• Title/Summary/Keyword: Mixed potential

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Charge-discharge behaviour of $LiNi_{0.85}Co_{0.15}O_2>/MPCF$ cell ($LiNi_{0.85}Co_{0.15}O_2/MPCF$전지의 충방전 특성)

  • 김상필;조정수;박정후;윤문수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.11a
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    • pp.25-28
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    • 1998
  • Lithiated cobalt and nickel oxides are becoming very attractive as active cathode materials for secondary lithium ion secondary battery. $LiCoO_2$ is easily synthesized from lithium cobalt salts, but has a relatively high oxidizing potential on charge. LiNiOz is synthesized by a more complex procedure and its nonstoichiometry significantly degraded the charge-discharge characteristics. But $LiNiO_2$ has a lower charge potential which increases the system stability. Lithiated cobalt and nickel oxides are iso-structure which make the preparation of solid solutions of $LiNi_{1-x}Co_xO_2$ for O$LiCoO_2 and LiNiO_2$ electrode. The aim of the presentb paper is to study the electrochemical behaviour, as weU as the possibilities for practical application of layered Iithiated nickel oxide stabilized by $Co^{3+}$ substitution as active cathode materials in lithium ion secondary battery.

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Effect of Phase Separation on Anaerobic Degradation of Phenol (페놀의 혐기성분해에 대한 상분리의 영향)

  • Park, Ju-Seok;Shin, Hang-Sik;Bae, Byung-Uk
    • Journal of Korean Society of Water and Wastewater
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    • v.8 no.1
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    • pp.27-33
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    • 1994
  • With the rapid industrialization, an ever-increasing quantity and kind of new organic compounds pose environmental problems due to their toxicity and physiological effect. However, research on the biodegradation of these compounds under anaerobic condition is very limited inspite of its efficiency and economical advantage. In this research, the pH effect on the ring cleavage of phenol under anaerobic condition was investigated, and the theory of phase separation was applied to the degradation of phenol for investigating the role of acidogenic bacteria. Results, obtained from biochemical methane potential(BMP) assay for 15.5 days of incubation, showed that acidic condition was more desirable for phenol degradation than alkaline condition. By both unacclimated methanogenic granular sludge and two mixed cultures, phenol was completely removed within six weeks of incubation with a gas conversion rate of over 86% of theoretical one. However, phenol was not degraded by unacclimated acidogenic culture, and thus it is considered as a syntrophic substrate. In case of phase separated biochemical methane potential(PSBMP) assay, in which acidogenic and methanogenic culture were seeded separately and consecutively, those that had been subjected to normal acidogens for 3 to 4 weeks showed higher gas production than those seeded with sterile or frozen culture.

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Novel thermoplastic toughening agents in epoxy matrix for vacuum infusion process manufactured composites

  • Bae, Jin-Seok;Bae, Jihye;Woo, Heeju;Lee, Bumjae;Jeong, Euigyung
    • Carbon letters
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    • v.25
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    • pp.43-49
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    • 2018
  • This study suggests the novel thermoplastic toughening agent, which can be applied in the monomer forms without increasing the viscosity of the epoxy resin and polymerized during the resin curing. The diazide (p-BAB) and dialkyne (SPB) compounds are synthesized and mixed with the epoxy resin and the carbon fiber reinforced epoxy composites are prepared using vacuum infusion process (VIP). Then, flexural and drop weight tests are performed to evaluate the improvement in the toughness of the prepared composites to investigate the potential of the novel toughening agent. When 10 phr of p-BAB and SPB is added, the flexural properties are improved, maintaining the modulus as well as the toughness is improved. Even with a small amount of polytriazolesulfone polymerized, due to the filtering effect of the solid SPB by the layered carbon fabrics during the VIP, the toughening and strengthening effect were observed from the novel toughening agent, which could be added in monomer forms, p-BAB and SPB. This suggests that the novel toughening agent has a potential to be used for the composites prepared from viscosity sensitive process, such as resin transfer molding and VIP.

Photocurrent Properties of TiO2 Nanorods Grown on FTO by Hydrothermal Method

  • Kim, Hyun;Yang, Bee Lyong
    • Journal of the Korean Ceramic Society
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    • v.52 no.6
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    • pp.531-534
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    • 2015
  • In this work, we undertake a comparative study of the crystallographic microstructures and photo-catalytic properties of rutile $TiO_2$ nanorods grown on FTO facing up and down by a hydrothermal method. An analysis of the fine structures showed that $TiO_2$ nanorods grown on FTO facing up were mixed with sea urchin and microsphere. These structures induced a vertical orientation of the nanorods on FTO. The saturated photocurrent densities of the $TiO_2$ nanorods grown both up and down were $1.5mA/cm^2$ in the former case, the IPCE was increased to 10% at 300~350 nm. The onset potential (${\fallingdotseq}$ flat band potential) of the nanorods grown on FTO facing up is negatively shifted to a value of -0.31 V. This is caused by an increase in the surface state, in this case the number of oxygen vacancies, and by the formation of $Ti^{3+}$. Therefore, the FTO facing direction is considered as a critical factor during the hydrothermal reaction for $TiO_2$ growth so as to develop an efficient photo-catalytic system.

A Study on the Liquefaction Potential Evaluation of Reclaimed Land Using Laboratory Test and Field Tests (현장 및 실내시험을 이용한 준설매립지반의 액상화 평가에 관한 연구)

  • Kim, Jong-Kook;Chae, Young-Su
    • Proceedings of the Korean Geotechical Society Conference
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    • 2005.03a
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    • pp.1528-1537
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    • 2005
  • The purpose of this study is investigated the method for estimation of the liquefaction on the reclaimed land, located in Incheon and assessed the ability of liquefaction under the condition of criteria, which is the magnitude '6.5' of seismic on the basis of the domestic seismic characteristics. Performed not only field test but the experiment as well to study how the fine content would affect into the dreging and reclaimed land and also estimated the safety factor through the empirical method and anticipated detail method based on the results. Within the reclaimed land, there are many sized soils which are almost extended from well-graded silty sand(SM) to poor-graded fine grained sand, and which have the condition, so called, the liquefaction which is easily to bring into under the circumstances within the ground. However, partly, now that the soil is mixed with silt and silty clay which include the content of fine grained dust quite a bit, the difficulties and inconveniences has been expected while trying to find the ratio of cyclic resistance, but finally Seed and Idriss method showed the most way when we estimate the safety factor on the liquefaction.

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A Study on the Effect of the Rhizobacterium, Bacillus sp. SH1RP8 and Potassium Family Polymers on the Crop Growth under Saline (염 환경 하에서 Bacillus sp. SH1RP8와 Polyacrylate Polymers가 작물 생장에 미치는 영향에 관한 연구)

  • Hong, Sun Hwa;Kim, Ji Seul;Park, Jang Woo;Lee, Eun Young
    • KSBB Journal
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    • v.30 no.3
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    • pp.97-102
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    • 2015
  • This study aimed to evaluate the potential plantgrowth promoting effects of potassium polyacrylate, a superabsorbent polymer, and Bacillus sp. SH1RP8, a family of plant-growth-promoting bacteria. Potassium polyacrylate was selected as the polymer for use due to its high molecular weight and its ability to retain and continuously supply moisture. Plant-growth-promoting rhizobacteria (PGPR) were isolated from the soil and applied to plants growing in dry environments, such as saline conditions. The moisture absorption and retention abilities of potassium polyacrylate were evaluated at a high temperature ($50^{\circ}C$) and in a dry condition, during which time the polymer showed a water retention potential of 19606.07% after 29 days. To overcome the reaming problem in the soil environment, natural polymers (such as cellulose) were mixed with the potassium acrylate. The shoot growths of Peucedanum japonicum Thunb and Arundo donax were significantly enhanced when treated with the mixture of the isolated rhizosphere bacterium SH1RP8 and potassium polyacrylate (63.5 and 124.3%, respectively).

Electronic State of ZnO Doped with Elements of IIIB family, Calculated by Density functional Theory (범밀도함수법을 이용하여 계산한 IIIB족 원소가 도핑된 ZnO의 전자상태)

  • Lee, Dong-Yoon;Lee, Won-Jae;Min, Bok-Ki;Kim, In-Sung;Song, Jae-Sung;Kim, Yang-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.7
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    • pp.589-593
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    • 2005
  • The electronic states of ZnO doped with Al, Ga and In, which belong to III family elements in periodic table, were calculated using the density functional theory. In this study, the calculation was performed by two Programs; the discrete variational Xa (DV-Xa) method, which is a sort of molecular orbital full potential method; Vienna Ab-initio Simulation Package (VASP), which is a sort of pseudo potential method. The fundamental mixed orbital structure in each energy level near the Fermi level was investigated with simple model using DV-Xa. The optimized crystal structures calculated by VASP were compared to the measured structures. The density of state and the energy levels of dopant elements were shown and discussed in association with properties.

Fundamental Study on Cathodic Protection and Material Development as Erosion-Control Methods of Oceanic Centrifugal Pump(1) (해상용 원심펌프 임펠러의 침식억제법으로 음극방식 및 재료개발에 관한 기초연구 1)

  • 이진열;임우조
    • Journal of Advanced Marine Engineering and Technology
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    • v.19 no.2
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    • pp.56-66
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    • 1995
  • Recently, with theraped advancement in th oceanology such an ocean-going vessel and oceanic structures, there is a need to study the cavitation erosion-corrosion control of pump impeller, the partial element of ocean machinery, for more effective operation. Especially, the cathodic protection (impressed current method & Al-sacrificial anode method) was applied to sea water, and Cu-alloy material mixed Zn & Al was used as a control method of cavitation erosion-corrosion. In this study, used the piezoelectric vibrator with 20KHz, 24.mu.m to cavity generation apparatus, and investigated the weight loss, weight loss rate, electrode potential & current density etc. under this condition. According to test result, thos describes how to indentify an influence of the cathodic protection and Al & Zn addition in material development for the control of cavitation erosion-corrosion, and those will serve as fundamental data on the cavitation erosion-corrosion control of oceanic centrifugal pump.

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Anaerobic co-digestion of food waste leachate with microalgae for improvement of methane production (메탄생산 향상을 위한 음폐수와 미세조류의 혐기성 통합소화)

  • Lee, Kwanyong;Chantrasakdakul, Phrompol;Kim, Daegi;Park, Jongjin;Choi, Jang-Seung;Park, Ki Young
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.1
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    • pp.55-60
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    • 2014
  • Food waste leachate (FWL) is a serious pollutant waste coming from the food waste recycling facilities in Korea. FWL has a high organic matter content and high COD to nitrogen (COD/N) ratio, which can disturb efficient methane production in the anaerobic digestion of FWL. In the present study a microalga, Clorella vulgaris (C.V), was used as co-substrate for the FWL anaerobic digestion in order to supply nutrients, decrease the COD/N ratio and increase its methane yield. Different co-digestion mixtures (COD/N ratios) were studied by using biochemical methane potential test and modified Gompertz equation for kinetic study. Mixed substrate of FWL and C. vulgaris in the co-digestion clearly showed more the biomethane yield than the sole substrates. The maximum methane production, 827.7 mL-$CH_4$/g-VS added, was obtained for COD/N ratio of 24/1, whereas the highest improvement of methane yield was found for COD/N ratio of 15/1.

Corrosion Fatigue Characteristics of A106-GrB Steel Weldments in NaC1 solution (A106 GrB강 용접부의 염수중 부식피로특성)

  • 김철한
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.6 no.3
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    • pp.65-72
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    • 1997
  • The horizontal corrosion fatigue tester has been developed for investigating environmental strength. Using this tester, we investigated about corrosion fatigue caracteristics for A106-Gr B steel weldments in 3.5% synthetic seawater and room temperature. Considered parameter is only frequency of 1, 3 and 5Hz.. and Corrosion fatigue crack length was measured by DC potential difference method. From the results, we could find that the horizontal corrosion fatigue tester could be well applied to estimation of fatigue strength. and, In case of 5Hz., corrosion fatigue crack growth pate of A106-Gr B steel weldment was transgranular, and of 1 and 3Hz. showed that transgranular and interfranular was mixed. Also, Material constants of corrosion fatigue crack growth estimated in each frequency were C=9.33$\times$$10^{-9}$ and m=2.93 in 1Hz., C=9.77$\times$$10^{-10}$ and m=3.47 in 3Hz., C=1.02$\times$$10^{-10}$ and m=4.05 in 5Hz

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