• Bulletin of the Korean Chemical Society
• /
• v.19 no.6
• /
• pp.654-660
• /
• 1998

$[Fe^{II}Fe^{III}BPLMP(OAc)_2](BPh_4)_2$ (1), a new model for the reduced form of the purple acid phosphatases, has been synthesized by using a dinucleating ligand, 2,6-bis[((2-pyridylmethyl)(6-methyl-2-pyridylmethyl)amino) methyl]-4-methylphenol (HBPLMP). Complex I has been characterized by X-ray diffraction method as having (μ-phenoxo)bis(acetato)diiron core. Complex 1 was crystallized in the monoclinic space group C2/c with the following cell parameters: a=41.620(6) Å, b=14.020(3) Å, c=27.007(4) Å, β=90.60(2)°, and Z=8. The iron centers in the complex 1 are ordered as indicated by the difference in the Fe-O bond lengths which match well with typical $Fe^{III}-O\; and\; Fe^{II}-O$ bond lengths. Complex 1 has been studied by electronic spectral, NMR, EPR, SQUID, and electochemical methods. Complex 1 exhibits strong bands at 592 nm, 1380 nm in $CH_3CN$ (ε = 1.0 × 103 , 3.0 × 102). These are assigned to $phenolate-to-Fe^{III}$ and intervalence charge-transfer transitions, respectively. Its NMR spectrum exhibits sharp isotropically shifted resonances, which number half of those expected for a valence-trapped species, indicating that electron transfer between $Fe^{II}\;and\;Fe^{III}$ centers is faster than NMR time scale. This complex undergoes quasireversible one-electron redox processes. The $Fe^{III}_2/Fe^{II}Fe^{III}\;and\;Fe^{II}Fe^{III}/Fe^{II}_2$ redox couples are at 0.655 and -0.085 V vs SCE, respectively. It has $K_{comp}=3.3{\times}10^{12}$ representing that BPLMP/bis(acetate) ligand combination stabilizes a mixed-valence $Fe^{II}Fe^{III}$ complex in the air. Complex 1 exhibits a broad EPR signal centered near g=1.55 which is a characteristic feature of the antiferromagnetically coupled high-spin $Fe^{II}Fe^{III}$ system $(S_{total}=1/2)$. This is consistent with the magnetic susceptibility study showing the weak antiferromagnetic coupling $(J= - 4.6\;cm^{-1},\; H= - 2JS_1{\cdot}S2)$ between $Fe^{II}\; and \;Fe^{III}$center.

• Journal of Plant Biology
• /
• v.25 no.2
• /
• pp.83-99
• /
• 1982

In this study, thirty-two stands in Kwangnung forest located in the central part of Korea were preferentially selected. In each stand, all stems for trees and shrubs were recorded by species and their girths were measured down to 5cm. In addition, several enviromental factors such as field soil pH, field soil moisture, soil compressibility, depth of soil, thickness of litter layer, elevation and basal area were measured. Three soil cores were sampled and various physical and chemcial properties was determined. The vegetational data were subjected to three kinds of multivariate ordination(PO, PCA, RA). The results suggested that Kwangnung forest was consisted of three forest types: coniferous, mixed and broad leaved forest communities. The relation between the stand scores of ordination and several environmental factors were investigated in terms of correlation analysis in order to examine the relationships between the vegetation and certain environmental factors. As a result of this analysis, the amount of sand content in A1 horizon decreased frm the coniferous to broad leaved forest, while maximum field capacity, pore space, exchangeable cations, loss on ignition, soil pH nad the amount of total nitrogen had a tendancy to increase significantly. However, easily soluble phosphorus appeared to have little to do with the forest types. The result of species ordination of centered-standardized PCA suggested that the major successional pathway in Kwangnung forest was; Pinus densifloralongrightarrowQuercus mongolica, Q. serrata, Q. alienalongrightarrowCarpinus laxifloralongrightarrowC. erosa in sequence. This trend is in good agreement with the past studies. In three kinds of ordination (centered PCA, centered-standardized PCA and RA) based on nineteen species and twenty-five stands, the total variances accounted for the first three axes were 77%, 46% and 63% respectively. The estimated beta diversity in Kwangnung forest assumed as a coenocline, was 1.5~1.8 HC. Increasing the effect of the sampling errors on ordination perfermance, this low heterogeneity seems to cause the poor concentration of the total variance. The results from the four kinds of ordination were in good agreement with each other, especially between PO, centered-standardized PCA and RA appeared robust. It seems to be worthy of applying multivariate method for analyzing other forest communities in Korea.

• Journal of Korean Theatre Studies Association
• /
• no.52
• /
• pp.229-270
• /
• 2014

Ostermeier's Hamlet has no particular contemporary reinterpretation. Alternately devoting to show retrospect in illusion and existence through revenging actions. However, Shakespeare's metaphorical and implicative language is dissipated and the style of the play is not an illusive space-time, but a tragic theatrical production that uses rough language to express the depth of the story. The Perfomance of Hamlet is a sensuous jumble up of a diverse range of mass media. The double roles that the actors carry out give an affect of isolation between the audience and the play itself showing both empathy and liberty. Ostermeier's Hamlet distinctively shows a post-modern performance through the prominent elements of dirt, the use of mixed genre, theatric emphasis, making an image and the fulfillment of acting. Nonetheless, Ostermeier's performance stays off the point on the breakup strategy of the post-modern drama without suspending the narrative of Shakespeare's Hamlet. Besides aiming to show a performance centered by the imagery of physical expression, his performance shows New Realism in the 1960's, showing everyday life. Ostermeier thinks, that theatre helps give contemporary people an accurate reality check in the constant unstable periods of time. Therefore, Hamlet shows post-modern physical expression and outspoken dramaturgy using the effects of mass media in New Realism without breaking up realistic narration. With being the aberration of the Castle Helsingor, the main character Hamlet, expresses lunacy and can be considered as metaphor for young adults whom are broken down and isolated from the economic system. He is a substitute for those who experience agony, anger, torment, etc. and other suppressed emotions in everyday life. With the method of direction in the portrayal of Hamlet show signs of succession in the abundant popularization of the classics by communicating with the audience by following the trend of modern mass media and audio-visual perception; emphasizing the point of the philosophical topic 'life and death,' 'life and theatre,' and 'illusion and reality.'

• Journal of Physiology & Pathology in Korean Medicine
• /
• v.33 no.2
• /
• pp.116-122
• /
• 2019

The aim of this study is to evaluate the anti-inflammatory effect of Hataedock treatment using Coptidis Rhizome and Glycyrrhiza Uralensis (CG) mixed extract in allergic rhinitis induced NC/Nga mice. We divided NC/Nga mice into 3 groups as follows; allergic rhinitis-induced group after CG Hataedock treatment (CGT, n=10), no treatment group (Ctrl), allergic rhinitis elicited group (ARE). To induce allergic rhinitis, NC/Nga mice of 3 weeks age were sensitized on 7, 8 and 9week by Ovalbumin (OVA) antigen in intranasal space. Hataedock using CG extract was administered on week 3 in allergic rhinitis-induced group (CGT) after Hataedock treatment. To identify distribution of Interlukin (IL)-4, Cluster of differentiation 40 (CD40), high-affinity IgE receptor ($Fc{\varepsilon}RI$), substance P, Matrix metallopeptidase 9 (MMP-9), Nuclear $factor-{\kappa}B$ ($NF-{\kappa}B$) p65, Inducible nitric oxide synthase (iNOS) and Cycloxygenase-2 (COX-2), we used histological examination. CGT significantly inhibited IL-4 and CD40 response compared with ARE. The reduction of Th2 cytokine expression decreased inflammatory mediators such as $Fc{\varepsilon}RI$, substance P, MMP-9, $NF-{\kappa}B$ p65, iNOS and COX-2. Such immunological improvement induced reduction of respiratory epithelial damage and mucin secretion in goblet cell. These results indicate that Hataedock treatment suppresses allergic rhinitis through modulating of Th2 responses and diminishing various inflammatory mediators in nasal mucosal tissue. It might have potential applications for prevention and treatment of allergic rhinitis.

• Earthquakes and Structures
• /
• v.16 no.3
• /
• pp.349-358
• /
• 2019

Long span cable-stayed bridges are extremely vulnerable to dynamic excitations such as which caused by traffic load, wind and earthquake. Studies on cable-stayed bridge vibration control have been keenly interested by researchers and engineers in design new bridges and assessing in-service bridges. In this paper, a novel Hybrid-Tuned Mass Damper (H-TMD) is proposed and a hybrid control model named Mixed Logic Dynamic (MLD) is employed to build the bridge-H-TMD system to mitigate the vibrations. Firstly, the fundamental theory and modeling process of MLD model is introduced. After that, a new state switching design of the H-TMD and state space equations for different states are proposed to control the bridge vibrations. As the state switching designation presented, the H-TMDs can applied active force to bridge only if the structural responses are beyond the limited thresholds, otherwise, the vibrations can be reduced by passive components of dampers without active control forces provided. A new MLD model including both passive and active control states is built based on the MLD model theory and the state switching design of H-TMD. Then, the case study is presented to demonstrate the proposed methodology. In the case study, the control scheme with H-TMDs is applied for a long span cable-stayed bridge, and the MLD model is established and simulated with earthquake excitation. The simulation results reveal that the suggested method has a well damping effect and the established system can be switched between different control states as design excellently. Finally, the energy consumptions of H-TMD schemes are compared with that of Active Tuned Mass Damper (ATMD) schemes under variable seismic wave excitations. The compared results show that the proposed H-TMD can save energy than ATMD.

• Korean Journal of Heritage: History & Science
• /
• v.36
• /
• pp.69-86
• /
• 2003

This article introduce the manufacturing technique of Silla potteries based on the result excavated from Songogdong and Mulchunri site in Gyungju. As a result, we selected the kiln-site to produce Silla potteries and knew the feature which following to make them. 1. The Environmental elements to take a kiln-site were abundant fuel, plenty water and suitable soil. In particular, efficient usage of refracted winds and reserved space of forepart in the kiln-site were importantly applied to select place of kiln-site. 2. The structure of the kiln-body have been changing according to the time. It could be massproduced by produce-group from the middle and end of sixth centry which the fireplace-kiln was generalized. 3. The work center of equipments were related kiln-site. It consisted of mixed wheel, keepingpit and ditch. We knew that a look-out shed had been appeared according to utility purpose variously. 4. It sees as trimming trace of inner and outter aspects in excavated potteries and we knew that wheel had been turn to the contrast watch direction. For producing pottery of the good guality, various kiln-tools had been used already at Silla period and they used for the different purpose. 5. We intended to know method for laying the potteries in the kiln through the example of the adherent pottery to be melted. Finally, manufature and tomb-site are separated by the time through current situation of Songokdong and Mulchonri site. At the same time, we could know that group of Chounbuk kiln-site moved from the south to the north step by step.

• The Journal of Pediatrics of Korean Medicine
• /
• v.33 no.2
• /
• pp.22-31
• /
• 2019

Objective This study is to learn the effects of Hataedock method using Coptidis rhizoma and Glycyrrhiza uralensis mixed extract on inflammatory response in allergic rhinitis-induced obese NC/Nga mice. Materials and Methods The mice were fed with high fat-diet to be obese, and were divided into 3 groups as follows; allergic rhinitis-induced obese mice group with Hataedock method (CGT, n=10), no treatment group (Ctrl), allergic rhinitis elicited obese mice group (ARE). To induce allergic rhinitis, NC/Nga mice of 3 weeks age were sensitized on 7, 8 and 9 weeks by ovalbumin antigen in intraperitoneal space. After 7 days of final sensitization, allergic rhinitis was initially induced in mice through nasal cavities for 5 days. After 1-week, allergic rhinitis was induced again by the same method. Histological examination was used to identify distribution of IL-4, CD40, STAT6, $Fc{\varepsilon}RI$, substance P, MMP-9, NF-${\kappa}B$ p65, iNOS and COX-2. Results Hataedock method significantly reduced IL-4, STAT6 and CD40 response (p<0.05). In CGT, the inhibition of Th2 differentiation decreased inflammatory mediators such as $Fc{\varepsilon}RI$, substance P, MMP-9, NF-${\kappa}B$ p65, iNOS and COX-2 (all p<0.05). The immunological improvement led reduction of respiratory epithelial damage and mucin secretion in goblet cell. Conclusion The results of this study show that the Hataedock method suppresses the expression of allergic rhinitis by decreasing the inflammatory mediators through the regulation of Th2 differentiation even when the inflammation reaction is increased by obesity. Therefore, Hataedock may have potential preventive measure of allergic rhinitis accompanied by obese.

• Journal of the Korea Society of Computer and Information
• /
• v.26 no.5
• /
• pp.23-30
• /
• 2021

In this paper, we propose an extended reality-based simultaneous multi presence system in a process of remote cooperative work. The proposed system generates a ring-shaped invisible screen which surrounds a user, and it provides position and manipulation of remote workspace and personal workspace. With the proposed system, the user easily navigates the several workspace for the remote collaboration or he/she selects a specific space for immersion. The proposed system also provides manipulation of personal workspace for the user during the remote cooperative work. We conducted a user study to prove effectiveness of the proposed system. According to the results, the proposed system increased understanding spatial information and usage of time during the remote cooperative work.

• Journal of the Architectural Institute of Korea Planning & Design
• /
• v.35 no.7
• /
• pp.89-99
• /
• 2019

The purpose of this study is to reveal the meaning of Le Corbusier's works focused on Maison Guiette. This House was completed in 1926, 4 year later than the work of the Citrohan and also, this house is the only remaining mixed use Dwelling in Belgium. It offers a fine example of the early architectural concepts of Le Corbusier's. Despite these important facts, the meanings of the ideas of this house have not been paid attention as much as other houses constructed at the same period, such as Maison La Roche, Maison Stein de Monzie, Villa Savoye, etc. In his book, 'Oeuvre Complete 1910-1929', Le Corbusier mentioned as follows: "A special solution imposed by Belgian housing developments characterized by a dimension of 6 meters of frontage and a very great depth. The staircase serving the various floors is like the ladder of Jacob climbs Charlie Chaplin in the "Kid" and This house is an architectural experiments of his ideas. And this study aims at analysing the relationship between Maison Guiette and spaces on the basic of Le Corbusier's 'Five Points of a New Architecture' which had a great effects on architectural history and became a fundamental elements for the change into the Modern housing. By analysing the points in regard with the Features of Architectural Concept Applied in Maison Guiette, The Five Points are the background of the interpenetration of the interior and the exterior. To attain this, this research appraises each points in detail in regards with Maison Guiette. The study of Maison Guiette will be an important architectural subject to clarify the meaning of his later works and ideas.

• Journal of the Architectural Institute of Korea Planning & Design
• /
• v.35 no.9
• /
• pp.65-75
• /
• 2019

This study aims at analyzing the therapeutic design characteristics implemented in the indoor atriums of the outpatient areas in four children's hospitals in London and San Francisco. A mixed-method approach was used to examine the spatial configurations and design elements in the atriums, while a literature review was conducted to understand the therapeutic design characteristics relevant to atrium spaces and children's healthcare facilities. The spatial design and the pattern of use of the atrium in each hospital were studied during field visits and interviews with the hospital management staff. Based on the literature review and the observations from the field study, a Visibility Graphic Analysis was chosen to examine the visibility, accessibility, and intelligibility of the spatial configurations in the atriums of each hospital. In addition, the openness, restfulness, and vibrant ambience of the design elements in the atriums of each hospital were investigated by surveying fifty-two design professionals on the quality of the design elements in the atriums. A spatial configuration analysis, confirmed that all the atrium spaces had high visibility, accessibility, and intelligibility due to their high connectivity, integration, intelligibility, and because the atriums were laid out in the open lobby space, along the major circulation axis, or in the circulation intersection. In the survey of the design element evaluation, all atriums proved to be appropriate in terms of openness, while the adequacy of restfulness and vibrant ambience differed depending on the hospitals. Notably, location and orientation, access, natural light, outdoor view, and play facilities were found significant environmental design elements determining the successful implementation of the therapeutic design in the atriums. The observations from the aforementioned are further discussed to enhance the therapeutic design quality of atrium spaces in children's hospitals.