• Title/Summary/Keyword: Mixed refining

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Radiation Shielding Property of Concrete Using the Rapidly Cooled Steel Slag from Oxidizing Process in the Converter Furnace as Fine Aggregate

  • Kim, Jin-Man;Cho, Sung-Hyun;Kwak, Eun-Gu
    • Journal of the Korea Institute of Building Construction
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    • v.12 no.5
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    • pp.478-489
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    • 2012
  • Each year, about four million tons of steel slag, a by-product produced during the manufacture of steel by refining pig iron in the converter furnace, is generated. It is difficult to recycle this steel slag as aggregate for concrete because the reaction with water and free-CaO in steel slag results in a volume expansion that leads to cracking. However, the steel slag used in this study is atomized using an air-jet method, which rapidly changes the melting substance at high temperature into a solid at a room temperature and prevents free-CaO from being generated in steel slag. This rapidly-cooled steel slag has a spherical shape and is even heavier than natural aggregate, making it suitable for the aggregate of radiation shielding concrete. This study deals with the radiation shielding property of concrete that uses the rapidly-cooled steel slag from the oxidizing process in the converter furnace as fine aggregate. It was shown that the radiation shielding performance of concrete mixed with rapidly-cooled steel slag is even more superior than that of ordinary concrete.

A Study of Iron Pot Casting and Bellows Technology (토제 거푸집 무쇠솥 주조와 불미기술 연구)

  • Yun, Yonghyun;Doh, Jungmann;Jeong, Yeongsang
    • Korean Journal of Heritage: History & Science
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    • v.53 no.2
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    • pp.4-23
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    • 2020
  • The purpose of this study was to explore the diversity of Korea's iron casting technology and to examine various casting methods. The study involved a literature review, analysis of artifacts, local investigation of production tools and technology, and scientific analysis of casting and cast materials. Bellows technology, or Bulmi technology, is a form of iron casting technology that uses bellows to melt cast iron before the molten iron is poured into a clay cast. This technology, handed down only in Jeju Island, relies on use of a clay cast instead of the sand cast that is more common in mainland Korea. Casting methods for cast iron pots can be broadly divided into two: sand mold casting and porcelain casting. The former uses a sand cast made from mixing seokbire (clay mixed with soft stones), sand and clay, while the latter uses a clay cast, formed by mixing clay with rice straw and reed. The five steps in the sand mold casting method for iron pot are cast making, filling, melting iron into molten iron, pouring the molten iron into the cast mold, and refining the final product. The six steps in the porcelain clay casting method are cast making, cast firing, spreading jilmeok, melting iron into molten iron, pouring the molten iron, and refining the final product. The two casting methods differ in terms of materials, cast firing, and spreading of jilmeok. This study provided insight into Korea's unique iron casting technology by examining the scientific principles behind the materials and tools used in each stage of iron pot casting: collecting and kneading mud, producing a cast, biscuit firing, hwajeokmosal (building sand on the heated cast) and spreading jilmeok, drying and biyaljil (spreading jilmeok evenly on the cast), hapjang (combining two half-sized casts to make one complete cast), producing a smelting furnace, roasting twice, smelting, pouring molten iron into a cast, and refining the final product. Scientific analysis of the final product and materials involved in porcelain clay casting showed that the main components were mud and sand (SiO2, Al2O3, and Fe2O3). The release agent was found to be graphite, containing SiO2, Al2O3, Fe2O3, and K2O. The completed cast iron pot had the structure of white cast iron, comprised of cementite (Fe3C) and pearlite (a layered structure of ferrite and cementite).

Changes in Benzo(a)pyrene Content During Processing of Corn Oil (옥수수 기름의 제조공정별 벤조피렌 함량 변화)

  • Kim, Duk-Sook;Lee, Keun-Bo
    • Food Science and Preservation
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    • v.16 no.1
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    • pp.75-81
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    • 2009
  • Benzo(a)pyrene[B(a)P] levels were determined in processed oils and by-products of corn oil, and removal protocol was formulated. The cause of high level B(a)P contents in corn oil was established. Corn germ had a B(a)P level more than 80% that of whole corn. B(a)P content in final deodorized corn oil was $2.15{\mu}g/kg$, after the usual refining process. B(a)P contents less than $2.0{\mu}g/kg$ could not be attained by routine refining process. However, deodorized corn oil, with B(a)P level of $0.09{\mu}g/kg$, could be prepared by treatment of oil with approximately 2% (w/w) mixed granules(acidic clay:active carbon= 90:10[w/w]). The optimal amount of active carbon was 10% (w/w) that of acidic clay;higher levels of active carbon was not required. The optimal particle size of active carbon was $50{\sim}100$ mesh, removal of B(a)P from bleached corn oil was efficient at this mesh size.

An Investigation of Treatment Effects of Limestone and Steel Refining Slag for Stabilization of Arsenic and Heavy Metal in the Farmland Soils nearby Abandoned Metal Mine (폐금속 광산 주변 비소 및 중금속 오염농경지의 안정화 처리를 위한 석회석과 제강슬래그의 처리효과 검토)

  • Yun, Sung-Wook;Kang, Sin-Il;Jin, Hae-Geun;Kim, Ha-Jin;Lim, Young-Cheol;Yi, Ji-Min;Yu, Chan
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.5
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    • pp.734-744
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    • 2011
  • A soil stabilization method is an effective and practical remediation alternative for arsenic (As) and heavy metal contaminated farmland soils nearby abandoned metal mine in Korea. This method is a technique whereby amendments are incorporated and mixed with a contaminated soil. Toxic metal bind to the amendments, which reduce their mobility in soil, so the successful stabilization of multi-element contaminated soil depends on the combination of critical elements in the soil and the type of amendments. The objective of this study is to investigate the treatment effects and applicability of limestone (LS) and steel refining slag (SRS) as the amendment for farmland soil contaminated with As and heavy metals, and a lab-column test was conducted for achieving this purpose. The result showed that soil treated with LS and SRS maintained pH buffer capacity and, as a result, the heavy metal leaching concentration was quite low below the water quality standard compared to untreated soil which leachate exceeding the water quality standard was observed, however, the arsenic concentration rather increased with increasing mixture ratio of SRS. This was believed to be related to phosphorus (P) contained in SRS, and dominancy in the competitive adsorption relation between As and P binding strongly to iron might be different according to soil characteristic. We suggested that LS is a effective amendment for reducing heavy metals in soil, and SRS should be used after investigating its applicability based on the adsorption selectivity of arsenic and phosphorus in selected soil.

A Comparison on the Effect of Soil Improvement Methods for the Remediation of Heavy Metal Contaminated Farm Land Soil (중금속 오염 농경지 토양의 복원을 위한 토량개량법의 효과 비교)

  • Yun, Sung-Wook;Jin, Hae-Geun;Kang, Sin-Il;Choi, Seung-Jin;Lim, Young-Cheol;Yu, Chan
    • Journal of the Korean Geotechnical Society
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    • v.26 no.7
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    • pp.59-70
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    • 2010
  • A long-term field demonstration experiment on selected stabilization methods to reduce the heavy metal mobility in farmland soil contaminated by heavy metals was conducted. The field demonstration experiment was established on the contaminated farmland with wooden plates (thickness = 1 cm), of which the dimension were width = 200 cm, Length = 200 cm, height = 80 cm, filled with treated soil, which was mixed with lime stone and steel refining slag except on control plot. Soil samples in the plots were collected and analyzed during the experiment period (6 months) after the installation of the plots. The field demonstration experiment results showed that the application lime stone at the ratio of 5% was effective for immobilizing heavy metal components in contaminated farmland soil.

Deep learning-based approach to improve the accuracy of time difference of arrival - based sound source localization (도달시간차 기반의 음원 위치 추정법의 정확도 향상을 위한 딥러닝 적용 연구)

  • Iljoo Jeong;Hyunsuk Huh;In-Jee Jung;Seungchul Lee
    • The Journal of the Acoustical Society of Korea
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    • v.43 no.2
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    • pp.178-183
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    • 2024
  • This study introduces an enhanced sound source localization technique, bolstered by a data-driven deep learning approach, to improve the precision and accuracy of direction of arrival estimation. Focused on refining Time Difference Of Arrival (TDOA) based sound source localization, the research hinges on accurately estimating TDOA from cross-correlation functions. Accurately estimating the TDOA still remains a limitation in this research field because the measured value from actual microphones are mixed with a lot of noise. Additionally, the digitization process of acoustic signals introduces quantization errors, associated with the sampling frequency of the measurement system, that limit the precision of TDOA estimation. A deep learning-based approach is designed to overcome these limitations in TDOA accuracy and precision. To validate the method, we conduct comprehensive evaluations using both two and three-microphone array configurations. Moreover, the feasibility and real-world applicability of the suggested method are further substantiated through experiments conducted in an anechoic chamber.

Material Characteristic of Slags and Iron Bloom Produced by Smelting Process Using Sand Iron (사철 제련을 통해 생산된 슬래그와 괴련철의 재료과학적 특성 비교)

  • Cho, Sung Mo;Cho, Hyun Kyung;Kwon, In Cheol;Cho, Nam Chul
    • Journal of Conservation Science
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    • v.34 no.1
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    • pp.39-50
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    • 2018
  • This study replicated traditional smelting methods to produce iron blooms from sand iron. The metallurgical properties of the slag and the iron blooms were analyzed. The sand iron materials used in the smelting experiments, which were based on ancient documents, were collected from Gyeong-Ju and Pohang. Analysis by WD-XRF and XRD showed that Gyeong-Ju's sand iron contains a high-titanium, with magnetite, and Pohang's sand iron contains a low-titanium, which magnetite and ilmenite were mixed. Analysis of the slag with XRD, and the micro-structure with metal microscopes and SEM-EDS, confirmed that the major compounds in the slag of the Gyeong-Ju's sand iron were fayalite and $w\ddot{u}stite$, and those in the slag of the Pohang's sand iron were titanomagnetite and fayalite. The differences in the main constituents were confirmed according to the Ti quantity. Finally, we observed the microstructures of the iron blooms. In the case of the iron bloom produced from Gyeong-Ju's sand iron, the outside was found to be dominantly a pearlite of eutectoid steel, while the inside was a hypo-eutectoid steel where ferrite and pearlite were mixed together. While, the major component of the iron bloom produced from Pohang's sand iron was ferrite, which is almost like pure iron. However, there were many impurities inside the iron blooms. Therefore, this experiment confirmed that making ironware required a process that involved removing internal impurities, refining, and welding. It will be an important data to identify the characteristics of iron by-products and the site through traditional iron-making experiments under various conditions.

Quality Analysis of Fly Ash Through Correlation between Density by Hydrometer and Test Report (Hydrometer법을 이용한 밀도 측정값과 시험 성적서간 상관분석을 통한 플라이애시의 품질특성 분석)

  • Song, Heung-Ho;Han, Cheon-Goo
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.4
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    • pp.305-312
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    • 2017
  • To evaluate the reliability of fly ash quality supplied to ready-mixed concrete plant using mass cylinder and hydrometer, in this research, the correlationship between the fly ash properties provided from certification and density measurement with suspension was evaluated. As a result, the reliability of the certification, except fineness and loss on ignition, all properties had a discord. Additionally, in the case of density, fineness, and L.O.I, the relation with the density measured using hydrometer showed high correlation, especially fineness was strongly related with the density measured using hydrometer. Furthermore, according to the comparative analysis with previous research, the fly ash used in this research was similar measurement with raw powder without any refining process, it is considered that the constant error of blaine test or using raw ash sample as a fly ash. In current standard regarding fly ash, the fineness range of class 2 can be changed from $3,000-4,500cm^2/g$ to $3,500-4,500cm^2/g$ for improved quality of fly ash in fineness aspect.

Determination of trace impurities of HFC-134a by gas chromatograph with atomic emission detector (GC/AED) (GC/AED를 이용한 HFC-134a의 미량 불순물 분석)

  • Kim, Myeongja;Lim, Jeongsik;Lee, Jinbok;Lee, Jeongsoon
    • Analytical Science and Technology
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    • v.30 no.5
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    • pp.240-251
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    • 2017
  • 1,1,1,2-Tetrafluoroethane (HFC-134a), which is used as refrigerant in air conditioners, has been recently regulated as a greenhouse gas and is recommended for reuse by refining. It is very important to quantitatively analyze trace impurities present in the refrigerant to evaluate the criteria for reuse. In this study, trace impurities including C, H, Cl, and F, which are difficult to quantify because there are no reference materials, were quantitatively analyzed by a gas chromatograph-atomic emission detector (GC/AED); for this analysis, this was preceded by a qualitative analysis with a GC-mass selective detector (GC/MSD). In addition, the AED response was investigated using a hydrocarbon mixed reference material, which was proportional to the number of atoms in the component. Fifteen refrigerant components were detected as trace impurities in HFC-134a by qualitative analysis of trace impurities including C, H, Cl, and F in the samples. Based on the results of the qualitative analysis, quantitative analysis of trace impurities using AED showed that the highest mole fractions were for the $CHClF_2$ component ($45438.38{\mu}mol/mol$) in one sample and for the $C_2H_2ClF_3$ component ($1311.47{\mu}mol/mol$) in another sample. From this study, it has been shown that it is possible for this analytical method to be applied to the qualitative and quantitative analysis of trace compounds in refrigerants, which are difficult to quantify because of the absence of reference materials.

Characteristics of the Warm-Mix Asphalt Mixtures Using the Modified Sulfur Binder (개질 유황결합재를 사용한 중온아스팔트 혼합물의 특성)

  • Kim, Se-Won;Park, Hung-Suck;Kim, Jong-Kyu;Jung, Yong-Wook
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.489-495
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    • 2016
  • In this study, the Warm-Mix Asphalt was prepared using a modified Sulfur Binder mixed with an additive of a polymer component in sulfur, which is an industrial by-product generated in the crude oil refining process. The dynamic stability and durability characteristics of the prepared Warm-Mix Asphalt was evaluated by the indirect tensile strength, the tensile strength ratio before and after water immersion and freezing-thawing, and the dynamic stability by wheel tracking test. The Warm-Mix Asphalt Mixtures using Modified Sulfur Binder has a tensile strength ratio before and after water immersion of 0.88, which is about 1.13 times that of the Warm-Mix formed modified Asphalt, and the tensile strength ration before and after freezing-thawing is also 0.82, thus, all tensile strength ratios satisfied the KS quality standard value of 0.75 or more. The indirect tensile strength was 1.6MPa which was twice the KS quality standard value of 0.8MPa, and about 1.24 times higher than that of normal heated asphalt 1.29MPa. In addition, the dynamic stability by the wheel tracking test was 14,075 times/mm, which was about 15 times higher than that of normal heated asphalt and about 3 times higher than that of the Warm-Mix formed modified Asphalt, showing excellent resistance to plastic deformation such as fatigue cracks.