• Carbon letters
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• 제15권2호
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• pp.117-124
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• 2014

Conductive polymer composites (CPCs) consist of a polymeric matrix and a conductive filler, for example, carbon black, carbon fibers, graphite or carbon nanotubes (CNTs). The critical amount of the electrically conductive filler necessary to build up a continuous conductive network, and accordingly, to make the material conductive; is referred to as the percolation threshold. From technical and economical viewpoints, it is desirable to decrease the conductive-filler percolation-threshold as much as possible. In this study, we investigated the effect of polymer/conductive-filler interactions, as well as the processing and morphological development of low-percolation-threshold (${\Phi}c$) conductive-polymer composites. The aim of the study was to produce conductive composites containing less multi-walled CNTs (MWCNTs) than required for pure polypropylene (PP) through two approaches: one using various mixing methods and the other using immiscible polymer blends. Variants of the conductive PP composite filled with MWCNT was prepared by dry mixing, melt mixing, mechanofusion, and compression molding. The percolation threshold (${\Phi}c$) of the MWCNT-PP composites was most successfully lowered using the mechanofusion process than with any other mixing method (2-5 wt%). The mechanofusion process was found to enhance formation of a percolation network structure, and to ensure a more uniform state of dispersion in the CPCs. The immiscible-polymer blends were prepared by melt mixing (internal mixer) poly(vinylidene fluoride) (PVDF, PP/PVDF, volume ratio 1:1) filled with MWCNT.

• 한국융합학회논문지
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• 제11권10호
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• pp.219-224
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• 2020

입상재료를 균일하게 혼합하기 위한 입자 교반기는 다양한 산업 분야에서 널리 활용되는 기계 장치로써 응용 분야와 혼합 조건에 따라 다양한 형태로 개발되어 사용되고 있다. 하지만 대부분 산업용 교반기의 구동 자유도는 2 자유도 이하로써 혼합재료의 기계적 특성 및 교반기의 구조를 제외한 운전 조건 측면에서 최적 교반을 위한 인자의 선택범위는 넓지 않다. 운전 조건의 선택 범위를 확대하기 위해 본 논문에서는 다관절 로봇과 입자용 드럼 믹서를 융합한 다자유도 로봇 교반기를 제안하였고 가상 작동 환경에서 교반 성능을 평가하였다. 입자 유동 해석 기법인 이산요소법을 이용하여 다자유도 로봇 믹서의 성능 예측 시뮬레이션을 수행하였고 제안된 장치 설계안이 기존 교반기보다 개선된 혼합 성능을 발휘할 수 있다는 것을 확인하였다.

• 한국세라믹학회지
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• 제47권2호
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• pp.163-168
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• 2010

Effects of compositions on the microwave dielectric properties of the MgO-$TiO_2$ system were investigated as a function of the molar ratio of MgO to $TiO_2$ ($0.9{\leq}MgO/TiO_2\;(x){\leq}1.2$). With the compositional changes, secondary phases of $MgTi_2O_5$ and $Mg_2TiO_4$ were also detected along with $MgTiO_3$. Microwave dielectric properties of the specimens were dependent on the types of phases developed in the sintered specimens. A single phase of $MgTiO_3$ showed a dielectric constant (K) of 18.2, a quality factor (Qf) of 198,000 GHz, and a temperature coefficient of resonant frequency (TCF) of $-51\;ppm/^{\circ}C$. However, the dielectric properties of the specimens with a secondary phase of $MgTi_2O_5$ (K=19.9, Qf=48,000 GHz) and/or $Mg_2TiO_4$ (K=15.6, Qf=56,000 GHz) were worsened. Dependence of the microwave dielectric properties on the secondary phase of the MgO-$TiO_2$ system was also discussed in terms of dielectric mixing rules.

• Advances in concrete construction
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• 제10권1호
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• pp.71-79
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• 2020

Ultra-high-performance concrete (UHPC) is recognized as a promising material in future civil engineering projects due to its outstanding mechanical and durability properties. However, the lack of local UHPC materials and official standards, especially for prestressed UHPC structures, has limited the application of UHPC. In this research, a large-scale prestressed bridge girder composed of nonproprietary UHPC is produced and investigated. This work has two objectives to develop the mixing procedure required to create UHPC in large batches and to study the flexural behavior of the prestressed girder. The results demonstrate that a sizeable batch of UHPC can be produced by using a conventional concrete mixing system at any precast factory. In addition, incorporating local aggregates and using conventional mixing systems enables regional widespread use. The flexural behavior of a girder made by this UHPC is investigated including flexural strength, cracking pattern and development, load-deflection curve, and strain and neutral axis behaviors through a comprehensive bending test. The experimental data is similar to the theoretical results from analytical methods based on several standards and recommendations of UHPC design.

• 한국분말재료학회지
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• 제22권4호
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• pp.266-270
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• 2015

The synthesis of NiTi alloy powders by hydrogen reduction and dehydrogenation process of NiO and $TiH_2$ powder mixtures is investigated. Mixtures of NiO and $TiH_2$ powders are prepared by simple mixing for 1 h or ball milling for 24 h. Simple-mixed mixture shows that fine NiO particles are homogeneously coated on the surface of $TiH_2$ powders, whereas ball milled one exhibits the morphology with mixing of fine NiO and $TiH_2$ particles. Thermogravimetric analysis in hydrogen atmosphere reveals that the NiO and $TiH_2$ phase are changed to metallic Ni and Ti in the temperature range of 260 to $290^{\circ}C$ and 553 to $639^{\circ}C$, respectively. In the simple-mixed powders by heat-up to $700^{\circ}C$, agglomerates with solid particles and solidified liquid phase are observed, and the size of agglomerates is increased at $1000^{\circ}C$. From the XRD analysis, the presence of liquid phase is explained by the formation and melting of $NiTi_2$ inter-metallic compound due to an exothermic reaction between Ni and Ti. The simple-mixed powders, heated to $1000^{\circ}C$, lead to the formation of NiTi phase but additional Ni-, Ti-rich and Ti-oxide phases. In contrast, the microstructure of ball-milled powders is characterized by the neck-grown particles, forming $Ni_3Ti$, Ti-oxide and unreacted Ni phase.

• Journal of Mechanical Science and Technology
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• 제16권10호
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• pp.1336-1345
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• 2002

A triboelectrostatic separation system using a fluidized bed tribocharger for the removal of PVC material in the mixture of PVC/PS plastics is designed and evaluated as a function of electric field strength, air flow rate, and the mixing ratio of two-component mixed plastics. It consists of a fluidized-bed tribocharger, a separation chamber, a collection chamber and a controller. PVC and PS particles can be imparted negative and positive surface charges, respectively, due to the difference in the work function values of plastics suspended in the fluidized-bed tribocharger, and can be separated by passing them through an external electric field. Experimental results show that separation efficiency is strongly dependent on the electric Deld strength and particle mixing ratio. In the optimum conditions of 150 Ipm air flow rate and 2.6 kV/cm electric field strength a highly concentrated PVC (99.1%) can be recovered with a yield of more than 99.2% from the mixture of PVC and PS materials for a single stage of processing.

• 농업과학연구
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• 제47권4호
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• pp.921-931
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• 2020

This study was carried out to determine the factor of a separating system according to the pepper varieties and the absence of a card cleaner system. The pepper varieties of Jeokyoung and AR-Legend were transplanted on November 20, 2019 and tested on March 18, 2020 with a harvesting speed of 0.2 m·s-1 for 10 pepper plants. The performance evaluation was determined by analyzing the separation efficiency of the peppers and the foreign matter mixing rate. The pepper harvester with a card cleaner showed a higher separation efficiency of the peppers compared to the pepper harvester without a card cleaner. The average separation efficiency of peppers on the pepper harvester with a card cleaner was higher at 13.5% for Jeokyoung and 1.9% for AR-Legend than that without a card cleaner. The mixing ratio of foreign materials on the pepper harvester with a card cleaner was lower at 8.7% and 2.5% for Jeokyoung and AR-Legend than that without a card cleaner, respectively. For the two-way ANOVA results according to the variety and the card cleaner, there was no effect on the separation efficiency of the peppers, but there was an effect on the foreign matter mixing rate.

• 한국식품영양과학회지
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• 제36권1호
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• pp.100-104
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• 2007

피복물질과 오징어 간유의 혼합 비율에 따른 미세캡슐화 특성을 알아보았다. 유화액의 점도와 안정성은 피복물질의 함량이 높을수록 증가하는 경향을 나타내었고, 미세캡슐화 효율은 43.86$\sim$29.49%로 7:3>4:6>3:7>5:5>6:4의 순으로 나타났으나 7:3의 경우 분말내 oil 함량이 낮아 적절하지 않을 것으로 판단된다. 수분결합지수는 피복물질 함량이 낮을수록 낮은 수분결합력을 보였으며, 입자의 크기는 모두 10 ${\mu}m$ 이하로 나타났다. 지방산 조성은 모든 실험구에서 다가불포화지방산의 함량이 50% 이상이었으며, 또한 다가불포화지방산에 대한 포화지방산의 비율은 모든 혼합비가 2.10 이상으로 높게 나타났다.

• 전기학회논문지
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• 제67권12호
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• pp.1633-1640
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• 2018

Epoxy resin is a polar thermosetting polymer that is widely employed in different branches of industry and everyday life, due to their stable physical and chemical properties. Of all the polymer materials currently being used in the electrical insulation industry, epoxy resin is the most widely used kind, chosen as the base polymer material in the present study. Composites were prepared according to the mixing ratio (MS: MA, 1: 9, 3: 7, 5: 5, 7: 3, 9: 1)of mixture for Heterogeneous Minerals(Micro Silica:MS, Micro Alumina:MA) (MS+MA). We have investigated for AC electrical insulation breakdown characteristics and the dielectric properties (permittivity, dielectric loss, and conductivity) with frequency changes. The electrical AC insulation breakdown performance was improved with the increase of the mixing ratio of MS according to heterogeneous mineral material mixture(MS+MA). As Dielectric properties, the dielectric constant and dielectric loss increased with decreasing frequency and decreased with increasing MS content ratio of heterogeneous mineral mixture. Tensile strength and flexural strength according to the mixing ratio (MS + MA) of epoxy / heterogeneous mineral mixture were studied by mechanical properties. The performance of mechanical tensile and flexural strength was significantly improved as the fill contents ratio of MS increased.

• Applied Biological Chemistry
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• 제7권
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• pp.39-43
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• 1966

This experiment was carried out to determine how the water soluble, the available phosphoric acid and the urea-N would change as time went by, when mixtures of calcium superphosphate and urea were made. Two kinds of materials, i. e., calcium superphosphate and urea were engaged in this experiment. Two kinds of mixed fertilizer, i. e., A and B were made up by mixing these materials to satisfy the following ratio. 1) Urea 1+ calcium superphosphate 1${\cdots}\;{\cdots}$A 2) Urea 1+ calcium superphosphate 2${\cdots}\;{\cdots}$B A and B pIaced placed in desiccators respectively a six-month period. During the time of storage, the water soluble, the available $P_2O_5$ and the urea-N were measured once a month, seven times with the control measurement. The results may be summarized as follows. 1. The urea-N in both A and B showed no change by the passage of time. This fact suggested that the mixing of calcium superphosphate with urea was not unfavourable. 2. A and B showed no diminishing in the water soluble and the available $P_2O_5$ in the process of time. This fact indicated that the combination of calcium superphosphate with urea was not unfeasible.