• 제목/요약/키워드: Mixed Gases

검색결과 229건 처리시간 0.025초

Electrochemical Lithium Insertion/Extraction for Carbonaceous Thin Film Electrodes in Propylene Carbonate Solution

  • Fukutsuka, Tomokazu;Abe, Takeshi;Inaba, Minoru;Ogumi, Zempachi;Matsuo, Yoshiaki;Sugie, Yosohiro
    • Carbon letters
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    • 제1권3_4호
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    • pp.129-132
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    • 2001
  • Carbonaceous thin films were prepared from acetylene and argon gases by plasma assisted chemical vapor deposition (Plasma CVD) at 873 K. The carbonaceous thin films were characterized by mainly Raman spectroscopy, and their electrochemical properties were studied by cyclic voltammetry and charge-discharge measurements in propylene carbonate (PC) solution. Raman spectra showed that crystallinity of carbonaceous thin films is correlated by the applied RF power. The difference of the applied RF power also affected on the results of cyclic voltammetry and charge-discharge measurements. In PC solution, intercalation and de-intercalation of lithium ion can occur as well as in the mixed solution of EC and DEC.

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Combustion and Emission Characteristics of Diesel Engine by Mixing DME and Bunker Oil

  • Ryu, Younghyun;Dan, Tomohisa
    • Journal of Advanced Marine Engineering and Technology
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    • 제36권7호
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    • pp.885-893
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    • 2012
  • DME (Dimethyl ether) is regarded as one of the candidates of alternative fuels for diesel engine, because of its higher cetane number suitable for a compression ignition engine. Also, DME is a simple chemical structure, colorless gas that is easily liquefied and transported. On the other hand, Bunker oil (JIS C heavy oil) has long been used as a basic fuel in marine diesel engines and is the lowest grade fuel oil. In this study, the combustion and emission characteristics were measured experimentally in the direct injection type diesel engine operated with DME and Bunker oil mixed fuel. From our experimental results, it is induced that DME and Bunker oil blended fuel would be an effective fuel which can reduces the concentration of harmful matter in exhaust gases.

Hot-Tube Oxidation Test에 의한 디젤엔진오일의 산화안정성 평가 (Evaluation of Oxidation Stability for Diesel Engine Oil by Hot-Tube Oxidation Test)

  • 정근우;조원오;김영운;서인옥;임수진
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 1998년도 제28회 추계학술대회
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    • pp.175-180
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    • 1998
  • This paper describes evaluation of oxidation stability for diesel engine oils by Hot-tube oxidation tester at high temperature. Evaluation was rated by visual inspection of lacquer in capillary glass tube and TAN determination of used oil. Air, NO$_2$-air and SO$_2$-air mixed gases were used as oxidizing gas. One oil which has low oxidation stability is selected and reformulated by addition of some additives such as antioxidant, detergent and disperant to improve oxidation stability. As a results of reformulation, antioxidant and detergent was effective for improvement of high temperture oxidation stability on diesel engine oil.

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Mutagenicity of Diesel-Exhaust Particulates

  • Yoo, Young S.
    • Journal of Korean Society for Atmospheric Environment
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    • 제10권E호
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    • pp.325-331
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    • 1994
  • Organic extracts of diesel- exhaust particulates were analyzed for mutagenicity using Ames Salmonella typhimurium assay system. An experimental diesel microbus used was drived on the chassis dynamometer according to CVS-75 mode. The samples were taken from the mixed gases in a dilution tunnel. With a high-volume air sampler equipped with double filter holders, particulate matters were collected on a teflon-coated glass fiber filter placed behind a activated carbon filter. After ultrasonic extraction with benzene- ethanol and evaporation to dryness, the residue was dissolved in dimethylsulfoxide. Each sample was tested toward 2 strains, TA100 and TA98 by the pre-incubation method in the absence and presence of S-9mix. Average concentration of diesel- exhaust particulates was about 116.6mg/m$^3$, and 44.1~62.2 % to the total weight of particulates, consisted of organic matters. The mutagenicities of diesel- exhaust particulate organic matters were 4,512 and 2,205 revertants/m$^3$ toward TA100 without and with S-9mix, respectively. Those toward TA98 were 13,367 and 3,715 revertants/m$^3$, respectively.

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HCCI 엔진 부실내 소기특성에 대한 이론 및 수치해석적 연구 (THEORETICAL AND NUMERICAL STUDY ON SCAVENGE CHARACTERISTICS IN A SUBCHAMBER OP AN HCCI ENGINE)

  • 서용권;허형석
    • 한국전산유체공학회지
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    • 제10권2호
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    • pp.21-29
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    • 2005
  • In this paper, we present the theoretical and numerical results of scavenge characteristics in a small subchamber of an HCCI(Homogeneous Charge Compression Ignition) engine. Two theoretical models are proposed in prediction of the scavenge time and the efficiency; one is the non-mixing model in which the input gas(CH4) and the existing gas(air) do not mix at all, and the other is the fully-mixed model in which the two gases are assumed to mix completely before ejection. Focus is also given to the effect on the scavenge performance of the size of the chamber outlet.

MOCVD 반응로내 GaN 성장에 미치는 입구형상의 영향 (Effect of inlet configuration on the growth rate of GaN layer in a MOCVD reactor)

  • 윤성규;백병준;박복춘
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 추계학술대회
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    • pp.67-72
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    • 2003
  • Numerical calculation has been performed to investigate the effect of inlet configuration on the growth rate of GaN layer on the heated susceptor. The conventional single inlet, where the gas is mixed by force in the inlet, is compared with separated flow inlet. Two-parallel gas flow $H_{2}$ and $NH_{3}$ are separated by a plate with finite length which are also parallel to the susceptor. The effect of separated plate length, carrier gas and flow rate of each precursor on the mixing of reactant gases and growth rate were investigated. Furthermore the three dimensional model is employed to predict the transverse variation of growth rate.

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고주파플라즈마 CVD법에 의한 다이아몬드상 탄소박막의 합성 (Synthesis of Diamond-Like Carbon Films by R.F.Plasma CVD)

  • 박상현;이덕출
    • 대한전기학회논문지
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    • 제39권10호
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    • pp.1037-1043
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    • 1990
  • Diamond thin films were synthesized from the mixed gases of methane and hydrogen on silicon substrates by RF plasma chemical vapor deposition and deposited films were investigated by SEM, X-ray diffractometry and Raman spectroscopy. It is found that high quality diamond-like carbon films were successfully synthesized by PECVD under the deposition condition of 1-10 vol% of methane concentration, 0.15-0.4torr of reactor pressure, 500W of RF power, and 5-20hr of reaction time. Especially, cubo-octahedral diamond-like carbon particles were synthesized by employing 1.0 vol % of methane concentration and 0.4torr of the reactor pressure.

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Removal of Hydrogen Sulfide and Methylmercaptan Using Thiobacillus in a Three Phase Fluidized Bed Bioreactor

  • KIM, KYUNG-RAN;KWANG-JOONG OH;KYUNG-YONG PARK;DONGUK KIM
    • Journal of Microbiology and Biotechnology
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    • 제9권3호
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    • pp.265-270
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    • 1999
  • A three phase fluidized bed bioreactor immobilized with Thiobacillus sp. IW was tested to remove hydrogen sulfide and methylmercaptan with high loading rate. In a single gas treatment, the bioreactor removed 92- 98% of hydrogen sulfide with loading rate of 15- 66 g/l/h and removed 87-98% of methylmercaptan with loading rate of 14-60 gl/sup -1/h/sup -1/. In the mixed gas treatment, the removal efficiencies of hydrogen sulfide and methylmercaptan maintained at 89-99% for various inlet loading rates and were not affected by the inlet loading ratio of both gases in low loading rates. When the inlet concentration of methylmercaptan increased 3.8 times and was maintained for 30 h to observe the response of the bioreactor to sudden environmental change, the removal efficiency of methylmercaptan was maintained at an average of 91%.

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RF Magnetron Sputtering 법으로 제조된 AIN 박막에 관한 연구 (A study on the AIN thin films fabricated by RF magnetron sputtering)

  • 남창길;최승우;천희곤;조동율
    • 한국진공학회지
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    • 제6권1호
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    • pp.44-49
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    • 1997
  • 반응성 RF 스퍼터링 장치에 반응성 질소와 작업가스 아르곤을 동시에 주입하면서 Al을 스퍼터링하여 AIN박막을 형성하였다. polycarbonate기판이나 이 디스크 표면 위의 micron크기의 pregroove형태의 손상이 일어나지 않을 정도의 저온의 저온을 유지키 위하여 플라즈마(plasma) 자체 온도($100^{\circ}C$이하)로 가열하면서 silicon과 glass기판 위에 AIN박막을 증착시켰다. 여러 증착변수 변화에 따른 박막의 결정성, 단면형상 및 굴절율 변화 등을 분석 하였다.

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정전기(靜電氣) 방전(放電)과 삼성분계(三成分系) 가연성(可燃性) 혼합기체(混合氣體)의 최소점화(最小點火) Energy 측정(測定)에 관한 연구(硏究) (Electrostatic Discharge and the Minimum Ignition Energy Measurement of Three-Component Flammable Gas Mixtures)

  • 이관형;최상원;정재희;이덕출
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1997년도 하계학술대회 논문집 E
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    • pp.1819-1823
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    • 1997
  • When flammable gases are mixed with air or oxygen in the explosion concentration range and are ignited by sufficiently large electrostatic discharge energy, they may explode causing severe disaster in workplaces. The minimum ignition energy (MIE) of single gas-air mixtures has been already investigated by many researchers, but the MIE of mixtures of more than three substances is not examined yet. The purpose of this study is to investigate the MIE of several three-component gas mixtures experimentally. The result of our experiment shows that the MIE of some gas mixtures is quite different from that we expected based on the characteristics of individual gas-air mixture.

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