• Title/Summary/Keyword: Mixed gas

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Development of hydrogen-oxygen mixed gas torch for joining of vacuum glazing (진공유리 접합을 위한 수소-산소 혼합가스 토치 개발)

  • Hwang, Soon-Ho;Lee, Young-Lim;Jeon, Euy-Sik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.11
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    • pp.3074-3079
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    • 2009
  • Efficient energy use becomes necessary since energy consumption has dramatically been increasing due to continuous economic development and population growth. In particular, high efficient vacuum glazing needs to be introduced to buildings where enormous energy loss occurs through windows and has been rarely used yet due to its high price and performance. Therefore, in this study, torch for glass welding was developed with CFD(Computational Fluid Dynamics) and experiments. Torch shape, nozzle diameter, nozzle arrangement etc. were mainly optimized and hydrogen-oxygen mixed gas fuels the torch. Finally, glass welding with the developed torch has been successful, showing that it can be used to develop economic vacuum glazing.

Pressure-Temperature Diagram of Critical Condition for Disproportionation of Nd-Fe-B Alloy in Hydrogen

  • Kwon, H.W.;Kim, D.H.;Yu, J.H.
    • Journal of Magnetics
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    • v.15 no.4
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    • pp.155-158
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    • 2010
  • The HDDR (hydrogenation, disproportionation, desorption, and recombination) process can be used as an effective way of converting a no coercivity Nd-Fe-B ingot material, with a coarse $Nd_2Fe_{14}B$ grain structure, to a highly coercive one with a fine grain structure. Careful control of the HDDR process can lead to an anisotropic powder with good $Nd_2Fe_{14}B$ grain texture; the most critical step for inducing texture is disproportionation. The critical conditions (hydrogen pressure and temperature) for the disproportionation reaction of fully hydrogenated $Nd_{12.5}Fe_{81.1-(x+y)}B_{6.4}Ga_xNb_y$ (x = 0 or 0.3, y = 0 or 0.2) alloys, in different atmospheres of pure hydrogen and a mixed gas of hydrogen and argon, was investigated with TPA (thermopiezic analyser). From this, the hydrogen pressure-temperature diagram showing the critical conditions was established. The critical disproportionation temperature of the fully hydrogenated $Nd_{12.5}Fe_{81.1-(x+y)}B_{6.4}Ga_xNb_y$ alloys was slightly increased as the hydrogen pressure decreased in both pure hydrogen and mixed gas. The critical disproportionation temperature of the hydrogenated alloys was higher in the mixed gas than in pure hydrogen. Addition of Ga and Nb increased the critical disproportionation temperature of the fully hydrogenated Nd-Fe-B alloys.

Corrosion of Fe-2.25%Cr-1.6%W Steel at 600 and 700℃ in N2/(0.5, 2.5)%H2S-mixed Gas

  • Lee, Dong Bok;Bak, Sang Hwan
    • Journal of Surface Science and Engineering
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    • v.49 no.4
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    • pp.339-343
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    • 2016
  • ASTM T23 steel with a composition of Fe-2.25%Cr-1.6%W corroded at 600 and $700^{\circ}C$ for 5-70 h in $N_2$/(0.5, 2.5)%$H_2S$-mixed gas at 1 atm. It corroded rapidly, forming the outer FeS scale and the inner (FeS, $FeCr_2O_4$)-mixed scale. The ensuing outward diffusion of $Fe^{2+}$ ions during corrosion led to the protrusion of FeS platelets over the outer FeS scale. The formation of FeS at the surface facilitated the oxidation of Cr to $FeCr_2O_4$ in the inner scale. Since the nonprotective FeS scale existed over the whole scale, T23 steel displayed poor corrosion resistance in the $H_2S$-containing atmosphere.

Corrosion of Fe-(8.5~36.9) wt% Cr Alloys at 600~800℃ in (N2, H2S, H2O)-Mixed Gases (Fe-(8.5~36.9) wt% Cr합금의 600~800℃, (N2,H2S,수증기)-혼합 가스분위기에서의 부식)

  • Kim, Min Jung;Lee, Dong Bok
    • Korean Journal of Metals and Materials
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    • v.50 no.3
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    • pp.218-223
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    • 2012
  • Fe-(8.5, 18.5, 28.3, 36.9) wt% Cr alloys were corroded between 600 and $800^{\circ}C$ for up to 70 h in a 1 atm gas mixture that consisted of 0.0242 atm of $H_2S$, 0.031 atm of water vapor, and 0.9448 atm of nitrogen gas. Their corrosion resistance increased with an increment in the Cr content. The Fe-8.5%Cr alloy corroded fast, forming thick, fragile, nonadherent scales that consisted primarily of an outer FeS layer and an inner (Fe, Cr, O, S)-mixed layer. The outer FeS layer grew into the air by the outward diffusion of $Fe^{2+}$ ions, whereas the inner mixed layer grew by the inward diffusion of oxygen and sulfur ions. At the interface of the outer and inner scales, voids developed and cracking occurred. The Fe-(18.5, 28.3, 36.9)% Cr alloys displayed much better corrosion resistance than the Fe-8.5Cr alloy, because thin $Cr_2O_3$ or $Cr_2S_3$ scales formed.

The Use of Gas Chromatograph for the Measurement of Engine Exhaust Gas Composition (엔진 배기가스 성분 측정 을 위한 Gas Chromatograph 의 이용)

  • 김승수;정영교
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.9 no.6
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    • pp.743-749
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    • 1985
  • In this study the usefulness of Gas Chromatograph for the measurement of engine exhaust gas composition was confirmed. It was found that the composition of standard gas which was used for the calibration of Gas Chromatograph should not be greatly different from that of exhaust gas. Although self-evident, it cannot be overemphasized that utmost attention should be paid to prevent even a minute amount of air being mixed into the gas throughout the sampling process.

Influences of Surfactant Tween 80 on the Gas Production, Cellulose Digestion and Enzyme Activities by Mixed Rumen Microorganisms

  • Lee, Sung S.;Ha, Jong K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.16 no.8
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    • pp.1151-1157
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    • 2003
  • The surfactant Tween 80 was evaluated for its ability to influence cumulative gas production, cellulose digestion, and enzyme activities by mixed ruminal microorganisms grown on barley grain or Orchardgrass hay. The addition of Tween 80 at a level of 0.10% significantly (p<0.05) decreased the cumulative gas production rate from both barley grain or Orchardgrass hay substrates. However, 0.05% Tween 80 did not affect gas production rates compared to the control treatment. The addition of 0.05% Tween 80 to cultures growing on barley grain resulted in a significant increase in cellulase (90.01%), xylanase (90.73%) and amylase (487.25%) activities after 30 h incubation. Cultures utilizing Orchardgrass hay had a significant increase in cellulase (124.43%), xylanase (108.86%) and amylase (271.22%) activities after 72 h incubation. These increases in activities were also observed with cultures supplemented with 0.10% Tween 80 throughout all the incubation times tested. These results indicated that the addition of 0.05% Tween 80 could greatly stimulate the release of some of key enzymes without decreasing cell growth rate in contrast to trends reported with aerobic microorganism. Our data indicates potential uses of the surfactant Tween 80 as a feed additive for ruminant animals.

Estimation of Synthesis Gas Composition by Biomass Fuel Conditions using Thermodynamic Equilibrium Model (열역학적 평형모델을 이용한 바이오매스 연료조건에 따른 합성가스 조성의 예측)

  • Hong, Seong-Gu
    • Journal of The Korean Society of Agricultural Engineers
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    • v.57 no.1
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    • pp.79-87
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    • 2015
  • A thermochemical equilibrium model was constructed for predicting composition of synthesis gas in biomass gasification. The model included estimation of equilibrium constants using Gibbs free energy. After constructing the model, the results were compared with the experimental values and predictions from a previous model. Gas compositions were reasonably well agreed with them and showed effects of operational and fuel condition. When the reaction temperature increased, the lower heating values decreased due to the decrease in CH4 concentrations. The methane concentrations were lower than those observed in experimental results. The model was used to predict the gas composition and heating values for the cases of mixed fuel of charcoal and un-dry woodchips. Although downdraft gasifiers require fuels less than 15% of moisture contents, the model results indicated that the mixed fuel with charcoal and woodchips which had over 25% of moisture contents could be used in the downdraft gasifiers. It might be explained by increase in energy density resulting from mixing charcoal. The results imply that the efforts and costs for drying biomass fuels could be reduced by mixing charcoal or fuels with higher calorific values.

The Effect of Substrate Bias Voltage during the Formation of BN film by R. F. Sputtering Method (RF 스퍼터링법에 의한 BN박막 증착시 기판 바이어스전압의 영향에 관한 연구)

  • 이은국;김도훈
    • Journal of Surface Science and Engineering
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    • v.29 no.2
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    • pp.93-99
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    • 1996
  • In this work BN thin films were deposited on Si substrate by R. F. sputtering method at $200^{\circ}C$ and in Ar + $N_2$ mixed gas atmosphere. In order to investigate the effect of ion bombardment on substrate for c-BN bonding, substrate bias voltage was applied. The optimum substrate bias voltage for c-BN bonding was determined by FTIR analysis on specimens which were deposited with various bias voltages. Then BN thin film was deposited with this optimum condition and its phase, morphology, chemical composition, and refractive index were compared with those of BN film which was deposited without bias voltage. FTIR results showed that BN films deposited with substrate bias voltage were composed of mixed phases of c-BN and h-BN, while those deposited without bias voltage were h-BN only. When pure Ar gas was used for sputtering gas, BN films were delaminated easily from substrate in air, while when 10% $N_2$ gas was added to the sputtering gas, although c-BN specific infrared peak was reduced, delamination did not occur. GXRD and TEM results showed that BN films were amorphous phases regardless of substrate bias voltage, and AES results showed that the chemical compositions of B/N were about 1.7~1.8. The refractive index of BN film deposited with bias voltage was higher than that without bias voltage. The reason is believed to be the existence of c-BN bonding in BN film and the higher density of film that deposited with the substrate bias voltage.

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Effect of shield gas on the characteristics of $CO_2$ laser welded 600MPa grade high strength steel (600MPa급 자동차용 고장렬강판의 $CO_2$ 레이저 용접부의 특성에 미치는 보호가스의 영향)

  • Han Tae-Kyo;Lee Bong-Keun;Kang Chung-Yun
    • Laser Solutions
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    • v.7 no.2
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    • pp.19-26
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    • 2004
  • The effect of shield gas on the weldability, mechanical properties and formability of CO2 laser weld joint in 600MPa grade high strength steel was investigated. Bead on plate welds were made under various welding speed and shield gas. Tensile test was carried out under the load of perpendicular and parallel direction to the weld line, Formability of the joint was evaluated by Erichsen test. As the welding speed increases, the porosity fraction decreases. The porosity fraction in the joint used Ar-$50\%He$ mixed gas as a shield gas was lower than that of the joint used Ar gas. Hardness at the weld metal of full penetrated joint was nearly equal to that of water quenched raw metal. In a tensile test under a perpendicular load to the weld axis, strength and elongation of joint produced by optimum condition were nearly equal to those of base metal. However, the strength of joint in a tensile test under a parallel load to weld axis was higher than that of raw metal, but the elongation of joint was lower than that of raw metal. Elongation and formability were further increased by the method of using Ar+He mixed gas as a shield gas as compared with Ar gas. Formabilities of joints were recorded ranging from $58\%\;to\;70\%$ of that of base metal with different shield gases.

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Development of Volume Modified Sorption Model and Prediction for Volumetric Strain of Coal Matrix (흡착에 의한 석탄암체의 부피변화가 고려된 흡착모델 개선 및 부피변형률 예측)

  • Kim, Sang-Jin;Sung, Won-Mo
    • Journal of the Korean Institute of Gas
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    • v.19 no.2
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    • pp.37-44
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    • 2015
  • We proposed the improved Langmuir adsorption relations considering volume change effect of coal matrix during primary production of CBM and Enhanced-CBM with injection of carbon dioxide or CCS in coalseam but also volumetric strain. To verify this model, experimental data of pure gas adsorption such as $CO_2$, $CH_4$, and $N_2$ on coals were used to compare conventional Langmuir model with this model. From the results, we obtained that the larger adsorption capacity of coal and the higher adsorption affinity of gas, the larger error occur with Langmuir model. Using this model, however, we found not only substantially better fit in all condition but also reasonable volumetric strain of the coal matrix. We also applied this volume modified pure gas adsorption model to the IAS model to describe gas adsorption and volumetric strain for mixed gas. This modified-IAS model fitting experimental data by Hall et al(1994) improved accuracy of mixed gas adsorption calculation compared with conventional model.