• 제목/요약/키워드: Mixed Particle

검색결과 816건 처리시간 0.027초

준설토의 침강속도 추정모델의 개발 (A Model for Settling Rate of the Dredged Soil)

  • 윤상묵;장병욱;원정윤;김성필
    • 한국농공학회논문집
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    • 제47권1호
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    • pp.51-59
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    • 2005
  • The settling rate of the dredged soil may vary with mineral composition, grain size distribution, initial con contration and salt concentration of suspension of the site. A series of settling column test was performed to investigate the settling rate characteristics of solid suspension material from dredging and reclamation. The settling rate of soil mixed with various size of particles depended on clay fraction which showed a inherent flux. A model was developed to predict the particle flux of mixed soil from the clay flux and its applicability was verified.

회분과 반회분의 혼합형 공정에 의해 생성된 단분산 실리카 미립자에 관한 연구 (A Study on the Monodispersed Silica Fine Particles Prepared by Using Batch-Semibatch Mixed Process)

  • 김기도;김희택
    • 공업화학
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    • 제10권8호
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    • pp.1180-1185
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    • 1999
  • 본 연구에서는 입경 제어가 용이하며 입자의 배열 상태가 치밀화된 매우 단분산된 실리카 미립자를 합성키 위하여 회분과 반회분의 적용 순서를 달리한 혼합 공정을 이용, TEOS(Tetraethylorthosilicate)의 가수분해로부터 실리카 미립자를 제조하였다. 실험은 회분과 반회분 각각의 공정을 회분-회분, 회분-반회분, 반회분-회분, 반회분-반회분의 네가지 형태로 순서를 바꾸어 혼합 적용하였으며, 각각의 공정에서 생성된 실리카 입자에 대하여 평균 입경, 입도분표, 수율, 그리고 입자의 치밀화 등을 측정, 비교하였다. 실험결과 최종 평균 입경과 수율은 반회분-반회분>회분-반회분>회분-회분>반회분-회분 공정의 순서로 컸으며, 입도 분포와 입자의 치밀화 정도는 회분-반회분>회분-회분>반회분-회분>반회분-반회분의 순서로 단분산되고 치밀한 결과를 보였다. 이중 반회분-회분, 반회분-반회분과 같이 반회분식으로 먼저 실험하여 입자를 생성한 경우는 두 번째 공정의 종류에 관계없이 모두 2차 핵 생성이 일어나는 결과를 보였으며, 이중 반회분-회분의 혼합 공정에 의해서 생성된 입자는 2차의 회분식 공정 단계에서 반응물이 첨가된 후 시간이 경과함에 따라 오히려 입자가 감소하는 결과를 보였다. 결과적으로 상기 네 가지 공정 중 회분-반회분 순서의 혼합 공정에 의해 생성된 실리카 미립자가 가장 단분산되고 입자의 치밀화가 양호한 상태로 쉽게 입경 제어를 할 수 있음을 알 수 있었다.

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PFOA Free 불소 고분자 및 실리카 나노졸을 이용한 self cleaning 표면 가공에 관한 연구 (A Study on the Self-cleaning Surface Finishing Using PFOA Free Fluoric Polymer and Silica Nano-sol)

  • 박성민;권일준;김란;염정현;윤남식;이경남
    • 한국염색가공학회지
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    • 제21권6호
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    • pp.1-11
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    • 2009
  • Super-hydrophobic surface, with a water contact angle greater than $150^{\circ}$, has a self cleaning effect termed 'lotus effect'. We introduced super-hydrophobicity onto aramid/rayon mixture fabric with dual-scale structure by assembling silica nano-sol. Mixture fabric was treated with silica nano-sol, fluoric polymer using various parameters such as particle size, concentration. Silica nano-sol size were measured using particle size analyzer. Morphological changes by particle size were observed using field emission scanning electron microscopy(FE-SEM), contact angle measurement equipment. The contact angle of water was about $134.0^{\circ}$, $137.0^{\circ}$, $143.0^{\circ}$, $139.5^{\circ}$ and $139.0^{\circ}$ for mixture fabric coated with 100.2nm, 313.7nm, 558.2nm, 628.5nm and 965.4nm silica nano-sol, compared with about $120.0^{\circ}$ for mixture fabric coated with fluoric polymer. When we mixed particle sizes of 100.2nm and 558.2nm by 7:3 volume ratio, the contact angle of water was about $146.2^{\circ}$. And we mixed particle sizes of 313.7nm and 558.2nm by 7:3 volume ratio, the contact angle of water was about $141.8^{\circ}$. Also we mixed particle sizes of 558.2nm and 965.4nm by 7:3 volume ratio, the best super-hydrophobicity was obtained. In this paper, we fabricated the water-repellent surfaces with various surface structures by using four types of silica nano-sol, and we found that the dual-scale structure was very important for the super-hydrophobicity.

Preparation of Silica Nanoparticles via Two-Step Process Utilizing Mixed Chlorosilane Residues

  • Su, Yonghong;Xu, Bugang;Cai, Jixiang;Chen, Liang;Huang, Bing
    • 한국세라믹학회지
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    • 제55권6호
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    • pp.562-569
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    • 2018
  • We propose an economic and facile method for the preparation of silica nanoparticles through a two-step process utilizing chlorosilane residues. Mixed chlorosilane residue was alcoholized with absolute ethanol as a first step to form tetraethoxysilane (TEOS). The TEOS was then utilized as a silicon source to synthesize silica nanoparticles in a sol-gel method. The alcoholysis process was designed and optimized utilizing the Taguchi experimental design method and the yield of TEOS was as high as 82.2% under optimal synthetic conditions. Similarly, the Taguchi method was also utilized to study the effects of synthesis factors on the particle size of silica nanoparticles. The results of statistical analysis indicate that the concentration of ammonia has a greater influence on particle size compared to the mass fractions of TEOS and polyethylene glycol (4.6% and 9.7%). The purity of the silica particles synthesized in our experiments is high, but the specific surface area and pore volume are small.

도매전력시장에서 N-발전사업자의 보수행렬을 이용한 꾸르노 모델의 내쉬균형점 도출을 위한 방법론 (Approach for Evaluating the Nash Equilibrium of Cournot Game Model for N-Gencos by Using Payoff Matrix in Wholesale Electricity Market)

  • 박종배;임정열;이기송;신중린
    • 대한전기학회논문지:전력기술부문A
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    • 제54권2호
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    • pp.97-106
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    • 2005
  • This paper presents a method for evaluating the nash equilibrium of the Cournot model for N-Gencos in wholesale electricity market. In wholesale electricity market, the strategies of N-Gencos can be applied to the game model under the conditions, which the Gencos determine their strategies to maximize their benefit. Generally, the Lemke algorithm has known as the approach to evaluate the mixed nash equilibrium in the only two-player game model. In this paper, we have developed the necessary condition for obtaining the mixed nash equilibrium of N-player by using the Lemke algorithms. However, it is difficult to find the mixed nash equilibrium of two more players by using the analytic method since those have the nonlinear characteristics. To overcome the above problem, we have formulated the object function satisfied with the proposed necessary conditions for N-player nash equilibrium and applied the modified particle swarm optimization (PSO) method to obtain the equilibrium for N-player. To present the effectiveness the proposed necessary condition and the evaluation approach, this paper has shown the results of equilibrium of sample system and the cournot game model for 3-players.

음이온/비이온 혼합 계면활성제 용액에서의 고형오구의 세척성 (Detergency of Particulate Soil in Anion/Nonionic Surfactant Mixed Solution)

  • 강인숙
    • 한국의류산업학회지
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    • 제13권5호
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    • pp.790-796
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    • 2011
  • This study was designed to investigate the influence of ratio of anionic/nonionic surfactant mixture on detergency of particulate soil under various solutions. The detergency of the particulate soil was determined by adhesion of particle to fabric and its removal from fabric separately. The PET fabric and ${\alpha}-Fe_2O_3$were used as materials of textile and model of particulate soil, respectively. The detergency was investigated as a function of surfactants concentration, ionic strength, kinds of electrolyte and mole numbers of oxyethylene ether of nonionic surfactant in different ratio of anionic/nonionic surfactant mixture. Although some deviations exist, the adhesion of particle to fabric generally increased with decreasing its removal from fabric. The detergency of particulate soil on PET fabric was relatively higher in anionic/nonionic surfactant mixed solution than in each single surfactant solution, but the influence of ratio of anionic/nonionic surfactant mixture on detergency of particulate soil was low. Generally the detergency of particulate soil on fabric was at its maximum at 0.1% surfactant concentration, $1{\times}10^{-3}$ ionic strength, $Na_5P_3O_{10}$ electrolytes and 10 mole numbers of oxyethylene ether of nonionic surfactant, regardless of ratio of anionic/nonionic surfactant mixture.

Phase Inversion Emulsification and Enhancement of Physical Properties for Cationic Emulsified Asphalt

  • Lee, Eun-Kyoung
    • Elastomers and Composites
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    • 제50권4호
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    • pp.265-273
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    • 2015
  • In this work, the emulsified asphalt with high phase stability and storage stability was prepared by using phase inversion emulsification and the surfactant mixed with cationic and nonionic surfactants. It was found that the asphalt together with Span 20, nonionic surfactant and DDA (Dimethyl Dodecyl Amine), cationic surfactant showed the most stable phase. The phase stability of the emulsified asphalt, therefore, was investigated through the particle size with mixed surfactant content, rheology behavior and Zeta potential value; the particle size decreased with the increase of the mixed surfactant content but the viscosity increased. The shear thinning behaviors and the Zeta potential value with 50 mV~60 mV were shown, which was found to be considered stable. In addition, SBR latex(Styrene-butadiene-rubber) and water dispersed Epoxy (EPD) were used to enhance the physical properties of the emulsified asphalt. The swelling and adhesion features of the emulsified asphalt were also studied with $CaCO_3$, Silica, and Montmorillonite (MMT). It was shown that the addition of SBR latex and MMT can be another way to improve the physical properties of the emulsified asphalt in that the lowest swelling feature was found.

견 세리신/폴리우레탄 혼합필름의 특성 (The Characteristics of Silk Sericin/polyurethane Mixed Film)

  • 김문정;배도규
    • 한국잠사곤충학회지
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    • 제40권2호
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    • pp.143-149
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    • 1998
  • For the application of silk sericin, silk sericin powders were prepared by various spray dry conditions and the characteristics of silk sericin/polyurethane mixed films were investigated. When the sericin was dried from the solution at higher inlet and outlet temperature, larger sizes of the powder particles were obtained. It was also found that inlet and outlet temperatures were important factors affecting the shape and surface characteristics of sericin power particle. The many holes and empty spaces were observed at the surface and cross section of sericin/PU mixed film. With the increase of the amount of sericin powder in the mixed films, the size and number of holes and empty spaces were increased. The thickness of sericin/PU mixed film was increased with the content of sericin powder. As the portion of sericin powder increase, the tenacity is decreased while the elongation slightly increased.

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라텍스 입자구조가 필름형성 및 필름물성에 미치는 영향 (II);모델 복합 라텍스 입자의 필름형성 거동 (Effect of Latex Particle Morphology on the Film Properties of Acrylic Coatings (II);Film Forming Behavior of Model Composite Latex)

  • 주인호;우종표
    • 한국응용과학기술학회지
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    • 제21권2호
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    • pp.132-139
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    • 2004
  • Film forming behavior of monodispersed model composite latexes with particle size of 190 nm, which consist of n-butyl acrylate as a soft phase monomer and methyl methacrylate as a hard phase monomer with different morphology was examined. Five different types of model latexes were used in this study such as random copolymer particle, soft-core/hard-shell particle, hard-core/soft-shell particle, gradient type particle, and mixed type particle. The film forming behavior was evaluated using pseudo on-line measurements of the cumulative weight loss, the UV transmittance, and the tensile fracture energy. Each stages of film formation I, II were not sensitive to the morphology of model latexes, but stage-ill was largely dependent on the morphology of model latexes. The chain mobility of polymer which composed the shell component was found to dominantly determine the behavior of film forming stage-III.

개선된 입자와법을 이용한 급 출발하는 실린더 주위의 비정상 점성 유동 시뮬레이션 (Simulations of the Unsteady Viscous Flow Around an Impulsively Started Cylinder Using Improved Vortex Particle Method)

  • 진동식;이상환;이주희
    • 대한기계학회논문집B
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    • 제24권5호
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    • pp.733-743
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    • 2000
  • We solve the integral representation of the Navier-Stokes equations in a lagrangian view by tracking the particles, which have vortex strengths. We simulate the unsteady viscous flow around an impulsively started cylinder using the vortex particle method. Particles are advanced via the Biot-Savart law for a lagrangian evolution of particles. The particle strength is modified based on the scheme of particle strength exchange. The solid boundary satisfies the no-slip boundary condition by the vorticity generation algorithm. We newly modify the diffusion scheme and the boundary condition for simulating an unsteady flow efficiently. To save the computation time, we propose the mixed scheme of particle strength exchange and core expansion. We also use a lot of panels to ignore the curvature of the cylinder, and not to solve the evaluation of the surface density. Results are compared to those from other theoretical and experimental works.