• 제목/요약/키워드: Mixed Sludge

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Physical and Chemical Properties of Cement Mortar with Gamma-C2S

  • Lee, Sung-Hyun;Kim, Kyungnam;Mabudo, Mabudo;Song, Myong-Shin
    • Journal of the Korean Ceramic Society
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    • v.53 no.2
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    • pp.194-199
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    • 2016
  • Presently, for the cement industry, studies that seek to reduce $CO_2$, because of the development of the plastic industry and demand for reduction of energy use, have been actively conducted among them, studies attempting to use Gamma-$C_2S({\gamma}-C_2S)$ to fix $CO_2$ have been actively conducted. The ${\gamma}-C_2S$ compound has an important function in reacting to $CO_2$ and stiffening through carbonatization in the air. The ${\gamma}-C_2S$ compound, reacting to $CO_2$ in the air, generates $CaCO_2$ within the pore structure of cement materials and densifies the pore structure this leads to an improvement of the durability and to the characteristic of resistance against neutralization. Therefore, in this experiment, in order to synthesize ${\gamma}-C_2S$, limestone sludge and waste foundry sands are used these materials are plasticized for 30 or 60 minutes at $1450^{\circ}C$, and are prevented from being cooled in the temperature range of $30{\sim}1000^{\circ}C$ when they are about to be cooled. XRD analysis and XRF analysis are used to determine the effects of this process on ${\gamma}-C_2S$ synthesization, the temperature at which a thing is plasticized, and the conditions for cooling that obtain in the plasticized clinker also, in order to confirm the $CO_2$ capture function, analysis of the major hydration products is conducted through an analysis of carbonatization depth and compressive strength, and through MIP analysis and XRD Rietveld analysis. As a result of these analyses, it is found that when ${\gamma}-C_2S$ was synthesized, the clinker that was plasticized at $1450^{\circ}C$ for one hour demonstrated the highest yield rate the sample with which the ${\gamma}-C_2S$ was mixed generated $CaCO_3$ when it reacted with $CO_2$ therefore, carbonatization depth and porosity were reduced, and the compressive strength was increased.

A Study of Milk Waste Recycling as an Energy Source and Reduction of Pollution by Anaerobic Digestion (혐기성 소화를 통한 유가공 폐기물의 에너지원으로의 재활용과 오염 감소 방안에 관한 연구)

  • Lim, Samuel;Lim, Hyun-Ji;Jung, Kook-Jin
    • Journal of Dairy Science and Biotechnology
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    • v.27 no.1
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    • pp.13-18
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    • 2009
  • We confirmed methane production and reduction of pollution during anaerobic digestion of milk waste and analyzed the economic potential of using milk waste as a renewable energy source. The milk waste sludge was obtained from the Pasteur milk factory and processed by anaerobic digestion to produce methane. The methane production from two completely mixed tank reactors with an effective capacity of 6 ${\ell}$, 15 days of hydraulic retention time (HRT), and a mid-temperature of $35^{\circ}C$ averaged 4.11 ${\ell}$/day. The total chemical oxygen demand (TCOD) during production decreased from an initial 31,416 mg/${\ell}$ to 13,500 mg/${\ell}$, showing a maximum TCOD removal efficiency of 60%. When HRT was reduced to 12 days, methane production increased by 44% under a high-temperature condition of $55^{\circ}C$. An economic analysis based on these results was applied to a Korean milk factory of typical size and demonstrated that the installation of an anaerobic digester could provide sufficient economic profit.

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Population growth and vermicomposting rate of earthworm (Eisenia fetida) according to amounts of feed supply and initial densities of earthworm populations (줄지렁이(Eisenia fetida) 입식 밀도 및 먹이 급이량에 따른 지렁이 개체군 생장 및 먹이 섭식효율)

  • Bae, Yoon-Hwan;Park, Kwang-Il
    • Journal of the Korea Organic Resources Recycling Association
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    • v.14 no.4
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    • pp.104-112
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    • 2006
  • Population growths of earthworm were investigated when the earthworm populations with different levels of initial densities per unit area were fed with cow dung mixed with paper mill sludge. The tested levels of earthworm densities were as follows; $1kg/m^2$, $2kg/m^2$, $3kg/m^2$, $5kg/m^2$. There were no significant differences in population growth rates 60 and 90 days after feed supply among the tested densities of earthworm. Therefore, it was suggested that initial densities of earthworm populations per unit area higher than $3kg/m^2$ should not be favorable because of the cost for purchasing earthworm. Vermicomposting rates of earthworm on feed were also investigated when different amounts of feed were supplied repeatedly to unit area of nursery bed with $5kg/m^2$ of initial densities earthworm populations. The tested amounts of feed at each supplying time were as follows; $16kg/m^2$, $24kg/m^2$, $32kg/m^2$, $40kg/m^2$. The more the amount of feed at each supplying time, the higher vermicomposting rate and population growth rate. Therefore, it should be more favorable for earthworm breeders to supply more than $40kg/m^2$ of feed at each supplying time, because it would reduce time and labor cost.

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Studies on the Environmentally and Ecologically Stable Revegetation Measures on Rock Cut-Slopes - Effect of Hydroseeding Measures with Forest Topsoil - (암절취(岩切取) 훼손(毁損)비탈면에 대한 환경생태적(環境生態的)으로 안정(安定)된 녹화공법(綠化工法)에 관(關)한 연구(硏究) (II) - 산림표층토(山林表層土)를 이용한 종비토(種肥土)뿜어붙이기공법(工法)의 시공효과(施工效果) 분석(分析) -)

  • Woo, Bo-Myeong;Kim, Kyung-Hoon
    • Journal of Korean Society of Forest Science
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    • v.87 no.3
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    • pp.383-390
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    • 1998
  • The purpose of this study was to evaluate the effect of new materials with forest topsoil for hydroseeding measures that is environmentally and ecologically stable revegetation measures on rock cut-slopes. Field hydroseeding experiment was used with a completely randomized design at highway rock cut-slopes in April, 1997. Results obtained in this study were summarized as follows: Particle size distribution of 3 mixed-soil materials that consisted of forest topsoil, decomposed granite soil, compost, sludge, and bottom ash did not show a significant difference. As appending the amount of forest topsoil, soil bulk density was increased. Soil hardness was slightly increased in early period, and then decreased with the flourishing of plants. The number of individuals increased, more than $3,000seedlings/m^2$, after 1 month, and it was decreased as time passes because of competition between the seeded species and the naturally emerged species. In addition to the seeded species, seeding plot has more than 6 species (Rubus crataegifolius, Eleusine indica, Erigeron canadensis, Lycopersicon esculentum var. cerasiforme, etc.) per $m^2$ were naturally appeared in the first year. From the viewpoint of species diversity promotion, the capability of using forest topsoil as seed bank sources was high. In order to apply in the field, the investigation and analysis of topsoil availability (quantity and quality of seed source, soil texture and organic composition) should be carried out before-hand.

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Analysis of RCSTP And MWTP Pollutants Treatment Efficiency in Bong-Hwa Gun (봉화군 마을하수도 및 하수처리장의 오염물질 처리 효율 분석)

  • Park, Minsoo;Im, Jiyeol;Gil, Kyungik
    • Journal of Wetlands Research
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    • v.19 no.1
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    • pp.69-79
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    • 2017
  • Protected area of water for supply source is located mostly of rural area in Korea. Normally, sewage treatment system is poor to manage in rural, because low population and density. Rural area need sewage treatment system to supervise supply source of water. In this study, analysis on operation result of 4 RCSTP and MWTP is located at the rural area. Higher concentration of pollutant were inflows to MWTP than RCSTP, and effluent quality standard is satisfaction. However, RCSTP effluent pollutant concentrations was researched higher than MWTP. The organic matter(BOD, COD) were about 5% of a high treatment efficiency to a median. The nutrient(T-N, T-P) were detected Up to high 30%. Also, we analyzed to effect reactor operational parameters on the pollutant treatment efficiency like mixed liquer suspended solid(MLSS), dissolved oxygen(DO) and sludge retention time(SRT). As a result, pollutant treatment efficiency showed fluctuation in accordance with operating condition. Thus, it is necessary to manage the reactor operation condition for management of rural area sewage treatment.

A Fundamental Study on the Adsorption Capacity of Heavy Metals by Earthworms Cast (지렁이 분변토의 중금속흡착능에 관한 기초연구)

  • Son, Hee-Jeong;Kim, Hyeong-Seok;Song, Young-Chae;Sung, Nak-Chang;Kim, Soo-Saeng
    • Journal of the Korea Organic Resources Recycling Association
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    • v.4 no.2
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    • pp.55-62
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    • 1996
  • The purpose of this study is the evaluation of adsorption capacity of casts for heavy metals comparing with the activated carbon. The casts was obtained from vermicomposting of the mixed organic sludges which were generated from the treatment facilities for leather wastewater and cattle wastewater. The physico-chemical characteristics of cast was investigated. Also, the batch adsorption experiments of cast and activated carbon for heavy metals were carried out, and the results were analyzed by Freundlich isotherm. The buffering capacity to the acidic wastewater was founded in the cast, and the cation exchange capacity of cast impling adsorption capacity for soluble substances was evaluated as about 55me/100g. Those were implied that the cast have a large potential as a good adsorbent for soluble pollutants in wastewater. From the results of batch experiments, the removal efficiencies of tested various heavy metals including Pb, Cu, Cd, and Cr were very high value as 89-98% for the activated car-bon, and 80~95% for the casts except for Zn. The adsorption equilibriums for the two materials were achieved within 90 minutes. The order of preferable metals in the adsorption was found to be Pb>Cu>Cd>Cr>Zn on the cast and to be Pb>Cd>Cu>Cr>Zn on the activated carbon, respectively. From the above results, it might be con-cluded that cast is effectively available as a good adsorbent to treating the heavy metal bearing wastewater.

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The Solidification Characteristics of Recycled Aggregate Mixed with Incineration Ash and Waste Concrete (소각재와 폐콘크리트를 이용한 재생골재의 고형화 특성)

  • Yeon, Ikjun;Ju, Soyoung;Lee, Sangwoo;Shin, Taeksoo;Kim, Kwangyul
    • Journal of the Korean GEO-environmental Society
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    • v.9 no.5
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    • pp.5-13
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    • 2008
  • In this study, It was carried out to evaluate the feasibility of recycled crushed concrete as aggregate used cement mortar replace sand and to investigate engineering properties of recycled aggregate for hazardous waste solidification. The compressive strength of cement mortar replaced 5-15% (wt.) recycled aggregate was over $163kgf/cm^2$ which is the standard of first grade concrete block class C. And cement mortar was examined to evaluate the stability by leaching test. Cu, Cd, Pb, Cr, and As as the heavy metals were proved very stable but mercury (Hg) was leached high concentration because it was simply tied to the cement surface. We investigated the crystal structures of cement mortar and they had shown the peaks of $Ca(OH)_2$, ettringite, and CSH (calcium silicate hydrate). As the result, the longer curing time, the higher CSH peak that means to increase compressive strength and the cement mortar was more stable. Therefore it was shown that it may be possible to apply hazardous waste solidification using recycled aggregate, fly ash and sewage sludge ash.

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A study on the denitrification and microbial community characteristics by the change of C/N ratio of molasses and nitrate nitrogen (당밀과 질산성 질소의 C/N ratio 변화에 따른 탈질 및 미생물 군집 특성에 관한 연구)

  • Eom, Hanki;Kim, Sungchul
    • Korean Journal of Microbiology
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    • v.54 no.2
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    • pp.105-112
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    • 2018
  • To compare the denitrification efficiency, this study used molasses and methanol were used as external carbon sources. Specific experimental conditions were classified according to C/N ratio conditions. The batch test showed that the denitrification efficiency increased as C/N ratios of molasses and methanol rose. The most suitable C/N ratio of molasses turned out 4:1 considering the concentration of the residue chemical oxygen demand (COD) and the denitrification efficiency, which was 91.4%. Specific denitrification rate (SDNR) drawn as a kinetic factor demonstrated that molasses and methanol showed similar SDNR values as C/N ratios of molasses and methanol increased. Under the condition of C/N ratio 4:1, 0.0292 g $NO_3{^-}-N$ removal/g mixed liquor volatile suspended solid (MLVSS)/day (molasses), 0.0299 g $NO_3{^-}-N$ removal/g MLVSS/day (methanol) were found. Sludge adapted to molasses showed that Bacterium Pseudomonas sp. and Bergeylla sp. dominated through an analysis of microbial community. In addition, some bacteria were high convergences than the variety of microbial community. Accordingly, it was assumed that molasses focus on growing microorganisms specialized in denitrification and applied as a replaceable external carbon source that can enhance denitrification performance.

Study on Determination of Design Factor of Bioreactor for Sulfate Reduction in Mine Drainage (광산배수 내 황산염 저감을 위한 생물반응기의 설계인자 도출 연구)

  • Kim, Kang-Ho;Kang, Chan-Ung;Kim, Sun-Joon;Kim, Tae-Heok;Ji, Won-Hyun;Jang, Hang-Seok;Park, Hyun-Sung
    • Journal of the Korean Society of Mineral and Energy Resources Engineers
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    • v.55 no.6
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    • pp.527-537
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    • 2018
  • Column tests of a sulfate reducing bacteria (SRB) bioreactor were conducted to determine the design factors for sulfate-rich mine drainage. Various substrates were applied to the bioreactor, including cow manure and its mixture with a mushroom compost, with rice straw and limestone as subsidiary materials. This procedure provided a removal efficiency of up to 82% of the total sulfur with the mixture of cow manure (70%), mushroom compost (10%) and rice straw (20%), and higher efficiencies were observed after 2 days of retention time. In the downflow condition of the flow direction, oxygen supply and re-oxidation of the sulfates occurred, causing a decrease in sulfate removal efficiency. The addition of an inorganic sludge containing heavy metals, which was intended for production of metal-sulfides in the bioreactor, had a negative effect on the long-term operation owing to arsenic release and toxicity to the SRB. The results thus show that a bioreactor using a mixed substrate with cow manure and operating in the downflow direction could reduce sulfates and total dissolved sulfur content; this process confirms the applicability of the SRB bioreactor to sulfate-rich saline drainage.

High Temperature Application of Iron Removal Chemical Cleaning Solvent in the Secondary Side of Nuclear Steam Generators (증기발생기 2차측 제철화학세정액의 고온적용)

  • Hur, D.H.;Lee, E.H.;Chung, H.S.;Kim, U.C.
    • Nuclear Engineering and Technology
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    • v.26 no.1
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    • pp.140-148
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    • 1994
  • A qualification test was performed for the iron removal chemical cleaning of the secondary side of nuclear steam generators at the selected temperature, 1$25^{\circ}C$, higher than the standard application temperature, 93$^{\circ}C$. The field cleaning condition for a nuclear unit was tested in a bench scale test loop including a SUS 316 stainless steel autoclave with one gallon capacity as a test vessel. The kinetics of sludge dissolution, corrosion of the secondary side materials and change of solvent chemistry were monitored. Test results indicated that more thorough cleaning was accomplished in less than half of the cleaning time required at 93$^{\circ}C$. And the total corrosions of the secondary side materials were found to be less than the values at 93$^{\circ}C$. While the solvent is recirculated and heated by an external chemical cleaning equipment for the conventional 93$^{\circ}C$ process, the secondary side is heated by the lateral heat of the primary coolant without the recirculation of the cleaning solution, and the solvent is mixed by vigorous boiling induced by periodic ventilation for the high temperature process. The requirement that the reactor coolant pumps should be running during the cleaning operation is the major disadvantage of the high temperature process which also should be considered when chemical cleaning is planned for steam generators under operation.

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