• Title/Summary/Keyword: Misfit

Search Result 147, Processing Time 0.028 seconds

Evaluations of Microstructure and Hydrogenation Properties on $Mg_2NiH_x$ ($Mg_2NiH_x$ 수소저장합금의 미세결정구조 및 수소화 특성평가)

  • Seok, Song;Shin, Kyung;Kweon, Soon-Yong;Ur, Soon-Chul;Lee, Young-Geun;Hong, Tae-Whan
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.16 no.3
    • /
    • pp.238-243
    • /
    • 2005
  • Mg and Mg-based alloys are most important hydrogen storage materials. It is a lightweight and low-cost materials with high hydrogen storage capacity. However, the formation of hydride at high temperature, the deterioration effect, the hydriding and dehydriding kinetics are bad factor for application. In this study, Mg and Ni have been produced by hydrogen induced mechanical alloying(HIMA) process. The raw materials, Mg(purity 99.9%) chip and Ni(purity 99.95%) chip was prepared by using a planetary ball mill apparatus(FRITSCH pulverisette 5). The balls to chips mass ratio(BCR) are 30:1. The hydrogen pressure induced 2.0MPa and milling times were 12, 24, 48, 72, 96 hours with a rotating speed of 200rpm. X-ray diffraction(XRD) analysis was made to characterize the crystallite size and misfit strain. The crystallite size measured by laser particle size analysis(PSA). Microstructure changes were investigated by scanning electron microscopy(SEM) and the transmission electron microscopy(TEM). The hydrogen storage properties were evaluated by using an Sivert's type automatic pressure-composition-therm(PCT) apparatus.

Effects of Mo and Si on the Coercivity of CoCrTa/CrMo and CoCrTa/CrSi Thin Film Media (CoCrTa/CrX (X=Mo, Si) 자성박막의 보자력에 미치는 Mo와 Si의 영향)

  • 조준식;남인탁;홍양기
    • Journal of the Korean Magnetics Society
    • /
    • v.9 no.4
    • /
    • pp.203-209
    • /
    • 1999
  • Effects of Mo and Si addition in Cr underlayer on magnetic properties of CoCrTa/CrMo and CoCrTa/Si thin films media were investigated. Thin films were prepared with DC magnetron sputtering system. The thickness of CoCrTa magnetic layer and Cr underlayer were fixed at 300 $\AA$ and 700 $\AA$, respectively. The substrate heating temperature was kept constant at 26$0^{\circ}C$ for both magnetic layer and underlayer preparation. The coercivity increase of CoCrTa film was realized due to Mo addition in Cr underlayer. Si addition made a small decrease in coercivity. Coercivity increase seems to be attributed by the improvement of preferred orientation of Cr(200) plane. It is found that lattice fit between Cr(200) and CoCrTa(1120) of CrMo underlayer is better than that of CrSi underlayer. This small misfit may also contribute coercivity increase.

  • PDF

An Extension of Unified Bayesian Tikhonov Regularization Method and Application to Image Restoration (통합 베이즈 티코노프 정규화 방법의 확장과 영상복원에 대한 응용)

  • Yoo, Jae Hung
    • The Journal of the Korea institute of electronic communication sciences
    • /
    • v.15 no.1
    • /
    • pp.161-166
    • /
    • 2020
  • This paper suggests an extension of the unified Bayesian Tikhonov regularization method. The unified method establishes the relationship between Tikhonov regularization parameter and Bayesian hyper-parameters, and presents a formula for obtaining the regularization parameter using the maximum posterior probability and the evidence framework. When the dimension of the data matrix is m by n (m >= n), we derive that the total misfit has the range of m ± n instead of m. Thus the search range is extended from one to 2n + 1 integer points. Golden section search rather than linear one is applied to reduce the time. A new benchmark for optimizing relative error and new model selection criteria to target it are suggested. The experimental results show the effectiveness of the proposed method in the image restoration problem.

Three dimensional stress analysis of implant-supported prosthesis with various misfit (적합도가 다른 임플랜트 지지 보철물의 삼차원적 응력 분석)

  • Yang, Hong-So;Chung, Hyun-Ju;Park, Yeong-Joon;Park, Sang-Won;Kunavisarut, Chatchai
    • Journal of Dental Rehabilitation and Applied Science
    • /
    • v.17 no.4
    • /
    • pp.307-314
    • /
    • 2001
  • To evaluate the effect of misfit in two implant-supported fixed partial dentures in the posterior of the mandible, variations of the standard finite element models were made by changing the location of the gap as follows: 1) no gap present; 2) located between the gold cylinder and the abutment on the distal implant; 3) gap located between the gold cylinder and the abutment on the mesial implant. The results of this study were as follows: 1. When the location of the gap was close to the load applied on the prosthesis, the stress in the prosthesis, implant components and surrounding bone increased. 2. The presence of cantilever increased the stress in the prosthesis, implant and surrounding bone significantly, regardless of the presence of the gap. 3. When there was a gap between the prosthesis and abutment, the stress in the bone around the implant increased. 4. When passive fit was achieved, the stress was distributed widely in each component with less peak stress in each component. 5. The inner structures of the implant components, the gold screw and the abutment screw bear more stress when the prosthesis did not exhibit passive fit with the abutments than when passive fit was present.

  • PDF

A Comparison of Three Low Back Disability Questionnaires With Rasch Analysis (라쉬분석을 이용한 세 가지 요통 장애 설문지의 비교)

  • Kim, Gyoung-Mo;Park, So-Yeon;Yi, Chung-Hwi
    • Physical Therapy Korea
    • /
    • v.18 no.3
    • /
    • pp.94-102
    • /
    • 2011
  • The purpose of this study was to review existing assessment tools for patients with low back pain and improve them through combination. A total of 314 patients with low back pain participated. Their condition was assessed using the Oswestry Disability Questionnaire (ODQ), the Quebec Back Pain Disability Scale (QBPD), and the Back Pain Functional Scale (BPFS). Rasch analysis was applied to identify inappropriate items, item difficulties, and the separation index. In this study, the 'sex life' item of the ODQ (10 items) and the 'sleeping' item of the BPFS (12 items) showed misfit statistics, whereas all items of the QBPD (20 items) were appropriate. After combining the ODQ, QBPD and BPFS, Rasch analysis was applied. The 'pain intensity', and the 'sex life' item of the ODQ and the 'throw a ball' item of QBPD showed misfit statistics. These 3 items were retained for further analysis. The remaining 42 combined ODQ-QBPD-BPFS items were arranged according to difficulty. For all subjects, the most difficult item was 'pain intensity', whereas the easiest was 'take food out of the refrigerator'. As the separation index of 42 combined ODQ-QBPD-BPFS was higher than that of the three questionnaires separately, difficulty of items varied with some need for rearrangement. The results of this study confirmed the possibility and need for a new back pain disability assessment tool, and produced one. Further study is needed to refine the questionnaire in consideration of psychosocial and occupational factors.

Application of Rasch Analysis to the Korean Version of the Fullerton Advanced Balance Scale (한국어판 플러턴 어드밴스드 균형 척도의 라쉬분석)

  • Kim, Gyoung-mo
    • Physical Therapy Korea
    • /
    • v.23 no.1
    • /
    • pp.46-54
    • /
    • 2016
  • Background: Rasch analysis estimates the probability that a respondent will endorse an item and select a particular rating for that item. It has the advantage of placing both the items and the person along a single ration scale and calibrates person ability and item difficulty onto an interval scale by logits. In addition, Rasch analysis is a useful tool for exploring the validity of questionnaires that have been developed using traditional methods. Therefore, it has been recommended as a method for developing and evaluating functional outcome measures. Objects: The purpose of this study was to investigate the item fit, item difficulty, and rating scale of the Korean version of the Fullerton Advanced Balance Scale (KFAB) using Rasch analysis. Methods: Total 97 subjects (39 males and 58 females) with dwelling elderly adults were participated, but 3 people were excluded for misfit persons. Rasch analysis was then done by means of the Winsteps program to determine the item fit, item difficulty, rating scale, and reliability of the KFAB. Results: In this study, the 'standing with feet together and eyes closed', 'two-footed jump', 'walk with head turns', and 'stand on foam, eyes closed' items shown misfit statistics. The most difficult item was 'stand on one leg', whereas the easiest item was 'turn in full circle'. The rating scale was acceptable with all criteria. Both item and person separation indices and reliability showed acceptable values. This would indicated that each domain covers a useful range of item difficulty that is appropriate for measuring a person with a wide range of functional ability. Conclusion: The KFAB has been proven reliable, valid and an appropriate tool with which to evaluate the balance of the elderly people.

Determination of Lattice Parameters and Observation of Lattice Misfits on Rene 80 Cast Blades (Rene 80 주조블레이드에서 격자상수의 결정 및 격자어긋남의 관찰)

  • An, Seong-Uk
    • Analytical Science and Technology
    • /
    • v.6 no.5
    • /
    • pp.515-520
    • /
    • 1993
  • By the real use of Rene 80 cast blades at high temperature ${\gamma}^{\prime}$ precipitates in the matrix(${\gamma}$) mainly due to the operating temperature. These precipitates play main role for strenthening of the blades. Generally known that dislocation density increases due to ${\gamma}-{\gamma}^{\prime}$ mismatch by the generation and growth of the precipitates, because the lattice parameter of ${\gamma}^{\prime}$ is higher than that of ${\gamma}$. These lattice parameters of ${\gamma}$ and ${\gamma}^{\prime}$ are determined through the CBED(Convergent Beam Electron Diffraction) method by STEM(Scanning Transmission Electron Microscope) in this work. And also studied, whether and how much the dislocation density increases by the generation and growth of the precipitates.

  • PDF

Inversion of Resistivity Tomography Data Using EACB Approach (EACB법에 의한 전기비저항 토모그래피 자료의 역산)

  • Cho In-Ky;Kim Ki-Ju
    • Geophysics and Geophysical Exploration
    • /
    • v.8 no.2
    • /
    • pp.129-136
    • /
    • 2005
  • The damped least-squares inversion has become a most popular method in finding the solution in geophysical problems. Generally, the least-squares inversion is to minimize the object function which consists of data misfits and model constraints. Although both the data misfit and the model constraint take an important part in the least-squares inversion, most of the studies are concentrated on what kind of model constraint is imposed and how to select an optimum regularization parameter. Despite that each datum is recommended to be weighted according to its uncertainty or error in the data acquisition, the uncertainty is usually not available. Thus, the data weighting matrix is inevitably regarded as the identity matrix in the inversion. We present a new inversion scheme, in which the data weighting matrix is automatically obtained from the analysis of the data resolution matrix and its spread function. This approach, named 'extended active constraint balancing (EACB)', assigns a great weighting on the datum having a high resolution and vice versa. We demonstrate that by applying EACB to a two-dimensional resistivity tomography problem, the EACB approach helps to enhance both the resolution and the stability of the inversion process.

Microwave Properties and Microstructures of (Ba,Sr)TiO3 Thin Films on Various Substrates with Annealing Temperature (다양한 기판위에 증착된 BST 박막의 열처리 온도에 따른 마이크로파 유전성질과 미세구조 변화)

  • Cho, Kwang-Hwan;Kang, Chong-Yun;Yoon, Seok-Jin;Kim, Hyun-Jai
    • Korean Journal of Materials Research
    • /
    • v.17 no.7
    • /
    • pp.386-389
    • /
    • 2007
  • The dielectric properties of $(Ba_{0.5}Sr_{0.5})TiO_3$ ferroelectric thin films have been investigated according to the substrates in order to optimize the their properties. MgO, r-plane sapphire, and poly-crystalline sapphire (Alumina) substrates have been used to deposite $(Ba_{0.5}Sr_{0.5})TiO_3$ ferroelectric thin films by RF magnetron sputtering. The BST thin films deposited on the single crystal (100)MgO substrates have high tunability and low dielectric loss. These results are caused by a low misfit between the lattice parameters of the BST films and the substrate. The BST films deposited on r-plane sapphire have relatively high misfit, and the tunability of 17% and dielectric loss of 0.0007. To improve the dielectric properties of the BST films, the post-annealing methods has been introduced. The BST films deposited on (100)MgO, (1102)r-plane sapphire, and poly-crystalline sapphire substrates have best properties in post-annealing conditions of $1050^{\circ}C$, $1100^{\circ}C$, and $1150^{\circ}C$, respectively. The different optimal post-annealing conditions have been found according to the different misfits between the films and substrates, and thermal expansion coefficients. Moreover, the films deposited on alumina substrate which is relatively cheap have a good tunability properties of 23% by the post-annealing.

Influences of Spinodal Decomposition of InGaAsP Layer on Photoluminescence Characteristics (InGaAsP 에피막의 Spinodal분해 조직구조가 Photoluminescence 특성에 미치는 영향)

  • Lee, Jong-Won
    • Korean Journal of Materials Research
    • /
    • v.5 no.8
    • /
    • pp.936-944
    • /
    • 1995
  • The effects of Spinodal decomposition induced phase separated microstructure of InGaAsP/InP heterostructure on photoluminescence(PL) intensity and FWHM(full-width at half maximum) were investigated in this study. Lattice mismatches were measured by double crystal x-ray diffractometer, and the microstructures of phase separated InGaAsP were observed by transmission electron microscopy. It was found that the misfit stress calculated from lattice mismatch was related to the periodicity of Spinodal modulation. Strong dependence of PL intensity and FWHM on the modulation periodicity was also found. For systematic understanding of these observations, the interaction elastic strain energy function induced by misfit stress was proposed. The calculation illustrated that the microstructure of the epilayer such as Spinodal decomposition played an important role in determining the optoelectronic properties such as PL intensity and PL FWHM.

  • PDF