature and crystallization temperature. compression tests were performed in the temperature ranging from $560^{\circ}C$ to $700^{\circ}C$ with $20^{\circ}C$ interval. Relationship between microstructure, including fracture surface morphology, and mechanical behavior was studied. The peak stress of Fe-base amorphous alloy was over 2GPa and expected to have a good wear resistance, but it is expected hard to deform because of low ductility. The peak stress and elongation of two crystalline phases composite was over 1GPa and about 20%, therefore it is possible to deform high strength wear resistant materials such as engine valve.