• Title/Summary/Keyword: Mineralogy

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Establishing A Database for the Management and Utilization of Geological Research Data: Focusing on the Classification of Rocks and Minerals and 3D Models (지질 연구 자료의 관리와 활용을 위한 데이터베이스 구축: 암석, 광물의 분류와 3D 모델을 중심으로)

  • Ko, Bokyun;Lee, Chang-Wook;Park, Sungjae;Lee, Ki-Young
    • Journal of the Korean earth science society
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    • v.41 no.2
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    • pp.137-146
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    • 2020
  • A great number of geological research data have been produced by individually conducted researchers and then personally stored in domestic universities and research institutes. However, it is difficult to share data with other researchers owing to low and limited accessibility. The purpose of this study is to systematically establish metadata for inaccessible data, to manage them collectively and to provide opportunities for utilizing the data to those who require efficient research methods. Approximately 1,000 geological specimens (900 rocks and fossils, 100 thin sections) were gathered, along with their metadata such as high-resolution photographs, classification, name, owner, address, and geographical coordinates of the sample site, to establish their features. Additionally, 3D modeling data for 100 rocks and fossils were generated. On the basis of this study, it is possible for researchers to access and share crucial geological data that have a high potential to be lost and have been neglected in restricted spaces; by avoiding the wasted time, energy, and costs caused by repetitive collection of data, researchers may perform effective research and achieve qualified and competitive research results. Moreover, vulnerable and important geological data in the field can be protected from damage caused by indiscriminate, repetitive collection of specimens that have previously been secured. Through the establishment of additional metadata concerning the diversity of rocks, fossils, and thin sections kept at other universities and research institutes, much more data can be recognized, leading to advanced research results. Furthermore, specialized comparison and analysis of basic mineralogy and petrology knowledge are anticipated, based on the use of the metadata.

Controls on Diagenetic Mineralogy of Sandstones and Mudrocks from the Lower Hayang Group (Cretaceous) in the Daegu Area, Korea (대구 부근 하부 하양층군(백악기) 사암과 이암의 속성 광물과 속성 작용의 규제 요인)

  • Shin, Young-Sik;Choo, Chang-Oh;Lee, Yoon-Jong;Lee, Yong-Tae;Koh, In-Seok
    • Journal of the Korean earth science society
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    • v.23 no.7
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    • pp.575-586
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    • 2002
  • Authigenic minerals found in sandstones and mudrocks of the Lower Hayang Group (Cretaceous) in the central part of the Kyungsang Basin are carbonate minerals (calcite, dolomite), clay minerals (illite, chlorite, C/S, I/S and kaolinite), albite, quartz and hematite. Characteristic diagenetic mineral assemblages are as follows: albite-chlorite (including C/S)-hematite in the Chilgog Formation, albite-illite-calcite in the Silla Conglomerate, illite-chlorite-hematite in the Haman Formation and albite-chlorite-dolomite in the Panyawol Formation, respectively. Among clay minerals reflecting the physical and chemical change of the diagenetic process, illite, the dominant clay mineral, occurs in every formation in the study area. Chlorite occurs mainly in green or gray sandstones and mudrocks, or in sandstones and mudrocks of the Chilogok Formation which contains a high content of volcanic materials. Based on the mineral assemblage, diagenetic minerals are strongly related with source rocks. Judging from the illite crystallinity, diagenesis of sandstones and mudrocks in the study area reached the late diagenetic stage or low grade metamorphisim. The diagenetic process was much influenced by intrusion of the Bulguksa granite, content of organic materials, grain size, and depositional environment rather than burial depth.

A Study on Geology and Clay Minerals of the Landslide Area in the Munhyun-dong, Nam-gu, Pusan (부산시 남구 문현동 산사태 지역의 지질 및 점토광물에 대한 연구)

  • 황진연;김선경;김춘식
    • Journal of the Korean Geotechnical Society
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    • v.15 no.1
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    • pp.113-125
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    • 1999
  • In this study the occurrence and mineralogical characteristics of clay minerals from the Munhyun-dong landslide area in Pusan city were examined by XRD, SEM, and chemical analyses. Several types of clay minerals such as halloysite, vermiculite, mica/vermiculite interstratified mineral, vermiculite/smectite interstratified mineral, kaolinite and illite are found abundantly in the area. The occurrence of clay minerals suggest that they have been formed by weathering of andesite which is the bedrock of the area. It is believed that halloysite was formed in the early stage of weathering, and vermiculite, mica/vermiculite interstratified mineral and mica/vermiculite interstratified mineral were formed in the middle stage, and finally, kaolinite was formed. The clay minerals occurring in the central part of the landsliding area and within the slip surface are dominated by expandable minerals such as halloysite, vermiculite and vermiculite/smectite interstratified mineral. These clay minerals expand by absorbing water and effectively decrease the shear resistance of the rock mass, and therefore, they could be an important factor for the landslide. The analyses of geology and mineralogical characteristics of the area suggest that the landslide was caused by combination of various factors including steep slope, heavy rainfall, abundant joints, alteration of the rocks, and occurrence of expandable clay minerals. The result of this study suggests that the investigation for the prevention of possible landslide must include the examination of clay mineralogy as well as the site geology.

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Study on Phase Relation and Synthesis of Pyrochlore in the System of Ca-Ce-Zr-Ti-O (Ca-Ce-Zr-Ti-O System에서의 파이로클로어 합성 및 상관계에 대한 연구)

  • Chae Soo-Chun;Bae In-Kook;Jang Young-Nam;Yudintsev S.V.
    • Economic and Environmental Geology
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    • v.37 no.6 s.169
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    • pp.603-612
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    • 2004
  • Pyrochlore is known as one of the most promising materials for the immobilization of radionuclide in high level waste. This study included the synthesis, phase relation and characteristics of $pyrochlore(CaCeZr_xTi_{2-x}O_{7,\;x=0.2\~2.0)$ in the system of Ca-Ce-Zr-Ti-O. Using the CPS(Cold pressing and sintering) method, the mixtures of $CaCO3_,\;CeO_2,\;ZrO_2\;and\;TiO_2$ oxides were pressed, and sintered at $1100\~1600^{\circ}C$ for 20 hours. The optimal synthetic conditions at various compositions were differed from 1300 to $1600^{\circ}C$ Even in the optimal temperatures, pyrochlore or fluorite coexisted with minor amount of perovskite, $CeO_2\;or\;Ce_{0.75}Zr_{0.25}O_2$. It was confirmed that pyrochlore and fluorite structures were stable at $x\leq0.6\;and\;x\geq1.0$, respectively. Especially, the compositions of pyrochlore or fluorite showed non-stoichiometric compositions in that contents of Ca and Ti were more deficient and those of Zr and Ce were more excess than batch compositions with the increase of x value. These characteristics stemmed from the behavior of elements occupied at eight- and six-coordinated site, and then caused the coexistence of perovskite, $CeO_2\;or\;Ce_{0.75}Zr_{0.25}O_2$ along with pyrochlore or fluorite.

Geochemistry and K-Ar Age of the Imog Granite at the southwestern Part of the Hambaeg Basin, Korea (함백분지(咸白盆地) 남서부(南西部)에 분포(分布)하는 이목화강암(梨木花崗岩)의 지화학(地化學) 및 K-Ar 연대측정(年代測定))

  • Hong, Young Kook
    • Economic and Environmental Geology
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    • v.19 no.2
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    • pp.97-107
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    • 1986
  • The Cretaceous Imog granite is a calc·alkaline, subsolvus monzogranite and shows characteristics of "I-type" and "magnetite·series" granite by mineralogy and chemical composition. Many of the major and trace element characteristic of the Imog granite are consistent with a relationship by fractional crystallization of a basic magma. The primary magma of the granite derived from the subduction of oceanic crust at the destructive plate margin. The granite shows light REE enrichment with (Ce/Yb)N ratios of 7.77~12.55. All the REE patterns show Eu negative anomalies ($Eu/Eu^*=0.69$) in the pluton. The Imog granite at the southwestern part of the Hambaeg basin may be intruded along the tectonic intersections of the E-W and N-S lines such as deep faults and fractures. Radiometric age determination on the granite reveals as $96.7{\pm}2.0Ma$ by K-Ar dating on biotite.

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Gold-Silver Mineralization of the Au-Ag Deposits at Yeongdong District, Chung-cheongbuk-Do (충청북도(忠淸北道) 영동지역(永同地域) 금은광상(金銀鑛床)의 금은광화작용(金銀鑛化作用)에 관한 연구(硏究))

  • Choi, Seon Gyu;Chi, Se Jung;Park, Sung Won
    • Economic and Environmental Geology
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    • v.21 no.4
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    • pp.367-380
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    • 1988
  • Most of the gold (-silver) vein deposits at Yeongdong District are mainly distributed in the precambrian metamorphic rocks. Based on the Ag/Au total production and ore grade ratios, the chemical composition of electrum and the associated sulfides, the gold(-silver) deposits at Yeongdong District may be classified into 4 classes: pyrrhotite - type gold deposits( I), pyrite - type gold deposits (IT A; massive vein), pyrite - type gold deposits (II B; nonmassive vein) and argentite - type gold - silver deposits(III). The chemical study on electrum(including native gold) revealed that Au content (2.8 to 92.4 atomic%) of electrums varies very widely for different classes of deposits. The Au content of electrum associated with pyrrhotite (Class I), ranging from 47.1 to 92.4 atomic% Au, is clearly higher than that associated with pyrite (Classes IIA, IIB and III). In contrast, classes I, II, and III deposits do not show clear differences in Au content of electrum. In general, pyrrhotite - type gold deposits(I) are characterized by features such as simply massive vein morphology, low values in the Ag/Au total production and ore grade ratios, the absence or rarity of silver - bearing minerals except electrum, and distinctively simple mineralogy. Although the geological and mineralogical features and vein morphology of pyrite - type gold deposits(IIA)are very similar to those of pyrrhotite - type gold deposits (I), Class II A deposits reveal significant differences in the associated iron sulfide (i. e. pyrite) with electrum and Au content of electrum. The Ag/Au total production and ore grade ratios from Class II A deposits are relatively slightly higher than those from Class I deposits. Pyrite - type gold deposits(II B) and argentite - type gold - silver deposits (III) have many common features; complex vein morphology, medium to high values in the Ag/Au total production and ore grade ratios and the associated iron sulfide (i. e. pyrite). In contrast to Class II B deposits, Class III deposits have significantly high Ag/Au total production and ore grade ratios. It indicates distinct difference in the abundance of silver minerals (i. e. native silver and argentite). The fluid inclusion analyses and mineralogical data of electrum tarnish method indicate that the gold mineralization of Classes I and II A deposits was deposited at temperatures between $230^{\circ}$ and $370^{\circ}C$, whereas the gold (-silver) mineralization of Classes ITB and ill formed from the temperature range of $150^{\circ}-290^{\circ}C$. Therefore, Classes I and IT A deposits have been formed at higher temperature condition and/or deeper positions than Classes IIB and III.

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Geochemical Behavior of Metals in the Contaminated Paddy Soils around Siheung and Deokeum Mines through Laboratory Microcosm Experiments (실내 microcosm실험에 의한 시흥광산 및 덕음광산 주변 오염 논토양내 중금속의 지구화학적 거동 연구)

  • 김정현;문희수;안주성;김재곤;송윤구
    • Economic and Environmental Geology
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    • v.35 no.6
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    • pp.553-565
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    • 2002
  • Seasonal variations in vertical distributions of metals were investigated in the contaminated paddy soils around Siheung Cu-Pb-Zn and Deokeum Au-Ag mines. Geochemical behavior of metals was also evaluated with respect to redox changes during the cultivation of rice. Two microcosms simulating the rice-growing paddy field were set up in the laboratory. The raw paddy soils from two sites showed differences in mineralogy, metal concentrations and gecochemical parameters, and it is suggested that high proportions of exchangeable fractions in metals may give high dissolution rates at Deokeum. In both microcosms of Siheung and Deokeum, redox differences between surface and subsurface of paddy soils were maintained during the flooded period of 18 weeks. Siheung soil had neutral to alkaline pH conditions, while strongly acidic conditions and high Eh values were found at the surface soil of Deokeum. The concentrations of dissolved Fe and Mn were higher in the subsurface pore waters than in interface and upper waters from both microcosms, indicating reductive dissolution under reducing conditions. On the contrary, dissolved Pb and Zn had high concentrations at the surface under oxidizing conditions. From the Siheung microcosm, release of dissolved metals into upper waters was decreased. presumably by the trap effect of Fe- and Mn-rich layers at the interface. However, in the Deokeum microcosm, significant amounts of Pb and Zn were released into upper water despite the relatively lower contents in raw paddy soil, and seasonal variations in the chemical fractionation of metals were observed between flooded and drained conditions. Under acidic conditions, rice may uptake high amounts of metals from the surface of paddy soils during the flooded periods, and increases of exchangeable phases may also increase the bioavailability of heavy metals in the drained conditions.

The Nature of Gold Mineralization in the Archean Sunrise Dam Gold Deposit in Western Australia (호주 Sunrise Dam 광상의 금 광화작용)

  • Sung, Yoo-Hyun;Choi, Sang-Hoon
    • Economic and Environmental Geology
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    • v.43 no.5
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    • pp.429-441
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    • 2010
  • The Sunrise Dam gold deposit is located approximately 850 km ENE of Perth, in the eastern part of the Yilgam Craton, Western Australia. The mine has produced approximately 153 t of Au at an average grade of 4.2 g/t, which stands for the most significant gold discoveries during the last decade in Western Australia. The deposit occurs in the Laverton Tectonic Zone corresponding to the corridor of structural complexity in the Laverton greenstone belt, and characterized by tight folding and thrusting. The mine stratigraphy consists of a complexly deformed and altered volcaniclastic and volcanic rocks. These have been overlain by a turbidite sequence containing generally well-sorted siltstones, sandstones and magnetite-rich shales, which are consistently fining upwards. These sequences have been intruded by quartz diorite, ultramafic dikes, and rhyodacite porphyry (Archean), and lamprophyre dikes (Palaeoproterozoic). These rocks constitute the asymmetric NNE-trending Spartan anticline with north-plunging thrust duplication of the BIF unit. The deposit is located on the western limb of this structure. Transported, fluvial-lacustrine and aeolean sediments lie unconformably over the deposit showing significant variation in relief. Gold mineralization occurs intermittently along a NE-trending corridor of ca. 4.5 km length. The 20 currently defined orebodies are centered on a series of parallel, gently-dipping ($\sim30^{\circ}$) and NESW trending shear zones with a thrust-duplex architecture and high-strain characteristics. The paragenetic sequence of the Sunrise Dam deposit can be divided into five hydrothermal stages ($D_1$, $D_2$, $D_3$, $D_4a$, $D_4b$), which are supported by distinctive features of the mineralogical assemblages. Among them, the D4a stage is the dominant episode of Au deposition, followed by the $D_4b$ stage, which is characterized by more diverse ore mineralogy including base metal sulfides, sulfosalts, and telluride minerals. The $D_4a$ stage contains higher proportions of microscopic free gold (48%) than D4b stage (12%), and pyrite is the principal host for native gold (electrum) followed by tetrahedrite-group minerals in both stages.

Soil Mineralogy (토양광물)

  • Jang, Yong-Seon
    • Korean Journal of Soil Science and Fertilizer
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    • v.31
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    • pp.36-44
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    • 1998
  • 우리 나라에서 토양의 점토광물에 관한 최초의 연구는 1958년 김제지방의 답 토양에 관한 연구로 (Dewan, 1958)시작되었다. 1960년대 시작하여 1970년대 까지는 주로 토양점토광물의 동정이 이루어 졌다. 점토광물의 동정(同定)에 사용된 잔적토(殘積土)(Residual Soil)로는 화강암(花崗岩), 화강편마암(花崗片麻岩), 현무암(玄武岩), 석회암(石灰岩), 혈암(頁岩), 제(第)3기층(紀層), 홍적층(洪積層) 유래 토양과 토양종류별(土壤種類別)로는 과부식회색토(寡腐植灰色土), 염류토(鹽類土), 충적토(沖積土), 적황색토(赤黃色土), 화산회토(火山灰土), 퇴적토(堆積土), 갈색토(褐色土), 암쇄토(岩碎土), 저위생산답(低位生産畓)이였으며, 토양점토광물(土壤粘土鑛物)과 작물수량성(作物收量性) 관계에 관한 연구가 실시되었다. 1980년대에 들어와서는 토양중의 1차광물과 점토광물의 풍화에 대한 안정도와 1차광물의 동정이 행해졌으며, 이밖에 Kaolinite 입자의 전하에 관한 연구등 점토광물의 흡착과 활성 연구, 점토광물의 토양개량재로서의 흡착과 화학적 특성 변화 연구와 점토광물의 토양개량 시용효과에 관한 연구가 행해졌다. 1990년대에 들어와서는 토양 중의 1차광물과 점토광물의 정량에 대한 자료가 축척되었고, 토양의 풍화에 대한 안정성과 생성기작, Zeolite와 새로운 광물이 합성되었다. 또한 합성광물을 이용한 농업과 산업광물로의 응용성 환경 산업에서의 적용가능성에 대한 평가가 시도되었다. 토양의 점토광물의 조성에 관한 연구는 토양 모재를 중심으로 이루어졌는데, 화강암(花崗岩)에서는 Halloysite, 화강편마암(花崗片麻岩)에서는 Kaolinite, Metahalloysite, Illite, 산성암(酸性岩)에서는 Kaolinite, Venrmiculite와 Chlorite의 중간광물, 현무암(玄武岩)에서는 Illite, Kaolinite, Vermiculite, 석회암(石灰岩)에서는 Vermiculite-Chlorite 중간광물, Kaolinite와 Illite, 혈암(頁岩)에서는 Kaolinite, Halloysite, Illite 외 Vermiculite-Chlorite, 화산회토(火山灰土)에서는 Allophane이 주광물이었다. Soil Taxonomy와 토양광물과의 관계에서, 답 토양에서는 Entisols의 주점토광물은 2:1형과 1:1형 광물이지만 Inceptisols와 Alfisols에서는 Halloysite가 대부분이다. 밭 토양의 경우는 Alfisols의 주점토광물은 Vermiculite, Illite, Kaolinite이었고, Ultisols에서는 Vermiculite-Chlorite 중간광물이었다. 산림토양에서는 Inceptisols중에서 Andept는 Allophane, Alfisols에서는 2:1 광물이지만, Ultisols에서는 Halloysite이다. 모재별 조암 광물의 풍화와 점토광물의 생성과정에서 화강암(花崗岩)과 화강편마암(花崗片麻岩)의 장석류(長石類)는 kaoline광물로, 이 밖의 운모광물(雲母鑛物), 녹니석(綠泥石), 각섬석(角閃石), 휘석(輝石)으로부터 생성된 illite, chlorite, vermiculite는 풍화중간에 혼층단계(混層段階)를 거쳐서 kaoline 광물로 풍화된다. 석회암(石灰岩) 토양의 smectite가 Mg농도가 높은 토양용액으로부터 침전되어 생성되었거나 운모 또는 chlorite에서 유래된 vermiculite의 변성작용에 의해 생성되고, 혈암(頁岩)토양의 점토에 illite가 주로 풍화에 저항성이 큰 미립자의 함수백운모(含水白雲母)로부터 유래되며, 현무암(玄武岩) 중의 장석류(長石類)는 kaoline광물로, 휘석(輝石)은 chlorite${\rightarrow}$illite의 풍화과정을 거친다. Zeolite, 함불석 Bentonite, Bentonite 등 우량점토 광물이 분포과 광물조성, 이화학적 특성이 조사되었고, 토양의 물리적, 화학적 성질의 개선을 필요로 하는 토양의 개량을 위해서 Bentonite, Zeolite, Vermiculite 등의 토양 개량재(改良材)로서의 기초연구와 이들 개량재 시용효과에 관한 연구 등이 주로 논토양에서 수행되었다. 점토광물과 수량관계를 보면 Montmorillonite를 주점토광물로 함유된 답 토양의 수도수량이 1:1 광물을 주점토광물로 함유하고 있는 토양에서의 수도수량 보다 높았다. 토양광물에 관한 기초연구(基礎硏究)로서 양이온교환능과 포화이온의 영향, 입자의 전기화학적 성질, 흡탈착 성질, 표면적과 등전점, 해성점토에 대한 압밀점토(壓密粘土)의 변형율(變形率)의 추정 등이 주로 연구되었다. 부가가치가 낮거나 폐기되는 광물을 이용하여 토양개량재 혹은 흡착제를 형성하는 연구가 알카리 처리에 의한 Zeolite 합성에 집중되었다.

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The Changes of Specific Surface Area of Soils after Peroxidation and Its Implication for the Calculation of Critical toads of Soil Acidification (Peroxidation 전후의 토양 비표면적 변화와 토양산성화 임계부하량 계산에의 의의)

  • Yeo, Sang-Jin;Lee, Bumhan;Soyoung Sung;Kim, Soo-Jin
    • Journal of the Mineralogical Society of Korea
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    • v.15 no.3
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    • pp.195-204
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    • 2002
  • Mineralogy and the exposed surface area are two of the most important factors controlling dissolution and weathering rates of soils. The mixture of inorganic and organic materials of various size distributions and structures that constitute soils makes the calculation of weathering rates difficult. The surface area of soil minerals plays an important role in most of programs for calculating the weathering rates and critical loads. The Brunauer-Emmett-Teller (BET) measurement is recommended for the measurement of specific surface area. However, BET values measured without organic matter removal are in fact those far all the N2-adsorbed surface areas, including the surfaces covered and aggregated with organisms. Surfaces occupied by organisms are assumed to be more reactive to weathering by organic activities. Therefore, the BET surface area difference before and after organic removal depicts the area occupied by organisms. The present study shows that the BET values after organic matter removal using $H_2$O$_2$ are larger than those without removal by 1.68~4.87 $m^2$/g. This implies that BET measurement without organic removal excludes the reactive area occupied by organisms and that the area occupied by organisms in soils is much larger than expected. It is suggested that specific surface area measurement for calculating weathering rates of mineral soils should be made before and after organic matter removal. The results of a column experiment are presented to demonstrate the potential retarding influence that this organic matter may have on mineral dissolution and weathering.