• Title/Summary/Keyword: Mixed Compound

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Effects of Halogenated Compounds, Organic Acids and Unsaturated Fatty Acids on In vitro Methane Production and Fermentation Characteristics

  • Choi, N.J.;Lee, S.Y.;Sung, H.G.;Lee, S.C.;Ha, J.K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.17 no.9
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    • pp.1255-1259
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    • 2004
  • The objective of this study was to evaluate the effects of halogenated compounds, organic acids, unsaturated fatty acids and their mixtures on in vitro methane production and fermentative characteristics of mixed rumen microorganisms. Agents used in two in vitro experiments were bromoethanesulfonic acid (BES) and pyromellitic diimide (PMDI) as halogenated compound, fumarate and malate as organic acid, and linoleic acid and linolenic acid as unsaturated fatty acid sources. Ruminal fluid collected from a Holstein steer fed tall fescue and concentrate mixtures was incubated at $39^{\circ}C$ for 48 h with addition of those materials. Single supplementation of halogenated compounds, organic acids or unsaturated fatty acids decreased in vitro methane production (p<0.05). The second experiment was designed to investigate effects of combination of one of halogenated compounds and either organic acids or fatty acids on methane production. Lower concentration of methane and lower A:P ratio were observed with PMDI compared with BES (p<0.01). In general medium pH, VFA, total gas and hydrogen production, and dry matter degradability were affected by addition of the same compounds. In addition, PMDI+malate treatment resulted in the highest molar proportion of propionate, and lowest A:P ratio and methane production (p<0.01). Hydrogen production was highest in PMDI+linolenic acid and lowest in BES+malate treatment (p<0.01). PMDI+malate combination was the most recommendable in reducing methane production without too much influence on digestibility under conditions of present studies.

Effects of Synbiotics Containing Anaerobic Microbes and Prebiotics on In vitro Fermentation Characteristics and In situ Disappearance Rate of Fermented-TMR

  • Lee, Shin-Ja;Shin, Nyeon-Hak;Chu, Gyo-Moon;Lee, Sung-Sill
    • Asian-Australasian Journal of Animal Sciences
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    • v.24 no.11
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    • pp.1577-1586
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    • 2011
  • This study was carried out to estimate effects of synbiotics containing anaerobic microorganisms and prebiotics on in vitro fermentation characteristics and in situ disappearance rate of fermented total mixed ration (F-TMR). For the in vitro trial, ninety vinyl bags were prepared to analyze temperature, pH, ammonia concentration, microbial growth rate and short chain fatty acid concentration. For the in situ trial, one hundred twenty nylon bags were prepared to analyze dry matter (DM), acid detergent fiber (ADF) and neutral detergent fiber (NDF) disappearance rate. Treatments consisted of a basal diet (US) with prebiotics and probiotics from anaerobic mold (MS), bacteria (BS), yeast (YS) or compound (CS). It was found that temperatures at 14 and 21 days were significantly higher (p<0.05) in the YS and CS than in the others. The pH at 21 days was lower in the CS than in the US. The synbiotic treatments had significantly increased (p<0.05) ammonia concentration at 21 days. The DM disappearance at 72 h was significantly higher (p<0.05) in the MS and CS than in the others. ADF and NDF disappearance rate tended to increase at a rate similar to the DM disappearance rate. Therefore, this study suggests that synbiotics (probiotics with prebiotics) may partially help the quality of fermentation and digestibility of TMR (MS and CS) as fiber disappearance.

A Study on the Distribution of VOC Concentrations by Attachment Position of Air Samplers for Working Environment Measurement (작업환경측정 시료 채취기의 부착 위치에 따른 유기화합물의 농도 분포에 관한 연구)

  • Kwon, Yung-Gyu;Won, Jung Il;Jang, Hyung Seok;Sim, Sang-hyo
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.25 no.3
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    • pp.328-337
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    • 2015
  • Objectives: The purpose of this study is to investigate differences in concentration according to the position at the left or right shoulder within a 30 cm of radius of workers' respirators and provide basic data for the establishment of an industrial health policy. Methods: Personal samples were collected from a total of 65 workers from 27 manufacturing firms in South Gyeongsang-do Province from November 5, 2011 to December 30, 2012 after classifying the laborers into left- and right-side groups. The organic compound samples were collected and analyzed in accordance with the NIOSH Manual of Analytical Methods (NMAM) 1501. Results: In terms of the concentration of organic compounds collected from both left and right shoulders at the position of workers' respirators, isobutyl acetate was the highest with 145 ppm at the left shoulder, followed by ethyl acetate (133.5 ppm) and toluene (38.13 ppm). At the right shoulder, on the contrary, ethyl acetate (149.3 ppm) was the highest, followed by toluene (46.26 ppm), xylene (29.63ppm) and isopropyl alcohol (28.06 ppm). Overall, the right shoulder was higher than the left shoulder in terms of concentrations. Conclusions: For the measurement of the working environment, workers' personal samples should be collected at the place closest to the respirator. In terms of the reduction of error, the attachment of two sample media is expected to reduce errors in exposure assessment.

A Study on the Fabrication for High Quality Ferrite Plastic Magnets (고품위 페라이트 본드자석 제조에 관한 연구)

  • 신용진;문형욱;진성빈;정왕일
    • Electrical & Electronic Materials
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    • v.10 no.5
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    • pp.440-446
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    • 1997
  • This research has been performed for the fabrication of high quality ferrite plastic magnet. The magnetic properties of S $r_{5.9}$F $e_2$ $O_3$ ferrite bonded magnets by injection moulding with a variety of applied magnetic field were investigated. 0.3wt% CaCO3, 0.2wt% $SiO_2$, 0.5wt% $Al_2$ $O_3$and 0.5wt% N $a_2$ $SiO_3$are added in order to improve the magnetic properties of Sr-ferrite plastic magnets during the powder fabrication. For carbon coating on chemical compound specimen, 5wt% polyvinyl alcohol is added, and then calcinated under $N_2$ environment of 12$25^{\circ}C$. The particle size is distributed from 0.9~1.2${\mu}{\textrm}{m}$ which approximates to the single domain. The obtained Sr ferrite powder is well mixed with silane coupling and calcium stearate of 1wt%. Nest, the specimen is pelleted after kneading each of them with polyamidel2 as a binder. When the temperature of injection and mould were 25$0^{\circ}C$ and 8$0^{\circ}C$ respectively at injection pressure of 200kgf/$\textrm{cm}^2$, the degree of orientation was 85.3% under the applied magnetic field of 12kOe. As the results, when the packing density of Sr ferrite powder was 90wt%, the magnetic properties of Sr ferrite bonded magnet were follows : $_{B}$ $H_{c}$=2.41kOe, Br=3.1kG, (BH)$_{max}$=2.21MgOe. Especially, the Sr-ferrite bonded magnet with 10wt% N $d_2$F $e_{14}$B additive were as follows : $_{B}$ $H_{c}$=2.57kOe, Br=3.14kG and (BH)$_{max}$=2.39MGOe.GOe.GOe.GOe.e.

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Processing of vinegar pickled sardine (정어리 초절임제품의 가공)

  • Lee, Eung-Ho;Lee, Jeong-Suk;Son, Kwang-Tae;Kim, Jin-Soo;Oh, Kwang-Soo;Cho, Soon-Yeong
    • Applied Biological Chemistry
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    • v.36 no.5
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    • pp.339-345
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    • 1993
  • To utilize effectively sardine as a material of pickled products, we investigated on processing of vinegar pickled sardine. The moisture, the crude ash and histamine contents showed a little change during vinegar pickling of salted sardine. The pH and viable cell counts decreased during vinegar pickling of salted sardine. The pickled sardine processed with vinegar seasoning solution mixed antioxidants was retarded in lipid oxidation during processing. The principal taste compounds of vinegar pickled sardine were organic acid (acetic acid), IMP and free amino acids such as histidine, lysine, glutamic acid and arginine. The vinegar pickled sardine was higher in the contents of limiting amino acids of cereal such as lysine, and 20 : 4 and polyunsaturated fatty acid such as 20 : 5 and 22 : 6 than those of other processed foods.

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Characteristics Change on the Surface of Pyrite by Bioleaching with Thiobacillus ferrooxidans(ATCC 19859) and Isolated Strain Thiobacillus KY (Thiobacillus ferrooxidans (ATCC 19859)와 분리균주 Thiobacillus KY에 의한 생물학적 침출에 따른 황철석의 표면 특성변화)

  • 이인화;기민희;김시욱
    • KSBB Journal
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    • v.15 no.3
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    • pp.254-261
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    • 2000
  • A bacterial leaching was conducted for pyrite with Thiobacillus ferrooxidans(ATcC 19859) and Thiobacillus KY isolated from acid mine water around Kwangyang area to characterize the surface of substrate as reaction progress at the optimum condition under 9K medium for 3- days. It was found that the surface crystallinity changes referred to hkl plane was observed for 20 days leached by T. ferrooxidans similar changes also observed for 10 days leached pyrite by Thiobacillus KY. Based on he results of SEM-EDS the atomic ratios of Fe, S and Si on the surface were changed to sulfur rich phase but exposed Si ratio decreased from 16.94% to 4.85% during 30days mainly due to reprecipitating of Fe and S as a mixed compound.

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Recovery of Zirconium from Spent Pickling Acid through Precipitation Using BaF2 and Electrowinning in Fluoride Molten Salt (BaF2 침전 및 불화물 용융염 전해 제련을 통한 폐 산세액 내 지르코늄 회수)

  • Han, Seul Ki;Nersisyan, Hayk H.;Lee, Young Jun;Choi, Jeong Hun;Lee, Jong Hyeon
    • Korean Journal of Materials Research
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    • v.26 no.12
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    • pp.681-687
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    • 2016
  • Zirconium(Zr) nuclear fuel cladding tubes are made using a three-time pilgering and annealing process. In order to remove the oxidized layer and impurities on the surface of the tube, a pickling process is required. Zr is dissolved in HF and $HNO_3$ mixed acid during the process and pickling waste acid, including dissolved Zr, is totally discarded after being neutralized. In this study, the waste acid was recycled by adding $BaF_2$, which reacted with the Zr ion involved in the waste acid; $Ba_2ZrF_8$ was subsequently precipitated due to its low solubility in water. It is very difficult to extract zirconium from the as-recovered $Ba_2ZrF_8$ because its melting temperature is $1031^{\circ}C$. Hence, we tried to recover Zr using an electrowinning process with a low temperature molten salt compound that was fabricated by adding $ZrF_4$ to $Ba_2ZrF_8$ to decrease the melting point. Change of the Zr redox potential was observed using cyclic voltammetry; the voltage change of the cell was observed by polarization and chronopotentiometry. The structure of the electrodeposited Zr was analyzed and the electrodeposition characteristics were also evaluated.

Analysis on the Harmful Effect of Recycled Powder and Properties of Concrete Admixture by Recycled Powder (재생미분말의 유해성 분석 및 재생미분말을 혼입한 콘크리트의 특성)

  • Lee, Seung-Hwan;Choi, Ik-Chang;Han, Sang-Kuk
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.14 no.4
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    • pp.289-295
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    • 2008
  • The disposal of constructive waste is emerging as a national and social issue and the recycled powder generated by the production of reproductive aggregate is all being abolished or buried Analysis on the harmful effect of recycled powder indicated that because it contained massive cytotoxicity, it could derive secondary pollution to soil and subterranean water. This study set on an idea that one way to recycle recycled powder was to use it as a compound of concrete. In order to study that prospect, recycled powder, instead of cement, was mixed and a comparative analysis was conducted on the mechanical properties and workability. From experimental results, it was judged that application of recycled powder of cement replacement ratio below 20% was available with chemical admixtures. Also application of recycled powder was available to high strength concrete.

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Effects of Curcuma aromatica Extract and Orange Rind Mixed Liquor on the Quality of Cypselurus agoo agoo Roe Treated with Electrolyzed Water (강황 추출물, 오렌지피 및 전해수 처리가 날치(Cypselurus agoo agoo)알의 품질에 미치는 효과)

  • Kim, Koth-Bong-Woo-Ri;Kim, Dong-Hyun;SunWoo, Chan;Hong, Yong-Ki;Ahn, Dong-Hyun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.45 no.2
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    • pp.122-131
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    • 2012
  • This study was performed to examine the effects of Curcuma aromatica (CA) and orange rind on the quality and sensory score of flying fish $Cypselurus$ $agoo$ $agoo$ roe treated with electrolyzed water during frozen storage ($-18^{\circ}C$). The pH was decreased with increasing amounts of CA extract added to flying fish roe and during frozen storage. The flying fish roe treated with CA extract showed increased yellowness, as compared to flying fish roe with no CA extract added and untreated with electrolyzed water (untreated). The flying fish roe containing CA extract maintained greater hardness than did untreated flying fish roe. The volatile basic nitrogen and trimethylamine contents of treated flying fish roe were lower than those of untreated flying fish roe during frozen storage. The results of volatile organic compound tests showed that the contents of alcohol, acid and ketone compounds in flying fish roe treated with CA extract and orange rind were relatively decreased, but the limonene content of treated flying fish roe was increased compared to that of untreated flying fish roe. In sensory evaluation, flying fish roe containing 0.05 and 0.1% of CA were preferred over others. In conclusion, CA and orange rind increased the quality and sensory scores of flying fish roe treated with electrolyzed water.

Effects of Hf Addition on Microstructure and Hot Workability of Fe-30at.%A1-5at.%Cr Alloy (Hf가 첨가된 Fe-30at.%A1-5at.%Cr 합금의 미세조직 및 열간압연가공 특성)

  • Yoon, Kye-Lim;Lee, Doh-Jae;Baek, Dae-Hwa;Lee, Kyung-Ku
    • Journal of Korea Foundry Society
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    • v.21 no.6
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    • pp.336-342
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    • 2001
  • This study was carried out to examine the effects of adding 0.3at.%Hf in Fe-30at.%Al-5at.%Cr alloy on the variation of microstructures and hot workability. The effect of hot rolling on mechanical properties was estimated by measuring the elongation and tensile strength after rolling at 800 and 1000 respectively. Microstructure of Fe-30at.%Al-5at.%Cr alloy was consisted of large equiaxed grains and it was changed to quasi-equiaxed or columnar structures by adding 0.3at.%Hf to Fe-30at.%Al-5at.%Cr alloy. Every specimens showed a decreased tensile strength after hot rolling compared to that of before rolling. The elongation was increased by hot rolling. Remarkable changes in elongation by hot rollong was observed such as from 1.4% to 4.5% elongation at the specimen of 0.3at.%Hf added to Fe-30at.%Al-5at.%Cr. Fe-30at.%Al-5at.%Cr alloy showed typical cleavage fracture on tensile failure and hot rolling has negligible effects on fracture mode in this alloy. However at the alloy containing Hf fracture mode was changed by hot rolling from intergranular to mixed intergranular and transgranular fracture mode.

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