• Title/Summary/Keyword: Mixed ratios

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Development of TLD Algorithms by Monochromatic Fluorescence Radiations and Continuous Spectrum X-rays (단일에너지 형광 X선 및 연속 스펙트럼 X선장에 의한 TLD 알고리즘 개발)

  • Kim, Jang-Lyul;Kim, Bong-Hwan;Chang, Si-Young;Lee, Jai-Ki
    • Journal of Radiation Protection and Research
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    • v.23 no.3
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    • pp.159-174
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    • 1998
  • Personal dosimetry system is required to measure the personal dose equivalent accurately in a wide range of radiation fields, but the dose evaluation algorithms have been developed with the X-ray fields described in MOST Ordinance (equivalent to the ANSI N13.11) from which the actual fields to be monitored may be significantly different. To evaluate the dose more accurately when workers are exposed to the non-ANSI N13.11 radiation fields, two algorithms for monochromatic radiations (one algorithm was used for various ratios of TL dosimeter and the other for matrix approximation) were developed with the experimental data of the energy responses of the $CaSO_4:Dy$ TL materials irradiated by monochromatic X-ray fields recently established in KAERI, and compared with the another algorithm developed on the basis of the ANSI N13.11 continuous spectrum X-ray fields. Then it follows the discussions for some results of the algorithm testing including mixed fields irradiations and angular response conducted in IAEA/RCA intercomparison as well as ANSI and ISO continuous spectrum X-ray and monochromatic radiation fields. The developed algorithms were successfully performed the test not only in the continuous spectrum X-ray fields given by MOST Ordinance but also in the several non-MOST Ordinance radiation fields which could be encountered in the practical working environments.

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Soil-to-Plant Transfer Factors of $^{99}Tc$ for Korean Major Upland Crops (우리나라 주요 밭작물에 대한 $^{99}Tc$의 토양-작물체 전이계수)

  • Choi, Yong-Ho;Lim, Kwang-Muk;Jun, In;Keum, Dong-Kwon
    • Journal of Radiation Protection and Research
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    • v.36 no.4
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    • pp.209-215
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    • 2011
  • In order to investigate the soil-to-plant transfer factor (TF) of $^{99}Tc$ for Korean major upland crops (soybean, radish and Chinese cabbage), pot experiments were performed in a greenhouse. Soils were collected from four upland fields (two for soybean and two for radish and Chinese cabbage) around Gyeongju radioactive-waste disposal site. Three to four weeks before sowing, dried soils were mixed with a $^{99}Tc$ solution and the mixtures were put into pots and irrigated. TF values were expressed as the ratios of the $^{99}Tc$ concentrations in plants (Bq $kg^{-1}$-dry or fresh) to those in soils (Bq $kg^{-1}$-dry). There was no great difference in the TF value between soils. The TF values for soybean seeds were extremely lower than those for the straws, indicating a very low mobility of $^{99}Tc$ to seeds. As representative TF values of $^{99}Tc$, $1.8{\times}10^{-1}$, $1.2{\times}10^1$, $3.2{\times}10^2$ and $1.3{\times}10^2$ (for dry plants), arithmetic means for two soils, were proposed for soybean seeds, radish roots, radish leaves and Chinese cabbage leaves, respectively. In the case of the vegetables, proposals for fresh plants were also made. The proposed values are not sufficiently representative so successive updates are needed.

Preparation and Characterization of Crosslinked Copolymer Membrane Containing Sulfonated Poly(ether sulfone) and p-Phenylene Terephthalamide Segments (Sulfonated Poly(ether sulfone)과 p-Phenylene Terephthalamide 세그먼트를 포함하는 가교 공중합체 멤브레인의 제조 및 특성 연구)

  • Kim, Jung-Min;Hwang, Seung-Sik;Cho, Chang-Gi
    • Polymer(Korea)
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    • v.35 no.2
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    • pp.106-112
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    • 2011
  • Aromatic copolyamides were prepared and their applicability to proton exchange membrane was studied. The copolymers contain two segments; thermally stable and mechanically strong poly (p-phenylene terephthalamide) (PPTA), and easily processable and good film-forming polysulfone. For the copolymers, different ratios of amine-terminated sulfonated ether sulfone monomer, terephthaloyl chloride, and p-phenylene diamine were sequentially reacted. The obtained copolymers were mixed with trimethylolpropane triglycidyl ether (TMPTGE), thermally cured, and converted into proton exchange membranes for fuel cell application. The reactions at each step and the molecular characteristics of precursor copolymers were confirmed by $^1H$ NMR, FTIR, and titration. The performance of the membranes was measured in terms of water uptake and proton conductivity. The water uptake, ion exchange capacity (IEC), and proton conductivity of the membranes increased with the increase of sulfonated ether sulfone segment content. Membrane containing 60 mol% sulfonic acid sulfone segment showed 1.88 meq/g IEC value. Water uptake was limited less than 110 wt% and the highest proton conductivity was up to $7.4{\times}10^{-2}$ S/cm ($25^{\circ}C$, RH=100%).

Development of Nurserγ Soil for Rice Seedling (Phyllite를 이용한 수도용(水稻用) 육묘(育苗) 상토개발(床土開發))

  • Park, Young-Hee;Chang, Ki-Woon;Hong, Jei-Gu
    • Journal of the Korea Organic Resources Recycling Association
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    • v.10 no.2
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    • pp.71-81
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    • 2002
  • The study was carried out to develop nursery soil for rice seedling of phyllite. First of all, physico-chemical properties of used phyllite in the study through the analysis for agricultural utilization evaluation are as following. Bulk density(BD) of phyllite was $1.31g/cm^3$ each other and porosity had 65% of entire pore size. Also, the water holding capacity(WHC) was 43% at 1/3bar pressure, which phyllite has high WHC. According to, the results the experiments for nursery soil were conducted by mixing the materials such as phyllite, zeolite and hill soil. The mixing ratios were 30, 50, and 70% for zeolite and hill soil into phyllite. These mixed materials were packed in a box by adding 0, 1 and 2g of N-fertilizer. At seedling test, there were increases in the growth of shoot and root of rice for phyllite to zeolite and phyllite to hill soil, respectively. On the other hand, the length of leaf increased with increasing application rate of phyllite, while length and a number of root increased with increasing application rate of hill soil. The growth in the plots of phyllite to zeolite and phyllite to hill soil was better than in control plot. Finally, phyllite plot had efficient results when it compared with others and the study used with phyllite will have to more research and effort for agricultural useful material.

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Scientific Investigation for Conservation Methodology of Bracket Mural Paintings of Daeungjeon Hall in Jikjisa Temple (직지사 대웅전 포벽화 보존방안을 위한 과학적 조사)

  • Lee, Hwa Soo;Kim, Seol Hui;Han, Kyeong Soon
    • Journal of Conservation Science
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    • v.34 no.2
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    • pp.107-118
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    • 2018
  • This report does studied for making the method of conserving bracket murals in Daeungjeon of Jikjisa Temple, through the scientific way. Results of evaluated the conservation status at the braket mural paintings, most serious damage is structural damage like cracks, breakage, and delamination. After optical investigation, a characteristic point wasn't found such as underdrawing or traces of a coat of paint. The ultrasonic examination speed by each wall painting was measured from about 195.8 m/s to 392.7 m/s, according to the location of the surface, and it was able to compare the surface properties according to the location. In Infrared-thermal image measurement shows that wall layer separation and paint layer delamination are closely detected, therefore it was able to judge of damage on the objective way. Material analysis revealed that the walls were made by sand and weathering soil. The wall layer combined sand with less than fine sand size by nearly 5:5, and the finishing layer was found to have mixed medium sand and fine sand at approximately 6:4 rates. However, In case of finishing layer, mixing ratios of sizes less than very fine sand were found to be significantly lower than wall. Therefore, it is estimated that the plysical damage such as the separation between the layers of the walls created in the braket mural paintings, is continuously caused by changes in the internal stresses and volume ratio caused by the density differences between the wall and the finishing layers.

Parametric Study on Gloss Property of UV Curable Coated Steel (자외선 코팅 강판의 광택도에 미치는 공정 변수에 대한 연구)

  • Hwang, Dong Seop;Cho, Dong Chul;Yoo, Hye Jin;Kim, Jong Sang;Cheong, In Woo
    • Journal of Adhesion and Interface
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    • v.15 no.3
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    • pp.116-122
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    • 2014
  • This work deals with the effects of different oligomers, monomers, photoinitiators, and steel plates on the variation of gloss for UV coated steel plates at $20^{\circ}$ and $60^{\circ}$ (ASTM D523). The gloss value was more significantly varied with $20^{\circ}$ angle as compared with $60^{\circ}$. No substantial change in gloss was observed for the type of single oligomer; however, the gloss varied with the mixing ratios of oligomers, type and mixing ratio of monomers, type and concentration of photoinitiator, and type of steel plate. The maximum gloss value was observed when the mixing ratio of polyurethane acrylate (UA) to epoxy acrylate (EA) was 70 : 30, the mixing ratio of trimethylolpropantriacrylate (TMPTA) to tetrahydrofurfurylacrylate (THFA) was 5 : 5, the content of the mixed oligomer (UA : EA = 70 : 30) was 90 wt%, respectively. Darocur MBF of liquid type showed better gloss property than the solid type of Irgacure 184, and the gloss was decreased as the concentration of Darocur MBF increased from 1 to 4 wt%. Regarding the type of steel plate, GI steel plate showed better gloss property as compared with EG and primer-coated steel plates. The maximum gloss values of 95 GU and 120 GU, respectively, at $20^{\circ}$ and $60^{\circ}$ angles throughout the parametric study in the absence of leveling agents enhancing the gloss.

Enhanced Pathogenicity of Bacillus thuringiensis Mixed with a Culture Broth of an Entomopathogenic Bacterium, Xenorhabdus sp. (제노랍두스 곤충병원세균 배양액의 비티 미생물 약제 약효증진 효과)

  • Seo, Sam-Yeol;Ahn, Haet-Nim;Eom, Seong-Hyeon;Im, Eun-Yeong;Park, Ji-Young;Kim, Yong-Gyun
    • Korean journal of applied entomology
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    • v.51 no.1
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    • pp.39-45
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    • 2012
  • The entomopathogenic bacterium, $Xenorhabdus$ sp., was isolated from an entomopathogenic nematode, $Steinernema$ $monticolum$. When these bacteria were injected into the hemocoel of the diamondback moth, $Plutella$ $xylostella$, they caused significant mortality. However, the bacterium was not pathogenic when it was administered orally. This study showed that $Xenorhabdus$ sp. significantly enhanced oral pathogenicity of $Bacillus$ $thuringiensis$ (Bt) against the last instar larvae of $P.$ $xylostella$. Different ratios of culture broth of $Xenorhabdus$ sp. and Bt showed significantly different pathogenicities against $P.$ $xylostella$. In field tests, the optimal bacterial mixture significantly enhanced control efficacy against $P.$ $xylostella$ compared to Bt treatment alone. These results demonstrated that $Xenorhabdus$ sp. culture broth can be developed as a potent biopesticide by enhancing the insecticidal efficacy of Bt.

Evaluation for Properties of Domestic Pond Ash Aggregate and Durability Performance in Pond Ash Concrete (국산 매립회의 골재특성 평가 및 매립회 콘크리트의 내구 성능 평가)

  • Lee, Bong-Chun;Jung, Sang-Hwa;Kim, Joo-Hyung;Kwon, Seung-Jun
    • Journal of the Korea Concrete Institute
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    • v.23 no.3
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    • pp.311-320
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    • 2011
  • Fly ash (FA), byproduct from power plant has been actively used as mineral admixture for concrete. However, since bottom ash (BA) is usually used for land reclaim or subbase material, more active reuse plan is needed. Pond ash (PA) obtained from reclaimed land is mixed with both FA and BA. In this study, 6 PA from different domestic power plant are prepared and 5 different replacement ratios (10%, 20%, 30%, 50%, and 70%) for fine aggregate substitutes are considered to evaluate engineering properties of PA as fine aggregate and durability performance of PA concrete. Tests for fine aggregate of PA for fineness modulus, density and absorption, soundness, chloride and toxicity content, and alkali aggregate reaction are performed. For PA concrete, durability tests for compressive strength, drying shrinkage, chloride penetration/diffusion, accelerated carbonation, and freezing/thawing are performed. Also, basic tests for fresh concrete like slump and air content are performed. Although PA has lower density and higher absorption, its potential as a replacement material for fine aggregate is promising. PA concrete shows a reasonable durability performance with higher strength with higher replacement ratio. Finally, best PA among 6 samples is selected through quantitative classification, and limitation of PA concrete application is understood based on the test results. Various tests for engineering properties of PA and PA concrete are discussed in this paper to evaluate its application to concrete structure.

Characteristics of the Warm-Mix Asphalt Mixtures Using the Modified Sulfur Binder (개질 유황결합재를 사용한 중온아스팔트 혼합물의 특성)

  • Kim, Se-Won;Park, Hung-Suck;Kim, Jong-Kyu;Jung, Yong-Wook
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.489-495
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    • 2016
  • In this study, the Warm-Mix Asphalt was prepared using a modified Sulfur Binder mixed with an additive of a polymer component in sulfur, which is an industrial by-product generated in the crude oil refining process. The dynamic stability and durability characteristics of the prepared Warm-Mix Asphalt was evaluated by the indirect tensile strength, the tensile strength ratio before and after water immersion and freezing-thawing, and the dynamic stability by wheel tracking test. The Warm-Mix Asphalt Mixtures using Modified Sulfur Binder has a tensile strength ratio before and after water immersion of 0.88, which is about 1.13 times that of the Warm-Mix formed modified Asphalt, and the tensile strength ration before and after freezing-thawing is also 0.82, thus, all tensile strength ratios satisfied the KS quality standard value of 0.75 or more. The indirect tensile strength was 1.6MPa which was twice the KS quality standard value of 0.8MPa, and about 1.24 times higher than that of normal heated asphalt 1.29MPa. In addition, the dynamic stability by the wheel tracking test was 14,075 times/mm, which was about 15 times higher than that of normal heated asphalt and about 3 times higher than that of the Warm-Mix formed modified Asphalt, showing excellent resistance to plastic deformation such as fatigue cracks.

THE EFFECT OF MONOMER TO POWDER RATIO ON POLYMERIZATION SHRINKAGE-STRAIN KINETICS OF POLYMER-BASED PROVISIONAL CROWN AND FIXED PARTIAL DENTURE MATERIALS

  • Kim, Sung-Hun
    • The Journal of Korean Academy of Prosthodontics
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    • v.45 no.6
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    • pp.735-742
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    • 2007
  • Statement of problem. Although a number of previous investigations have been carried out on the polymerization shrinkage-strain kinetics of provisional crown and fixed partial denture (FPD) materials, the effect of the changes of liquid monomer to powder ratio on its polymerization shrinkage-strain kinetics has not been reported. Purpose. The purpose of this study was to investigate the influence of liquid monomer to powder ratio of polymer-based provisional crown and FPD materials on the polymerization shrinkage-strain kinetics. Material and methods. Chemically activated acrylic provisional materials (Alike, Jet, Snap) were investigated. Each material was mixed with different liquid monomer to powder ratios by volume (1.0:3.0, 1.0:2.5, 1.0:2.0, 1.0:1.5, 1.0:1.0). Time dependent polymerization shrinkage- strain kinetics of all materials was measured by the bonded-disk method as a function of time at $23^{\circ}C$. Five recordings were taken for each ratio. The results were statistically analyzed using one-way ANOVA and the multiple comparison Scheffe test at the significance level of 0.05. Trends were also examined by linear regression. Results. At 5 minutes after mixing, the polymerization shrinkage-strains of all materials ranged from only 0.01% to 0.49%. At 10 minutes, the shrinkage-strain of Alike was the highest, 3.45% (liquid monomer to powder ratio=1.0:3.0). Jet and Snap were 2.69% (1.0:2.0) and 1.58% (1.0:3.0), respectively (P>0.05). Most shrinkage (94.3%-96.5%) occurred at 30 minutes after mixing for liquid monomer to powder ratio, ranging from 1.0:3.0 to 1.0:1.0. The highest polymerization shrinkage-strain values were observed for the liquid monomer to powder ratio of 1.0:3.0. At 120 minutes after mixing, the shrinkage-strain values were 4.67%, 4.18%, and 3.07% for Jet, Alike, and Snap, respectively. As the liquid monomer to powder ratio increased, the shrinkage-strain values tend to be decreased linearly (r=-0.769 for Alike, -0.717 for Jet, -0.435 for Snap, $r^2=0.592$ for Alike, 0.515 for Jet, 0.189 for Snap; P<0.05). Conclusion. The increase of the liquid monomer to powder ratio from 1.0:3.0 to 1.0:1.0 had a significant effect on the shrinkage-strain kinetics of polymer-based crown and FPD materials investigated. This increased the working time and decreased the shrinkage-strain during polymerization.